CN103992046A - Anti-oxidation glass film-on and preparation method thereof - Google Patents
Anti-oxidation glass film-on and preparation method thereof Download PDFInfo
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- CN103992046A CN103992046A CN201410204842.9A CN201410204842A CN103992046A CN 103992046 A CN103992046 A CN 103992046A CN 201410204842 A CN201410204842 A CN 201410204842A CN 103992046 A CN103992046 A CN 103992046A
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Abstract
The invention relates to the technical field of a glass film-on and in particular relates to an anti-oxidation glass film-on. The anti-oxidation glass film-on comprises 1000 parts by weight of ultrapure water, and 2 parts by weight of chelating agent, 1 part by weight of anti-oxidant, 8 parts by weight of surfactant, 1 part by weight of preservative, 1 part by weight of mildew-proof agent and a proper amount of PH value regulator which are all added to the ultrapure water. The invention also discloses a preparation method of the anti-oxidation glass film-on. The anti-oxidation glass film-on obtained according to the formula and the process has an excellent anti-oxidation technical effect and is applied to the construction of a glass film containing an easily oxidizing noble metal layer, and a film glued by the anti-oxidation glass film-on is greatly improved in anti-oxidation performance and increased in service life.
Description
Technical field
The present invention relates to adhering film to glass liquid technical field is installed, particularly a kind of resistance to oxidation adhering film to glass is installed liquid, meanwhile, the invention also discloses the preparation method that this resistance to oxidation adhering film to glass is installed liquid.
Background technology
The application of adhering film to glass aspect energy-saving safe can be traced back to nineteen sixties, Zi3M company application first item adhering film to glass is the history of existing four more than ten years so far, adhering film to glass can be divided into safety film, thermal isolation film, decorating film by its function, is widely used in the fields such as automobile, building, electronic product, household electrical appliance.
At present, adhering film to glass is all that the subsides of liquid dress are installed in spray between glass and film pressure sensitive adhesive in construction, this kind installed liquid and be take water as main body, wherein adds appropriate lubricant and cleaning additive, and it is a kind of economical and practical good method that this installation liquid is used in the adhering film to glass of containing metal coating not.But along with scientific and technical fast development, the function that adhering film to glass has been given prominence to again heat-insulating and energy-saving in safety, in attractive in appearance, the function film of a large amount of metals and metal medium combination emerges, in product structure design, increase and intercept element, therefore use original installation liquid can not adapt to prior art requirement.
Summary of the invention
The deficiency existing for above-mentioned prior art, the object of this invention is to provide a kind of resistance to oxidation adhering film to glass liquid is installed, and preparation is simple, with low cost, be applied in the adhering film to glass construction containing oxidizable layer of precious metal its film that is stuck, antioxidant property increases substantially, and extend work-ing life.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
Resistance to oxidation adhering film to glass of the present invention is installed liquid, comprises ultrapure water 1000 mass parts, sequestrant 2 mass parts that add in respectively to ultrapure water, antioxidant 1 mass parts, tensio-active agent 8 mass parts, sanitas 1 mass parts, mould inhibitor 1 mass parts and appropriate pH value conditioning agent.
Wherein, described ultrapure electrical conductivity of water is greater than 15 megaohms.
Wherein, described sequestrant is one or more the miscellany in ethylenediamine tetraacetic acid (EDTA), disodium ethylene diamine tetraacetate, nitrilotriacetic acid and diethylene triamine pentacetic acid (DTPA) sodium salt.
Wherein, described antioxidant is one or more the miscellany in dimercaprol dimercaptopropanol, Zonon D and benzotriazole.
Wherein, described tensio-active agent is fatty alcohol-polyoxyethylene ether, polyxyethylated alcohol amide, the miscellany of one or more in polyoxyethylene alkylphenol ether.
Wherein, described sanitas is one or more the miscellany in compound in triazine class, water-based chloromethyl/methylisothiazolinone mixture, water-based chloromethyl/methylisothiazolinone, N-/O-formal mixture.
Wherein, described mould inhibitor is one or both the miscellany in MIT, CMIT.
Wherein, described pH value conditioning agent is one or more the miscellany in citric acid, tartrate, second hydroxy-ethylenediamine, hydramine.
