CN103937090A - Antibacterial and skin care polypropylene fiber master batch and fabric - Google Patents
Antibacterial and skin care polypropylene fiber master batch and fabric Download PDFInfo
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- CN103937090A CN103937090A CN201410079736.2A CN201410079736A CN103937090A CN 103937090 A CN103937090 A CN 103937090A CN 201410079736 A CN201410079736 A CN 201410079736A CN 103937090 A CN103937090 A CN 103937090A
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
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- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
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- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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Abstract
The present invention provides an antibacterial and skin care polypropylene fiber master batch and a fabric thereof, wherein 2-7% by weight of a myrica rubra leaf extract, 1.5-5% by weight of a pomelo peel extract, 6-12% by weight of an auxiliary agent and the balance of a polypropylene resin are uniformly mixed and added to a twin screw extruder to carry out melting granulation to prepare the antibacterial and skin care polypropylene fiber master batch, and 25-50% by weight of the antibacterial and skin care polypropylene fiber master batch and 50-75% of a polypropylene resin are subjected to mixing, melting, spinning and weaving to obtain the fabric. According to the present invention, the spinnability is good, and the fiber strength is high; after the material of the present invention is made into various personal clothing, elaborate care can be unwittingly provided for human body during wearing, significant effects of soften, white, tender and smooth skin achievement, antibacterial, anti-oxidation, ultraviolet ray absorption, black removing, sallow complexion removing and the like can be provided, and the beneficial changes in human body functions and the skin are easily promoted; and the waste resources are reused so as to provide huge social, ecological, environmental and economic benefits.
Description
Technical field
The present invention relates to a kind of master batch and fabric thereof, particularly relate to a kind of antibiotic skin-care polypropylene fibre master batch and fabric, belong to chemical fibre technical field.
Background technology
Along with the development of chemical fibres industry state of the art and improving constantly of people's quality of life, that people also more and more pay attention to is ventilative to the moisture absorption of garment material, the pursuit of antibiotic health care, uvioresistant and comfort etc., in order to adapt to people's demand, the various new synthon of manufacturing of employing new technology constantly come out, and various functional fabrics also emerge in an endless stream.
Polypropylene fibre (polypropylene fiber) is commonly called as polypropylene fibre, and it is to make by propylene the fiber that raw material makes through polymerization, melt spinning.Because its raw material sources enrich, cheap, production technique is simple, light weight is soft and have good advantages such as wet, perspire, heat retention, anti-mould and anti-moth of leading, be widely used in dress ornament, decoration and industry articles for use, particularly be easy to be woven into fabric with natural fiber or man-made fiber blending, the textiles that very suitable manufacture underwear, T-shirt, sheet etc. directly contact with human body skin.But because above-mentioned fabric does not possess antibiotic skin-care function, be easily infected with the various dirts in various human secretions and environment while contacting with human body skin, breed bacteria or microorganism, often cause very large injury to human body, affects the healthy of people.
For these reasons, people are more placed on attention on research and development antibacterial polypropylene fabric lining.At present, a lot of for the antiseptic-germicide kind of polypropylene fibre fabric, it mainly comprises inorganic antiseptic, organic antibacterial agent and natural antibacterial agent.And inorganic antiseptic and organic antibacterial agent day by day feel a draft because of its known or potential toxic side effect.Natural antibacterial agent is that antimicrobial component contained from natural phant extracts and forms, and has good biocompatibility, antimicrobial long-acting and to advantages such as human-body safety have no side effect, in application, is day by day subject to people's attention.But due to the difference in selection or preparation method and defect, natural antibacterial agent easily causes that in polypropylene fibre master batch cohesion, maldistribution and mixed effect are poor, finally cause spinning technique difficulty, fibre strength is low, the fabric flexibility and the crease resistance that are made into are poor, make the problems such as wearing feeling and ventilation property variation.And function ratio is more single, in uvioresistant, promote new cell regeneration, improve cytoactive, strengthen skin cells immunizing power, delay senility, be obviously short of aspect the skin-protection and health-care such as removing spots and whitening, nutritive ingredient can not effectively be absorbed, and cannot promote the useful variation of function of human body and skin.
Red bayberry (Myrica rubra) is Myruca ceas aiphyllium plant, in China, distribute very wide, mainly be distributed in the provinces such as Zhejiang on the south the Changjiang river, Fujian, Hunan, the resource of its leaf is very abundant, orchard worker is for improving red bayberry yield and quality, all can prune Hairy Waxmyrtle every year, and the branches and leaves of pruning are often given it up.In fact, in Folium Myricae rubrae, be rich in the biological activitys such as aldehydes matter, be a kind of plant resources with potentiality to be exploited, according to the herbal > > of < < China, record Folium Myricae rubrae bitter, micro-pungent, warm in nature, eliminating dampness is dispeled the wind, antipruritic, main skin eczema, useful Folium Myricae rubrae among the people is controlled the custom (Chinese medicine voluminous dictionary 1979) of the diseases such as scald, too fat to move, stomachache.There are some researches show, from Folium Myricae rubrae, separation obtains phenolic compound, terpene lactone and alkaloid etc. have stronger restraining and sterilizing bacteria effect, there are very high pharmaceutical use [Lin Jianyuan etc., " total flavone extracting process and anti-oxidant activity research thereof in Folium Myricae rubrae " < < Food science > > 2011, 32 (20): 26-29], one of its main active ingredient phenolic compound is mainly by ampelopsin, the flavonoid compounds such as Quercetin and proanthocyanidin compounds form, there is stronger anti-oxidant activity, can remove activity in vivo oxyradical, prevent that microbial film lipid is by superoxide radical and hydroxy radical qiao oxidation [Xia Qile etc., " research of Waxberry leaf extract anti-oxidant activity " < < Food science > > 2004, 25 (8): 80-82], there is antianaphylaxis, anticancer, antithrombotic, adjust blood fat, improve microcirculation, strengthen cell viability, improve immunizing power, the multiple potential physiological function such as delay senility.Modern pharmacological research confirms, ampelopsin is a poly-hydroxy flavonoid compound, not only there is extremely strong Green Tea Extract oxidation and UV absorbing properties, and platelet activation factor (PAF) is had to special antagonistic action, can suppress the inflammation and the pruritus [Zang Baoxia etc. that by platelet activation factor, are caused, " effect of ampelopsin to platelet activation factor antagonism " < < Acta Pharmaceutica Sinica > > 2003,38 (11): 831-833].Experiment shows, Waxberry leaf extract is to large intestine bar mattress, bacillus subtilis mattress, Staphylococcus aureus mould mattress, head mold, aspergillus niger has stronger restraining effect [Mo Kaiju etc., " research of Waxberry leaf extract bacteriostatic action " journal > > of < < Hubei Institute For Nationalities natural science edition 2008 (3): 269-272], it is melanic synthetic in body that Waxberry leaf extract can also suppress, Exposure to Sunlight dermatitis and various color spot are all had and obviously resist effect [Liv M, Karl M, Reidar B.ntioxi dant activity of fruit exudates and C-Methylated Dihydrochalcones from Myricagale.Planta Medica, 1995, 61 (6): 515-518].
