CN103992712A - A self-cleaning air type exterior wall coating material and a preparing method thereof - Google Patents
A self-cleaning air type exterior wall coating material and a preparing method thereof Download PDFInfo
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- CN103992712A CN103992712A CN201410197513.6A CN201410197513A CN103992712A CN 103992712 A CN103992712 A CN 103992712A CN 201410197513 A CN201410197513 A CN 201410197513A CN 103992712 A CN103992712 A CN 103992712A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 46
- 238000000576 coating method Methods 0.000 title claims abstract description 46
- 238000004140 cleaning Methods 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 44
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 claims abstract description 26
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 claims abstract description 26
- 229940112669 cuprous oxide Drugs 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010445 mica Substances 0.000 claims abstract description 9
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 9
- 239000010456 wollastonite Substances 0.000 claims abstract description 9
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 24
- 239000002002 slurry Substances 0.000 claims description 20
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 238000004581 coalescence Methods 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- 230000008719 thickening Effects 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 8
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 6
- -1 poly carboxylic acid ammonium salt Chemical class 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 4
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 239000010408 film Substances 0.000 claims description 4
- 230000004044 response Effects 0.000 claims description 4
- 229920000609 methyl cellulose Polymers 0.000 claims description 3
- 239000001923 methylcellulose Substances 0.000 claims description 3
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical group CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 claims description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 claims description 2
- 230000002421 anti-septic effect Effects 0.000 claims description 2
- OKTJSMMVPCPJKN-YPZZEJLDSA-N carbon-10 atom Chemical compound [10C] OKTJSMMVPCPJKN-YPZZEJLDSA-N 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 229940047670 sodium acrylate Drugs 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 8
- 229910052799 carbon Inorganic materials 0.000 abstract description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003344 environmental pollutant Substances 0.000 abstract description 3
- 231100000719 pollutant Toxicity 0.000 abstract description 3
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- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 1
- 239000001569 carbon dioxide Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
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Landscapes
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a self-cleaning air type exterior wall coating material and a preparing method thereof. The coating material comprises following components by weight: 40-45% of organic emulsion, 2-8% of superfine cuprous oxide powder, 10-15% of powdered active carbon, 5-8% of superfine silicon dioxide powder, 3-7% of superfine wollastonite powder, 3-6% of superfine talcum powder, 3-6% of superfine mica powder, 0.6-1.1% of a thickening agent, 0.5-0.8% of a dispersant, 0.2-0.4% of a defoaming agent, 1-3% of a film coalescing aid, 0.1-0.4% of an aseptic and 15-20% of water. The coating material and the preparing method have advantages of simple production conditions, capability of purifying air, and the like. The prepared self-cleaning air type coating material adsorbs particle pollutants in air by utilization of micropores of the powdered active carbon, thus significantly reducing hazy weather, and the coating material also decomposes various kinds of oil fume, benzene type compounds, and other toxic gases under exposure of visible light, thus decomposing organic pollutants into pollution-free water and carbon dioxide, and therefore the coating material has enhanced functions of reducing the hazy weather, purifying the air, and the like.
Description
Technical field
The invention belongs to the technical field of building coating, be specifically related to a kind of automatically cleaning air type exterior coating and preparation method thereof.
Background technology
In recent years, aggravation along with global air pollution, lasting haze weather more and more appears in daily life, can damage to the respiratory tract of human body in air, float a large amount of particles, dust, pollutent virus etc., once be sucked by human body, will stimulate and destroy respiratory mucosa, make nasal cavity become dry, destroy respiratory mucosa defence capability, bacterium enters respiratory tract, easily causes upper respiratory tract infection.In addition, it can also cause the symptoms such as bronchial asthma, lung cancer, conjunctivitis, rickets of child, and it becomes the another killer who affects people's living environment, has badly influenced people's healthy and living environment.Along with the fast development of China's economy and the enhancing gradually of people's environmental consciousness, people are more and more higher to the requirement of atmospheric environment especially outside air.
Therefore, remove airborne obnoxious flavour significant to improving health of people level.The exterior coating relating at present has a lot, as a kind of environment-friendly type building exterior coating (publication number is CN 1O304503 A) of Shen Qunhua application, the beneficial effects such as that this coating has is pollution-free, making method is simple, required equipment is few, set time is short, low for the requirement for environmental conditions applying, fungicidal properties is excellent, but it is the environmental protection to self coating just, cannot clean air; Equally also there are some by light-catalyzed reaction, to reach the atmospheric cleaning exterior coating purifying air, as a kind of environment-friendly type photocatalystic outer wall coating of Shanghai University's application and preparation method thereof (application publication number is CN 11546584 A), but this coating producing process is special, cost is expensive, and the TiO using
2the pollution substance that catalyzer can only could effectively be degraded in atmosphere under the irradiation of UV-light, therefore it is universal to can not get market.
