CN103961270A - Carbon-removing antifouling transparent protection liquid and preparation method thereof - Google Patents

Abstract

The invention discloses a carbon-removing antifouling transparent protection liquid and a preparation method thereof. The protection liquid comprises, by weight, 0.5% to 1.5% of a surfactant, 0.1% to 0.5% of a hydrophilic natural polymer active material, 0.05% to 0.1% of poly-hexamethyl biguanide, 1.0% to 5.0% of water soluble silicone oil, 5% to 10% of edible alcohol, 10% to 15% moisturizing emollients, 0% to 0.5% of citric acid and 0.1% to 0.3% of essence, with the balance being deionized water. Aiming at shortcomings of the prior art, the invention prepares the carbon-removing antifouling transparent protection liquid having not only a blocking function of a common transparent protection liquid, but also functions of removing stains mildly and providing skin care. The carbon-removing antifouling transparent protection liquid has the advantages of convenience in use, remarkable effect and the like.

Description

A kind of clean antifouling stealth protection liquid of carbon and preparation method thereof

Technical field

The present invention relates to a kind of protective liquid, refer in particular to a kind of clean antifouling stealth protection liquid of carbon and preparation method thereof.

Background technology

People are in the middle of routine work, and the skin of exposure tends to be subject to the practitioner of the industries such as pollution and intrusion, particularly colliery, finance, medical treatment, the machinery of various dirts, dust and antibacterial.Because of work taken up feature, the easy skin permeation texture of the spot deep layers such as the frequent powder contacting of skin, greasy dirt, pathogenic bacteria, be difficult to wash these spots by general cleaning method and traditional cleaning skin articles for use, meanwhile, clean and also can damage skin frequently.For example: mechanic contacts the organic solvents such as machine oil, kerosene, paint, and skin is had to stimulation in various degree, that the skin part that the person that can make Long Term Contact exposes occurs is dry, decortication, breach and the symptom such as irritated.Also have China's coal-mine workman's number very huge, coal miner is in the mining environment of down-hole, carbon black powders granularity is little, easily be bonded on skin, being bonded at fine carbon black with it and antiperspirant and sebum mixes, adhesion strength is high, be difficult to wash off with common articles for washing, must use the articles for washing that alkalescence is higher, the frequent higher articles for washing of alkalescence that uses, not only washes rear uncomfortablely, and excessively defat meeting makes xerosis cutis, coarse, wrinkle is many, be easy to conceal dirt, also easily cause irritable inflammation simultaneously, have a strong impact on miner's beauty treatment and health.When counting, be infected with various bacteria and virus practitioner every day of financial industry at work, is unfavorable for health.In order to prevent these occupational hazards, conventionally the method preventing is to wear mask and protective gloves, but inconvenient at work, affect work efficiency, do not reach desirable protection effect yet, in addition, on market, also there is in recent years the Protection Product (being also stealthy liquid gloves) of similar liquid gloves effect, although there are the effects such as certain antifouling, dustproof, bacteriological protection, but also have many problems, the thin film company property for example forming is poor, not wear-resisting, short, function singleness of shelf-life etc., makes practical effect not obvious.

Summary of the invention

The technical problem to be solved in the present invention is to provide one and not only has barriers function, also has the effect of gentle decontamination, nursing skin, have easy to use, antifouling stealth protection liquid of clean carbon of the advantage such as effect is remarkable and preparation method thereof.

The technical scheme that the present invention solves the problems of the technologies described above employing is:

A kind of clean antifouling stealth protection liquid of carbon, the percentage by weight of described protective liquid prescription is:

Surfactant: 0.5～1.5%;

Hydrophilic natural macromolecule active material: 0.1～0.5%;

Poly-hexamethyl biguanide 0.05～0.1%;

Water-soluble silicon oil 1.0～5.0%;

Edible ethanol 5～10%;

Humectants and emollients 10～15%;

Citric acid 0～0.5%;

Essence 0.1～0.3%;

Deionized water is surplus;

Described surfactant is alkyl polyglucoside APG0814, anion and amphoteric amino acids class surfactant, one or both in coco betaine;

Described humectants and emollients is one or both of Polyethylene Glycol apoplexy due to endogenous wind of glycerol, propylene glycol, sorbitol, molecular weight 200～800.

This preparation method is as follows:

[1], the preparation of film former: first humectants and emollients is joined in the rustless steel emulsion tank of 50L, add hydrophilic macromolecule active material, open high-shear emulsion machine and stir after 10 minutes, stop stirring, leave standstill thawing for subsequent use after 2 hours;

[2], by formula ratio, deionized water is joined in material-compound tank, be warmed up to 50～60 DEG C, open and stir, add surfactant, stir 10～20 minutes, it is dissolved completely;

[3], open cooling water, make the feed liquid in material-compound tank cool to 30～35 DEG C, the film former that adds step [1] to prepare, stirs 20～30 minutes, transparent to solution till, with citric acid adjusting pH value to 6.5～7.0;

[4], again add water-soluble silicon oil, poly hexamethylene biguanide, edible ethanol, essence, stir 10 minutes, after stopping stirring, leave standstill 30 minutes, discharging detects, and pH value 6.5～7.0 obtains this protective liquid.

