CN104051573A - Film covering and texture surface making technology for silicon wafer - Google Patents
Film covering and texture surface making technology for silicon wafer Download PDFInfo
- Publication number
- CN104051573A CN104051573A CN201410271292.2A CN201410271292A CN104051573A CN 104051573 A CN104051573 A CN 104051573A CN 201410271292 A CN201410271292 A CN 201410271292A CN 104051573 A CN104051573 A CN 104051573A
- Authority
- CN
- China
- Prior art keywords
- silicon chip
- mask
- silicon wafer
- coating
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 69
- 239000010703 silicon Substances 0.000 title claims abstract description 69
- 238000005516 engineering process Methods 0.000 title claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000000034 method Methods 0.000 claims abstract description 29
- 239000011248 coating agent Substances 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002253 acid Substances 0.000 claims abstract description 9
- 210000002268 wool Anatomy 0.000 claims description 23
- 235000008216 herbs Nutrition 0.000 claims description 20
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- 239000000428 dust Substances 0.000 claims description 17
- 238000005530 etching Methods 0.000 claims description 15
- 238000004140 cleaning Methods 0.000 claims description 10
- 230000008021 deposition Effects 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- 239000000758 substrate Substances 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 239000011734 sodium Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 238000002310 reflectometry Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 238000001228 spectrum Methods 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 230000008602 contraction Effects 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229910021419 crystalline silicon Inorganic materials 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0236—Special surface textures
- H01L31/02363—Special surface textures of the semiconductor body itself, e.g. textured active layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Abstract
The invention provides a film covering and texture surface making technology for a silicon wafer. In the silicon wafer processing process, the surface of the silicon wafer is coated with a layer of mixed silica solution which is even in thickness and contractile, then a layer of carbon powder is evenly deposited on the surface of a silica solution coating, after drying or standing, a film covering layer of a regular structure is formed on the surface of the silicon wafer, the surface of the silicon wafer in a corresponding area is exposed due to contraction of the silica solution, acid corrosion, washing and film removing are conducted on the surface of the silicon wafer after film covering is conducted according to a conventional production technology, and therefore a regular and orderly texture surface can be formed. According to the technology, the even texture surface can be prepared. According to the texture surface prepared according to the technology, absorption of different wave lengths in a solar spectrum can be enhanced, reflectivity is greatly reduced, and therefore the photoelectric converting efficiency of a solar cell can be further improved, the overall economic benefit is improved, and the production cost of unit capacity is reduced.
Description
Technical field
The present invention relates to the technology of preparing of solar energy battery adopted silicon chip, be specifically related to a kind of silicon chip mask process for etching, belong to solar energy battery adopted silicon chip mask making herbs into wool technical field.
Background technology
Solar energy, as a kind of renewable and clean energy resource, is progressively paid close attention to by common people and is used.In numerous solar products, the market share of silica-based solar cell assembly reaches more than 90%.Silicon wafer suede is the silicon materials that a kind of surface has in order accurate or periodic micro structure, after making herbs into wool, sunlight is had to very low reflectivity and very high absorptivity, and it is to almost all absorbing near infrared light near ultraviolet.Matte has the characteristic of wide spectral absorption, can improve the photoelectric conversion efficiency of solar module, therefore in solar cell preparation, has very large application prospect.
Polycrystalline silicon surface wool manufacturing method, generally adopts following steps: silicon chip is carried out prerinse and removes damage layer; Adopt ultrasonic atomization process or electrostatic painting process to cover the discontinuous plastic grain film of one deck as mask at silicon chip surface; Silicon chip be placed in acid, aqueous slkali corrodes making herbs into wool; Silicon chip after step 3 is washed to plastic grain film with acetone, then use washed with de-ionized water, dry silicon chip.
The people such as Ai Fanfan (artificial lens journal, in April, 2009) adopt " silicon nitride mask legal system alternative emitter crystalline silicon solar cell ", Chinese patent CN101814547 to adopt printing grid line mask mode to prepare crystal silicon solar cell with selective emitter; CN102412338 adopts optical mask treatment technology to carry out making herbs into wool.Although said method is obtained certain effect, technique is more complicated, preparation cost is also higher, and making herbs into wool effect is not ideal, and industrial application has larger difficulty.