Summary of the invention
The object of the present invention is to provide and can issue in visible ray effect a kind of automatically cleaning air type exterior coating of third contact of a total solar or lunar eclipse katalysis and preparation method thereof.
To achieve these goals, the present invention is by the following technical solutions: a kind of automatically cleaning air type exterior coating, described coating is to comprise that following component is prepared from by mass percentage: organic emulsion 40%～45%, ultrafine cuprous oxide powder 2%～8%, powdered carbon 10%～15%, superfine silicon dioxide powder 5%～8%, ultra-fine wollastonite powder 3%～7%, superfine talcum powder 3%～6%, ultrafine mica powder 3%～6%, thickening material 0.6%～1.1%, dispersion agent 0.5%～0.8%, defoamer 0.2%～0.4%, film coalescence aid 1%～3%, sanitas 0.1%～0.4%, water 15%～20%.
Described thickening material is methylcellulose gum, carboxymethyl cellulose, Natvosol or Vltra tears.
Described dispersion agent is sodium acrylate dipersant SN-5040 or poly carboxylic acid ammonium salt dispersion agent SN-5029.
Described defoamer is defoamer OS-5202.
Described film coalescence aid is film coalescence aid alcohol ester 12, propylene glycol phenylate or ethylene glycol phenyl ether.
Described sanitas is coating antiseptic N-396.
Described organic emulsion is silicone modified acrylic resin.
A preparation method for automatically cleaning air type exterior coating, comprises the following steps:
(1) ultrafine cuprous oxide powder, water and dispersion agent are put into sand mill, be mixed and made into the slurries that ultrafine cuprous oxide powder concentration is 10%～25%;
(2) superfine silicon dioxide powder, ultra-fine wollastonite powder, superfine talcum powder, ultrafine mica powder, defoamer, film coalescence aid, sanitas are joined in high speed disperser, be mixed and made into slurry;
(3) slurry in organic emulsion, ultrafine cuprous oxide powder slurries and step 2 is mixed, and drip thickening material, and stir 1h and can be made into automatically cleaning air type exterior coating, finally prepared coating is joined to sand mill and grind twice, filter discharging barrelling.
Described ultrafine cuprous oxide powder adopts following steps preparation: the CuSO for preparing respectively 1.0mol/L
4and 1.0mol/LC
6h
12o
6the NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction soln heated constant temperature to 50 ℃, first by CuSO
4solution and NaOH solution mix and blend in reactor are prepared Cu (OH)
2presoma, then by C
6h
12o
6solution adds reactor, continues stirring reaction; Centrifugation after question response completes, successively washs respectively 3 times with deionized water and dehydrated alcohol, finally sample is placed in to loft drier, dry at 45 ℃, obtains ultrafine cuprous oxide powder.
Wherein in coating, contained ultrafine cuprous oxide powder can issue third contact of a total solar or lunar eclipse catalytic oxidation at visible ray, and contained powdered carbon can utilize the airborne particulate pollutant of micro-porous adsorption, thus this coating have easy production, cheap, purify air, significantly reduce the advantages such as haze weather.
The present invention has advantages of that working condition is simple, purify air etc.Prepared automatically cleaning air type exterior coating, both can utilize the airborne particulate pollutant of micro-porous adsorption of powdered carbon, significantly reduce haze weather, also can under radiation of visible light, can decompose the toxic gas such as various cooking fumes in atmosphere, benzene class, organic pollutant degradation, be free of contamination water and carbonic acid gas, this coating has the function such as minimizing haze weather, Cleaning Air of reinforcement.
Embodiment
Below in conjunction with specific embodiment, the present invention is described further.
Embodiment 1
Ultrafine cuprous oxide powder adopts following steps preparation: the CuSO for preparing respectively 1.0mol/L
4and 1.0mol/LC
6h
12o
6the NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction soln heated constant temperature to 50 ℃, first by CuSO
4solution and NaOH solution mix and blend in reactor are prepared Cu (OH)
2presoma, then by C
6h
12o
6solution adds reactor, continues stirring reaction; Centrifugation after question response completes, successively washs respectively 3 times with deionized water and dehydrated alcohol, finally sample is placed in to loft drier, dry at 45 ℃, obtains ultrafine cuprous oxide powder.
