CN104069024B - A kind of thickener blend composition and its application in cosmetics - Google Patents
A kind of thickener blend composition and its application in cosmetics Download PDFInfo
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- CN104069024B CN104069024B CN201310101198.8A CN201310101198A CN104069024B CN 104069024 B CN104069024 B CN 104069024B CN 201310101198 A CN201310101198 A CN 201310101198A CN 104069024 B CN104069024 B CN 104069024B
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- scleroglucan
- thickener
- viscosity
- thyltaurate
- docosyl alcohol
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Abstract
The invention discloses a kind of thickener blend composition and its application in cosmetics.The thickener blend composition is comprising Scleroglucan and ammonium acryloyldime-thyltaurate/25 Methacrylate Crosspolymer of docosyl alcohol polyethers as thickener.In a preferred embodiment, in composition, the weight ratio of Scleroglucan and ammonium acryloyldime-thyltaurate/25 Methacrylate Crosspolymer of docosyl alcohol polyethers is 1:20 to 20:1.The invention also discloses application of the said composition in the cosmetics comprising electrolyte.
Description
Technical field
The present invention relates to cosmetic field, and in particular to a kind of compound for thickening, the compound can cooperate with lifting
Viscosity, still has superior thickening capabilities especially in the system containing electrolyte.
Background technology
Commonly use thickener to lift the viscosity of formula in cosmetics, it is therefore an objective to go back while the mobility for changing product
Can be with the stability of improving product.Therefore thickener is widely used as a kind of important source material of cosmetics.General thickener
Generally there is dose-effect relationship when using, both concentration was higher, the viscosity that product increases is more.But, with thickener
Add, also impact can be produced using sensation to product.Excessive thickener can reduce pleasant feeling when product is used.Efficiently increase
Thick ----preferable thickening effect, the always research emphasis of cosmetic formulations exploitation is reached using a small amount of thickener.
The thickening efficiency of thickener is affected by several factors in filling a prescription, and wherein electrolyte is the very important point.On a small quantity
The presence of electrolyte will produce impact to the thickening efficiency of thickener.The actual work(of present consumer's common concern formula
Effect so that formulator adds substantial amounts of additive in exploitation formula to reach effect of anticipation, and these additives typically all contain
There is the electrolyte of very high concentration, very big impact can be caused to the viscosity of system and stability.Find a kind of increasing of electrolyte-resistant
Thick dose or thickener compound system, have directive significance for formula of the exploitation containing a large amount of additives very much.
The present invention is first by Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 methacrylate of docosyl alcohol polyethers
Cross-linked polymer is compounding as thickener blend composition, provides efficient thickening effect.The thickener blend composition can be added in cosmetics,
Especially in the cosmetics comprising electrolyte, still possess efficient thickening effect.
Content of the invention
Present invention aim at providing a kind of thickener compounded combination, the compounded combination can effectively be cooperateed with and improve thickener
Thickening efficiency, and the system has outstanding electrolyte-resistant ability.
The invention provides a kind of thickener blend composition, which includes Scleroglucan and ammonium acryloyldime-thyltaurate/mountain
- 25 Methacrylate Crosspolymer of Yu alcohol polyethers is made to be about thickener, and carrier.In one embodiment, combine
In thing, the concentration of Scleroglucan is about 0.01-2 weight %, ammonium acryloyldime-thyltaurate/- 25 metering system of docosyl alcohol polyethers
The concentration of acid esters cross-linked polymer is about 0.01-2 weight %.In a preferred embodiment, in composition Scleroglucan concentration
About 0.01-1 weight %, ammonium acryloyldime-thyltaurate/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers dense
Degree is about 0.01-1 weight %.In preferred embodiment, the concentration of Scleroglucan about 0.05 weight % in composition, third
The concentration of alkene acyl dimethyltaurine ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers is about 0.05 weight %.
In one embodiment, Scleroglucan and ammonium acryloyldime-thyltaurate/docosyl alcohol in thickener blend composition
The weight ratio about 1 of -25 Methacrylate Crosspolymer of polyethers:20 to 20:1.In a preferred embodiment, pyrenomycetes
Glue and the weight ratio about 1 of ammonium acryloyldime-thyltaurate/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers:10
To 10:1.In a preferred embodiment, Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 methyl-prop of docosyl alcohol polyethers
The weight ratio about 1 of olefin(e) acid ester cross-linked polymer:6 to 6:1.In preferred embodiment, Scleroglucan and acryloyl two
The weight ratio about 1 of N-methyltaurine ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers:2 to 2:1.Most preferably
Embodiment in, the Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 methacrylate of docosyl alcohol polyethers crosslinking
The weight ratio about 1 of polymer:1.
