CN1040664C - 在离子交换系统中从含Li+稀溶液中捕获和浓缩Li+的方法 - Google Patents

在离子交换系统中从含Li+稀溶液中捕获和浓缩Li+的方法 Download PDF

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Publication number
CN1040664C
CN1040664C CN94119180A CN94119180A CN1040664C CN 1040664 C CN1040664 C CN 1040664C CN 94119180 A CN94119180 A CN 94119180A CN 94119180 A CN94119180 A CN 94119180A CN 1040664 C CN1040664 C CN 1040664C
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CN
China
Prior art keywords
solution
bed
lithium
concentrated
dilute
Prior art date
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Expired - Fee Related
Application number
CN94119180A
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English (en)
Chinese (zh)
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CN1107519A (zh
Inventor
F·W·利维特
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Praxair Technology Inc
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Praxair Technology Inc
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Publication date
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Publication of CN1107519A publication Critical patent/CN1107519A/zh
Application granted granted Critical
Publication of CN1040664C publication Critical patent/CN1040664C/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/04—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/04—Processes using organic exchangers
    • B01J39/05—Processes using organic exchangers in the strongly acidic form
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/02—Preparation of oxygen
    • C01B13/0229—Purification or separation processes
    • C01B13/0248—Physical processing only
    • C01B13/0259—Physical processing only by adsorption on solids
    • C01B13/0262—Physical processing only by adsorption on solids characterised by the adsorbent
    • C01B13/027—Zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2210/00—Purification or separation of specific gases
    • C01B2210/0043—Impurity removed
    • C01B2210/0046—Nitrogen

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Manufacture And Refinement Of Metals (AREA)
CN94119180A 1993-12-23 1994-12-22 在离子交换系统中从含Li+稀溶液中捕获和浓缩Li+的方法 Expired - Fee Related CN1040664C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US172,297 1993-12-23
US08/172,297 US5451383A (en) 1993-12-23 1993-12-23 Lithium recovery
US172297 1993-12-23

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN98105274A Division CN1202385A (zh) 1993-12-23 1998-02-25 在离子交换系统中从含Li+稀溶液中捕获和浓缩Li+的方法

Publications (2)

Publication Number Publication Date
CN1107519A CN1107519A (zh) 1995-08-30
CN1040664C true CN1040664C (zh) 1998-11-11

Family

ID=22627107

Family Applications (2)

Application Number Title Priority Date Filing Date
CN94119180A Expired - Fee Related CN1040664C (zh) 1993-12-23 1994-12-22 在离子交换系统中从含Li+稀溶液中捕获和浓缩Li+的方法
CN98105274A Pending CN1202385A (zh) 1993-12-23 1998-02-25 在离子交换系统中从含Li+稀溶液中捕获和浓缩Li+的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN98105274A Pending CN1202385A (zh) 1993-12-23 1998-02-25 在离子交换系统中从含Li+稀溶液中捕获和浓缩Li+的方法

Country Status (8)