The technological progress that adopts technique scheme the present invention to obtain is:

The present invention adopts natural green surfactant, the composite skin forming such as hydrophilic natural macromolecule active material and humectants and emollients hinders protection cleaning solution, on the basis that intercepts formula system, add natural green surfactant, environment-friendly type antibacterial, emollient, not only play the barrier action of the harmful substances such as isolation dirt, and work complete or be infected with dirt after easily clean up with clear water, there is protection, clean, skin moistening, the several functions such as sterilization, also meet people to product efficacy variation, natural, environmental protection, gentle, nontoxic non-stimulated demand.

The surfactant that the present invention adopts is alkyl polyglucoside APG0814, anion and amphoteric amino acids class surfactant, one or both in cocamido propyl betaine, raw material sources are in natural, all belong to green surfactant, biodegradation is complete, nontoxic to human body, gentle non-stimulated, there is good broad spectrum antibiotic activity; Surface tension is low, gentle decontamination, and foam exquisiteness, good stability, pH value is alkalescence, and acidic materials are had to certain neutralization.

The poly hexamethylene biguanide that the present invention adopts, belongs to nontoxic level, is a kind of water miscible antibacterial, non-stimulated to skin.

The hydrophilic natural macromolecule active material that the present invention adopts: be the crosslinked acrylate copolymer of a kind of warp (water solublity resin of thickening CBP-I type), it is acid that pH value is, gene in molecule is after alkaline matter neutralize ions, there is hydrophilic, negative charge is mutually exclusive, and strand disperse is stretched, and significantly expands, forming transparent hydrophilic gel, is also a kind of pH value regulator.

The water-soluble silicon oil that the present invention adopts, not only can deep layer Glycerin, also can play grease proofing, waterproof action.

The humectants and emollients that the present invention adopts is one or both of Polyethylene Glycol apoplexy due to endogenous wind of glycerol, propylene glycol, sorbitol, molecular weight 200～800.Auxiliary element: edible ethanol, both made disinfectant, make again film forming adjuvant.

In addition, outstanding effect of the present invention is as follows:

1. the feature of this product is that pH value is 7 neutral transparence aqueous solution, non-stimulated to skin, environmentally safe, barrier propterty is good, not only dirt, harmful dust are had to fabulous buffer action, and antibacterial, virus are had to shielding action, also have antibacterial, sterilize, prevent the functions such as xerosis cutis.

2. before the feature of this product is work; this product is evenly rubbed and is applied in skin surface; slightly dry; the stealthy protective film being invisible to the naked eye at skin surface formation one deck also can be firmly held on skin; prevent that the dirt such as dust, greasy dirt from infiltrating skin texture; after operation; very easily rinse well with clear water; because thin film contains surfactant; and there is good hydrophilic; can quickly and easily thin film and subsidiary Fouling Cleaning be fallen, realized clean and prevented that dirt deposition is in the function of skin.In this product, containing skin care ingredient, after thin film is retained and cleaned, can play effect of skin protection skin moistening, skin is had and well moistens nursing role, and can make protection, decontamination, antibacterial, skin protection multiple efficacies once complete.

3. this product belongs to environmental type product, hinder on liquid (stealthy liquid gloves) basis and added natural green surfactant and hydrophilic natural macromolecule active material at traditional skin, the several functions such as antifouling, decontamination, antibacterial, skin protection are rolled into one, market prospect is wide, both convenient and swift, there is environmental protection.

Detailed description of the invention

Embodiment 1:

Surfactant A PG0814 1g,

Hydrophilic natural macromolecule active material 0.3g,

Poly-hexamethyl biguanide 0.08g,

Water-soluble silicon oil 3g,

Edible ethanol 8g,

PEG400 10g,

Citric acid 0.1g,

Essence 0.1g,

Deionized water 77.42g.

Preparation method:

The preparation method of the clean antifouling stealth protection liquid of carbon, this preparation method is as follows:

[1], the preparation of film former: first humectants and emollients PEG400 is joined in the rustless steel emulsion tank of 50L, add hydrophilic macromolecule active material, open high-shear emulsion machine and stir after 10 minutes, stop stirring, leave standstill thawing for subsequent use after 2 hours;

[2], by formula ratio, deionized water is joined in material-compound tank, be warmed up to 50 DEG C, open and stir, add surfactant A PG0814, stir 15 minutes, it is dissolved completely;

[3], open cooling water, make the feed liquid in material-compound tank cool to 35 DEG C, the film former that adds step [1] to prepare, stirs 25 minutes, transparent to solution till, with citric acid adjusting pH value to 6.5～7.0;

[4], again add water-soluble silicon oil, poly hexamethylene biguanide, edible ethanol, essence, stir 10 minutes, after stopping stirring, leave standstill 30 minutes, discharging detects, and pH value 6.5～7.0 obtains this protective liquid.

