CN103992689B - High temperature resistant ink is printed without ketone table without benzene - Google Patents
High temperature resistant ink is printed without ketone table without benzene Download PDFInfo
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- CN103992689B CN103992689B CN201410167029.9A CN201410167029A CN103992689B CN 103992689 B CN103992689 B CN 103992689B CN 201410167029 A CN201410167029 A CN 201410167029A CN 103992689 B CN103992689 B CN 103992689B
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Abstract
The invention discloses one and print high temperature resistant ink without benzene without ketone table, comprise ink and solidifying agent, in described ink, the mass fraction of each component is respectively: urethane resin 25 ~ 40 parts, polyvinyl acetate ethene 10 ~ 15 parts, ester alcoholic solvent 30 ~ 45 parts, 1-Methoxy-2-propyl acetate 0.6 ~ 1 part, pigment 5 ~ 15 parts, dispersion agent 0.3 ~ 0.6 part, polyethylene wax powder 0.3 ~ 0.6 part, adhesion promoter 0.8 ~ 1.5 part, 0.8 ~ 1.5 part, static inhibitor, matting agent 5 ~ 10 parts, defoamer 0.3 ~ 0.6 part and high temperature resistant auxiliary agent 0.3 ~ 0.8 part, the mass fraction of solidifying agent is 1 ~ 2 part.The present invention adopts two-pack type to design, and adds hardness and the sticking power of ink film, can effectively prevent set-off, fall ink, has excellent high temperature resistant boiling resistance energy, and increases the quality guaranteed period of ink.
Description
Technical field
The present invention relates to Printing ink producing technical field, particularly relate to the high temperature resistant ink of a kind of table print.
Background technology
For a long time, packaging industry printing-ink is main mainly with benzene kind solvent type gravure ink for plastic film, and benzene kind solvent not only pollutes the environment, and can damage human body.At present, world many countries has been prohibited or has been limited use benzene kind solvent.In addition, for the external application flexible packing material of food, medicine etc., require through high-temperature sterilization sterilization and environmentally-friendly sanitary, this just requires the printing-ink using suitable high-temperature boiling resistant.
Summary of the invention
The technical problem that the present invention mainly solves is to provide one and prints high temperature resistant ink without benzene without ketone table, employing two-pack type designs, and adds hardness and the sticking power of ink film, can effectively prevent set-off, fall ink, there is excellent high temperature resistant boiling resistance energy, and increase the quality guaranteed period of ink.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is:
There is provided a kind of and print high temperature resistant ink without benzene without ketone table, comprise ink and solidifying agent, described ink is by urethane resin, polyvinyl acetate ethene, ester alcoholic solvent, 1-Methoxy-2-propyl acetate, pigment, dispersion agent, polyethylene wax powder, adhesion promoter, static inhibitor, matting agent, defoamer and high temperature resistant auxiliary agent composition, the mass fraction of above-mentioned each component is respectively: urethane resin 25 ~ 40 parts, polyvinyl acetate ethene 10 ~ 15 parts, ester alcoholic solvent 30 ~ 45 parts, 1-Methoxy-2-propyl acetate 0.6 ~ 1 part, pigment 5 ~ 15 parts, dispersion agent 0.3 ~ 0.6 part, polyethylene wax powder 0.3 ~ 0.6 part, adhesion promoter 0.8 ~ 1.5 part, 0.8 ~ 1.5 part, static inhibitor, matting agent 5 ~ 10 parts, defoamer 0.3 ~ 0.6 part and high temperature resistant auxiliary agent 0.3 ~ 0.8 part, the mass fraction of solidifying agent is 1 ~ 2 part.
In a preferred embodiment of the present invention, described urethane resin is the polymkeric substance by isophorone diisocyanate and polypropylene-1，2-ethandiol ether.
In a preferred embodiment of the present invention, described ester alcoholic solvent is mixed according to ratio of quality and the number of copies 30:10:8:2 by n-propyl, Virahol, ethyl ester and n-propyl alcohol.
In a preferred embodiment of the present invention, described adhesion promoter is modified chlorinated polypropylene.
In a preferred embodiment of the present invention, described static inhibitor is grouped into by the one-tenth of following massfraction: the quaternary cationics of 45% ~ 50%, the monoethanolamine of 15% ~ 18%, the acetic acid of 15% ~ 18%, the Virahol of 15% ~ 18% and 3% ~ 5% water.
