CN103992712B - A kind of automatically cleaning air type exterior coating and preparation method thereof - Google Patents
A kind of automatically cleaning air type exterior coating and preparation method thereof Download PDFInfo
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- 239000011248 coating agent Substances 0.000 title claims abstract description 40
- 238000000576 coating method Methods 0.000 title claims abstract description 40
- 238000004140 cleaning Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 44
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims abstract description 26
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229940112669 cuprous oxide Drugs 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000013530 defoamer Substances 0.000 claims abstract description 13
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002562 thickening agent Substances 0.000 claims abstract description 11
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010445 mica Substances 0.000 claims abstract description 9
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 9
- 239000003755 preservative agent Substances 0.000 claims abstract description 9
- 230000002335 preservative effect Effects 0.000 claims abstract description 9
- 239000010456 wollastonite Substances 0.000 claims abstract description 9
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-YPZZEJLDSA-N carbon-10 atom Chemical class [10C] OKTJSMMVPCPJKN-YPZZEJLDSA-N 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 13
- 239000002002 slurry Substances 0.000 claims description 10
- -1 acids ammonium salt Chemical class 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 4
- 229910000366 copper(II) sulfate Inorganic materials 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 230000004044 response Effects 0.000 claims description 4
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 3
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- 235000010981 methylcellulose Nutrition 0.000 claims description 3
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical group CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 230000002421 anti-septic effect Effects 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 229940047670 sodium acrylate Drugs 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 4
- 239000003344 environmental pollutant Substances 0.000 abstract description 4
- 231100000719 pollutant Toxicity 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 238000001179 sorption measurement Methods 0.000 abstract description 3
- 239000001569 carbon dioxide Substances 0.000 abstract description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000011109 contamination Methods 0.000 abstract description 2
- 238000010411 cooking Methods 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 239000003517 fume Substances 0.000 abstract description 2
- 238000005286 illumination Methods 0.000 abstract description 2
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 2
- 230000002787 reinforcement Effects 0.000 abstract description 2
- 239000002341 toxic gas Substances 0.000 abstract description 2
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 3
- 239000003125 aqueous solvent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 210000001533 respiratory mucosa Anatomy 0.000 description 2
- 210000002345 respiratory system Anatomy 0.000 description 2
- 206010010741 Conjunctivitis Diseases 0.000 description 1
- 206010058467 Lung neoplasm malignant Diseases 0.000 description 1
- 206010057190 Respiratory tract infections Diseases 0.000 description 1
- 206010046306 Upper respiratory tract infection Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001555 benzenes Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 208000030603 inherited susceptibility to asthma Diseases 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 210000003928 nasal cavity Anatomy 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 208000007442 rickets Diseases 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of automatically cleaning air type exterior coating and preparation method thereof, automatically cleaning air type exterior coating includes following component and is prepared from by mass percentage: organic emulsion 40%～45%, ultrafine cuprous oxide powder 2%～8%, powdered activated carbon 10%～15%, superfine silicon dioxide powder 5%～8%, ultra-fine wollastonite in powder 3%～7%, superfine talcum powder 3%～6%, ultrafine mica powder 3%～6%, thickening agent 0.6%～1.1%, dispersant 0.5%～0.8%, defoamer 0.2%～0.4%, coalescents 1%～3%, preservative 0.1%～0.4%, water 15%～20%. The present invention has the advantage that working condition is simple, purify air etc. Prepared automatically cleaning air type exterior coating, both the particulate pollutant in the micro-porous adsorption air of powdered activated carbon can have been utilized, substantially reduce haze weather, can also be the toxic gas such as the various cooking fumes in decomposable asymmetric choice net air, benzene class under visible light illumination, being free of contamination water and carbon dioxide organic pollutant degradation, namely this coating has the functions such as the minimizing haze weather of reinforcement, Cleaning Air.
Description
Technical field
The invention belongs to the technical field of building coating, be specifically related to a kind of automatically cleaning air type exterior coating and preparation method thereof.
Background technology
In recent years, aggravation along with global air pollution, lasting haze weather more and more occurs in daily life, can the respiratory tract of human body be damaged, the substantial amounts of granule that floats in air, dust, pollutant virus etc., once be sucked by human body, will stimulate and destroy respiratory mucosa, making nasal cavity become dry, destroying respiratory mucosa defence capability, antibacterial enters respiratory tract, it is easy to cause upper respiratory tract infection. Additionally, it can also cause the symptoms such as bronchial asthma, pulmonary carcinoma, conjunctivitis, rickets of child, it becomes the another killer affecting people's living environment, has badly influenced the healthy of people and living environment. Along with the enhancing gradually of the fast development of China's economy and people's environmental consciousness, people are more and more higher to the requirement of atmospheric environment especially outdoor air.