Shaddock is Rutaceae citrus, claims again " pomelo ", " fragrant throwing " etc., and china natural resources is abundant, in Zhejiang, all there are a large amount of cultivations on the ground such as Fujian, Guangdong.Shaddock pulp contains multiple nutritional components, and juice is many, delicate fragrance, sour-sweet, Liang Run, is that people like one of fruit of food, is also the fruit of the medical circle tool dietotherapy benefit of generally acknowledging.Yet, after the pulp of edible shaddock, can produce a large amount of pomelo peels, often as waste, be dropped, become very important source of pollution, both uneconomical more not environmental protection.Documents and materials demonstration, the sweet acid of pomelo peel taste, cold in nature, has food digesting stomach fortifying, promotes the production of body fluid to quench thirst, preventing phlegm from forming and stopping coughing, the effect of laxation defaecation.Also on the books at < < Compendium of Materia Medica > >, pomelo peel can be aid digestion, except turgor, reduce phlegm.The traditional Chinese medical science thinks, pomelo peel has cough-relieving, reduces phlegm, regulates the flow of vital energy, anti-inflammatory, the effect such as antipruritic.Modern scientific research is found, pomelo peel is except containing the mineral substance such as carotene, Vb, Vc, Vp and potassium, calcium, phosphorus, magnesium, sodium, be rich in the Multiple components such as pectin, organic acid, protein, pigment, naringin, shaddock essence, naringin (Naringin) claim again naringin, narigin, aurantiin, be a kind of flavanone compounds, have strong ultraviolet absorption peak.Various biological activity and pharmacological action that it has are confirmed by the experimental results, have antianaphylaxis, hypotensive, anti-inflammatory, antibacterial, anti-ageing, press down enzyme, protect the liver reducing blood-fat, the effect such as anti-oxidant, removing spots and whitening and strengthening immunity, now in medical science and foodstuffs industry, obtained application.But not yet finding so far that pomelo peel and Folium Myricae rubrae are composite is added into the precedent that antibiotic skin-care fabric is made in acrylic resin blend, also has no bibliographical information.
Summary of the invention
The object of the invention is to solve the deficiency that above-mentioned prior art exists, a kind of antibiotic skin-care polypropylene fibre master batch is provided, improved being added into pomelo peel and Folium Myricae rubrae and extracting composition and easily produce the poor problem of cohesion, maldistribution and mixed effect, good spinnability, fibre strength is high.
Meanwhile, the present invention also provides and has utilized this antibiotic skin-care polypropylene fibre master batch melt-spinning, weave fabric, this fabric contains the bioactive ingredients existing with Folium Myricae rubrae and pomelo peel extraction composition complex form, soft, crease resistance, ventilation property and skin-friendly are good, percutaneous rate is controlled, directly contact for a long time with human body skin, with regard to forming, to human body, carry out antibacterial, in the time of antiultraviolet, slowly releasing nutritive ingredient is absorbed by skin, removing spots and whitening, be beneficial to the useful variation that promotes function of human body and skin, and waste resource recycling, containing huge society, ecological, environment and economy benefit.