Embodiment 2:

N-cocoyl Glycine sodium 1.2g,

Hydrophilic natural macromolecule active material 0.2g,

Poly-hexamethyl biguanide 0.1g,

Water-soluble silicon oil 2.5g,

Edible ethanol 6g,

Propylene glycol 12g,

Citric acid 0.2g,

Essence 0.1g,

Deionized water 77.7g.

Preparation method:

The preparation method of the clean antifouling stealth protection liquid of carbon, this preparation method is as follows:

[1], the preparation of film former: first humectants and emollients propylene glycol is joined in the rustless steel emulsion tank of 50L, add hydrophilic macromolecule active material, open high-shear emulsion machine and stir after 10 minutes, stop stirring, leave standstill thawing for subsequent use after 2 hours;

[2], by formula ratio, deionized water is joined in material-compound tank, be warmed up to 55 DEG C, open and stir, add surfactant N-cocoyl Glycine sodium, stir 10 minutes, it is dissolved completely;

[3], open cooling water, make the feed liquid in material-compound tank cool to 30 DEG C, the film former that adds step [1] to prepare, stirs 30 minutes, transparent to solution till, with citric acid adjusting pH value to 6.5～7.0;

[4], again add water-soluble silicon oil, poly hexamethylene biguanide, edible ethanol, essence, stir 10 minutes, after stopping stirring, leave standstill 30 minutes, discharging detects, and pH value 6.5～7.0 obtains this protective liquid.

Embodiment 3:

Cocamido propyl betaine 1g,

Hydrophilic natural macromolecule active material 0.2g,

Poly-hexamethyl biguanide 0.08g,

Water-soluble silicon oil 4g,

Edible ethanol 6g,

Glycerol 12g,

Citric acid 0.1g,

Essence 0.2g,

Deionized water 76.42g;

Preparation method

The preparation method of the clean antifouling stealth protection liquid of carbon, this preparation method is as follows:

[1], the preparation of film former: first humectants and emollients glycerol is joined in the rustless steel emulsion tank of 50L, add hydrophilic macromolecule active material, open high-shear emulsion machine and stir after 10 minutes, stop stirring, leave standstill thawing for subsequent use after 2 hours;

[2], by formula ratio, deionized water is joined in material-compound tank, be warmed up to 55 DEG C, open and stir, add surfactant cocamido propyl betaine, stir 10 minutes, it is dissolved completely;

[3], open cooling water, make the feed liquid in material-compound tank cool to 30 DEG C, the film former that adds step [1] to prepare, stirs 25 minutes, transparent to solution till, with citric acid adjusting pH value to 6.5～7.0;

[4], again add water-soluble silicon oil, poly hexamethylene biguanide, edible ethanol, essence, stir 10 minutes, after stopping stirring, leave standstill 30 minutes, discharging detects, and pH value 6.5～7.0 obtains this protective liquid.

Performance test (this product compared with similar products)

Project kind	This product	Market 1# product	Market 2# product
				Outward appearance	Water white transparency	Colourless viscous liquid	Milky thick liquid
Dry film forming speed (consumption 3g)	5s	20s	30s
				Cleaning effect	Good	Generally	Generally
Zest	Nothing	Nothing	Have
				PH value	7.0	8.2	8.7

Claims (2)

1. the antifouling stealth protection liquid of clean carbon, is characterized in that, described protective liquid prescription

Percentage by weight is:

Surfactant: 0.5～1.5%;

Hydrophilic natural macromolecule active material: 0.1～0.5%;

Poly-hexamethyl biguanide 0.05～0.1%;

Water-soluble silicon oil 1.0～5.0%;

Edible ethanol 5～10%;

Humectants and emollients 10～15%;

Citric acid 0～0.5%;

Essence 0.1～0.3%;

Deionized water is surplus;

Described surfactant is alkyl polyglucoside APG0814, anion and amphoteric amino acids class surfactant, one or both in coco betaine;

Described humectants and emollients is one or both of Polyethylene Glycol apoplexy due to endogenous wind of glycerol, propylene glycol, sorbitol, molecular weight 200～800.

2. the preparation method of the antifouling stealth protection liquid of clean carbon according to claim 1, is characterized in that, this preparation method is as follows:

[1], the preparation of film former: first humectants and emollients is joined in the rustless steel emulsion tank of 50L, add hydrophilic macromolecule active material, open high-shear emulsion machine and stir after 10 minutes, stop stirring, leave standstill thawing for subsequent use after 2 hours;

[2], by formula ratio, deionized water is joined in material-compound tank, be warmed up to 50～60 DEG C, open and stir, add surfactant, stir 10～20 minutes, it is dissolved completely;

[3], open cooling water, make the feed liquid in material-compound tank cool to 30～35 DEG C, the film former that adds step [1] to prepare, stirs 20～30 minutes, transparent to solution till, with citric acid adjusting pH value to 6.5～7.0;

[4], again add water-soluble silicon oil, poly hexamethylene biguanide, edible ethanol, essence, stir 10 minutes, after stopping stirring, leave standstill 30 minutes, discharging detects, and pH value 6.5～7.0 obtains this protective liquid.