In a preferred embodiment of the present invention, the model of described matting agent is OK-412, in the preparation process of ink, need add the powdery of this model and aqueous matting agent respectively, and the ratio of weight and number of described powdery and aqueous matting agent is 1:3.In the preparation process of ink, first add ground liquid matting agent, reach the capillary effect of anti-settling, delustring and change, can better combine with other components of ink, after add the matting agent of powdery, this is unground former powder, can reach the effect of antiblocking after adding.
In a preferred embodiment of the present invention, described high temperature resistant auxiliary agent is tetrafluoroethylene wax.
In a preferred embodiment of the present invention, described solidifying agent is polymeric polyisocyanate.
In a preferred embodiment of the present invention, described dispersion agent is polyester-polyamide multipolymer.
In a preferred embodiment of the present invention, described solidifying agent separates with ink to be deposited, and is added in ink by solidifying agent when ink uses again.
The invention has the beneficial effects as follows: the present invention prints high temperature resistant ink without benzene without ketone table, the printing of multilayer copolymerization milk film can be adapted to, have employed the low-melting ink vehicle of high temperature resistant, anti-yellowing change, improve the problems such as tradition easy to change, the bleeding of table printing ink and xanthochromia; The present invention adopts two-pack type to design, and is separated by ink deposit with solidifying agent, and solidifying agent adds and enters in ink when in use, the quality guaranteed period of ink was extended to 1 year from one month, decreases the waste of ink; The present invention is under the condition of 121 DEG C after the boiling of 30min, and layer of ink or smooth, not set-off, adhesion, color is unchanged.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Embodiment 1:
In the present embodiment, the present invention prints high temperature resistant ink without benzene without ketone table, comprise ink and solidifying agent, solidifying agent is polymeric polyisocyanate, wherein ink is grouped into by the one-tenth of following mass fraction: urethane resin 30 parts, polyvinyl acetate ethene 12 parts, ester alcoholic solvent 35.7 parts, 1-Methoxy-2-propyl acetate 0.8 part, pigment 10 parts, polyester-polyamide multipolymer (dispersion agent) 0.5 part, polyethylene wax powder 0.5 part, modified chlorinated polypropylene (adhesion promoter) 1 part, 1 part, static inhibitor, matting agent 8 parts, defoamer 0.5 part and 0.5 part, tetrafluoroethylene wax (high temperature resistant auxiliary agent), the mass fraction of polymeric polyisocyanate is 1.5 parts.Wherein, the urethane resin in composition refers to the polymkeric substance by isophorone diisocyanate and polypropylene-1，2-ethandiol ether; Ester alcoholic solvent is mixed according to ratio of quality and the number of copies 30:10:8:2 by n-propyl, Virahol, ethyl ester and n-propyl alcohol; Static inhibitor is grouped into by the one-tenth of following massfraction: the quaternary cationics of 48%, the monoethanolamine of 16%, the acetic acid of 16%, the Virahol of 16% and 4% water; The model of matting agent is OK-412, has used the flatting silica of powdery in this model matting agent and aqueous deglossing liquid in the present invention, and the parts by weight of deglossing liquid are 6 parts, and the parts by weight of flatting silica are 2 parts.
Above-mentioned moiety print high temperature resistant ink without benzene without ketone table, be prepared from by the following step:
1) configure resin liquid, being dissolved by the urethane resin in above-mentioned formulation weight number becomes urethane liquid;
2) pre-dispersed, 1/10th of the urethane liquid weight 1/3rd and step 1) of ester alcoholic solvent in above-mentioned mass fraction configured joins in pre-mixing dispersion cylinder, open dispersion machine by even for its low rate mixing, again polyvinyl acetate ethene, pigment, polyester-polyamide multipolymer and deglossing liquid are joined gradually wherein in whipping process, then open dispersion machine to stir, form pre-dispersed mill base;
3) grinding distribution, carries out grinding distribution by pre-dispersed mill base, makes it to reach fineness needed for ink technique, obtains dispersible pigment color paste;
4) viscosity, form and aspect are adjusted, by the urethane liquid of remainder, ester alcoholic solvent, and 1-Methoxy-2-propyl acetate, polyethylene wax powder, modified chlorinated polypropylene, static inhibitor, flatting silica, defoamer and tetrafluoroethylene wax add in dispersible pigment color paste, the viscosity of adjustment ink and form and aspect, make finished product ink;
5) filter and package, finished product ink is filtered, and supporting solidifying agent is deposited separately, then carry out packaging warehouse-in.