Meanwhile, the invention also discloses the preparation method that resistance to oxidation adhering film to glass is installed liquid, it is characterized in that, comprise the steps:
1) prepare ultrapure water;
2) in ultrapure water, add sequestrant, stir and be warming up to 50-60C °;
3) to ultrapure water, add oxygenant again, stir while adding, until oxygenant dissolves completely;
4) add again after tensio-active agent, stir 30 minutes;
5) above-mentioned solution is cooled to rapidly below 40C °, the pH value of test soln, is adjusted to 7.5～8 with pH value conditioning agent by solution pH value;
6) successively add after sanitas and mould inhibitor stirring and dissolving again, obtain resistance to oxidation adhering film to glass liquid is installed.
Beneficial effect of the present invention is: the present invention adopts specific composition and engineering, reach good resistance to oxidation technique effect, be applied in the adhering film to glass construction containing oxidizable layer of precious metal its film that is stuck, antioxidant property increases substantially, and extend work-ing life.
Embodiment
Below in conjunction with embodiment, the present invention is further described.
Case 1:
Get ultrapure water (resistance value is greater than 15 megaohms) 1000g, in ultrapure water, add sequestrant (disodium ethylene diamine tetraacetate) 2g, stirring is warming up to 50C °, until completely dissolved, add again antioxidant (benzotriazole) 1g, stir while adding, until dissolve completely, add again tensio-active agent (fatty alcohol-polyoxyethylene ether) 8g, stir 30 minutes, above-mentioned solution is cooled to rapidly below 40C °, the pH value of test soln is 7, select pH value conditioning agent (citric acid and tartaric miscellany) appropriate, the test while splashing into, until behind solution PH=7.5～8, after adding sanitas (compound in triazine class) 1g to stir, add again mould inhibitor (MIT) 1g to stir, configuration completes, obtain resistance to oxidation adhering film to glass liquid is installed.
Case 2:
Get ultrapure water (resistance value is greater than 15 megaohms) 1000g, in ultrapure water, add sequestrant (ethylenediamine tetraacetic acid (EDTA)) 2g, stirring is warming up to 55C °, until completely dissolved, add again antioxidant (dimercaprol dimercaptopropanol) 1g, stir while adding, until dissolve completely, add again tensio-active agent (polyxyethylated alcohol amide) 8g, stir 30 minutes, above-mentioned solution is cooled to rapidly below 40C °, the pH value of test soln is 7.3, select pH value conditioning agent (second hydroxy-ethylenediamine) appropriate, the test while splashing into, until behind solution PH=7.5～8, after adding sanitas (water-based chloromethyl/methylisothiazolinone mixture) 1g to stir, add again mould inhibitor (CMIT) 1g to stir, configuration completes, obtain resistance to oxidation adhering film to glass liquid is installed.
Case 3:
Get ultrapure water (resistance value is greater than 15 megaohms) 1000g, in ultrapure water, add sequestrant (miscellany of nitrilotriacetic acid and diethylene triamine pentacetic acid (DTPA) sodium salt) 2g, stirring is warming up to 60C °, until completely dissolved, add again antioxidant (Zonon D) 1g, stir while adding, until dissolve completely, add again tensio-active agent (miscellany of polyxyethylated alcohol amide and polyoxyethylene alkylphenol ether) 8g, stir 30 minutes, above-mentioned solution is cooled to rapidly below 40C °, the pH value of test soln is 7.1, select pH value conditioning agent (hydramine) appropriate, the test while splashing into, until behind solution PH=7.5～8, after adding sanitas (N-/O-formal mixture) 1g to stir, add again mould inhibitor (CMIT) 1g to stir, configuration completes, obtain resistance to oxidation adhering film to glass liquid is installed.
Use the present invention with use conventional install liquid dress paste film weather resistance test data sheet one (carry out JC846-2007 standard and GB/T16422.3-1997 standard, sample is chosen the thermal isolation film of metal medium structure,
As can be seen from the above table, the changing value that the embodiment of the present invention is tested the visible region of front and back changing value is significantly less than pure water dress subsides sample and routine installation liquid dress subsides sample, illustrates that scale resistance is obviously better than pure water dress subsides sample and conventional installation liquid dress subsides sample.
