CN104059590B - A kind of self-vulcanizing toughened epoxy resin adhesive and preparation method thereof - Google Patents
A kind of self-vulcanizing toughened epoxy resin adhesive and preparation method thereof Download PDFInfo
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- CN104059590B CN104059590B CN201410251510.6A CN201410251510A CN104059590B CN 104059590 B CN104059590 B CN 104059590B CN 201410251510 A CN201410251510 A CN 201410251510A CN 104059590 B CN104059590 B CN 104059590B
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Abstract
The present invention relates to a kind of self-vulcanizing toughened epoxy resin adhesive and preparation method thereof, belong to technical field of polymer materials.Epoxyn of the present invention comprises the following raw material according to weight parts: epoxy resin 40-60 part, solidifying agent 30-50 part, epoxidized polybutadiene 10-20 part, dioctyl terephthalate 10-18 part, silane coupling agent 3-5 part, calcium carbonate 30-50 part.Epoxyn prepared by the present invention, can self-vulcanizing, has again preferably toughness, has and apply comparatively widely.This patent carries out toughening modifying by the technological approaches adding toughner in room temperature curing epoxy to epoxy resin, so that the preparation of the room temperature curing epoxy adhesive that various preparation technology is different, application purpose is different can be applied to preferably, aramid fiber reinforced composite can be advantageously applied to.
Description
Technical field
The present invention relates to a kind of epoxyn and preparation method thereof, more particularly, the present invention relates to a kind of self-vulcanizing toughened epoxy resin adhesive and preparation method thereof, belong to technical field of polymer materials.
Background technology
Epoxy resin is a kind of thermosetting resin, because having the characteristics such as excellent cementability, physical strength and electrical insulating property, and is widely used in the aspect such as tackiness agent, high-performance-light weight fibre reinforced composites, coating and matrices of composite material.In addition, epoxyn is widely used in sqtructural adhesive due to its good performance.But the ability that its obvious fragility and poor weathering resistance, resistance to fatigue, thermotolerance, water absorbability and shock resistance make it bear applied external force under heavily stressed is poor, is its unavoidable shortcoming.Therefore, need to carry out modification to epoxy resin.In addition, because epoxy resin viscosity is higher, to features such as the wetting property differences of aramid fiber, epoxy resin to be performed well in the preparation of aramid fiber reinforced composite, necessary modification must be carried out to epoxy resin, make prepared aramid fiber/epoxy resin composite material have best over-all properties.
It is CN101157835 that State Intellectual Property Office discloses a publication number in 2008.4.9, name be called the patent of invention of " a kind of modified epoxide resin adhesive and application thereof ", this patent provide a kind of can effectively fixing spring, make spring be not easy the tackiness agent come off from spring groove.The present invention provides the application of this tackiness agent in fixing spring simultaneously.Modified epoxide resin adhesive of the present invention, comprises the component of following mass parts: epoxy resin 100; TR sealant 50 ~ 200; White carbon black 5 ~ 15; Coupling agent 1 ~ 5; Amine curing agent 2 ~ 10.Compared with ordinary epoxy resin: the present invention adopts thiorubber to carry out modification to epoxy resin, it is a kind of toughness reinforcing method of reactive liquid polymerization, after thiorubber mixes with epoxy resin, thiol group in TR sealant and epoxy group(ing) react, identify oneself with in the epoxy resin structural of solidification, give the snappiness that epoxy resin is good.Therefore modified epoxide resin adhesive of the present invention can effectively fixing spring, make spring be not easy to come off from spring groove, maintain again other effective performances of epoxy resin simultaneously.
Epoxyn in above-mentioned patent has certain snappiness, but over-all properties is not good, cannot be advantageously applied to aramid fiber reinforced composite.
Summary of the invention
The present invention is intended to solve the problems of the technologies described above, and provides a kind of self-vulcanizing toughened epoxy resin adhesive, improves its over-all properties, can be advantageously applied to aramid fiber reinforced composite.
In order to realize foregoing invention object, its concrete technical scheme is as follows:
A kind of self-vulcanizing toughened epoxy resin adhesive, is characterized in that: comprise the following raw material according to weight parts:
Epoxy resin 40-60 part
Solidifying agent 30-50 part
Epoxidized polybutadiene 10-20 part
Dioctyl terephthalate 10-18 part
Silane coupling agent 3-5 part
Calcium carbonate 30-50 part.
A kind of self-vulcanizing toughened epoxy resin adhesive, is characterized in that: comprise the following raw material according to weight parts:
Epoxy resin 45-55 part
Solidifying agent 35-43 part
Epoxidized polybutadiene 12-17 part
Dioctyl terephthalate 11-15 part
Silane coupling agent 4-4.5 part
Calcium carbonate 35-40 part.
Epoxy resin of the present invention is E-44 epoxy resin.
Solidifying agent of the present invention is 554 solidifying agent.
Silane coupling agent of the present invention is KH-550 silane coupling agent.
A preparation method for self-vulcanizing toughened epoxy resin adhesive, is characterized in that: comprise following processing step:
A, take epoxy resin, epoxidized polybutadiene, silane coupling agent and calcium carbonate by recipe requirements, be uniformly mixed;
B, to mix further on two roller or three-roller as component A, for subsequent use;
C, take solidifying agent and dioctyl terephthalate by recipe requirements, after mixing, obtain B component, for subsequent use;
D, get component A that step B obtains and the B component that step C obtains, mixing, in cured at room temperature, obtains epoxyn.