Summary of the invention
The object of this invention is to provide a kind of silicon chip mask process for etching that can realize aborning popularization, simple process is easily gone, mask making herbs into wool is effective, can be applied in solar cell and prepare production field, obviously improves the photoelectric conversion efficiency efficiency of battery.
For achieving the above object, technical scheme of the present invention is:
A kind of silicon chip mask process for etching, comprises clean, mask, making herbs into wool, cleaning step, and described mask step is as follows:
In silicon chip substrate after clean, first use sol evenning machine with the rotating speed of 3500 revs/min, in 60 seconds, evenly apply one deck and have the Ludox mixed coating of autogenous shrinkage characteristic; Use gas phase deposition technology at Ludox coating surface uniform deposition one deck carbon dust, carbon dust deposit thickness is 2～3 μ m again; Then dry Ludox coating is shunk, finally form uniform sequential mask layer at silicon chip surface, after formation mask layer, should expose Ludox and shrink rear uniform sequential surface of silicon, expose uniform sequential surface of silicon.Above-mentioned Ludox is the mixed liquor of nano level silica dioxide granule and water and solvent oxidation sodium.
In above-mentioned mask step, can also be in the silicon chip substrate after clean, adopt sol evenning machine with the rotating speed of 3500 revs/min, in 60 seconds, evenly apply one deck and be added with the Ludox coating of carbon dust, wherein carbon dust deposit thickness is preferably 2～3 μ m; Then dry Ludox coating is shunk, finally form uniform sequential mask layer at silicon chip surface; The surface that this mask layer forms rear silicon chip should be the exposed structure of ordering rule, exposes uniform sequential surface of silicon.
Above-mentioned carbon powder particle granularity is 100～500nm.
After deposition or coating carbon dust, coating is carried out to drying operation, concrete operations are 120 DEG C of hot-air seasonings, the dehydration of Ludox coating is reunited and shrink, and form uniform sequential mask layer at silicon chip surface.After coating surface self or heating, can shrink and form uniform sequential mask layer.Leaving standstill the coating of shrinking as adopted does not need heating, and autogenous shrinkage solidifies.
In above-mentioned making herbs into wool step, acid (alkali) the corrosive liquid concentration after mask should be carried out suitable allotment improvement, as the acid after mask (alkali) corrosive liquid concentration should improve 5%～15% than normal concentration.Also can improve and further adjust with production technology.Be mainly the reaction speed of accelerating corrosion reaction, control corrosion depth.
Above-mentioned cleaning step is to adopt existing technique that Wafer Cleaning after making herbs into wool is fallen after surperficial mask coating, then silicon chip is put into pure water, utilizes ultrasonic wave to carry out degumming cleaning at 75 DEG C.Clean and dry later the matte with high light absorptivity that obtains preparing by this method.
The beneficial effect of obtaining:
Adopt mask process for etching of the present invention, can control easily silicon chip surface mask quality and uniformity thereof, obviously improve systematicness and the uniformity of silicon wafer wool making matte, thereby can further promote the absorptance of silicon chip and the matching with spectrum, improve cell piece efficiency, promote economic benefit.Simple process of the present invention is row, quality controllable easily, has a good application prospect.
Brief description of the drawings:
Fig. 1 is mask flow process 1 schematic diagram of the present invention
Fig. 2 is mask flow process 2 schematic diagrames of the present invention
Fig. 3 is making herbs into wool front and rear surfaces reflectivity comparison diagram of the present invention
1, silicon chip; 2, Ludox coating; 3, carbon dust.
Embodiment:
Below in conjunction with drawings and Examples, the present invention is described in further detail:
Embodiment 1
See Fig. 1, on silicon chip (1) substrate after clean, adopt sol evenning machine with the rotating speed of 3500 revs/min, in 50 seconds, evenly apply the Ludox coating (2) that one deck nanometer silicon dioxide particle and water and solvent oxidation sodium are made; Then use gas phase deposition technology at Ludox coating surface uniform deposition one deck carbon dust (3), carbon dust is of a size of 100～500nm, carbon dust deposit thickness is about 2～3 μ m, for 1/3rd left and right of making herbs into wool matte design thickness, is conducive to ensure making herbs into wool effect; Then dry Ludox coating is shunk, finally form uniform sequential mask layer at silicon chip surface, expose uniform sequential surface of silicon.After adopting subsequently existing technique to mask, silicon face carries out acid (alkali) erosion making herbs into wool, and the conventional working concentration of acid (alkali) concentration ratio exceeds 5%; After making herbs into wool, wash after silicon chip surface mask coating, then silicon chip is put into pure water, utilize ultrasonic wave to carry out degumming cleaning at 75 DEG C; Clean the matte with high light absorptivity that post-drying obtains preparing by this method.
