CN104005527B - A kind of patch stone for indoor wall decoration and its preparation method - Google Patents
A kind of patch stone for indoor wall decoration and its preparation method Download PDFInfo
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- CN104005527B CN104005527B CN201410175417.1A CN201410175417A CN104005527B CN 104005527 B CN104005527 B CN 104005527B CN 201410175417 A CN201410175417 A CN 201410175417A CN 104005527 B CN104005527 B CN 104005527B
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Abstract
The present invention provides a kind of patch stone for indoor wall decoration, described patch stone comprises PVC board sheet material layers successively by bottom to top layer, UV prime coat, film lower glue layer, UV have transferred imitative stone pattern imitative stone pattern transfer film, film upper glue layer, UV top coat layer, described PVC board sheet material layers comprises each component of following weight part number: polyvinyl chloride 66-70 part, anti-impact modifier 30-35 part, stablizer 1-3 part, lubricant 1-6 part. The present invention should further provide the preparation method of this patch stone. This patch stone hardness is big, shock resistance good, thickness is thin, light weight, is applicable to indoor wall decoration.
Description
Technical field
The present invention relates to building material technical field, it is specifically related to a kind of patch stone being applicable to indoor wall decoration, and the preparation method of this patch stone.
Background technology
Patch stone or claim emulation patch stone is that a kind of appearance is seen stone texture, is but the New Building Materials being made in conjunction with inorganic materials by full water-based material. Owing to it is radiationless, pollution-free, not only cost is low, plasticity-is strong, and crack resistence, water-impervious, tension are dialled performance etc. and be all better than stone material, and light quality, are widely used in external decoration of high-rise building, not only convenient construction but also can prevent from coming off.
But up to the present, also it is not applicable to the patch stone of indoor wall decoration.
Summary of the invention
Technical problem to be solved by this invention is for above the deficiencies in the prior art, it is provided that a kind of patch stone, and this patch stone hardness is big, shock resistance good, thickness is thin, light weight, is applicable to indoor wall decoration.
The technical solution adopted in the present invention is:
A kind of patch stone for indoor wall decoration, this patch stone comprises PVC board sheet material layers successively by bottom to top layer, UV prime coat, film lower glue layer, UV have transferred imitative stone pattern imitative stone pattern transfer film, film upper glue layer, UV top coat layer, described PVC board sheet material layers comprises each component of following weight part number:
As preferably, the model of described polyvinyl chloride is SG3 or SG4 or SG5. The molecular weight of polyvinyl chloride (PVC) RESINS is on the impact resistance impact of PVC composite sheet obviously, research finds, along with the increase (rising of K value) of PVC molecular weight, its conformational entropy increases, the increase of conformational entropy and intermolecular entanglement makes PVC change to ductile rupture by brittle rupture, notched Izod impact strength is significantly improved, and the shock strength of polymkeric substance increases.
As preferably, described anti-impact modifier is the mixture of one or more in CPE, ACR, ABS, MBS. PVC adds anti-impact modifier, it is possible to increase the toughness of PVC. But the interpolation of anti-impact modifier is not more many more many, and the consumption of anti-impact modifier becomes sigmoid curve relation with the raising of shock strength; And the kind of other additives and consumption also can affect the toughness of finished product PVC matrix material.
As preferably, described stablizer is the mixture of one or more in lead salt stabilizer, organic tin stablizer, calcium/zinc composite stabilizer, rare earth class stablizer. The selection of stablizer must be applicable to above-mentioned polyvinyl chloride, anti-impact modifier and softening agent, can have good synergy.
As preferably, described lubricant is the mixture of one or more in calcium stearate, paraffin, oxidized polyethlene wax, ester type waxes. The same stablizer of the choosing principles of lubricant.
As preferably, described film lower glue layer is that UV transfer glue point glue becomes; Described film upper glue layer is that UV transfer glue point glue becomes.
As preferably, the thickness of described PVC board sheet material layers is 1-2cm.
As preferably, the back side of described PVC board sheet material layers is matte surface, and is provided with latticed groove, the cross-sectional shape of described groove is semicircle.
