CN103992559A - Flame retardant plastic product and production method thereof - Google Patents
Flame retardant plastic product and production method thereof Download PDFInfo
- Publication number
- CN103992559A CN103992559A CN201410182504.XA CN201410182504A CN103992559A CN 103992559 A CN103992559 A CN 103992559A CN 201410182504 A CN201410182504 A CN 201410182504A CN 103992559 A CN103992559 A CN 103992559A
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- flame retardant
- raw material
- polypropylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The invention discloses a flame retardant plastic product. The flame retardant plastic product comprises, by weight, 80-120 parts of polypropylene, 5-10 parts of dibromopropyl, 2-4 parts of antimonony oxide and 3-5 parts of hydrated zinc borate. Compared with plastic products in the prior art, the plastic product produced in the invention has the advantages of low price, simple production process, good antistatic property and hidden safety trouble avoiding.
Description
Technical field
The present invention relates to material science, refer more particularly to a kind of flame retardant plastics goods and production method thereof.
Background technology
Plastics, synthetic rubber, synthon three widespread uses of large synthetic materials in the world today are well-known, and the most first with plastics, as one of present social four large base mateirals, plastics are all growing with each passing day in number of applications and the range of application in the fields such as building, electric power, telecommunication, electrical equipment, the energy, communications and transportation, agricultural, health care, aerospace, information and national defense industry at present.Plastics have many premium propertiess as a kind of important equivalent material, as light in quality, there is great plasticity-etc., but most plastics have an one fatal weakness, be exactly that they nearly all belong to inflammable or combustible material, as long as possess basic burning things which may cause a fire disaster, they can be lighted and sustained combustion in air, in present society, there are a lot of fire by lighting and causing about plastic material and caused personnel's heavy injures and deaths and the heavy losses of property, therefore utilize some means or method inflammable or flammable plastics can be become and be difficult for being lighted or lighting the rear utmost point short period of time from putting out, or it is very slow to be lighted afterfire speed, thereby can greatly reduce the generation of fire, this is the object of plastic flame technology namely.Now study a kind of flame retardant plastics goods, well solved this safety problem.
Summary of the invention
Technical problem to be solved by this invention be to provide a kind of safe and practical, low price, can be fire-retardant plastics, i.e. flame retardant plastics goods.
For solving the problems of the technologies described above, the present invention by the following technical solutions:
Flame retardant plastics goods, is characterized in that, comprise following weight part raw material: polypropylene 80-120 part, dibromopropyl 5-10 part, antimonous oxide 2-4 part, hydration zinc borate 3-5 part.
Preferably, the raw material of described each weight part is: polypropylene 90-110 part, dibromopropyl 7-8 part, antimonous oxide 3-4 part, hydration zinc borate 4-5 part.
Preferably, the raw material of described each weight part is: 100 parts of polypropylene, 7 parts of dibromopropyls, 3 parts of antimonous oxides, 4 parts of hydration zinc borates.
A production method for flame retardant plastics goods, is characterized in that, comprises the following steps:
(1) take by weight each raw material: polypropylene 80-120 part, dibromopropyl 5-10 part, antimonous oxide 2-4 part, hydration zinc borate 3-5 part;
(2) after will step (1) raw material mediating, in temperature, be 150 ℃-170 ℃, screw speed is 36r/min, under the condition that pulling speed is 0.52m/mim through twin-roll mixing, pulverize extrusion moulding, cooling and shaping;
(3) the more cooling product cutting after step (2) processing can be obtained to flame retardant plastics goods.
The present invention compared with prior art, has the following advantages: plastics that (1) the present invention produces are cheap, production technique is simple; (2) the present invention can be good at preventing plastics spontaneous combustion, hidden danger eliminates danger.
Embodiment
Below in conjunction with embodiment, technical scheme of the present invention is further described in detail.
Embodiment mono-:
(1) take by weight each raw material: 80 parts of polypropylene, 5 parts of dibromopropyls, 2 parts of antimonous oxides, 3 parts of hydration zinc borates;
(2) after will step (1) raw material mediating, in temperature, be 150 ℃, screw speed is 36r/min, under the condition that pulling speed is 0.52m/mim through twin-roll mixing, pulverize extrusion moulding, cooling and shaping;
(3) the more cooling product cutting after step (2) processing can be obtained to flame retardant plastics goods.
The present invention compared with prior art, has the following advantages: plastics that (1) the present invention produces are cheap, production technique is simple; (2) the present invention can be good at preventing plastics spontaneous combustion, hidden danger eliminates danger.
Embodiment bis-:
(1) take by weight each raw material: 120 parts of polypropylene, 10 parts of dibromopropyls, 4 parts of antimonous oxides, 5 parts of hydration zinc borates;
(2) after will step (1) raw material mediating, in temperature, be 170 ℃, screw speed is 36r/min, under the condition that pulling speed is 0.52m/mim through twin-roll mixing, pulverize extrusion moulding, cooling and shaping;
(3) the more cooling product cutting after step (2) processing can be obtained to flame retardant plastics goods.
