CN103980714A - High-refraction-index LED (Light Emitting Diode) organic silicon packaging material and preparation method thereof - Google Patents
High-refraction-index LED (Light Emitting Diode) organic silicon packaging material and preparation method thereof Download PDFInfo
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- 229910052710 silicon Inorganic materials 0.000 title claims abstract description 26
- 239000010703 silicon Substances 0.000 title claims abstract description 26
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 239000005022 packaging material Substances 0.000 title claims abstract description 16
- -1 silicon hydrogen Chemical class 0.000 claims abstract description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 23
- 239000001257 hydrogen Substances 0.000 claims abstract description 23
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000011347 resin Substances 0.000 claims abstract description 22
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 21
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 14
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 239000003112 inhibitor Substances 0.000 claims abstract description 10
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 8
- 239000000463 material Substances 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 229920002050 silicone resin Polymers 0.000 claims description 21
- 229910020388 SiO1/2 Inorganic materials 0.000 claims description 20
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 16
- 229920002545 silicone oil Polymers 0.000 claims description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 8
- QYLFHLNFIHBCPR-UHFFFAOYSA-N 1-ethynylcyclohexan-1-ol Chemical compound C#CC1(O)CCCCC1 QYLFHLNFIHBCPR-UHFFFAOYSA-N 0.000 claims description 3
- 230000001588 bifunctional effect Effects 0.000 claims description 3
- VTXMEXQKYKOHEN-UHFFFAOYSA-N bis[[ethenyl(dimethyl)silyl]oxy]-methyl-phenylsilane Chemical compound C=C[Si](C)(C)O[Si](C)(O[Si](C)(C)C=C)C1=CC=CC=C1 VTXMEXQKYKOHEN-UHFFFAOYSA-N 0.000 claims description 3
- RCNRJBWHLARWRP-UHFFFAOYSA-N ethenyl-[ethenyl(dimethyl)silyl]oxy-dimethylsilane;platinum Chemical compound [Pt].C=C[Si](C)(C)O[Si](C)(C)C=C RCNRJBWHLARWRP-UHFFFAOYSA-N 0.000 claims description 3
- VTYCDJPJGNRAHU-UHFFFAOYSA-N tris(2-methylprop-1-enylsilyloxy)-phenylsilane Chemical compound C1(=CC=CC=C1)[Si](O[SiH2]C=C(C)C)(O[SiH2]C=C(C)C)O[SiH2]C=C(C)C VTYCDJPJGNRAHU-UHFFFAOYSA-N 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 238000004806 packaging method and process Methods 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 3
- 238000013006 addition curing Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- MJULMZZKFYNTHK-UHFFFAOYSA-N ethenyl(phenyl)silicon Chemical compound C=C[Si]C1=CC=CC=C1 MJULMZZKFYNTHK-UHFFFAOYSA-N 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 11
- 150000002431 hydrogen Chemical class 0.000 description 8
- 238000007711 solidification Methods 0.000 description 8
- 230000008023 solidification Effects 0.000 description 8
- 238000001723 curing Methods 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000001816 cooling Methods 0.000 description 5
- 238000011049 filling Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 239000000741 silica gel Substances 0.000 description 4
- 229910002027 silica gel Inorganic materials 0.000 description 4
- 238000002834 transmittance Methods 0.000 description 4
- 229910018557 Si O Inorganic materials 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229910002808 Si–O–Si Inorganic materials 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- ARLJCLKHRZGWGL-UHFFFAOYSA-N ethenylsilicon Chemical compound [Si]C=C ARLJCLKHRZGWGL-UHFFFAOYSA-N 0.000 description 1
- NYMPGSQKHIOWIO-UHFFFAOYSA-N hydroxy(diphenyl)silicon Chemical group C=1C=CC=CC=1[Si](O)C1=CC=CC=C1 NYMPGSQKHIOWIO-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002210 silicon-based material Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a high-refraction-index LED (Light Emitting Diode) organic silicon packaging material and a preparation method thereof. The material consists of a component A and a component B, wherein the mass ratio of the component A to the component B is 5:1; the component A is prepared from the following raw materials in parts by mass: 140-160 parts of methyl high-phenyl vinyl silicon resin, 90-110 parts of vinyl phenyl silicon oil and 0.2-0.6 parts of platinum catalyst; the component B comprises 25-35 parts of high-phenyl vinyl silicon resin, 15-25 parts of methyl phenyl hydrogen silicon resin and 0.3-1 part of inhibitor. The methyl high-phenyl vinyl silicon resin is adopted to be reasonably combined with the vinyl phenyl silicon oil to provide silicon-vinyl, the high-phenyl vinyl silicon resin is adopted to be reasonably combined with the methyl phenyl hydrogen silicon resin to provide silicon hydrogen, in the presence of the catalyst and the inhibitor, the organic silicon packaging material obtained by uniformly mixing and stirring the components can have addition curing reaction when being heated, and can be applied to LED packaging to achieve the purpose of high light emission rate of an LED.