Carrier can be any cosmetic field acceptable carrier.For example, carrier can be aqueous carrier, such as water,
Including distilled water and deionized water.
Used in the thickener blend composition of the present invention can be added to cosmetics as functional additive.Therefore, the present invention
Further relate to comprising Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers
Application of the thickener blend composition in cosmetics.
The thickener blend composition of the present invention can cooperate with lifting viscosity, still have superior especially in the system containing electrolyte
Thickening capabilities, the thickener blend composition is suitable for inclusion in the cosmetics series of electrolyte.Therefore, the invention further relates to comprising little
Pyrenomycetes glue and the thickening agent combination of ammonium acryloyldime-thyltaurate/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers
Application of the thing in the cosmetics comprising electrolyte.
Cosmetics comprising thickener blend composition of the present invention can obtain higher viscous in the case of relatively low thickener consumption
The product of degree.And, the electrolyte-resistant ability of these cosmetics all gets a promotion, and this causes a large amount of interpolation in formula effectively to add
Plus agent is possibly realized.
Description of the drawings
Fig. 1 shows viscosity B coefficent of the solution of 0.05%HMB after the Scleroglucan for adding variable concentrations.
Fig. 2 shows viscosity B coefficent of the solution of 0.1%HMB after the Scleroglucan for adding variable concentrations.
Fig. 3 shows viscosity B coefficent of the solution of 0.3%HMB after the Scleroglucan for adding variable concentrations.
Fig. 4 shows viscosity B coefficent of the solution of 0.5%HMB after the Scleroglucan for adding variable concentrations.
Fig. 5 shows viscosity B coefficent of the solution of 1.0%HMB after the Scleroglucan for adding variable concentrations.
Specific embodiment
Unless otherwise defined, all technology used herein and scientific terminology have art ordinary skill people of the present invention
The identical meanings that member is commonly understood by.Although can be used to implement with similar or equivalent any method described herein and material or test
The present invention, but described herein be preferred method and material.For the purpose of the present invention, following term is defined below.
Terms used herein " about " refers to that difference can compared with the quantity of reference product, level, numerical value, dimension, size or consumption
The quantity, level of up to 30%, 20% or 10%, numerical value, dimension, size or consumption.Percentage composition used herein, unless separately
It is described, is by weight.
In full piece specification and claims, Unless Otherwise Requested, following word "comprising" and its variant " containing "
" including " is understood to mean that including described entirety or step, or one group of entirety or step, but is not excluded for any other whole
Body or step, or other one group of entirety or step.
According to the present invention, term " cosmetics " refers to, to smear, spray or other similar approach, intersperse among human body surface
Any position, such as skin, hair, refer to toenail, lips and teeth etc., with reach cleaning, maintenance, beauty, modification and change outward appearance, or
Revise human scent, the chemical industrial product for the purpose of maintaining a good state or fine chemical product.
The present invention is had been surprisingly found that based on following：Scleroglucan and ammonium acryloyldime-thyltaurate/docosyl alcohol polyethers -25
The composition of Methacrylate Crosspolymer can cooperate with lifting viscosity, still have excellent especially in the system containing electrolyte
Thickening capabilities more.Said composition as thickening agent addition agent in cosmetics, can particularly include the cosmetics of electrolyte
In, with superior thickening effect.
In composition, the concentration of Scleroglucan is about 0.01-2 weight %, and ammonium acryloyldime-thyltaurate/docosyl alcohol gathers
The concentration of -25 Methacrylate Crosspolymer of ether is about 0.01-2 weight %.In a preferred embodiment, Scleroglucan
Concentration be about 0.01-1 weight %, -25 methacrylate cross-linked polymeric of ammonium acryloyldime-thyltaurate/docosyl alcohol polyethers
The concentration of thing is about 0.01-1 weight %.In preferred embodiment, the concentration of Scleroglucan is about 0.05 weight %, propylene
The concentration of acyl dimethyltaurine ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers is about 0.05 weight %.