For solving the problems of the technologies described above, the invention provides a kind of antibiotic skin-care polypropylene fibre master batch and fabric thereof, it is characterized in that, described antibiotic skin-care polypropylene fibre master batch is the Waxberry leaf extract by weight percentage 2%～7%, the acrylic resin of 1.5%～5% pomelo peel extract and 6%～12% auxiliary agent and residue percentage composition mixes and adds melt pelletization in twin screw extruder to make, described fabric is acrylic resin mixing the melting by the antibiotic skin-care polypropylene fibre master batch of weight percentage 25%～50% and 50%～75%, through spinning, weave, bleaching and dyeing, sizing forms,
Described Waxberry leaf extract adopts following methods preparation: gather fresh Folium Myricae rubrae and clean, pulverize, add water making beating, squeezing, obtain pressed liquor and press residue, pressure marc is put into container and is added the water of 5～15 times of amounts of press residue, under 75～90 ℃ of conditions, extract 3～5 hours, filter, obtain squeezing juice, merge pressed liquor and squeezing juice, filter, filtrate is crossed D101 macroporous adsorptive resins, first use distilled water wash-out resin column to colourless, use afterwards 45～70% ethanol elution, collect elutriant, concentrating under reduced pressure, spraying is dry, with grinding body porphyrize, cross 100～120 mesh sieves, obtain Waxberry leaf extract,
Described pomelo peel extract adopts following methods preparation: gather fresh pomelo peel and clean, cut into pieces, be soaked in petroleum ether degreasing, after sherwood oil volatilizees naturally, 35%～70% ethanol that adds 2～5 times of amounts of pomelo peel, under 60～85 ℃ of conditions, extract 5～8 hours, filter, filtrate decompression is concentrated into thick pulpous state, the water-saturated n-butanol extraction that adds 1～3 times of amount of thick pulpous state, getting propyl carbinol, to be evaporated to mutually relative density be 1.05～1.20 medicinal extract shape, 75%～85% dissolve with ethanol that first adds 0.2～1.5 times of amount of medicinal extract shape, add again the acetone of 3～6 times of amounts of medicinal extract shape and the acticarbon of 1.5～3% times of amounts fully to vibrate, centrifugation, dry, with grinding body porphyrize, cross 100～120 mesh sieves, obtain pomelo peel extract,
In order to make Waxberry leaf extract, pomelo peel extract be dispersed in top layer and the inside of polypropylene fibre, meet the spinning property in spinning technique, when granulation, need be added into appropriate auxiliary agent, its adding technology is identical with the requirement of the existing common polypropylene fibre of spinning, repeats no longer one by one herein.
In the present invention, described auxiliary agent comprises molecular weight regulator, oxidation inhibitor, dispersion agent.
Molecular weight regulator in above-mentioned auxiliary agent is selected from 2,5-dimethyl-2, a kind of or its built agent in 5-bis-(t-butylperoxy) hexane, the tertiary butane of peroxidation, tertiary lauryl mercaptan, dicumyl peroxide, its add-on is 0.3～3.5% of antibiotic skin-care polypropylene fibre total amount.
Oxidation inhibitor in above-mentioned auxiliary agent is selected from a kind of or its built agent in antioxidant 1076, oxidation inhibitor 1098, oxidation inhibitor IR1010, irgasfos 168, and its add-on is 0.2～2% of antibiotic skin-care polypropylene fibre total amount.
Dispersion agent in above-mentioned auxiliary agent is to form by Poly Propylene Wax, nonane diacid and plant sterol are composite, wherein, described plant sterol is that the single or arbitrary proportion of Sitosterol, Stigmasterol, campesterol, brassicasterol mixes, its weight ratio is: Poly Propylene Wax: nonane diacid: plant sterol=85～90: 4～6: 6～9, the add-on of described dispersion agent is depending on the total amount of Waxberry leaf extract and pomelo peel extract, and the preferred add-on of the present invention is: Waxberry leaf extract and pomelo peel extract total amount: dispersion agent=1: 0.12～9.
Plant sterol in above-mentioned auxiliary agent, belong to vegetalitas steroidal compounds, it is the important composition composition of vegetable cell, also be a kind of active components of plants, extensively be present in plant cell membrane, its chemical structure and biological function are similar to cholesterol, and both are only side chain at difference part, have the good chemical propertys such as good fluidity, dissemination be strong.Wherein the most strikingly there is the effect that reduces cholesterol, and have anti-inflammatory, anti-oxidant, suppress tumour, prevention and cure of cardiovascular disease, anticancer, can promote wound healing, make muscle hyperplasia, strengthen the functions such as capillary vessel circulation, in addition, plant sterol also has stronger perviousness, the moisture that can keep skin surface, promote the metabolism of skin, suppress skin inflammation, eliminate skin keratin, prevent skin aging, the effect such as sun-proof.
Nonane diacid in above-mentioned auxiliary agent, claims again " lepargylic acid ", is middle long-chain biatomic acid, is important organic synthesis intermediate.Molecular formula C
9h
16o
4molecular weight 188.22, proportion 1.0291 (4 ℃), 1.225 (25 ℃), fusing point: 106.5 ℃ of boiling points: 286.5 ℃/178.3 ℃, main application is: be typically used as the raw material of production softening agent dioctyl azelate and spices, lubricating oil, finish, polyamide resin etc., have splendid flexibility and toughness.In addition, nonane diacid also can be used for protection and the treating for skin disease of skin, and energy competitive inhibition tyrosine oxidase, can stop " melanoid " to deposit in skin, thereby make skin pure white.
Applicant's surprised discovery under study for action, plant sterol can be worked in coordination with onset with nonane diacid, adjustable or accelerate Waxberry leaf extract, the activeconstituents of pomelo peel extract is to infiltration dynamics in skin, and energy steady seepage rate of release, increase the cuticular permeability of physiologic barrier, being beneficial to the activeconstituents having in raising fabric is evenly discharged on skin effectively, better see through skin surface and enter deep layer and body circulation, promote new cell regeneration, improve cytoactive, strengthen the immunizing power of skin cells, realize antibacterial, antianaphylaxis, anti-inflammatory, anti-oxidant, crease-resistant, absorb ultraviolet ray, the multiple efficacies such as removing spots and whitening.Preferably, when nonane diacid and plant sterol 4: 5～7, both synergies are best.
More unexpectedly be, applicant is from vast as the open sea existing compound, chance on, by Poly Propylene Wax, nonane diacid, plant sterol is composite in ratio of the present invention, mutual organic infiltration, too many levels is worked in coordination with onset, both can reduce it and polyacrylic fusing point is poor, again because of the existence of aliphatic chain, raising and consistency and stability, dissemination is strong, in the process of preparing antibiotic skin-care polypropylene fibre master batch, make Waxberry leaf extract and pomelo peel extract can disperse more fully in acrylic resin matrix, therefore produce cohesion while having solved granulation spinning, the problem that maldistribution and mixed effect are poor, spinning property and fibroblast intensity have greatly been improved.