Country Link
US (1) US5451383A (enExample)
EP (1) EP0659481A3 (enExample)
JP (1) JP3037574B2 (enExample)
KR (1) KR100196103B1 (enExample)
CN (2) CN1040664C (enExample)
BR (1) BR9405215A (enExample)
CA (1) CA2138862C (enExample)
TW (1) TW315357B (enExample)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5612150A (en) * 1994-03-16 1997-03-18 Hitachi, Ltd. Method and apparatus for treatment of a battery containing alkali metal
FR2726819A1 (fr) * 1994-11-15 1996-05-15 Centre Nat Rech Scient Procede pour reduire selectivement par echange d'ions, la concentration de l'une des especes chimiques presentes dans une solution
US5681477A (en) * 1995-10-25 1997-10-28 Praxair Technology, Inc. Thermally-driven ion-exchange process for lithium recovery
FR2743798B1 (fr) * 1996-01-18 1998-02-27 Air Liquide Procede de purification d'une solution de sels de lithium contaminee par des cations metalliques et utilisation de ce procede dans la fabrication de zeolites echangees au lithium
DE19708619A1 (de) * 1997-03-03 1998-09-17 Bayer Ag Verfahren und Vorrichtung zum Ionenaustausch in Zeolithen
US6048507A (en) * 1997-12-09 2000-04-11 Limtech Process for the purification of lithium carbonate
FR2775618B1 (fr) * 1998-03-03 2000-05-05 Air Liquide Adsorbant a taux d'echange heterogene et procede psa mettant en oeuvre un tel adsorbant
US6642168B1 (en) * 2001-04-27 2003-11-04 Uop Llc Method for metal loading of a multi-bed adsorbent system
FI121785B (fi) * 2009-03-11 2011-04-15 Outotec Oyj Menetelmä litiumbikarbonaatin puhdistamiseksi
JP5435632B2 (ja) * 2009-09-02 2014-03-05 独立行政法人産業技術総合研究所 粘土の層間イオンをリチウムイオンと交換したリチウム交換粘土の製造方法
US8309043B2 (en) * 2010-12-06 2012-11-13 Fmc Corporation Recovery of Li values from sodium saturate brine
JP2013013843A (ja) * 2011-07-01 2013-01-24 Taiheiyo Cement Corp アルカリ金属含有廃棄物の処理方法
CN102491364B (zh) * 2011-12-01 2013-04-10 上海绿强新材料有限公司 一种从含锂交换废液中回收再利用锂的方法及装置
US10604414B2 (en) * 2017-06-15 2020-03-31 Energysource Minerals Llc System and process for recovery of lithium from a geothermal brine
CN108439432A (zh) * 2018-04-25 2018-08-24 西安蓝晓科技新材料股份有限公司 一种锂钠分离的方法
CN112742361A (zh) * 2019-10-31 2021-05-04 中国石油化工股份有限公司 含钡吸附剂的制备方法和制备装置
CN114875249A (zh) * 2022-07-08 2022-08-09 太原理工大学 从富含钴锂溶液中选择性回收钴、锂的方法及产物的应用
CN116534878B (zh) * 2023-05-23 2025-07-04 河北地质大学 一种碳酸锂的制备工艺
FR3152727A1 (fr) 2023-09-08 2025-03-14 Arkema France Recyclage de cations lithium dans les tamis moléculaires

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4376100A (en) * 1981-11-23 1983-03-08 The Dow Chemical Company Lithium halide brine purification

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3033641A (en) * 1956-03-21 1962-05-08 Union Carbide Corp Process for cation separation using zeolitic materials
US2980499A (en) * 1957-01-29 1961-04-18 Dow Chemical Co Recovery of lithium from lithium bearing ores
US2980498A (en) * 1957-01-29 1961-04-18 Dow Chemical Co Recovery of lithium from lithium bearing ores
US3101246A (en) * 1960-10-14 1963-08-20 David L Hansford Recovery and separation of lithium values from salvage solutions
JPS5466311A (en) * 1977-11-07 1979-05-28 Japan Atom Energy Res Inst Collecting method for lithium in seawater
JPS5650113A (en) * 1979-09-29 1981-05-07 Agency Of Ind Science & Technol Recovering method for lithium from bittern
US4723962A (en) * 1985-02-04 1988-02-09 Lithium Corporation Of America Process for recovering lithium from salt brines
US4859217A (en) * 1987-06-30 1989-08-22 Uop Process for separating nitrogen from mixtures thereof with less polar substances
US5174979A (en) * 1989-10-06 1992-12-29 Uop Mixed ion-exchanged zeolites and processes for the use thereof in gas separations
US5152813A (en) * 1991-12-20 1992-10-06 Air Products And Chemicals, Inc. Nitrogen adsorption with a Ca and/or Sr exchanged lithium X-zeolite

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4376100A (en) * 1981-11-23 1983-03-08 The Dow Chemical Company Lithium halide brine purification

Also Published As

Publication number Publication date
KR950016861A (ko) 1995-07-20
CA2138862A1 (en) 1995-06-24
JPH07241479A (ja) 1995-09-19
KR100196103B1 (ko) 1999-06-15
EP0659481A2 (en) 1995-06-28
CN1107519A (zh) 1995-08-30
CN1202385A (zh) 1998-12-23
JP3037574B2 (ja) 2000-04-24
EP0659481A3 (en) 1995-08-23
TW315357B (enExample) 1997-09-11
BR9405215A (pt) 1995-10-17
US5451383A (en) 1995-09-19
CA2138862C (en) 1997-10-28

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