Take by mass percentage following component: silicone modified acrylic resin is 40%, ultrafine cuprous oxide powder is 5%, powdered carbon is 10%, and superfine silicon dioxide powder is 7%, and ultra-fine wollastonite powder is 6%, superfine talcum powder is 5%, ultrafine mica powder is 6%, and thickening material methylcellulose gum is 0.8%, and dispersion agent SN-5029 is 0.6%, defoamer OS-5202 is 0.4%, and film coalescence aid alcohol ester 12 is 2%, Liquid BPF-396 are 0.2%, water is 15%.
Ultrafine cuprous oxide powder, aqueous solvent and dispersion agent are put into sand mill, be mixed and made into slurries, make the slurries that ultrafine cuprous oxide powder concentration of slurry is 10%～25%;
Powdered carbon, superfine silicon dioxide powder, ultra-fine wollastonite powder, superfine talcum powder, ultrafine mica powder, defoamer, film coalescence aid, sanitas are joined in high speed disperser, be mixed and made into slurry;
Silicone modified acrylic resin, ultrafine cuprous oxide powder slurries and above-mentioned slurry are mixed, and drip thickening material after required viscosity, and stir 1h and can be made into automatically cleaning air type exterior coating, finally prepared coating is joined to sand mill and grind twice, filter discharging barrelling.
The coating of above-mentioned formula is directly coated on external wall and is used, dry 1h under normal temperature.
Embodiment 2
Ultrafine cuprous oxide powder adopts following steps preparation: the CuSO for preparing respectively 1.0mol/L
4and 1.0mol/LC
6h
12o
6the NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction soln heated constant temperature to 50 ℃, first by CuSO
4solution and NaOH solution mix and blend in reactor are prepared Cu (OH)
2presoma, then by C
6h
12o
6solution adds reactor, continues stirring reaction; Centrifugation after question response completes, successively washs respectively 3 times with deionized water and dehydrated alcohol, finally sample is placed in to loft drier, dry at 45 ℃, obtains ultrafine cuprous oxide powder.
Take by mass percentage following component: silicone modified acrylic resin is 42%, ultrafine cuprous oxide powder is 5%, powdered carbon is 12%, and superfine silicon dioxide powder is 5%, and ultra-fine wollastonite powder is 4%, superfine talcum powder is 4%, ultrafine mica powder is 4%, and thickening material Vltra tears is 0.8%, and dispersion agent SN-5040 is 0.6%, defoamer OS-5202 is 0.4%, and PPH is 2%, Liquid BPF-396 are 0.2%, water is 20% composition.
Ultrafine cuprous oxide powder, aqueous solvent and dispersion agent are put into sand mill, be mixed and made into slurries, make the slurries that ultrafine cuprous oxide powder concentration of slurry is 10%～25%;
Powdered carbon, superfine silicon dioxide powder, ultra-fine wollastonite powder, superfine talcum powder, ultrafine mica powder, defoamer, film coalescence aid, sanitas are joined in high speed disperser, be mixed and made into slurry;
Silicone modified acrylic resin, ultrafine cuprous oxide powder slurries and above-mentioned slurry are mixed, and drip thickening material after required viscosity, and stir 1h and can be made into automatically cleaning air type exterior coating, finally prepared coating is joined to sand mill and grind twice, filter discharging barrelling.
The coating of above-mentioned formula is directly coated on external wall and is used, dry 1h under normal temperature.
Although the present invention with preferred embodiment openly as above; but embodiment is not for limiting the present invention, be anyly familiar with this skill person, without departing from the spirit and scope of the invention; from working as, can make various changes or retouch, but equally within protection scope of the present invention.What therefore protection scope of the present invention should be defined with the application's claim protection domain is as the criterion.
Claims (9)
1. an automatically cleaning air type exterior coating, it is characterized in that described coating is to comprise that following component is prepared from by mass percentage: organic emulsion 40%～45%, ultrafine cuprous oxide powder 2%～8%, powdered carbon 10%～15%, superfine silicon dioxide powder 5%～8%, ultra-fine wollastonite powder 3%～7%, superfine talcum powder 3%～6%, ultrafine mica powder 3%～6%, thickening material 0.6%～1.1%, dispersion agent 0.5%～0.8%, defoamer 0.2%～0.4%, film coalescence aid 1%～3%, sanitas 0.1%～0.4%, water 15%～20%.
2. automatically cleaning air type exterior coating according to claim 1, is characterized in that: described thickening material is methylcellulose gum, carboxymethyl cellulose, Natvosol or Vltra tears.