According to the present invention, above-mentioned acrylic resin is fiber-grade pp resin well known in the art, its melting index is 5～45g/10min, if used the acrylic resin of low melt index, the flowing property of its melt is poor, and spinning processing performance is bad, is difficult to improve spinning speed, and used the acrylic resin of high fusion index, low-fiber physical and mechanical properties can be fallen.
Prepare master batch of the present invention and fabric technical process mainly comprises granulation, spinning, weaves, bleachinges and dyeing, shapes.
In the present invention, in related granulation, spinning, woven operational path and the existing acrylic resin of preparation, adding inorganic materials, to carry out granulation, spinning, woven operational path basic identical.First in acrylic resin, add Waxberry leaf extract, pomelo peel extract to mix, add during this time appropriate auxiliary agent, then adopt twin screw extruder melt pelletization to make and contain the antibiotic skin-care polypropylene fibre master batch that Folium Myricae rubrae extracts, pomelo peel extracts, wherein, Waxberry leaf extract addition is 5～16%, pomelo peel extract addition is 2～13%.
Above-mentioned prepared antibiotic skin-care polypropylene fibre master batch and acrylic resin are mixed again, are diluted to Waxberry leaf extract and pomelo peel extract predetermined concentration, adopt conventional melt-spinning technology flow process to carry out spinning, make antibiotic skin-care polypropylene fibre.
Antibiotic skin-care polypropylene fibre of the present invention can be pre-oriented yarn POY, drafting silk DT, stretch yarns DTY, or staple fibre.
According to different needs, above-mentioned staple fibre also can with cotton, fiber crops, hair, silk, terylene, polyamide fibre, acrylic fibers, polyvinyl chloride fibre, spandex, polyvinyl, viscose fiber blending.
In addition, that antibiotic skin-care polypropylene fibre of the present invention can be used as is woven, through compiling and the fibrous material of the fabric such as weft knitting, can use separately, also can be by a certain percentage and yarn and the fiber interweaving such as cotton, fiber crops, hair, silk, artificial cotton, adopt conventional weave, bleaching and dyeing, setting process makes fabric.
The fabric of producing according to the present invention not only preserved to greatest extent plain polypropylene fiber good lead the characteristics such as wet, perspire, heat retention, anti-mould and anti-moth, and physiologically active substance and nutritive ingredient that the raw materials such as Folium Myricae rubrae, pomelo peel, green plum branches and leaves, nonane diacid, plant sterol are had are fully introduced, mutual organic infiltration, synergy, there is the skin cells of enhancing vigor, the effects such as nourishes rough skin, and more can reach antibacterial, antianaphylaxis, anti-inflammatory, anti-oxidant, absorb ultraviolet ray, decompose melanochrome, the effects such as skin whitening.Add more especially plant sterol, nonane diacid and greatly improved the Transdermal absorption effect of human body skin when improving spinning property and fibroblast intensity; promote skin metabolism; remove the free radical in body; protection skin is avoided ultraviolet injury, anti-sunburn, and the melanochrome on desalination skin hinders human body melanic synthetic; suppress microorganism; improve the natural cover for defense function of skin comprehensively, increase skin brilliant white elasticity, delayed skin aging.Experiment showed, with fabric of the present invention and make various underclothes, can make human body obtain unawares meticulous care in the middle of dress, wearing continuously just to have for 4 weeks and make significantly the soft white delicacy of skin, sparkling clean, and have the effect of moving back black, de-etiolation, light spot.After tested: UPF value >=36 of this fabric, rate of ultraviolet shield reaches 90%; Streptococcus aureus, intestinal bacteria, Candida albicans etc. are had to stronger restraining effect, and bacteriostasis rate is more than 85%.And raw material sources of the present invention are extensive, and waste is fully used, both solved environmental issue, containing again huge society, ecology and economic benefit.
Embodiment
With embodiment, further illustrate the present invention below, but the present invention is not limited.
In the present invention, if not refer in particular to, all equipment, raw material and auxiliary agent etc. all can be buied from market or the industry is conventional, and all per-cent, part is weight unit.
Property indices in following examples, all adopts following testing method and standard:
One, antiultraviolet test: according to the evaluation > > of standard GB/T/T18830-2009 < < ultraviolet resistance of fabric, use UPF UPF and the ultraviolet ray transmissivity T of U.S. Labsphere (blue luxuriant and rich with fragrance optics) UV-2000F yarn fabric SPF (sun protection factor) analyser test BLENDED FABRIC.As the UPF>30 of fabric, during T (UVA) <5%, this fabric belongs to antiultraviolet product.
Two, antibacterial test: according to evaluation the 3rd part of standard GB/T/20944.3-2008 < < antibacterial textile performance: the method for succusion > > is tested, the anti-microbial property of sample is evaluated by bacteriostasis rate, and calculation formula is:
X
S=(A-B)/A
In formula: X
sfor bacteriostasis rate (%); A is by average colony number before test agent vibration; B is that if the average colony number after vibration is greater than the average colony number before vibration, bacteriostasis rate calculates by 0 by average colony number after test agent vibration.