The Advantageous Effects that the present invention brings:
The invention solves existing epoxyn over-all properties not good, the problem of aramid fiber reinforced composite cannot be advantageously applied to, epoxyn prepared by the present invention, can self-vulcanizing, there is again preferably toughness, have and apply comparatively widely.This patent carries out toughening modifying by the technological approaches adding toughner in room temperature curing epoxy to epoxy resin, so that the preparation of the room temperature curing epoxy adhesive that various preparation technology is different, application purpose is different can be applied to preferably, aramid fiber reinforced composite can be advantageously applied to.
Embodiment
embodiment 1
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 40 parts
30 parts, solidifying agent
Epoxidized polybutadiene 10 parts
Dioctyl terephthalate 10 parts
Silane coupling agent 3 parts
30 parts, calcium carbonate.
embodiment 2
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 60 parts
50 parts, solidifying agent
Epoxidized polybutadiene 20 parts
Dioctyl terephthalate 18 parts
Silane coupling agent 5 parts
50 parts, calcium carbonate.
embodiment 3
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 50 parts
40 parts, solidifying agent
Epoxidized polybutadiene 15 parts
Dioctyl terephthalate 14 parts
Silane coupling agent 4 parts
40 parts, calcium carbonate.
embodiment 4
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 46 parts
33 parts, solidifying agent
Epoxidized polybutadiene 19 parts
Dioctyl terephthalate 15 parts
Silane coupling agent 3.5 parts
48 parts, calcium carbonate.
embodiment 5
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 45 parts
35 parts, solidifying agent
Epoxidized polybutadiene 12 parts
Dioctyl terephthalate 11 parts
Silane coupling agent 4 parts
35 parts, calcium carbonate.
embodiment 6
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 55 parts
43 parts, solidifying agent
Epoxidized polybutadiene 17 parts
Dioctyl terephthalate 15 parts
Silane coupling agent 4.5 parts
40 parts, calcium carbonate.
embodiment 7
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 50 parts
39 parts, solidifying agent
Epoxidized polybutadiene 14.5 parts
Dioctyl terephthalate 13 parts
Silane coupling agent 4.25 parts
37.5 parts, calcium carbonate.
embodiment 8
A kind of self-vulcanizing toughened epoxy resin adhesive, comprises the following raw material according to weight parts:
Epoxy resin 47 parts
36 parts, solidifying agent
Epoxidized polybutadiene 16.5 parts
Dioctyl terephthalate 14.5 parts
Silane coupling agent 4.2 parts
38 parts, calcium carbonate.
embodiment 9
On the basis of embodiment 1-9, preferred:
Described epoxy resin is E-44 epoxy resin.
Described solidifying agent is 554 solidifying agent.
Described silane coupling agent is KH-550 silane coupling agent.
embodiment 10
A preparation method for self-vulcanizing toughened epoxy resin adhesive, comprises following processing step:
A, take epoxy resin, epoxidized polybutadiene, silane coupling agent and calcium carbonate by recipe requirements, be uniformly mixed;
B, to mix further on two roller or three-roller as component A, for subsequent use;
C, take solidifying agent and dioctyl terephthalate by recipe requirements, after mixing, obtain B component, for subsequent use;
D, get component A that step B obtains and the B component that step C obtains, mixing, in cured at room temperature, obtains epoxyn.
Claims (2)
1. a self-vulcanizing toughened epoxy resin adhesive, is characterized in that: comprise the following raw material according to weight parts:
E-44 epoxy resin 45-55 part
554 solidifying agent 35-43 parts
Epoxidized polybutadiene 12-17 part
Dioctyl terephthalate 11-15 part
KH-550 silane coupling agent 4-4.5 part
Calcium carbonate 35-40 part.
2. the preparation method of a kind of self-vulcanizing toughened epoxy resin adhesive according to claim 1, is characterized in that: comprise following processing step:
A, take epoxy resin, epoxidized polybutadiene, silane coupling agent and calcium carbonate by recipe requirements, be uniformly mixed;
B, to mix further on two roller or three-roller as component A, for subsequent use;
C, take solidifying agent and dioctyl terephthalate by recipe requirements, after mixing, obtain B component, for subsequent use;
D, get component A that step B obtains and the B component that step C obtains, mixing, in cured at room temperature, obtains epoxyn.
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CN201410251510.6A CN104059590B (en) | 2014-06-09 | 2014-06-09 | A kind of self-vulcanizing toughened epoxy resin adhesive and preparation method thereof |
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CN201410251510.6A CN104059590B (en) | 2014-06-09 | 2014-06-09 | A kind of self-vulcanizing toughened epoxy resin adhesive and preparation method thereof |
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CN104059590A CN104059590A (en) | 2014-09-24 |
CN104059590B true CN104059590B (en) | 2015-09-16 |
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Families Citing this family (2)
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CN104449419B (en) * | 2014-12-05 | 2016-08-24 | 烟台泰盛精化科技有限公司 | A kind of ultraviolet-heat dual cure optical adhesive containing POLYBUTADIENE EPOXY RESIN |
CN109486454A (en) * | 2017-09-09 | 2019-03-19 | 熊小利 | A kind of room temperature curing toughened epoxy resin adhesive and preparation method thereof |
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CN102212330A (en) * | 2010-04-07 | 2011-10-12 | 深圳市诚德来实业有限公司 | Epoxy resin adhesive for hollow fiber membrane end sealing as well as preparation and application methods thereof |
KR101493625B1 (en) * | 2010-09-15 | 2015-02-23 | 닛뽕소다 가부시키가이샤 | Liquid curable epoxy resin composition and adhesive agent containing same |
CN103436212B (en) * | 2013-09-05 | 2014-12-10 | 中国电子科技集团公司第二十八研究所 | Room-temperature-curing structural adhesive for composite plates |
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