Embodiment 2
See Fig. 2, in the silicon chip substrate after clean, adopt sol evenning machine with the rotating speed of 3500 revs/min, in 60 seconds, evenly apply one deck and be added with the Ludox coating of carbon dust; Wherein carbon dust granularity is 100～500nm, and carbon dust deposit thickness is about 1/3rd left and right of matte design thickness; Ludox adopts nanometer silicon dioxide particle and water and solvent oxidation sodium to make, and carbon powder content ensures that uniform sequential deposition forms the sedimentary deposit of 2～3 μ m.
Then dry Ludox coating is shunk, finally form uniform sequential mask layer at silicon chip surface, expose uniform sequential surface of silicon.After adopting subsequently existing technique to mask, silicon face carries out acid (alkali) erosion making herbs into wool, and the conventional working concentration of acid (alkali) concentration ratio exceeds 15%; After making herbs into wool, wash after silicon chip surface mask coating, then silicon chip is put into pure water, utilize ultrasonic wave to carry out degumming cleaning at 75 DEG C; Clean the matte with high light absorptivity that post-drying obtains preparing by this method.
From the silicon chip surface reflectivity contrast of Fig. 3 making herbs into wool front and back, adopt this above-mentioned mask etching method, can obviously improve systematicness and the uniformity of silicon wafer wool making matte, thereby can further promote the absorptance of silicon chip and the matching with spectrum, improve cell piece efficiency, promote economic benefit.
Above-described is only the application's specific embodiment, and described embodiment is not in order to limit this patent protection range, and the equivalent structure that therefore specification of every utilization this patent and accompanying drawing content are done changes, and in like manner all should be included in the application's protection range.
Claims (9)
1. a silicon chip mask process for etching, comprises clean, mask, making herbs into wool, cleaning step, it is characterized in that described mask step is as follows:
In silicon chip substrate after clean, first use sol evenning machine with the rotating speed of 3500 revs/min, in 60 seconds, evenly apply one deck and have the Ludox coating of autogenous shrinkage characteristic; Use again gas phase deposition technology at Ludox coating surface uniform deposition one deck carbon dust; Then dry Ludox coating is shunk, finally form uniform sequential mask layer at silicon chip surface; The surface that this mask layer forms rear silicon chip should be the exposed structure of ordering rule, exposes uniform sequential surface of silicon.
2. a kind of silicon chip mask process for etching according to claim 1, is characterized in that described carbon dust deposit thickness is about 2～3 μ m.
3. a kind of silicon chip mask process for etching according to claim 1, is characterized in that described Ludox is the mixed liquor of nano level silica dioxide granule and water and solvent oxidation sodium.
4. a kind of silicon chip mask process for etching according to claim 1, is characterized in that described mask step is as follows:
In silicon chip substrate after clean, adopt sol evenning machine with the rotating speed of 3500 revs/min, in 60 seconds, evenly apply one deck and be added with the Ludox coating of carbon dust; Then dry Ludox coating is shunk, finally form uniform sequential mask layer at silicon chip surface; The surface that this mask layer forms rear silicon chip should be the exposed structure of ordering rule, exposes uniform sequential surface of silicon.
5. a kind of silicon chip mask process for etching according to claim 4, is characterized in that in described mask layer, carbon dust deposit thickness is 2～3 μ m.
6. according to a kind of silicon chip mask process for etching described in claim 1,4, the granularity that it is characterized in that described carbon dust is 100～500nm.
7. according to a kind of silicon chip mask process for etching described in claim 1,4, it is characterized in that forming the uniform seal coat of point-like at silicon chip surface after described Ludox coating is shunk, the silicon chip substrate of covering and the surface being corroded are isolated.