Embodiment mono-
1. raw materials pretreatment:
1. prepare Waxberry leaf extract: gather fresh Folium Myricae rubrae and clean, pulverize, add water making beating, squeezing, obtains pressed liquor and press residue, pressure marc is put into container and is added the water of 7 times of amounts of press residue, under 85 ℃ of conditions, extract 3 hours, filter, obtain squeezing juice, merge pressed liquor and squeezing juice, filter, filtrate is crossed D101 macroporous adsorptive resins, first uses distilled water wash-out resin column to colourless, use afterwards 45% ethanol elution, collect elutriant, concentrating under reduced pressure, spraying is dry, with grinding body porphyrize, cross 120 mesh sieves, obtain Waxberry leaf extract.
2. prepare pomelo peel extract: gather fresh pomelo peel and clean, cut into pieces, be soaked in petroleum ether degreasing, after sherwood oil volatilizees naturally, 40% ethanol that adds 3 times of amounts of pomelo peel, under 75 ℃ of conditions, extract 6 hours, filter, filtrate decompression is concentrated into thick pulpous state, the water-saturated n-butanol extraction that adds 2 times of amounts of thick pulpous state, getting propyl carbinol, to be evaporated to mutually relative density be 1.05～1.20 medicinal extract shape, 75% dissolve with ethanol that first adds 0.9 times of amount of medicinal extract shape, add again the acetone of 5 times of amounts of medicinal extract shape and the acticarbon of 1.5% times of amount fully to vibrate, centrifugation, dry, with grinding body porphyrize, cross 120 mesh sieves, obtain pomelo peel extract,
2. composition of raw materials:
Acrylic resin 56kg, Waxberry leaf extract 9kg, pomelo peel extract 6.5kg, oxidation inhibitor 3kg, molecular weight regulator 5kg, dispersion agent 20.5kg.
Acrylic resin in above-mentioned raw materials is fiber-grade pp resin, its melting index is 35g/10min, described molecular weight regulator is 2,5-dimethyl-2,5-bis-(t-butylperoxy) hexane, oxidation inhibitor is oxidation inhibitor IR1010, and it is composite that dispersion agent is pressed the weight ratio of 89 parts of Poly Propylene Waxes, 6 parts of nonane diacids, 5 parts of plant sterols.
3. manufacturing process:
Prepare master batch of the present invention and fabric technical process mainly comprises granulation, spinning, weaves, bleachinges and dyeing, shapes.
1. granulation: accurately take acrylic resin 56kg, Waxberry leaf extract 9kg, pomelo peel extract 6.5kg, dispersion agent 20.5kg by composition of raw materials and add in impeller and stir 10 minutes, add during this time oxidation inhibitor 3kg, molecular weight regulator 5kg to mix, obtain compound, this compound adopts twin screw extruder melt pelletization (feed worm 50r/min, driving screw 150r/min) under 220 ℃ of conditions of temperature to make antibiotic skin-care polypropylene fibre master batch.
2. spinning: after taking above-mentioned prepared antibiotic skin-care polypropylene fibre master batch 30kg and acrylic resin 70kg and mixing, adopt conventional melt-spinning technology flow process to carry out spinning, spinning temperature is 230～250 ℃, by melt spinning machine, carries out the pre-oriented yarn POY that spinning makes Waxberry leaf extract content 2.7% and pomelo peel extractive content 1.95%.
3. weave, bleaching and dyeing, shape: get 2. pre-oriented yarn POY of step, with any currently known methods, be woven into knit fabric on weft knitting machine, this fabric bleachinging and dyeing routinely, setting process enter to bleaching and dyeing, shape, and make underwear for men and women, underpants.After tested: UPF value 173, UVA transmitance 1.65%, the bacteriostasis rate 84.2% of the bacteriostasis rate 90.2% of streptococcus aureus, colibacillary bacteriostasis rate 91.5%, Candida albicans, has good whitening effect.
Embodiment bis-
1. raw materials pretreatment:
1. prepare Waxberry leaf extract: gather fresh Folium Myricae rubrae and clean, pulverize, add water making beating, squeezing, obtains pressed liquor and press residue, pressure marc is put into container and is added the water of 10 times of amounts of press residue, under 90 ℃ of conditions, extract 5 hours, filter, obtain squeezing juice, merge pressed liquor and squeezing juice, filter, filtrate is crossed D101 macroporous adsorptive resins, first uses distilled water wash-out resin column to colourless, use afterwards 50% ethanol elution, collect elutriant, concentrating under reduced pressure, spraying is dry, with grinding body porphyrize, cross 110 mesh sieves, obtain Waxberry leaf extract.
2. prepare pomelo peel extract: gather fresh pomelo peel and clean, cut into pieces, be soaked in petroleum ether degreasing, after sherwood oil volatilizees naturally, 35% ethanol that adds 5 times of amounts of pomelo peel, under 85 ℃ of conditions, extract 5 hours, filter, filtrate decompression is concentrated into thick pulpous state, the water-saturated n-butanol extraction that adds 3 times of amounts of thick pulpous state, getting propyl carbinol, to be evaporated to mutually relative density be 1.05～1.20 medicinal extract shape, 75% dissolve with ethanol that first adds 0.6 times of amount of medicinal extract shape, adding the acetone of 3 times of amounts of medicinal extract shape and the charcoal absorption of 2.5 times of amounts to remove liquid fully vibrates again, centrifugation, dry, with grinding body porphyrize, cross 110 mesh sieves, obtain pomelo peel extract,
2. composition of raw materials:
Acrylic resin 54.4kg, Waxberry leaf extract 7kg, pomelo peel extract 10kg, oxidation inhibitor 2.3kg, molecular weight regulator 4.7kg, dispersion agent 21.6kg.