In other embodiments, Scleroglucan and ammonium acryloyldime-thyltaurate/docosyl alcohol in thickener blend composition
The weight ratio about 1 of -25 Methacrylate Crosspolymer of polyethers:20 to 20:1.In a preferred embodiment, pyrenomycetes
Glue and the weight ratio about 1 of ammonium acryloyldime-thyltaurate/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers:10
To 10:1.In preferred embodiment, Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 methyl of docosyl alcohol polyethers
The weight ratio about 1 of acrylate crosspolymers:2 to 2:1.In most preferred embodiments, the Scleroglucan and third
The weight ratio about 1 of alkene acyl dimethyltaurine ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers:1.
Scleroglucan is a kind of thickening efficiency than relatively low thickener, the water of concentration 0.05%, 0.1%, 0.3%, 0.5% and 1%
The viscosity of solution is 0,2,6,100 and 775mPa.s respectively.It can be seen that, under the concentration of the present invention, pyrenomycetes are used alone
The thickening effect of glue is unsatisfactory.Ammonium acryloyldime-thyltaurate/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers
When being used alone as thickener, the viscosity of the aqueous solution of concentration 0.05%, 0.1%, 0.3%, 0.5% and 1% is 0 respectively, 20,
1480th, 9960 and 53600.But, the thickening effect when both are applied in combination, with collaboration.In acryloyldimethyl ox sulphur
Scleroglucan is added to cause the viscosity urgency of solution in the solution of sour ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers
Acute rising, points out both to have thickening effects of collaboration.
And, ammonium acryloyldime-thyltaurate/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers is used as thickening
When agent is used alone, which can not resist the effect of electrolyte.For example, for 0.5% ammonium acryloyldime-thyltaurate/docosyl alcohol
For the solution of -25 Methacrylate Crosspolymer of polyethers, when the concentration of electrolyte (such as sodium chloride) is 0.10%,
The viscosity of solution is drastically fallen to approximately as 40mPa.s.And in 0.5% ammonium acryloyldime-thyltaurate/- 25 first of docosyl alcohol polyethers
0.5% Scleroglucan, even if in the presence of 0.10% electrolyte, solution is added in the solution of base acrylate crosspolymers
Viscosity still remain in 6920mPa.s.It can be seen that ammonium acryloyldime-thyltaurate/- 25 methacrylate of docosyl alcohol polyethers
The thickener blend composition of cross-linked polymer and Scleroglucan is resistant to the effect of electrolyte, still protects in the presence of electrolyte
Hold efficient thickening effect.
Present invention firstly provides by Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 metering system of docosyl alcohol polyethers
Acid esters cross-linked polymer is compounding as thickener blend composition, the thickening effect with collaboration.And, the thickening agent combination of the present invention
Thing can also resist the effect of electrolyte.Therefore, the thickener blend composition of the present invention can be added to cosmetics as additive
In.As which can resist the presence of electrolyte, thus the cosmetics being also applied for comprising electrolyte.
The present invention is expanded on further with reference to specific embodiment.It should be appreciated, however, that these embodiments are only used for
The bright present invention and be not meant to limit the scope of the invention.The test method of unreceipted actual conditions in the following example, generally
According to normal condition, or according to the condition proposed by manufacturer.Unless otherwise stated, all of percentage and number be by weight
Meter.
Embodiment 1：Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 methacrylate of docosyl alcohol polyethers crosslinking
Polymer synergistic thickening is tested
1. experiment material
Scleroglucan, trade name AMI GEL, purchased from Alban Muller International company；Acryloyl two
N-methyltaurine ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers, trade nameHMB, is purchased from
Clariant Chemical Co., Ltd., alternatively referred to as HMB herein；And deionized water.
2. laboratory apparatus：
Fixing agitator IKA RW20
Thermostat water bath Shanghai Yiheng Scientific Instruments Co., Ltd HWS28 type
Weigh balance METTLER TOLEDO PL602-S
III ULTRA of viscosimeter BROOKFIELD DV
3. experimental technique：
3.1 weigh appropriate Scleroglucan powder and ammonium acryloyldime-thyltaurate/- 25 metering system of docosyl alcohol polyethers
Acid esters crosslinked polymer powder
3.2 weigh deionized water, by Scleroglucan powder and ammonium acryloyldime-thyltaurate/- 25 first of docosyl alcohol polyethers
The mixture of base acrylate crosspolymers powder is slowly sprinkled in deionized water in the case of high-speed stirred, is stirred
Scattered colloid is heated to 80 DEG C and is kept stirring for 10 minutes by 3.3
3.4 are cooled to room temperature, carry out follow-up measurement experiment
4. experimental result
Scleroglucan be a thickening efficiency than relatively low thickener, under 0.05%, 0.1%, 0.3%, 0.5% and 1% concentration
The viscosity of the aqueous solution is 0,2,6,100 and 775mPa.s respectively.Table 1 shows the viscosity of Scleroglucan under variable concentrations.