8. a kind of silicon chip mask process for etching according to claim 1, is characterized in that in described making herbs into wool step, and the concentration of acid (alkali) corrosive liquid after mask rises 5%～15%.
9. a kind of silicon chip mask process for etching according to claim 1, it is characterized in that described cleaning step is to adopt common process that Wafer Cleaning after making herbs into wool is fallen after surperficial mask coating, silicon chip is put into pure water again, utilize ultrasonic wave to carry out degumming cleaning at 75 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410271292.2A CN104051573B (en) | 2014-06-17 | 2014-06-17 | A kind of silicon chip mask leather producing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410271292.2A CN104051573B (en) | 2014-06-17 | 2014-06-17 | A kind of silicon chip mask leather producing process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104051573A true CN104051573A (en) | 2014-09-17 |
| CN104051573B CN104051573B (en) | 2016-06-01 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410271292.2A Active CN104051573B (en) | 2014-06-17 | 2014-06-17 | A kind of silicon chip mask leather producing process |
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| Country | Link |
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| CN (1) | CN104051573B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107342336A (en) * | 2017-06-28 | 2017-11-10 | 常州欣彬纺织品有限公司 | A kind of preparation method of isotypy polycrystalline silicon suede |
| CN111916342A (en) * | 2017-08-10 | 2020-11-10 | 长江存储科技有限责任公司 | Wafer bonding method and structure thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009078190A1 (en) * | 2007-12-17 | 2009-06-25 | Toppan Printing Co., Ltd. | Pattern forming method and pattern formed body |
| US20100177384A1 (en) * | 2007-04-04 | 2010-07-15 | Saint-Gobain Glass France | Process for surface structuring of product having a sol-gel layer, product having a structured sol-gel layer |
| CN102903793A (en) * | 2012-09-27 | 2013-01-30 | 东方电气集团(宜兴)迈吉太阳能科技有限公司 | Preparing method of selective emitter battery slice mask |
-
2014
- 2014-06-17 CN CN201410271292.2A patent/CN104051573B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100177384A1 (en) * | 2007-04-04 | 2010-07-15 | Saint-Gobain Glass France | Process for surface structuring of product having a sol-gel layer, product having a structured sol-gel layer |
| WO2009078190A1 (en) * | 2007-12-17 | 2009-06-25 | Toppan Printing Co., Ltd. | Pattern forming method and pattern formed body |
| CN102903793A (en) * | 2012-09-27 | 2013-01-30 | 东方电气集团(宜兴)迈吉太阳能科技有限公司 | Preparing method of selective emitter battery slice mask |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107342336A (en) * | 2017-06-28 | 2017-11-10 | 常州欣彬纺织品有限公司 | A kind of preparation method of isotypy polycrystalline silicon suede |
| CN107342336B (en) * | 2017-06-28 | 2018-12-07 | 泉州泉一科技有限公司 | A kind of preparation method of isotypy polycrystalline silicon suede |
| CN111916342A (en) * | 2017-08-10 | 2020-11-10 | 长江存储科技有限责任公司 | Wafer bonding method and structure thereof |
| CN111916342B (en) * | 2017-08-10 | 2021-04-16 | 长江存储科技有限责任公司 | Wafer bonding method and structure thereof |
| US11342185B2 (en) | 2017-08-10 | 2022-05-24 | Yangtze Memory Technologies Co., Ltd. | Wafer bonding method and structure thereof |
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| Publication number | Publication date |
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| CN104051573B (en) | 2016-06-01 |
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Effective date of registration: 20171102 Address after: 6 417A room, building No. 1188, west two ring road, Shengze Town, Wujiang District, Jiangsu, Suzhou, 215228 Patentee after: Suzhou hair textile Co., Ltd. Address before: 221000 Jiangsu city of Xuzhou Province in the nine district, Xiang Wang Road No. 1 Patentee before: Xuzhou Institute of Industry Technology |
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Effective date of registration: 20181011 Address after: 215200 No. 1188 west two ring road, Shengze Town, Wujiang District, Suzhou, Jiangsu. Patentee after: Suzhou Shengze science and Technology Pioneer Park Development Co., Ltd. Address before: 215228 417A, 6 building, 1188 west two ring road, Shengze Town, Wujiang District, Suzhou, Jiangsu. Patentee before: Suzhou hair textile Co., Ltd. |
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