Therefore, the harmful gas in air is removed great to improving health of people horizontal terms. The exterior coating related at present has a lot, a kind of environment-friendly type building exterior coating (publication number is CN1O304503A) such as Shen Qunhua application, this coating have pollution-free, manufacture method is simple, equipment needed thereby is few, hardening time is short, require low, the beneficial effect such as fungicidal properties is excellent for the environmental condition of coating, but it is the environmental protection to self coating, it is impossible to clean air; Some are equally also had to reach to purify the atmospheric cleaning exterior coating of air by light-catalyzed reaction, a kind of environment-friendly type photocatalystic outer wall coating such as Shanghai University's application and preparation method thereof (application publication number is CN11546584A), but this coating producing process is special, cost intensive, and the TiO used2The polluter that catalyst could effectively can only be degraded in air under the irradiation of ultraviolet light, therefore can not get market and popularize.
Summary of the invention
It is an object of the invention to provide can at visible ray effect a kind of automatically cleaning air type exterior coating issuing third contact of a total solar or lunar eclipse catalytic action and preparation method thereof.
To achieve these goals, the present invention is by the following technical solutions: a kind of automatically cleaning air type exterior coating, described coating is to include following component to be prepared from by mass percentage: organic emulsion 40%～45%, ultrafine cuprous oxide powder 2%～8%, powdered activated carbon 10%～15%, superfine silicon dioxide powder 5%～8%, ultra-fine wollastonite in powder 3%～7%, superfine talcum powder 3%～6%, ultrafine mica powder 3%～6%, thickening agent 0.6%～1.1%, dispersant 0.5%～0.8%, defoamer 0.2%～0.4%, coalescents 1%～3%, preservative 0.1%～0.4%, water 15%～20%.
Described thickening agent is methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose or hydroxypropyl methyl cellulose.
Described dispersant is sodium acrylate dipersant SN-5040 or polycarboxylic acids ammonium salt dispersant SN-5029.
Described defoamer is defoamer OS-5202.
Described coalescents is coalescents alcohol ester 12, propylene glycol phenylate or ethylene glycol phenyl ether.
Described preservative is coating antiseptic N-396.
Described organic emulsion is silicone modified acrylic resin.
The preparation method of a kind of automatically cleaning air type exterior coating, comprises the following steps:
(1) putting in sand mill by ultrafine cuprous oxide powder, water and dispersant, being mixed and made into ultrafine cuprous oxide powder concentration is the serosity of 10%～25%;
(2) superfine silicon dioxide powder, ultra-fine wollastonite in powder, superfine talcum powder, ultrafine mica powder, defoamer, coalescents, preservative are joined in high speed disperser, be mixed and made into slurry;
(3) by the slurry mix homogeneously in organic emulsion, ultrafine cuprous oxide powder serosity and step 2, and dripping thickening agent, namely stirring 1h can be made into automatically cleaning air type exterior coating, obtained coating finally joins sand mill and grinds twice, filter, discharging barrelling.
Described ultrafine cuprous oxide powder adopts following steps to prepare: prepare the CuSO of 1.0mol/L respectively4And 1.0mol/LC6H12O6The NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction solution heated constant temperature to 50 DEG C, first by CuSO4Solution and NaOH solution mix and blend in reactor prepares Cu (OH)2Presoma, then by C6H12O6Solution adds reactor, continues stirring reaction; Question response complete after centrifugation, successively wash respectively 3 times with deionized water and dehydrated alcohol, finally sample be placed in drying baker, dry at 45 DEG C, namely obtain ultrafine cuprous oxide powder.
Photocatalysis oxidation reaction can be there is under visible light in wherein contained in coating ultrafine cuprous oxide powder, and contained powdered activated carbon can utilize the particulate pollutant in micro-porous adsorption air, therefore this coating have easy production, cheap, purify air, substantially reduce the advantages such as haze weather.
The present invention has the advantage that working condition is simple, purify air etc. Prepared automatically cleaning air type exterior coating, both the particulate pollutant in the micro-porous adsorption air of powdered activated carbon can have been utilized, substantially reduce haze weather, can also be the toxic gas such as the various cooking fumes in decomposable asymmetric choice net air, benzene class under visible light illumination, being free of contamination water and carbon dioxide organic pollutant degradation, namely this coating has the functions such as the minimizing haze weather of reinforcement, Cleaning Air.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1
Ultrafine cuprous oxide powder adopts following steps to prepare: prepare the CuSO of 1.0mol/L respectively4And 1.0mol/LC6H12O6The NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction solution heated constant temperature to 50 DEG C, first by CuSO4Solution and NaOH solution mix and blend in reactor prepares Cu (OH)2Presoma, then by C6H12O6Solution adds reactor, continues stirring reaction; Question response complete after centrifugation, successively wash respectively 3 times with deionized water and dehydrated alcohol, finally sample be placed in drying baker, dry at 45 DEG C, namely obtain ultrafine cuprous oxide powder.