Acrylic resin in above-mentioned raw materials is fiber-grade pp resin, its melting index is 35g/10min, described molecular weight regulator is the tertiary butane of peroxidation and tertiary lauryl mercaptan built agent, its weight ratio is: the tertiary butane of peroxidation: tertiary lauryl mercaptan=65: 35, oxidation inhibitor is oxidation inhibitor IR1010 and irgasfos 168 built agent, its weight ratio is: oxidation inhibitor is oxidation inhibitor IR1010: irgasfos 168=55: 45, and it is composite that dispersion agent is pressed the weight ratio of 85 parts of Poly Propylene Waxes, 7 parts of nonane diacids, 8 parts of plant sterols.
3. manufacturing process:
Prepare master batch of the present invention and fabric technical process mainly comprises granulation, spinning, weaves, bleachinges and dyeing, shapes.
1. granulation: accurately take acrylic resin 54.4kg, Waxberry leaf extract 7kg, pomelo peel extract 10kg, dispersion agent 21.6kg by composition of raw materials and add in impeller and stir 15 minutes, add during this time oxidation inhibitor 2.3kg, molecular weight regulator 4.7kg to mix, obtain compound, this compound adopts twin screw extruder melt pelletization (feed worm 50r/min, driving screw 150r/min) under 210 ℃ of conditions of temperature to make antibiotic skin-care polypropylene fibre master batch.
2. spinning: after taking above-mentioned prepared antibiotic skin-care polypropylene fibre master batch 35kg and acrylic resin 65kg and mixing, adopt conventional melt-spinning technology flow process to carry out spinning, spinning temperature is 230～250 ℃, by melt spinning machine, carries out the drafting silk DT that spinning makes Waxberry leaf extract content 2.45% and pomelo peel extractive content 3.5%.
3. weave, bleaching and dyeing, shape: get 2. drafting silk DT of step, with the woven one-tenth fabric of any currently known methods, this fabric bleachinging and dyeing routinely, setting process enter to bleaching and dyeing, shape, and make men's and ladies' shirts, nightwear.After tested: UPF value 219, UVA transmitance 2.36%, the bacteriostasis rate 89.4% to the bacteriostasis rate 93.2% of streptococcus aureus, colibacillary bacteriostasis rate 91.7%, Candida albicans, has good whitening effect.
Embodiment tri-
1. raw materials pretreatment:
1. prepare Waxberry leaf extract: gather fresh Folium Myricae rubrae and clean, pulverize, add water making beating, squeezing, obtains pressed liquor and press residue, pressure marc is put into container and is added the water of 6 times of amounts of press residue, under 75 ℃ of conditions, extract 5 hours, filter, obtain squeezing juice, merge pressed liquor and squeezing juice, filter, filtrate is crossed D101 macroporous adsorptive resins, first uses distilled water wash-out resin column to colourless, use afterwards 65% ethanol elution, collect elutriant, concentrating under reduced pressure, spraying is dry, with grinding body porphyrize, cross 115 mesh sieves, obtain Waxberry leaf extract.
2. prepare pomelo peel extract: gather fresh pomelo peel and clean, cut into pieces, be soaked in petroleum ether degreasing, after sherwood oil volatilizees naturally, 50% ethanol that adds 4 times of amounts of pomelo peel, under 70 ℃ of conditions, extract 6 hours, filter, filtrate decompression is concentrated into thick pulpous state, the water-saturated n-butanol extraction that adds 2.5 times of amounts of thick pulpous state, getting propyl carbinol, to be evaporated to mutually relative density be 1.05～1.20 medicinal extract shape, 80% dissolve with ethanol that first adds 1.2 times of amounts of medicinal extract shape, add again the acetone of 3.5 times of amounts of medicinal extract shape and the acticarbon of 1.5% times of amount fully to vibrate, centrifugation, dry, with grinding body porphyrize, cross 115 mesh sieves, obtain pomelo peel extract,
2. composition of raw materials:
Acrylic resin 51kg, Waxberry leaf extract 12kg, pomelo peel extract 7.5kg, oxidation inhibitor 2.9kg, molecular weight regulator 4.3kg, dispersion agent 22.3kg.
Acrylic resin in above-mentioned raw materials is fiber-grade pp resin, its melting index is 35g/10min, described molecular weight regulator is tertiary lauryl mercaptan and dicumyl peroxide built agent, its weight ratio is: tertiary lauryl mercaptan: dicumyl peroxide=45: 55, oxidation inhibitor is oxidation inhibitor IR1010 and irgasfos 168 built agent, its weight ratio is: oxidation inhibitor is antioxidant 1076: irgasfos 168=35: 65, and it is composite that dispersion agent is pressed the weight ratio of 87 parts of Poly Propylene Waxes, 5 parts of nonane diacids, 7 parts of plant sterols.
3. manufacturing process:
Prepare master batch of the present invention and fabric technical process mainly comprises granulation, spinning, weaves, bleachinges and dyeing, shapes.
1. granulation: accurately take acrylic resin 51kg, Waxberry leaf extract 12kg, pomelo peel extract 7.5kg, dispersion agent 22.3kg by composition of raw materials and add in impeller and stir 20 minutes, add during this time oxidation inhibitor 2.9kg, molecular weight regulator 4.3kg to mix, obtain compound, this compound adopts twin screw extruder melt pelletization (feed worm 50r/min under 200 ℃ of conditions of temperature, driving screw 150r/min), make antibiotic skin-care polypropylene fibre master batch.
2. spinning: after taking above-mentioned prepared antibiotic skin-care polypropylene fibre master batch 35kg and acrylic resin 65kg and mixing, adopt conventional melt-spinning technology flow process to carry out spinning, spinning temperature is 230～250 ℃, by melt spinning machine, carry out the staple fibre that spinning makes Waxberry leaf extract content 4.8%% and pomelo peel extractive content 3%, get 65 parts, this staple fibre and mix and be spun into 32S～80S yarn with 35 parts, cotton fibre.