The present invention also provides the preparation method of the above-mentioned patch stone for indoor wall decoration further, comprises the following steps:
(1) preparation of PVC board:
A () takes each raw material of formula ratio, add and carry out high-speed mixing in high-speed mixer, and be heated to 105-120 DEG C;
B () puts into cold mixed, below dry blend combination cooling to 50 DEG C;
C () metered charge carries out extrusion moulding to conical double screw extruder, screw rod Oil-temperature control is between 80-120 DEG C, spiral shell cylinder temperature temperature control is between 130-190 DEG C, merging core temperature is between 130-160 DEG C, and die temperature is between 150-180 DEG C, and die lip temperature controls between 130-160 DEG C, molten materials enters merging core through screw rod and branches to coat-hanger die, it is extruded at head shaping, carries out press polish and preliminary cooling through three-roll press-polishing trimming machine, obtain PVC sheet forming;
(2) carry out frosted process at the back side of PVC sheet forming, and the latticed groove of cross section semicircle is set;
(3) at surface roller coating or the spray painting UV primer of PVC sheet forming, UV-light illumination curing, forms UV prime coat;
(4) by UV transfer glue point glue on UV prime coat surface, and make its stream flat, form film lower glue layer;
(5) the UV transfer film that UV has transferred imitative stone pattern is fitted in film lower glue layer surface, row's bubble, and room temperature leaves standstill 3-5min, makes the laminating of imitative stone pattern transfer film firmly;
(6) by UV transfer glue point glue on imitative stone pattern transfer film surface, and make its stream flat, form film upper glue layer;
(7) at the surface showering of film upper glue layer or spraying UV finish paint, UV-light illumination curing, UV top coat layer;
(8) composite sheet obtained is cut by size, obtain the patch stone for indoor wall decoration.
Except the characteristics such as fire-retardant, weather-proof, anticorrosion, the water resistant generally possessed except requiring to possess PVC board for the building materials of indoor wall decoration and chemical corrodibility, electrical insulation capability, the mechanical property requirements such as hardness, shock resistance is also high especially, particularly shock resistance, and this is exactly the inferior position of PVC board. The present invention be used for indoor wall decoration patch stone compared with prior art, there is following remarkable advantage and useful effect:
(1) kind of each component and the choose reasonable of consumption in being filled a prescription by PVC board, impact resistance will be affected significant anti-impact modifier and introduce formula, the PVC type selecting impact resistance good, and optimization of C/C composites on the whole, each component in formula is made to play good synergy, so that the PVC board arrived shows excellence in the mechanical property such as hardness, shock resistance, it is applicable to the decoration of indoor wall;
(2) PVC board formula is simple, easily operates, is applicable to industrialization scale operation;
(3) patch stone comprises seven-layer structure, firmly bonding between each Rotating fields, difficult drop-off;
(4) in the seven-layer structure of patch stone, PVC board layer thickness is 1-2cm, and other Rotating fields thickness are all very little, and the thickness of patch stone can be estimated as roughly 1-2mm, so whole patch stone thickness is thin, light weight, and convenient installation;
(5) the PVC board sheet material layers back side is that frosted structure and the latticed groove of semicircle make this patch stone when installing, bonding with wall cement firmly, difficult drop-off, ensure use safety;
(6) preparation method of patch stone requires to design according to material prescription and structure, and repeatability is good, workable, is applicable to industrialized production.
Embodiment
Below in conjunction with embodiment, the present invention is further described in detail. It should be appreciated that following concrete explanation is all exemplary, it is intended to provide further instruction to the present invention. Unless otherwise explanation, all Science and Technology terms that the present invention uses have and the identical meanings that the technical field of the invention personnel understand usually.
Embodiment 1:
The present embodiment is used for the patch stone of indoor wall decoration, comprises PVC board sheet material layers, UV prime coat, film lower glue layer successively to top layer by bottom, imitates stone pattern transfer film, film upper glue layer, UV top coat layer.
Described PVC board layer thickness is 1.5cm; The back side is matte surface, and is provided with the latticed groove of semi-circular cross-section. Described UV prime coat is that UV priming paint roller coat UV-light illumination curing behind PVC board sheet material layers surface is formed. Described film lower glue layer is that UV transfer glue point glue flows flat, dry formation behind UV prime coat surface. Described imitative stone pattern transfer film is that the UV transfer film that UV has transferred imitative stone pattern is fitted in film lower glue layer surface and is formed. Described film upper glue layer is that UV transfer glue point glue is formed on imitative stone pattern transfer film surface. Described UV top coat layer is that UV-light illumination curing is formed after the showering UV finish paint of film upper glue layer surface.