Weigh following component by mass percentage: silicone modified acrylic resin is 40%, ultrafine cuprous oxide powder is 5%, powdered activated carbon is 10%, and superfine silicon dioxide powder is 7%, and ultra-fine wollastonite in powder is 6%, superfine talcum powder is 5%, ultrafine mica powder is 6%, and thickening agent methylcellulose is 0.8%, and dispersant SN-5029 is 0.6%, defoamer OS-5202 is 0.4%, and coalescents alcohol ester 12 is 2%, Liquid BPF-396 is 0.2%, water is 15%.
Putting in sand mill by ultrafine cuprous oxide powder, aqueous solvent and dispersant, be mixed and made into serosity, making ultrafine cuprous oxide powder concentration of slurry is the serosity of 10%～25%;
Powdered activated carbon, superfine silicon dioxide powder, ultra-fine wollastonite in powder, superfine talcum powder, ultrafine mica powder, defoamer, coalescents, preservative are joined in high speed disperser, is mixed and made into slurry;
By silicone modified acrylic resin, ultrafine cuprous oxide powder serosity and above-mentioned slurry mix homogeneously, and dripping thickening agent after required viscosity, namely stirring 1h can be made into automatically cleaning air type exterior coating, obtained coating finally joins sand mill and grinds twice, filter, discharging barrelling.
The coating of above-mentioned formula is applied directly on external wall and uses, dry 1h under room temperature.
Embodiment 2
Ultrafine cuprous oxide powder adopts following steps to prepare: prepare the CuSO of 1.0mol/L respectively4And 1.0mol/LC6H12O6The NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction solution heated constant temperature to 50 DEG C, first by CuSO4Solution and NaOH solution mix and blend in reactor prepares Cu (OH)2Presoma, then by C6H12O6Solution adds reactor, continues stirring reaction; Question response complete after centrifugation, successively wash respectively 3 times with deionized water and dehydrated alcohol, finally sample be placed in drying baker, dry at 45 DEG C, namely obtain ultrafine cuprous oxide powder.
Weigh following component by mass percentage: silicone modified acrylic resin is 42%, ultrafine cuprous oxide powder is 5%, powdered activated carbon is 12%, and superfine silicon dioxide powder is 5%, and ultra-fine wollastonite in powder is 4%, superfine talcum powder is 4%, ultrafine mica powder is 4%, and thickening agent hydroxypropyl methyl cellulose is 0.8%, and dispersant SN-5040 is 0.6%, defoamer OS-5202 is 0.4%, and PPH is 2%, Liquid BPF-396 is 0.2%, water is 20% composition.
Putting in sand mill by ultrafine cuprous oxide powder, aqueous solvent and dispersant, be mixed and made into serosity, making ultrafine cuprous oxide powder concentration of slurry is the serosity of 10%～25%;
Powdered activated carbon, superfine silicon dioxide powder, ultra-fine wollastonite in powder, superfine talcum powder, ultrafine mica powder, defoamer, coalescents, preservative are joined in high speed disperser, is mixed and made into slurry;
By silicone modified acrylic resin, ultrafine cuprous oxide powder serosity and above-mentioned slurry mix homogeneously, and dripping thickening agent after required viscosity, namely stirring 1h can be made into automatically cleaning air type exterior coating, obtained coating finally joins sand mill and grinds twice, filter, discharging barrelling.
The coating of above-mentioned formula is applied directly on external wall and uses, dry 1h under room temperature.
Although the present invention is with preferred embodiment openly as above; but embodiment is not for limiting the present invention, any it is familiar with this those skilled in the art, without departing from the spirit and scope of the invention; can make various changes or retouch from working as, but same within protection scope of the present invention. Therefore protection scope of the present invention should with being as the criterion that claims hereof protection domain defines.
Claims (3)
1. an automatically cleaning air type exterior coating, it is characterized in that described coating is to include following component to be prepared from by mass percentage: organic emulsion 40%～45%, ultrafine cuprous oxide powder 2%～8%, powdered activated carbon 10%～15%, superfine silicon dioxide powder 5%～8%, ultra-fine wollastonite in powder 3%～7%, superfine talcum powder 3%～6%, ultrafine mica powder 3%～6%, thickening agent 0.6%～1.1%, dispersant 0.5%～0.8%, defoamer 0.2%～0.4%, coalescents 1%～3%, preservative 0.1%～0.4%, water 15%～20%;
Described thickening agent is methylcellulose, carboxymethyl cellulose, hydroxyethyl cellulose or hydroxypropyl methyl cellulose;
Described dispersant is sodium acrylate dipersant SN-5040 or polycarboxylic acids ammonium salt dispersant SN-5029;
Described defoamer is defoamer OS-5202;
Described coalescents is coalescents alcohol ester 12, propylene glycol phenylate or ethylene glycol phenyl ether;
Described preservative is coating antiseptic N-396;
Described organic emulsion is silicone modified acrylic resin.