3. automatically cleaning air type exterior coating according to claim 1, is characterized in that: described dispersion agent is sodium acrylate dipersant SN-5040 or poly carboxylic acid ammonium salt dispersion agent SN-5029.
4. automatically cleaning air type exterior coating according to claim 1, is characterized in that: described defoamer is defoamer OS-5202.
5. automatically cleaning air type exterior coating according to claim 1, is characterized in that: described film coalescence aid is film coalescence aid alcohol ester 12, propylene glycol phenylate or ethylene glycol phenyl ether.
6. automatically cleaning air type exterior coating according to claim 1, is characterized in that: described sanitas is coating antiseptic N-396.
7. automatically cleaning air type exterior coating according to claim 1, is characterized in that: described organic emulsion is silicone modified acrylic resin.
8. according to a preparation method for claim 1 to 7 coating described in any, it is characterized in that comprising the following steps:
(1) ultrafine cuprous oxide powder, water and dispersion agent are put into sand mill, be mixed and made into the slurries that ultrafine cuprous oxide powder concentration is 10%～25%;
(2) superfine silicon dioxide powder, ultra-fine wollastonite powder, superfine talcum powder, ultrafine mica powder, defoamer, film coalescence aid, sanitas are joined in high speed disperser, be mixed and made into slurry;
(3) slurry in organic emulsion, ultrafine cuprous oxide powder slurries and step 2 is mixed, and drip thickening material, and stir 1h and can be made into automatically cleaning air type exterior coating, finally prepared coating is joined to sand mill and grind twice, filter discharging barrelling.
9. preparation method according to claim 8, is characterized in that: described ultrafine cuprous oxide powder adopts following steps preparation: the CuSO for preparing respectively 1.0mol/L
4and 1.0mol/LC
6h
12o
6the NaOH solution of solution and 5.0mol/L, its volume ratio is 2:2:1; By above-mentioned 3 kinds of reaction soln heated constant temperature to 50 ℃, first by CuSO
4solution and NaOH solution mix and blend in reactor are prepared Cu (OH)
2presoma, then by C
6h
12o
6solution adds reactor, continues stirring reaction; Centrifugation after question response completes, successively washs respectively 3 times with deionized water and dehydrated alcohol, finally sample is placed in to loft drier, dry at 45 ℃, obtains ultrafine cuprous oxide powder.
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| CN201410197513.6A CN103992712B (en) | 2014-05-12 | 2014-05-12 | A kind of automatically cleaning air type exterior coating and preparation method thereof |
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|---|---|---|---|
| CN201410197513.6A CN103992712B (en) | 2014-05-12 | 2014-05-12 | A kind of automatically cleaning air type exterior coating and preparation method thereof |
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| CN103992712B CN103992712B (en) | 2016-06-15 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312350A (en) * | 2014-11-11 | 2015-01-28 | 合肥不老传奇保健科技有限公司 | Composite silicon-acrylic acid exterior wall coating material with high solid content and high stability and preparation method thereof |
| CN106700896A (en) * | 2016-12-05 | 2017-05-24 | 江西龙正科技发展有限公司 | Anti-haze coating |
| CN108485407A (en) * | 2018-02-01 | 2018-09-04 | 东莞市佳乾新材料科技有限公司 | A kind of indoor purifying air type water paint |
| CN109897575A (en) * | 2019-03-15 | 2019-06-18 | 成都新柯力化工科技有限公司 | A kind of building wall is with subtracting haze coating and preparation method |
| CN112795258A (en) * | 2021-01-12 | 2021-05-14 | 贵州星汉科技有限公司 | Environment-friendly exterior wall coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03179063A (en) * | 1989-09-27 | 1991-08-05 | Saiden Kagaku Kk | Aqueous algae-, fungi-, and stainproof coating composition |
| CN101824262A (en) * | 2010-04-12 | 2010-09-08 | 徐州工业职业技术学院 | Novel self-cleaning coating for external wall and preparation method thereof |
| CN102139909A (en) * | 2011-02-22 | 2011-08-03 | 南京大学 | Method for synthesizing micron-nano-sized cuprous oxide micropowder by controlling shape of micron-nano-sized cuprous oxide micropowder |
| CN103382343A (en) * | 2013-07-01 | 2013-11-06 | 吴江市物华五金制品有限公司 | Coating for outer walls and preparation method thereof |
| CN103468046A (en) * | 2013-08-23 | 2013-12-25 | 洛阳好生活环保科技有限公司 | Activated carbon finishing paint |
-
2014
- 2014-05-12 CN CN201410197513.6A patent/CN103992712B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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