3. weave, bleaching and dyeing, shape: get 32S～80S yarn that 2. step mixes, then on warp knitting machine, be woven into fabric with any currently known methods.After tested: UPF value 96, UVA transmitance 3.7%, the bacteriostasis rate 65.3% to the bacteriostasis rate 75.4% of streptococcus aureus, colibacillary bacteriostasis rate 71.6%, Candida albicans, has good whitening effect.
Embodiment tetra-
Make underwear: first gather the made fabric of embodiment 1～3 and common fabric, then cutting garment piece, during cutting, by the centre of shirtfront and metathorax toward line centered by vertical direction, be cut into left clothing body, right clothing body, the left clothing dignity material in the present invention is the made fabric of embodiment 1～3, and right clothing dignity material is common fabric, left clothing body and right clothing body are sewed up, formed two kinds of underwears that fabric is symmetrical.
Whitening test: be the test of human body white-skinned face function, comprise transfer, metabolism and the test of raising skin brightness of accelerating dermal melanin.
Following white-skinned face function test all adopts human test's mode, measures melanin content and the brightness of skin with the dark red pigment tester of skin and skin colourity test probe+MPA9 tester.
Choose 30 volunteers, men and women half and half, wear and to human body, can not use any skincare product in first 3～5 days, the skin of underwear and human body contact site is measured melanin content and the skin brightness of tested skin with the dark red pigment tester of skin and skin colourity test probe+MPA9 tester.
1. melanin content mutation analysis
Dermal melanin content was reflected in test period, underwear and human body contact site dermal melanin content change with time.Its value is larger, and dermal melanin content is larger, otherwise dermal melanin content is lower.
Melanin content (T0) before each time point melanin content (Tn) after melanin content difference (Δ T)=wear underwear-wear underwear.
Table 1: the difference of underwear and human body contact site dermal melanin content and initial value
As shown in Table 1, within 4 weeks test periods, the dermal melanin content of common fabric and human body contact site be on the occasion of, numerical value is without considerable change, illustrate that common fabric does not have the melanic ability of transfer, the dermal melanin content of the fabric that embodiment 1～3 is made and human body contact site and the difference of initial value are negative value always; In the time of the 3rd week, melanin content difference is (3.25)～(3.48), and value reduces along with the prolongation of time, illustrates that the made fabric of embodiment 1～3 has transfer or reduces the ability of melanin content.
2. the mutation analysis of skin brightness
Skin brightness variation was reflected in test period, underwear and human body contact site skin brightness L value change with time.Its value is larger, and skin brightness is larger, otherwise skin brightness is lower.
L value (T0) before each time point L value (Tn) after skin brightness difference (Δ T)=wear underwear-wear underwear.
Table 2: the difference of underwear and human body contact site skin brightness L value and initial value
As shown in Table 2, within the cycle of test, the skin brightness numerical value of common fabric and human body contact site slightly changes, but not obvious, illustrates that common fabric does not have the ability that improves skin brightness.The skin brightness L of the fabric that embodiment 1～3 is made and human body contact site on the occasion of, and raise along with the prolongation of test duration, in the time of the 4th week, the difference of skin brightness L value and initial value reaches 0.67, illustrates that the made fabric of embodiment 1～3 has good whitening effect.
What more than enumerate is only specific embodiments of the invention.Obviously, the invention is not restricted to above examples of implementation, can also have many distortion.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention, all should think protection scope of the present invention.
Claims (2)
1. an antibiotic skin-care polypropylene fibre master batch and fabric thereof, it is characterized in that, described antibiotic skin-care polypropylene fibre master batch is to be mixed and added melt pelletization in twin screw extruder to make by the auxiliary agent of the Waxberry leaf extract of weight percentage 2%～7%, 1.5%～5% pomelo peel extract and 6%～12% and the acrylic resin of residue percentage composition, described fabric is to be mixed and melting by the acrylic resin of the antibiotic skin-care polypropylene fibre master batch of weight percentage 25%～50% and 50%～75%, through spinning, weave, bleaching and dyeing, shaping forms;
Described Waxberry leaf extract adopts following methods preparation: gather fresh Folium Myricae rubrae and clean, pulverize, add water making beating, squeezing, obtain pressed liquor and press residue, pressure marc is put into container and is added the water of 5～15 times of amounts of press residue, under 75～90 ℃ of conditions, extract 3～5 hours, filter, obtain squeezing juice, merge pressed liquor and squeezing juice, filter, filtrate is crossed D101 macroporous adsorptive resins, first use distilled water wash-out resin column to colourless, use afterwards 45～70% ethanol elution, collect elutriant, concentrating under reduced pressure, spraying is dry, with grinding body porphyrize, cross 100～120 mesh sieves, obtain Waxberry leaf extract,
Described pomelo peel extract adopts following methods preparation: gather fresh pomelo peel and clean, cut into pieces, be soaked in petroleum ether degreasing, after sherwood oil volatilizees naturally, 35%～70% ethanol that adds 2～5 times of amounts of pomelo peel, under 60～85 ℃ of conditions, extract 5～8 hours, filter, filtrate decompression is concentrated into thick pulpous state, the water-saturated n-butanol extraction that adds 1～3 times of amount of thick pulpous state, getting propyl carbinol, to be evaporated to mutually relative density be 1.05～1.20 medicinal extract shape, 75%～85% dissolve with ethanol that first adds 0.2～1.5 times of amount of medicinal extract shape, add again the acetone of 3～6 times of amounts of medicinal extract shape and the acticarbon of 1.5～3% times of amounts fully to vibrate, centrifugation, dry, with grinding body porphyrize, cross 100～120 mesh sieves, obtain pomelo peel extract,
Described auxiliary agent comprises molecular weight regulator, oxidation inhibitor, dispersion agent.