2. the preparation method of an automatically cleaning air type exterior coating according to claim 1, it is characterised in that comprise the following steps:
(1) ultrafine cuprous oxide powder, water and dispersant are put in sand mill, be mixed and made into the ultrafine cuprous oxide powder serosity that concentration is 10%～25%;
(2) superfine silicon dioxide powder, ultra-fine wollastonite in powder, superfine talcum powder, ultrafine mica powder, defoamer, coalescents, preservative are joined in high speed disperser, be mixed and made into slurry;
(3) by the slurry mix homogeneously in organic emulsion, ultrafine cuprous oxide powder serosity and step (2), and dripping thickening agent, namely stirring 1h can be made into automatically cleaning air type exterior coating, obtained coating finally joins sand mill and grinds twice, filter, discharging barrelling.
3. want the preparation method of automatically cleaning air type exterior coating described in 2 according to right, it is characterised in that: described ultrafine cuprous oxide powder adopts following steps to prepare: prepare the CuSO of 1.0mol/L respectively4And 1.0mol/LC6H12O6The NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction solution heated constant temperature to 50 DEG C, first by CuSO4Solution and NaOH solution mix and blend in reactor prepares Cu (OH)2Presoma, then by C6H12O6Solution adds reactor, continues stirring reaction; Question response complete after centrifugation, successively wash respectively 3 times with deionized water and dehydrated alcohol, finally sample be placed in drying baker, dry at 45 DEG C, namely obtain ultrafine cuprous oxide powder.
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| CN201410197513.6A CN103992712B (en) | 2014-05-12 | 2014-05-12 | A kind of automatically cleaning air type exterior coating and preparation method thereof |
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| CN201410197513.6A CN103992712B (en) | 2014-05-12 | 2014-05-12 | A kind of automatically cleaning air type exterior coating and preparation method thereof |
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| CN103992712B true CN103992712B (en) | 2016-06-15 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104312350A (en) * | 2014-11-11 | 2015-01-28 | 合肥不老传奇保健科技有限公司 | Composite silicon-acrylic acid exterior wall coating material with high solid content and high stability and preparation method thereof |
| CN106700896A (en) * | 2016-12-05 | 2017-05-24 | 江西龙正科技发展有限公司 | Anti-haze coating |
| CN108485407A (en) * | 2018-02-01 | 2018-09-04 | 东莞市佳乾新材料科技有限公司 | A kind of indoor purifying air type water paint |
| CN109897575B (en) * | 2019-03-15 | 2021-07-02 | 中烯新材料(福建)股份有限公司 | Haze-reducing coating for building wall and preparation method thereof |
| CN112795258A (en) * | 2021-01-12 | 2021-05-14 | 贵州星汉科技有限公司 | Environment-friendly exterior wall coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824262A (en) * | 2010-04-12 | 2010-09-08 | 徐州工业职业技术学院 | Novel self-cleaning coating for external wall and preparation method thereof |
| CN102139909A (en) * | 2011-02-22 | 2011-08-03 | 南京大学 | Method for synthesizing micron-nano-sized cuprous oxide micropowder by controlling shape of micron-nano-sized cuprous oxide micropowder |
| CN103382343A (en) * | 2013-07-01 | 2013-11-06 | 吴江市物华五金制品有限公司 | Coating for outer walls and preparation method thereof |
| CN103468046A (en) * | 2013-08-23 | 2013-12-25 | 洛阳好生活环保科技有限公司 | Activated carbon finishing paint |
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| JPH03179063A (en) * | 1989-09-27 | 1991-08-05 | Saiden Kagaku Kk | Aqueous algae-, fungi-, and stainproof coating composition |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101824262A (en) * | 2010-04-12 | 2010-09-08 | 徐州工业职业技术学院 | Novel self-cleaning coating for external wall and preparation method thereof |
| CN102139909A (en) * | 2011-02-22 | 2011-08-03 | 南京大学 | Method for synthesizing micron-nano-sized cuprous oxide micropowder by controlling shape of micron-nano-sized cuprous oxide micropowder |
| CN103382343A (en) * | 2013-07-01 | 2013-11-06 | 吴江市物华五金制品有限公司 | Coating for outer walls and preparation method thereof |
| CN103468046A (en) * | 2013-08-23 | 2013-12-25 | 洛阳好生活环保科技有限公司 | Activated carbon finishing paint |
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