Described PVC board sheet material layers comprises each component of following weight part number:
The preparation method of above-mentioned patch stone comprises the following steps:
(1) preparation of PVC board:
A () takes each raw material of formula ratio, add and carry out high-speed mixing in high-speed mixer, and be heated to 115 DEG C;
B () puts into cold mixed, below dry blend combination cooling to 50 DEG C;
C () metered charge carries out extrusion moulding to conical double screw extruder, screw rod Oil-temperature control is at 100 DEG C, spiral shell cylinder temperature temperature control is at 110 DEG C, merging core temperature is at 145 DEG C, and die temperature is at 165 DEG C, and die lip temperature controls at 145 DEG C, molten materials enters merging core through screw rod and branches to coat-hanger die, it is extruded at head shaping, carries out press polish and preliminary cooling through three-roll press-polishing trimming machine, obtain PVC sheet forming;
(2) carry out frosted process at the back side of PVC sheet forming, and the latticed groove of cross section semicircle is set;
(3) at surface roller coating or the spray painting UV primer of PVC sheet forming, UV-light illumination curing, forms UV prime coat;
(4) by UV transfer glue point glue on UV prime coat surface, and make its stream flat, form film lower glue layer;
(5) the UV transfer film that UV has transferred imitative stone pattern is fitted in film lower glue layer surface, row's bubble, and room temperature leaves standstill 5min, makes the laminating of imitative stone pattern transfer film firmly;
(6) by UV transfer glue point glue on imitative stone pattern transfer film surface, and make its stream flat, form film upper glue layer;
(7) at the surface showering of film upper glue layer or spraying UV finish paint, UV-light illumination curing, UV top coat layer;
(8) composite sheet obtained is cut by size, obtain the patch stone for indoor wall decoration.
Embodiment 2:
The present embodiment is used for the patch stone of indoor wall decoration, comprises PVC board sheet material layers, UV prime coat, film lower glue layer successively to top layer by bottom, imitates stone pattern transfer film, film upper glue layer, UV top coat layer.
Described PVC board layer thickness is 2cm; The back side is matte surface, and is provided with the latticed groove of semi-circular cross-section. Described UV prime coat is that UV priming paint roller coat UV-light illumination curing behind PVC board sheet material layers surface is formed. Described film lower glue layer is that UV transfer glue point glue flows flat, dry formation behind UV prime coat surface. Described imitative stone pattern transfer film is that the UV transfer film that UV has transferred imitative stone pattern is fitted in film lower glue layer surface and is formed. Described film upper glue layer is that UV transfer glue point glue is formed on imitative stone pattern transfer film surface. Described UV top coat layer is that UV-light illumination curing is formed after the showering UV finish paint of film upper glue layer surface.
Described PVC board sheet material layers comprises each component of following weight part number:
Preparation method is with embodiment 1.
Embodiment 3:
The present embodiment is used for the patch stone of indoor wall decoration, comprises PVC board sheet material layers, UV prime coat, film lower glue layer successively to top layer by bottom, imitates stone pattern transfer film, film upper glue layer, UV top coat layer.
Described PVC board layer thickness is 1.5cm; The back side is matte surface, and is provided with the latticed groove of semi-circular cross-section. Described UV prime coat is that UV priming paint roller coat UV-light illumination curing behind PVC board sheet material layers surface is formed. Described film lower glue layer is that UV transfer glue point glue flows flat, dry formation behind UV prime coat surface. Described imitative stone pattern transfer film is that the UV transfer film that UV has transferred imitative stone pattern is fitted in film lower glue layer surface and is formed. Described film upper glue layer is that UV transfer glue point glue is formed on imitative stone pattern transfer film surface. Described UV top coat layer is that UV-light illumination curing is formed after the showering UV finish paint of film upper glue layer surface.
Described PVC board sheet material layers comprises each component of following weight part number:
Preparation method is with embodiment 1.
The patch stone of embodiment 1-3 gained is carried out the detection of the performance index such as hardness, shock resistance degree, and detected result is in table 1. Wherein hardness is tested by Rockwell hardness test, and the testing standard of shock strength is GB/T1043-93, and the testing standard of tensile strength, elongation at break is GB/T1040-92, and the testing standard of yield strength, modulus in flexure is GB/T9341-2000.
Table 1
The raw material that embodiment is used, outside unless otherwise indicated, is applicable building material field and the commercially available industrial goods of PVC matrix material use.
The above embodiment of the present invention can not be used for limiting the present invention to the explanation of the present invention, and any change in the implication suitable with the claim book of the present invention and scope, all should think to be included in the scope of claim book.