The present invention compared with prior art, has the following advantages: plastics that (1) the present invention produces are cheap, production technique is simple; (2) the present invention can be good at preventing plastics spontaneous combustion, hidden danger eliminates danger.
Embodiment tri-:
(1) take by weight each raw material: 100 parts of polypropylene, 7 parts of dibromopropyls, 3 parts of antimonous oxides, 4 parts of hydration zinc borates;
(2) after will step (1) raw material mediating, in temperature, be 160 ℃, screw speed is 36r/min, under the condition that pulling speed is 0.52m/mim through twin-roll mixing, pulverize extrusion moulding, cooling and shaping;
(3) the more cooling product cutting after step (2) processing can be obtained to flame retardant plastics goods.
The present invention compared with prior art, has the following advantages: plastics that (1) the present invention produces are cheap, production technique is simple; (2) the present invention can be good at preventing plastics spontaneous combustion, hidden danger eliminates danger.
Embodiment tetra-:
(1) take by weight each raw material: 90 parts of polypropylene, 7 parts of dibromopropyls, 3 parts of antimonous oxides, 4 parts of hydration zinc borates;
(2) after will step (1) raw material mediating, in temperature, be 150 ℃, screw speed is 36r/min, under the condition that pulling speed is 0.52m/mim through twin-roll mixing, pulverize extrusion moulding, cooling and shaping;
(3) the more cooling product cutting after step (2) processing can be obtained to flame retardant plastics goods.
The present invention compared with prior art, has the following advantages: plastics that (1) the present invention produces are cheap, production technique is simple; (2) the present invention can be good at preventing plastics spontaneous combustion, hidden danger eliminates danger.
Embodiment five:
(1) take by weight each raw material: 110 parts of polypropylene, 8 parts of dibromopropyls, 4 parts of antimonous oxides, 5 parts of hydration zinc borates;
(2) after will step (1) raw material mediating, in temperature, be 170 ℃, screw speed is 36r/min, under the condition that pulling speed is 0.52m/mim through twin-roll mixing, pulverize extrusion moulding, cooling and shaping;
(3) the more cooling product cutting after step (2) processing can be obtained to flame retardant plastics goods.
The present invention compared with prior art, has the following advantages: plastics that (1) the present invention produces are cheap, production technique is simple; (2) the present invention can be good at preventing plastics spontaneous combustion, hidden danger eliminates danger.
It should be noted last that, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although the present invention is had been described in detail with reference to preferred embodiment, those of ordinary skill in the art is to be understood that, can modify or be equal to replacement technical scheme of the present invention, and not departing from the spirit and scope of technical solution of the present invention, it all should be encompassed in the middle of claim scope of the present invention.
Claims (4)
1. flame retardant plastics goods, is characterized in that, comprise following weight part raw material: polypropylene 80-120 part, dibromopropyl 5-10 part, antimonous oxide 2-4 part, hydration zinc borate 3-5 part.
2. flame retardant plastics goods according to claim 1, is characterized in that, the raw material of described each weight part is: polypropylene 90-110 part, dibromopropyl 7-8 part, antimonous oxide 3-4 part, hydration zinc borate 4-5 part.
3. flame retardant plastics goods according to claim 1, is characterized in that, the raw material of described each weight part is: 100 parts of polypropylene, 7 parts of dibromopropyls, 3 parts of antimonous oxides, 4 parts of hydration zinc borates.
4. a production method for flame retardant plastics goods according to claim 1, is characterized in that, comprises the following steps:
(1) take by weight each raw material: polypropylene 80-120 part, dibromopropyl 5-10 part, antimonous oxide 2-4 part, hydration zinc borate 3-5 part;
(2) after will step (1) raw material mediating, in temperature, be 150 ℃-170 ℃, screw speed is 36r/min, under the condition that pulling speed is 0.52m/mim through twin-roll mixing, pulverize extrusion moulding, cooling and shaping;
(3) the more cooling product cutting after step (2) processing can be obtained to flame retardant plastics goods.
Priority Applications (1)
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CN201410182504.XA CN103992559A (en) | 2014-04-30 | 2014-04-30 | Flame retardant plastic product and production method thereof |
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CN201410182504.XA CN103992559A (en) | 2014-04-30 | 2014-04-30 | Flame retardant plastic product and production method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104774376A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Halogen-free fire-retardation polypropylene composite material |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101121798A (en) * | 2006-08-09 | 2008-02-13 | 上海金发科技发展有限公司 | High-luster low-surface precipitation anti-flaming polypropylene composite and preparation method thereof |
-
2014
- 2014-04-30 CN CN201410182504.XA patent/CN103992559A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101121798A (en) * | 2006-08-09 | 2008-02-13 | 上海金发科技发展有限公司 | High-luster low-surface precipitation anti-flaming polypropylene composite and preparation method thereof |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104774376A (en) * | 2015-03-26 | 2015-07-15 | 安徽海纳川塑业科技有限公司 | Halogen-free fire-retardation polypropylene composite material |
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Application publication date: 20140820 |
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