Description
Technical Field
The invention relates to the technical field of LED organic silicon packaging materials, in particular to a high-refractive-index LED organic silicon packaging material and a preparation method thereof.
Background
The LED is composed of a chip, a lead, a bracket, conductive adhesive, packaging materials and the like, liquid rubber is poured into a device provided with electronic elements and circuits in a filling, encapsulating or mould pressing mode for packaging, the main chain of organic silicon is Si-O-Si side group which is methyl, the whole molecular chain is spiral, and the special mixed chain molecular structure endows the device with a plurality of excellent performances, such as: the Si-O bond length and the bond angle are relatively large, the steric hindrance of the bond to the rotation of the side group is small, and the chain segment is very flexible, so that the low-temperature resistance is good, meanwhile, the Si-O bond energy is relatively high, so that the Si-O bond has good thermal stability and weather resistance, can work within a wide temperature range (-50-250 ℃), and has good hydrophobicity due to low surface energy (21-22 mN/m); low surface tension and flexibility can increase the permeability of polymer systems. The characteristics enable the organic silicon to have high light transmittance, good thermal stability, strong ultraviolet resistance, small internal stress, low hygroscopicity, and obviously better performance than epoxy resin, and become an ideal choice of LED packaging materials, however, the organic silicon material has a lower refractive index, the low refractive index can influence the light-emitting rate of the LED, and in order to improve the refractive index and radiation resistance of the material, the organic silicon packaging materials are generally prepared by vinyl silicon resin containing a certain amount of diphenyl siloxane chain links or methyl phenyl siloxane chain links and hydrogen-containing silicon oil, and the materials have low shrinkage and good cold and heat shock resistance.
Disclosure of Invention
The invention relates to a high-refractive-index LED (light-emitting diode) organic silicon packaging material and a preparation method thereof, and is characterized in that methyl high-phenyl vinyl silicone resin is reasonably matched with vinyl phenyl silicone oil to provide silicon-vinyl, high-phenyl hydrogen base silicone resin is reasonably matched with methyl phenyl hydrogen base silicone resin to provide silicon hydrogen base, and the organic silicon packaging material which is uniformly mixed and stirred can generate addition curing reaction by heating in the presence of a catalyst and an inhibitor, and can be used for LED packaging to achieve the purpose of high light-emitting rate of an LED.
In order to achieve the purpose, the technical solution of the invention is as follows: the LED organic silicon packaging material with the high refractive index consists of a component A and a component B, wherein the mass ratio of the component A to the component B is 5: 1, and the component A comprises the following raw materials in parts by mass: 140-160 parts of methyl high phenyl vinyl silicone resin, 90-110 parts of vinyl phenyl silicone oil and 0.2-0.6 part of platinum catalyst; the component B comprises 25-35 parts of high phenyl hydrogen silicon resin, 15-25 parts of methyl phenyl hydrogen silicon resin and 0.3-1 part of inhibitor.