Claims (9)
1. the patch stone for indoor wall decoration, it is characterized in that: described patch stone comprises PVC board sheet material layers successively by bottom to top layer, UV prime coat, film lower glue layer, UV have transferred imitative stone pattern imitative stone pattern transfer film, film upper glue layer, UV top coat layer, described PVC board sheet material layers comprises each component of following weight part number:
2. a kind of patch stone for indoor wall decoration according to claim 1, it is characterised in that: the model of described polyvinyl chloride is SG3 or SG4 or SG5.
3. a kind of patch stone for indoor wall decoration according to claim 1, it is characterised in that: described anti-impact modifier is the mixture of one or more in CPE, ACR, ABS, MBS.
4. a kind of patch stone for indoor wall decoration according to claim 1, it is characterised in that: described stablizer is the mixture of one or more in lead salt stabilizer, organic tin stablizer, calcium/zinc composite stabilizer, rare earth class stablizer.
5. a kind of patch stone for indoor wall decoration according to claim 1, it is characterised in that: described lubricant is the mixture of one or more in calcium stearate, paraffin, oxidized polyethlene wax, ester type waxes.
6. a kind of patch stone for indoor wall decoration according to claim 1, it is characterised in that: described film lower glue layer is that UV transfer glue point glue becomes; Described film upper glue layer is that UV transfer glue point glue becomes.
7. a kind of patch stone for indoor wall decoration according to claim 1, it is characterised in that: the thickness of described PVC board sheet material layers is 1-2cm.
8. a kind of patch stone for indoor wall decoration according to claim 1, it is characterised in that: the back side of described PVC board sheet material layers is matte surface, and is provided with latticed groove, and the cross-sectional shape of described groove is semicircle.
9. the preparation method of a kind of patch stone for indoor wall decoration according to claim 8, it is characterised in that comprise the following steps:
(1) preparation of PVC board:
A () takes each raw material of formula ratio, add and carry out high-speed mixing in high-speed mixer, and be heated to 105-120 DEG C;
B () puts into cold mixed, below dry blend combination cooling to 50 DEG C;
C () metered charge carries out extrusion moulding to conical double screw extruder, screw rod Oil-temperature control is between 80-120 DEG C, spiral shell cylinder temperature temperature control is between 130-190 DEG C, merging core temperature is between 130-160 DEG C, and die temperature is between 150-180 DEG C, and die lip temperature controls between 130-160 DEG C, molten materials enters merging core through screw rod and branches to coat-hanger die, it is extruded at head shaping, carries out press polish and preliminary cooling through three-roll press-polishing trimming machine, obtain PVC sheet forming;
(2) carry out frosted process at the back side of PVC sheet forming, and the latticed groove of cross section semicircle is set;
(3) at surface roller coating or the spray painting UV primer of PVC sheet forming, UV-light illumination curing, forms UV prime coat;
(4) by UV transfer glue point glue on UV prime coat surface, and make its stream flat, form film lower glue layer;
(5) the UV transfer film that UV has transferred imitative stone pattern is fitted in film lower glue layer surface, row's bubble, and room temperature leaves standstill 3-5min, makes the laminating of imitative stone pattern transfer film firmly;
(6) by UV transfer glue point glue on imitative stone pattern transfer film surface, and make its stream flat, form film upper glue layer;
(7) at the surface showering of film upper glue layer or spraying UV finish paint, UV-light illumination curing, UV top coat layer;
(8) composite sheet obtained is cut by size, obtain the patch stone for indoor wall decoration.
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201915581U (en) * | 2011-01-21 | 2011-08-03 | 程照 | Reflective insulation surface mounting stone |
CN201953014U (en) * | 2011-01-21 | 2011-08-31 | 程照 | Novel patch stone |
CN202108188U (en) * | 2011-05-16 | 2012-01-11 | 宁波华宝石节能建材有限公司 | Energy-saving chip-stone integrated insulation board |
CN102864890A (en) * | 2012-09-03 | 2013-01-09 | 宁波华宝石节能建材有限公司 | Paster stone as well as making method and construction method of paster stone |
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Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN201915581U (en) * | 2011-01-21 | 2011-08-03 | 程照 | Reflective insulation surface mounting stone |
CN201953014U (en) * | 2011-01-21 | 2011-08-31 | 程照 | Novel patch stone |
CN202108188U (en) * | 2011-05-16 | 2012-01-11 | 宁波华宝石节能建材有限公司 | Energy-saving chip-stone integrated insulation board |
CN102864890A (en) * | 2012-09-03 | 2013-01-09 | 宁波华宝石节能建材有限公司 | Paster stone as well as making method and construction method of paster stone |
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