2. antibiotic skin-care polypropylene fibre master batch according to claim 1 and fabric thereof, it is characterized in that, described dispersion agent is to form by Poly Propylene Wax, nonane diacid and plant sterol are composite, wherein, described plant sterol is that the single or arbitrary proportion of Sitosterol, Stigmasterol, campesterol, brassicasterol mixes, and its weight ratio is: Poly Propylene Wax: nonane diacid: plant sterol=85～90: 4～6: 6～9.
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104987600A (en) * | 2015-07-05 | 2015-10-21 | 陆思烨 | Natural antibacterial anti-aging polypropylene material and preparation method thereof |
| CN105001501A (en) * | 2015-08-15 | 2015-10-28 | 陆思烨 | Anti-bacterial cutting-chopping-resistant plastic cutting board and preparation method thereof |
| CN105037947A (en) * | 2015-08-25 | 2015-11-11 | 陆思烨 | Antibacterial health-care plastic spectacles frame and manufacturing method thereof |
| CN105297413A (en) * | 2015-10-22 | 2016-02-03 | 鲁杨 | Preparation method of canvas for insect-resistant mosquito-repelling travel tents |
| CN105839219A (en) * | 2016-05-14 | 2016-08-10 | 陆建益 | Antibacterial and anti-ultraviolet sea mud polypropylene fibers and preparation method thereof |
| CN106578603A (en) * | 2016-11-25 | 2017-04-26 | 南宁学院 | Ecological feed for ducks |
| CN110616508A (en) * | 2019-09-02 | 2019-12-27 | 百事基材料（青岛）股份有限公司 | Plant functional PP (polypropylene) spun-bonded non-woven fabric and preparation method thereof |
| CN111253675A (en) * | 2018-11-30 | 2020-06-09 | 中科纺织研究院（青岛）有限公司 | Plant source PP master batch and preparation method and application thereof |
| WO2020252994A1 (en) * | 2019-06-19 | 2020-12-24 | 季卫坤 | Method for preparing fiber added with quercitrin and fiber |
| CN112831125A (en) * | 2021-01-28 | 2021-05-25 | 宁波共振服饰有限公司 | Antibacterial skin-care polypropylene fiber master batch and fabric |
| CN115433440A (en) * | 2022-08-29 | 2022-12-06 | 福建华峰新材料有限公司 | Natural herbal antibacterial master batch for polymeric fiber, preparation method and fabric containing natural plant antibacterial component |
| CN115449915A (en) * | 2022-08-29 | 2022-12-09 | 邦特云纤(青岛)新材料科技有限公司 | Antibacterial synthetic fiber containing avocado and shea butter extracts and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1320728A (en) * | 2000-04-26 | 2001-11-07 | 上海石油化工股份有限公司 | Process for preparing polypropylene fibre containing gingko leaf extract |
| CN102727540A (en) * | 2012-06-25 | 2012-10-17 | 陆建益 | Method for preparing red bayberry leaf extract |
-
2014
- 2014-02-28 CN CN201410079736.2A patent/CN103937090A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1320728A (en) * | 2000-04-26 | 2001-11-07 | 上海石油化工股份有限公司 | Process for preparing polypropylene fibre containing gingko leaf extract |
| CN102727540A (en) * | 2012-06-25 | 2012-10-17 | 陆建益 | Method for preparing red bayberry leaf extract |
Non-Patent Citations (1)
| Title |
|---|
| 张怡 等: "柚子皮总黄酮提取工艺的研究", 《中国农学通报》 * |
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| CN104987600A (en) * | 2015-07-05 | 2015-10-21 | 陆思烨 | Natural antibacterial anti-aging polypropylene material and preparation method thereof |
| CN105001501A (en) * | 2015-08-15 | 2015-10-28 | 陆思烨 | Anti-bacterial cutting-chopping-resistant plastic cutting board and preparation method thereof |
| CN105037947A (en) * | 2015-08-25 | 2015-11-11 | 陆思烨 | Antibacterial health-care plastic spectacles frame and manufacturing method thereof |
| CN105297413A (en) * | 2015-10-22 | 2016-02-03 | 鲁杨 | Preparation method of canvas for insect-resistant mosquito-repelling travel tents |
| CN105839219A (en) * | 2016-05-14 | 2016-08-10 | 陆建益 | Antibacterial and anti-ultraviolet sea mud polypropylene fibers and preparation method thereof |
| CN106578603A (en) * | 2016-11-25 | 2017-04-26 | 南宁学院 | Ecological feed for ducks |
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| WO2020252994A1 (en) * | 2019-06-19 | 2020-12-24 | 季卫坤 | Method for preparing fiber added with quercitrin and fiber |
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| CN112831125A (en) * | 2021-01-28 | 2021-05-25 | 宁波共振服饰有限公司 | Antibacterial skin-care polypropylene fiber master batch and fabric |
| CN115433440A (en) * | 2022-08-29 | 2022-12-06 | 福建华峰新材料有限公司 | Natural herbal antibacterial master batch for polymeric fiber, preparation method and fabric containing natural plant antibacterial component |
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| CN115433440B (en) * | 2022-08-29 | 2023-11-14 | 福建华峰新材料有限公司 | Natural herbal antibacterial master batch for polymeric fibers, preparation method and fabric containing natural grass and wood antibacterial components |
| CN115449915B (en) * | 2022-08-29 | 2024-04-05 | 邦特云纤(青岛)新材料科技有限公司 | Antibacterial synthetic fiber containing extracts of avocado and shea butter and preparation method thereof |
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