The above is only better embodiment of the present invention, and the equivalence of making according to the technological principle described in patent claim of the present invention therefore all changes or revises, and is included in patent claim of the present invention.
Claims (9)
1. resistance to oxidation adhering film to glass is installed liquid, it is characterized in that: comprise ultrapure water 1000 mass parts, sequestrant 2 mass parts that add in respectively to ultrapure water, antioxidant 1 mass parts, tensio-active agent 8 mass parts, sanitas 1 mass parts, mould inhibitor 1 mass parts and appropriate pH value conditioning agent.
2. resistance to oxidation adhering film to glass according to claim 1 is installed liquid, it is characterized in that: described ultrapure electrical conductivity of water is greater than 15 megaohms.
3. resistance to oxidation adhering film to glass according to claim 1 is installed liquid, it is characterized in that: described sequestrant is one or more the miscellany in ethylenediamine tetraacetic acid (EDTA), disodium ethylene diamine tetraacetate, nitrilotriacetic acid and diethylene triamine pentacetic acid (DTPA) sodium salt.
4. resistance to oxidation adhering film to glass according to claim 1 is installed liquid, it is characterized in that: described antioxidant is one or more the miscellany in dimercaprol dimercaptopropanol, Zonon D and benzotriazole.
5. resistance to oxidation adhering film to glass according to claim 1 is installed liquid, it is characterized in that: described tensio-active agent is fatty alcohol-polyoxyethylene ether, polyxyethylated alcohol amide, the miscellany of one or more in polyoxyethylene alkylphenol ether.
6. resistance to oxidation adhering film to glass according to claim 1 is installed liquid, it is characterized in that: described sanitas is one or more the miscellany in compound in triazine class, water-based chloromethyl/methylisothiazolinone mixture, water-based chloromethyl/methylisothiazolinone, N-/O-formal mixture.
7. resistance to oxidation adhering film to glass according to claim 1 is installed liquid, it is characterized in that: described mould inhibitor is one or both the miscellany in MIT, CMIT.
8. resistance to oxidation adhering film to glass according to claim 1 is installed liquid, it is characterized in that: described pH value conditioning agent is one or more the miscellany in citric acid, tartrate, second hydroxy-ethylenediamine, hydramine.
9. the preparation method who according to the arbitrary described resistance to oxidation adhering film to glass of claim 1-8, liquid is installed, is characterized in that, comprises the steps:
1) prepare ultrapure water;
2) in ultrapure water, add sequestrant, stir and be warming up to 50-60C °;
3) to ultrapure water, add oxygenant again, stir while adding, until oxygenant dissolves completely;
4) add again after tensio-active agent, stir 30 minutes;
5) above-mentioned solution is cooled to rapidly below 40C °, the pH value of test soln, is adjusted to 7.5～8 with pH value conditioning agent by solution pH value;
6) successively add after sanitas and mould inhibitor stirring and dissolving again, obtain resistance to oxidation adhering film to glass liquid is installed.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410204842.9A CN103992046B (en) | 2014-05-14 | 2014-05-14 | Resistance to oxidation adhering film to glass installs liquid and preparation method thereof |
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| CN201410204842.9A CN103992046B (en) | 2014-05-14 | 2014-05-14 | Resistance to oxidation adhering film to glass installs liquid and preparation method thereof |
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| CN103992046A true CN103992046A (en) | 2014-08-20 |
| CN103992046B CN103992046B (en) | 2016-03-02 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205908A (en) * | 2020-01-17 | 2020-05-29 | 广州市华惠材料科技有限公司 | Intelligent dimming film mounting liquid, preparation method and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111205908A (en) * | 2020-01-17 | 2020-05-29 | 广州市华惠材料科技有限公司 | Intelligent dimming film mounting liquid, preparation method and application thereof |
| CN111205908B (en) * | 2020-01-17 | 2021-11-23 | 广州市华惠材料科技有限公司 | Intelligent dimming film mounting liquid, preparation method and application thereof |
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| CN103992046B (en) | 2016-03-02 |
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