On the basis of the scheme, the invention can be further improved as follows:
further, the methyl high phenyl vinyl silicone resin has a chemical general formula of (PhSiO)3/2) x1(Ph2SiO)x2 (Me2SiO)x3 (ViMe2SiO1/2) x4A compound of formula (I), wherein PhSiO3/2Is a trifunctional link, in which Ph2SiO、Me2SiO is a difunctional mer, ViMe2SiO1/2Is a monofunctional link; wherein Ph is phenyl, Me is methyl, Vi is vinyl, x1= 0.55-0.60, x2= 0.02-0.04, x3= 0.02-0.04, x4= 0.35-0.45, and the sum of the values is x1+ x2+ x3+ x4= 1;
the vinyl phenyl silicone oil has a chemical general formula of ViMe2 SiO ( Si Me2O)m (SiPh2O)n Si Me2A compound Vi, wherein Ph is phenyl, Me is methyl, Vi is vinyl, m and n are integers which are more than 10 and m + n is less than 50, and the molar percentage of the vinyl is 0.78%; 5 mol% phenyl and a viscosity of 3050mPa @;
the high phenyl hydrogen-based silicone resin has three functional chain links, two functional chain links and one functional chain linkHigher viscosity MDT resins of (a); has the chemical general formula of (PhSiO)3/2)y1(Ph2SiO)y2(Ph3SiO1/2) y3 (HMe2SiO1/2) y4A compound of formula (I), wherein PhSiO3/2Is a trifunctional link, in which Ph2SiO is a difunctional chain member, Ph3SiO1/2、HMe2SiO1/2Is a monofunctional link; ph is phenyl, Me is methyl, Vi is vinyl, y1= 0.5-0.6, y2= 0.02-0.03, y3= 0.02-0.03, y4= 0.3-0.4, and the sum of the values is y1+ y2+ y3+ y4= 1;
the methylphenylhydrosilicon resin is a lower viscosity MDT resin with trifunctional chain link, bifunctional chain link and monofunctional chain link; has the chemical general formula of (PhSiO)3/2)z1(Me2SiO)z2(Me3SiO1/2)z3 (HMe2SiO1/2) z4A compound of formula (I), wherein PhSiO3/2Is a trifunctional mer of formula Me2SiO is a difunctional mer, (Me)3SiO1/2)、(HMe2SiO1/2) Is a monofunctional link; wherein Ph is phenyl, Me is methyl, Vi is vinyl, z1= 0.45-0.55, z2= 0.08-0.09, z3= 0.06-0.07, z4= 0.30-0.35, and the sum of the values is z1+ z2+ z3+ z4= 1;
the platinum catalyst is one selected from platinum-1, 3-dimethyl-1, 3-diphenyl-1, 3-divinyl siloxane complex, platinum-1, 1, 3, 3-tetramethyl-1, 3-divinyl-disiloxane complex and chloroplatinic acid-divinyl tetramethyl disiloxane complex;
the inhibitor is one or more than one selected from 1-ethynylcyclohexanol, 3-diphenyl-1, 5-divinyl-1, 1, 5, 5-tetramethyltrisiloxane, 3-phenyl-1, 5-divinyl-1, 1, 3, 5, 5-pentamethyltrisiloxane and phenyl tris (dimethylvinylsiloxy) silane.
The preparation method of the high-refractive-index LED organosilicon packaging material comprises the steps of preparing a component A and preparing a component B; wherein,
the preparation of the component A comprises the following steps: sequentially adding 140-160 parts by mass of methyl high phenyl vinyl silicone resin, 90-110 parts by mass of vinyl phenyl silicone oil and 0.2-0.6 part by mass of platinum catalyst into a stirrer, and uniformly stirring to obtain the component A;
the preparation of the component B comprises the following steps: sequentially adding 25-35 parts by mass of high phenyl hydrogen silicone resin, 15-25 parts by mass of methyl phenyl hydrogen silicone resin and 0.1-0.3 part by mass of inhibitor into a stirrer, and uniformly stirring to obtain the component B;
during the use, will component A and component B according to the ratio of mass ratio 5: 1, carry out the misce bene, vacuum deaeration 30 ~ 45 minutes, glue or the filling is on waiting to encapsulate LED chip spare, slowly heats to 150 ℃ to solidification 2 ~ 3 hours at 150 ℃ constant temperature, stop heating, the cooling accomplishes the solidification.
The invention has the advantages and characteristics that: the component A of the high-refractive-index LED organosilicon encapsulating material provides silicon-vinyl for addition reaction during curing reaction and inhibits side reaction from occurring, so that a platinum catalyst generated by black substances is avoided; the component B provides a silicon-hydrogen group for addition reaction and an inhibitor during curing reaction; both the A component and the B component provide phenyl groups capable of improving refractive index and silicone resin for improving adhesion and adhesion; according to the improved scheme, the vinyl phenyl silicone oil with high viscosity and low viscosity in the component A is used in a matching way, and the MDT resin with high viscosity and low viscosity in the component B is used in a matching way, so that the components are favorably stirred and uniformly mixed.
Detailed Description
Example 1
Preparation of component A: sequentially adding 160 g of methyl high phenyl vinyl silicone resin, 90 g of vinyl phenyl silicone oil and 0.6 g of platinum-1, 3-dimethyl-1, 3-diphenyl-1, 3-divinyl siloxane complex into a stirrer, and stirring uniformly to obtain the component A;
the preparation of the component B comprises the following steps: sequentially adding 32 g of high phenyl hydrogen silicon resin, 20 g of methyl phenyl hydrogen silicon resin and 0.2 g of 3-phenyl-1, 5-divinyl-1, 1, 3, 5, 5-pentamethyl trisiloxane into a stirrer, and uniformly stirring to obtain the component B;
during the use, will component A and component B according to the ratio of mass ratio 5: 1, carry out the misce bene, vacuum deaeration 30 ~ 45 minutes, glue or the filling is on waiting to encapsulate LED chip spare, slowly heats to 150 ℃ to solidification 2 ~ 3 hours at 150 ℃ constant temperature, stop heating, the cooling accomplishes the solidification.