Table 1：Scleroglucan viscosity (mPa.s) is used alone
| Concentration % | 0.05 | 0.1 | 0.3 | 0.5 | 1 |
| Viscosity（mPa.s） | 0 | 2 | 6 | 100 | 775 |
But experiment finds, after Scleroglucan adds the aqueous solution of HMB, the viscosity of the aqueous solution of HMB can be significantly improved, is carried
The degree for rising is much larger than the viscosity that the Scleroglucan for adding has in itself.As a result as shown in table 2.
Table 2：The viscosity (mPa.s) of the solution of HMB+ Scleroglucan
As shown in table 2, after adding Scleroglucan in the aqueous solution of 0.05%, 0.1%, 0.3%, 0.5% and 1% HMB, glue
Degree is raised, and elevated degree is much larger than the viscosity that the Scleroglucan itself for adding has.Experiment is as can be seen that in variable concentrations
HMB solution in add Scleroglucan all be obviously improved the viscosity of product, and increased amplitude is much larger than these lower small nuts
The due viscosity of bacterium glue itself.Therefore, the combination of Scleroglucan and HMB has synergistic thickening effect.
Embodiment 2：Scleroglucan and ammonium acryloyldime-thyltaurate/- 25 methacrylate of docosyl alcohol polyethers crosslinking
Polymer compounding use can provide preferably resistance to ion energy
1. experiment material
Scleroglucan, trade name AMI GEL, purchased from Alban Muller International company；Acryloyl two
N-methyltaurine ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers, trade nameHMB, is purchased from
Clariant Chemical Co., Ltd.；Deionized water；Sodium chloride, purchased from Chemical Reagent Co., Ltd., Sinopharm Group.
2. laboratory apparatus：
Fixing agitator IKA RW20
Thermostat water bath Shanghai Yiheng Scientific Instruments Co., Ltd HWS28 type
Weigh balance METTLER TOLEDO PL602-S
III ULTRA of viscosimeter BROOKFIELD DV
2. experimental technique
3.1 weigh appropriate HMB powder or Scleroglucan powder and HMB powder
3.2 weigh appropriate NaCl
3.3 weigh deionized waters, by HMB powder or Scleroglucan powder and HMB mixture of powders in high-speed stirred
In the case of be slowly sprinkled in deionized water, then NaCl is sprinkled into system, stirs
Scattered colloid is heated to 80 DEG C by 3.4, and is kept stirring for 10 minutes
3.5 are cooled to room temperature, carry out subsequent experimental
4. experimental result and discussion
In cosmetic field, for many formulas, usually add various functions additive to realize ideal effect.
These additives typically all contain electrolyte, and electrolyte concentration is even higher sometimes.Using for these additives can be to system
Viscosity and stability cause very big impact, therefore it is required that thickener has the effect of tolerance electrolyte.
Solution and the body comprising 0.5%HMB and 0.5% two kinds of thickeners of Scleroglucan of 0.5%HMB is compared in experiment
Tie up to the situation that viscosity declines under different NaCl concentration.As a result as shown in Table 3 and Table 4.