Embodiment 2:
In the present embodiment, the present invention prints high temperature resistant ink without benzene without ketone table, comprise ink and solidifying agent, solidifying agent is polymeric polyisocyanate, wherein ink is grouped into by the one-tenth of following mass fraction: urethane resin 32.5 parts, polyvinyl acetate ethene 12 parts, ester alcoholic solvent 40 parts, 1-Methoxy-2-propyl acetate 0.82 part, pigment 12 parts, polyester-polyamide multipolymer (dispersion agent) 0.55 part, polyethylene wax powder 0.55 part, modified chlorinated polypropylene (adhesion promoter) 1.2 parts, 1.2 parts, static inhibitor, matting agent 8 parts, defoamer 0.55 part and 0.55 part, tetrafluoroethylene wax (high temperature resistant auxiliary agent), the mass fraction of polymeric polyisocyanate is 1.5 parts.Wherein, the urethane resin in composition refers to the polymkeric substance by isophorone diisocyanate and polypropylene-1，2-ethandiol ether; Ester alcoholic solvent is mixed according to ratio of quality and the number of copies 30:10:8:2 by n-propyl, Virahol, ethyl ester and n-propyl alcohol; Static inhibitor is grouped into by the one-tenth of following massfraction: the quaternary cationics of 48%, the monoethanolamine of 16%, the acetic acid of 16%, the Virahol of 16% and 4% water; The model of matting agent is OK-412, has used the flatting silica of powdery in this model matting agent and aqueous deglossing liquid in the present invention, and the parts by weight of deglossing liquid are 6 parts, and the parts by weight of flatting silica are 2 parts.
Above-mentioned moiety print high temperature resistant ink without benzene without ketone table, according in embodiment 1 preparation process preparation become processed oil ink.
Embodiment 3:
In the present embodiment, the present invention prints high temperature resistant ink without benzene without ketone table, comprise ink and solidifying agent, solidifying agent is polymeric polyisocyanate, wherein ink is grouped into by the one-tenth of following mass fraction: urethane resin 30 parts, polyvinyl acetate ethene 10 parts, ester alcoholic solvent 33 parts, 1-Methoxy-2-propyl acetate 0.75 part, pigment 9.5 parts, polyester-polyamide multipolymer (dispersion agent) 0.46 part, polyethylene wax powder 0.48 part, modified chlorinated polypropylene (adhesion promoter) 0.95 part, 0.95 part, static inhibitor, matting agent 8 parts, defoamer 0.46 part and 0.55 part, tetrafluoroethylene wax (high temperature resistant auxiliary agent), the mass fraction of polymeric polyisocyanate is 1.6 parts.Wherein, the urethane resin in composition refers to the polymkeric substance by isophorone diisocyanate and polypropylene-1，2-ethandiol ether; Ester alcoholic solvent is mixed according to ratio of quality and the number of copies 30:10:8:2 by n-propyl, Virahol, ethyl ester and n-propyl alcohol; Static inhibitor is grouped into by the one-tenth of following massfraction: the quaternary cationics of 50%, the monoethanolamine of 15%, the acetic acid of 16%, the Virahol of 15% and 4% water; The model of matting agent is OK-412, has used the flatting silica of powdery in this model matting agent and aqueous deglossing liquid in the present invention, and the parts by weight of deglossing liquid are 6 parts, and the parts by weight of flatting silica are 2 parts.
Above-mentioned moiety print high temperature resistant ink without benzene without ketone table, according in embodiment 1 preparation process preparation become processed oil ink.
The quality index of high temperature resistant ink is printed as following table without benzene without ketone table in above-described embodiment:
The present invention prints high temperature resistant ink without benzene without ketone table, can adapt to the printing of multilayer copolymerization milk film, have employed the low-melting ink vehicle of high temperature resistant, anti-yellowing change, improves the problems such as tradition easy to change, the bleeding of table printing ink and xanthochromia; The present invention adopts two-pack type to design, and is separated by ink deposit with solidifying agent, and solidifying agent adds and enters in ink when in use, the quality guaranteed period of ink was extended to 1 year from one month, decreases the waste of ink; The present invention is under the condition of 121 DEG C after the boiling of 30min, and layer of ink or smooth, not set-off, adhesion, color is unchanged.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (9)
1. one kind prints high temperature resistant ink without benzene without ketone table, it is characterized in that, comprise ink and solidifying agent, described ink is by urethane resin, polyvinyl acetate ethene, ester alcoholic solvent, 1-Methoxy-2-propyl acetate, pigment, dispersion agent, polyethylene wax powder, adhesion promoter, static inhibitor, matting agent, defoamer and high temperature resistant auxiliary agent composition, the mass fraction of above-mentioned each component is respectively: urethane resin 25 ~ 40 parts, polyvinyl acetate ethene 10 ~ 15 parts, ester alcoholic solvent 30 ~ 45 parts, 1-Methoxy-2-propyl acetate 0.6 ~ 1 part, pigment 5 ~ 15 parts, dispersion agent 0.3 ~ 0.6 part, polyethylene wax powder 0.3 ~ 0.6 part, adhesion promoter 0.8 ~ 1.5 part, 0.8 ~ 1.5 part, static inhibitor, matting agent 5 ~ 10 parts, defoamer 0.3 ~ 0.6 part and high temperature resistant auxiliary agent 0.3 ~ 0.8 part, the mass fraction of solidifying agent is 1 ~ 2 part,
The model of described matting agent is OK-412, in the preparation process of ink, first need add the liquid matting agent of this model, then add the powdery matting agent of this model, and the ratio of weight and number of described powdery and aqueous matting agent is 1:3.
2. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described urethane resin is the polymkeric substance by isophorone diisocyanate and polypropylene-1，2-ethandiol ether.
3. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described ester alcoholic solvent is mixed according to ratio of quality and the number of copies 30:10:8:2 by n-propyl, Virahol, ethyl ester and n-propyl alcohol.
4. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described adhesion promoter is modified chlorinated polypropylene.
5. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described static inhibitor is grouped into by the one-tenth of following massfraction: the quaternary cationics of 45% ~ 50%, the monoethanolamine of 15% ~ 18%, the acetic acid of 15% ~ 18%, the Virahol of 15% ~ 18% and 3% ~ 5% water.
6. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described high temperature resistant auxiliary agent is tetrafluoroethylene wax.
7. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described solidifying agent is polymeric polyisocyanate.
8. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described dispersion agent is polyester-polyamide multipolymer.
9. according to claim 1ly print high temperature resistant ink without benzene without ketone table, it is characterized in that, described solidifying agent separates with ink to be deposited, and is added in ink by solidifying agent when ink uses again.
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| CN201410167029.9A CN103992689B (en) | 2014-04-24 | 2014-04-24 | High temperature resistant ink is printed without ketone table without benzene |
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| CN201410167029.9A CN103992689B (en) | 2014-04-24 | 2014-04-24 | High temperature resistant ink is printed without ketone table without benzene |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3458529A4 (en) * | 2016-10-10 | 2019-06-05 | Hewlett-Packard Development Company, L.P. | Liquid ink containing polytetrafluoroethylene wax emulsion |
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| CN104292974B (en) * | 2014-09-30 | 2016-03-30 | 东莞市平波电子有限公司 | A kind of touch-screen acid-proof ink and preparation method thereof |
| CN104804551A (en) * | 2015-04-13 | 2015-07-29 | 陈良伢 | High-temperature-resistant ink containing modified resin |
| CN104910665A (en) * | 2015-06-08 | 2015-09-16 | 苏州博利迈新材料科技有限公司 | Chlorinated polypropylene paint and preparation method thereof |
| CN105368136A (en) * | 2015-12-28 | 2016-03-02 | 李栋军 | Conductive ink |
| CN108641476A (en) * | 2018-06-08 | 2018-10-12 | 常熟国和新材料有限公司 | A kind of high temperature resistant ink resin |
| CN111171626A (en) * | 2019-12-30 | 2020-05-19 | 广东东方一哥新材料股份有限公司 | High-temperature-resistant and wear-resistant surface printing resin |
| CN115558335B (en) * | 2022-10-12 | 2023-09-22 | 浙江浦江永进工贸有限公司 | Double-component recyclable surface printing extinction oil for BOPP treatment-free surface printing |
| CN115627097B (en) * | 2022-11-28 | 2023-10-27 | 浙江浦江永进工贸有限公司 | Preparation method of PVDC packaging ink |
| CN116179014A (en) * | 2023-01-17 | 2023-05-30 | 浙江浦江永进工贸有限公司 | Preparation method of halogen-free ink for electronic packaging |
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Patent Citations (3)
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| CN101654593A (en) * | 2008-08-18 | 2010-02-24 | 深圳佳德威油漆有限公司 | Method for preparing high-temperature resistant antibacterial non-stick paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| EP3458529A4 (en) * | 2016-10-10 | 2019-06-05 | Hewlett-Packard Development Company, L.P. | Liquid ink containing polytetrafluoroethylene wax emulsion |
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