Example 2
Preparation of component A: sequentially adding 140 g of methyl high phenyl vinyl silicone resin, 110 g of vinyl phenyl silicone oil and 0.2 g of chloroplatinic acid-divinyl tetramethyl disiloxane complex into a stirrer, and uniformly stirring to obtain the component A;
the preparation of the component B comprises the following steps: sequentially adding 25 g of high phenyl hydrogen silicon resin, 25 g of methyl phenyl hydrogen silicon resin and 0.1 g of 1-ethynylcyclohexanol in parts by mass into a stirrer, and uniformly stirring to obtain the component B;
during the use, will component A and component B according to the ratio of mass ratio 5: 1, carry out the misce bene, vacuum deaeration 30 ~ 45 minutes, glue or the filling is on waiting to encapsulate LED chip spare, slowly heats to 150 ℃ to solidification 2 ~ 3 hours at 150 ℃ constant temperature, stop heating, the cooling accomplishes the solidification.
Example 3
Preparation of component A: sequentially adding 150 g of methyl high phenyl vinyl silicone resin, 100 g of vinyl phenyl silicone oil and 0.4 g of platinum-1, 1, 3, 3-tetramethyl-1, 3-divinyl-disiloxane complex into a stirrer, and stirring uniformly to obtain the component A;
the preparation of the component B comprises the following steps: sequentially adding 35 g of high phenyl hydrogen silicon resin, 15 g of methyl phenyl hydrogen silicon resin and 0.3 g of phenyl tri (dimethyl vinyl siloxy) silane into a stirrer, and uniformly stirring to obtain the component B;
during the use, will component A and component B according to the ratio of mass ratio 5: 1, carry out the misce bene, vacuum deaeration 30 ~ 45 minutes, glue or the filling is on waiting to encapsulate LED chip spare, slowly heats to 150 ℃ to solidification 2 ~ 3 hours at 150 ℃ constant temperature, stop heating, the cooling accomplishes the solidification.
Uniformly mixing the component A and the component B described in the embodiments 1, 2 and 3 according to respective mass ratio, defoaming in vacuum for 30 minutes, leveling the mixture in a mold tank according to the requirements of GB/T528-2009, slowly heating to 130 ℃, curing at 130 ℃ for 2-3 hours at constant temperature, stopping heating, cooling, finishing curing, and preparing into a sheet. Testing one: according to GB2410-80
Testing the transmittance of the sheet sample; and (2) testing: preparing a dumbbell-shaped silica gel sample according to the GB/T528-2009 requirements, testing the tensile strength of the silica gel sample, and testing three: testing the hardness of the silica gel sample according to GB/T2411-2008; and (3) testing: the refractive index of the silica gel sample was measured using an Abbe refractometer.
Table one: performance index table
Performance index ﹨ sample | Example 1 | Example 2 | Example 3 |
Transmittance after curing (%) | 95.5/(585nm) | 95.3/(585nm) | 95.7/(585nm) |
Tensile Strength (MPa) | 6.55 | 6.17 | 6.39 |
Hardness after curing (A) | 65 | 69 | 67 |
Refractive index | 1.51 | 1.52 | 1.51 |
As can be seen from the table I, the light transmittance of the cured sheet samples (1 mm thick) of the samples of examples 1, 2 and 3 is above 95% at a wavelength of 585 nm, the tensile strength is above 6.17MPa, the hardness after curing is 66A-69A, and the refractive index is above 1.51, which all reach the expected target and are suitable for packaging power LEDs.
The above-mentioned embodiments are merely descriptions of the preferred embodiments of the present invention, and do not limit the scope of the present invention, and various modifications and improvements made to the technical solution of the present invention by those skilled in the art without departing from the spirit of the present invention should fall within the protection scope defined by the claims of the present invention.