Table 3：Impact of the NaCl of variable concentrations to the viscosity of 0.5%HMB solution
| NaCl concentration（%） | Absolute viscosity（mPa.s） | Relative viscosity * |
| 0.00 | 9960.00 | 1.00 |
| 0.02 | 1240.00 | 0.12 |
| 0.05 | 120.00 | 0.01 |
| 0.08 | 60.00 | 0.01 |
| 0.10 | 40.00 | 0.00 |
| 0.20 | 0.00 | 0.00 |
| 0.50 | 0.00 | 0.00 |
| 1.00 | 0.00 | 0.00 |
* relative viscosity represent under certain NaCl concentration the viscosity of thickener soln with without the identical thickener soln of NaCl
The ratio of viscosity
Table 4：Impact of the NaCl of variable concentrations to the viscosity of the solution comprising 0.5%HMB and 0.5% Scleroglucan
| NaCl concentration（%） | Absolute viscosity（mPa.s） | Relative viscosity * |
| 0.00 | 26520.00 | 1.00 |
| 0.02 | 25680.00 | 0.97 |
| 0.05 | 21360.00 | 0.81 |
| 0.08 | 10200.00 | 0.38 |
| 0.10 | 6920.00 | 0.26 |
| 0.20 | 4920.00 | 0.19 |
| 0.50 | 3040.00 | 0.11 |
| 1.00 | 1600.00 | 0.06 |
* relative viscosity refer under certain NaCl concentration the viscosity of thickener soln with without the identical thickener soln of NaCl
The ratio of viscosity
For HMB is as thickener, which is not resistant to the presence of electrolyte.For example, in 0.5% HMB solution, add
Electrolyte sodium chloride causes its viscosity drastically to decline.However, add Scleroglucan help solution in the solution of 0.5%HMB
The effect of tolerance electrolyte.Data find out that, without Scleroglucan, the electrolyte-resistant ability of HMB is not outstanding.In 0.02%NaCl
In the presence of, viscosity is almost lost, but after Scleroglucan is added, the electrolyte-resistant ability of product has obtained significantly carrying
Rise.In the solution of HMB, add Scleroglucan effectively improve the ability that system tolerates electrolyte.That is, pyrenomycetes
Glue and -25 Methacrylate Crosspolymer compounding use of ammonium acryloyldime-thyltaurate/docosyl alcohol polyethers can be provided more
Good resistance to ion energy.
Claims (5)
1. a kind of thickener blend composition, it is 1 by weight ratio which is:20 to 20:1 Scleroglucan and acryloyldimethyl taurine
Ammonium/- 25 Methacrylate Crosspolymer of docosyl alcohol polyethers composition.
2. composition as claimed in claim 1, it is characterised in that the Scleroglucan and ammonium acryloyldime-thyltaurate/
The weight ratio of -25 Methacrylate Crosspolymer of docosyl alcohol polyethers is 1:10 to 10:1.
3. composition as claimed in claim 1, it is characterised in that the Scleroglucan and ammonium acryloyldime-thyltaurate/
The weight ratio of -25 Methacrylate Crosspolymer of docosyl alcohol polyethers is 1:2 to 2:1.
4. application of the composition any one of claim 1-3 in cosmetics as thickener.
5. application as claimed in claim 4, the toiletry bag contain electrolyte.
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| CN106880516A (en) * | 2015-12-16 | 2017-06-23 | 广州世航生物科技有限公司 | A kind of rheology modifier and preparation technology with skin sense regulation performance |
| CN107648072B (en) * | 2017-10-27 | 2020-02-04 | 广州神采化妆品有限公司 | Cosmetic with brightening effect and mousse texture and preparation method thereof |
| JP2022531108A (en) * | 2019-04-30 | 2022-07-06 | ロレアル | Cosmetic composition in the form of oil-in-water emulsion |
| CN111249175B (en) * | 2020-03-13 | 2023-06-30 | 中山市天图精细化工有限公司 | Carbonic acid moisturizing essence composition aerosol and preparation method thereof |
| CN112932994B (en) * | 2021-02-26 | 2022-04-19 | 上海家化联合股份有限公司 | Sunscreen composition for reducing transdermal penetration of sunscreen |
| CN114306133B (en) * | 2021-12-29 | 2024-03-29 | 上海运佳黄浦制药有限公司 | Ion-resistant thickener, and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1204508A (en) * | 1997-07-04 | 1999-01-13 | 希巴特殊化学控股公司 | New scleroglucans and cosmetic compositions containing new compounds |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US7176172B2 (en) * | 2004-10-25 | 2007-02-13 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Quaternary ammonium polyol salts as anti-aging actives in personal care compositions |
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Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1204508A (en) * | 1997-07-04 | 1999-01-13 | 希巴特殊化学控股公司 | New scleroglucans and cosmetic compositions containing new compounds |
Non-Patent Citations (1)
| Title |
|---|
| Nu Skin(如新)焕新精华液;无;《http://www.cosdna.com/chs/cosmetic_765f32585.html》;20100421;第1-2页表格 * |
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