Claims (2)
1. A high-refractive-index LED organic silicon packaging material and a preparation method thereof are characterized in that: the LED organosilicon packaging material with the high refractive index is composed of a component A and a component B, wherein the mass ratio of the component A to the component B is 5: 1, and the component A comprises the following raw materials in parts by mass: 140-160 parts of methyl high phenyl vinyl silicone resin, 90-110 parts of vinyl phenyl silicone oil and 0.2-0.6 part of platinum catalyst; the component B comprises 25-35 parts of high phenyl hydrogen silicone resin, 15-25 parts of methyl phenyl hydrogen silicone resin and 0.3-1 part of inhibitor;
the preparation method of the LED organic silicon packaging material with the high refractive index comprises the preparation of a component A and the preparation of a component B; wherein,
the preparation of the component A comprises the following steps: sequentially adding 140-160 parts by mass of methyl high phenyl vinyl silicone resin, 90-110 parts by mass of vinyl phenyl silicone oil and 0.2-0.6 part by mass of platinum catalyst into a stirrer, and uniformly stirring to obtain the component A;
the preparation of the component B comprises the following steps: sequentially adding 25-35 parts by mass of high phenyl hydrogen silicone resin, 15-25 parts by mass of methyl phenyl hydrogen silicone resin and 0.1-0.3 part by mass of inhibitor into a stirrer, and uniformly stirring to obtain the component B.
2. The high-refractive-index LED organosilicon encapsulating material and the preparation method thereof according to claim 1, wherein the high-refractive-index LED organosilicon encapsulating material is characterized in that: the methyl high phenyl vinyl silicone resin has a chemical general formula of (PhSiO)3/2) x1 (Ph2SiO)x2 (Me2SiO)x3 (ViMe2SiO1/2) x4A compound of formula (I), wherein PhSiO3/2Is a trifunctional link, in which Ph2SiO、Me2SiO is a difunctional mer, ViMe2SiO1/2Is a monofunctional link; wherein Ph is phenyl, Me is methyl, Vi is vinyl, x1= 0.55-0.60, x2= 0.02-0.04, x3= 0.02-0.04, x4= 0.35-0.45, and the sum of the values is x1+ x2+ x3+ x4= 1; the vinyl phenyl silicone oil has a chemical general formula of ViMe2 SiO ( Si Me2O)m (SiPh2O)n Si Me2A compound Vi, wherein Ph is phenyl, Me is methyl, Vi is vinyl, m and n are integers which are more than 10 and m + n is less than 50, and the molar percentage of the vinyl is 0.78%; 5 mol% phenyl and a viscosity of 3050mPa @; the high phenyl hydrogen-based silicone resin is a higher viscosity MDT resin with trifunctional chain links, bifunctional chain links and monofunctional chain links; has the chemical general formula of (PhSiO)3/2)y1(Ph2SiO)y2(Ph3SiO1/2) y3 (HMe2SiO1/2) y4A compound of formula (I), wherein PhSiO3/2Is a trifunctional link, in which Ph2SiO is a difunctional chain member, Ph3SiO1/2、HMe2SiO1/2Is a monofunctional link; ph is phenyl, Me is methyl, Vi is vinyl, y1= 0.5-0.6, y2= 0.02-0.03, y3= 0.02-0.03, y4= 0.3-0.4, and the sum of the values is y1+ y2+ y3+ y4= 1; the methylphenylhydrosilicon resin is a lower viscosity MDT resin with trifunctional chain link, bifunctional chain link and monofunctional chain link; has the chemical general formula of (PhSiO)3/2)z1(Me2SiO)z2(Me3SiO1/2)z3 (HMe2SiO1/2) z4A compound of formula (I), wherein PhSiO3/2Is a trifunctional mer of formula Me2SiO is a difunctional mer, (Me)3SiO1/2)、(HMe2SiO1/2) Is a monofunctional link; wherein Ph is phenyl, Me is methyl, Vi is vinyl, z1= 0.45-0.55, z2= 0.08-0.09, z3= 0.06-0.07, z4= 0.30-0.35, and the sum of the values is z1+ z2+ z3+ z4= 1; the platinum catalyst is one selected from platinum-1, 3-dimethyl-1, 3-diphenyl-1, 3-divinyl siloxane complex, platinum-1, 1, 3, 3-tetramethyl-1, 3-divinyl-disiloxane complex and chloroplatinic acid-divinyl tetramethyl disiloxane complex; the inhibitor is one or more than one selected from 1-ethynylcyclohexanol, 3-diphenyl-1, 5-divinyl-1, 1, 5, 5-tetramethyltrisiloxane, 3-phenyl-1, 5-divinyl-1, 1, 3, 5, 5-pentamethyltrisiloxane and phenyl tris (dimethylvinylsiloxy) silane.
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