CN105970345A - Natural, green, ecological and environment-friendly functional fiber textile - Google Patents

Natural, green, ecological and environment-friendly functional fiber textile Download PDF

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Publication number
CN105970345A
CN105970345A CN201610349359.9A CN201610349359A CN105970345A CN 105970345 A CN105970345 A CN 105970345A CN 201610349359 A CN201610349359 A CN 201610349359A CN 105970345 A CN105970345 A CN 105970345A
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natural
fiber
germanium
environment
selenium
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成进学
成钢
陆小新
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Nantong Snakes Treating Institute
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Nantong Snakes Treating Institute
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/02Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/08Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses a natural, green, ecological and environment-friendly functional fiber textile, belonging to the technical field of ecological and environment-friendly fiber textile production. The functional fiber textile is prepared through blend spinning of green and environment-friendly antibacterial odor and mite removing selenium-germanium-enriched lucid ganoderma and naturally colored cotton blended nanopowder, selenium-germanium-enriched yeast, maize and cassava extract and polylactic acid fiber blended nanopowder, selenium-germanium-enriched spirulina, natural plant bagasse, flax residue and bamboo fiber blended nanopowder, natural antibacterial toxin filtering, element anion releasing and electromagnetic wave magnet therapy preventing selenium-germanium-enriched lucid ganoderma spirulina blended nanopowder, cotton, hemp, wool, silk, polypropylene fibers, acrylic fibers, polyester and nylon. The functional fiber textile has the beneficial effects that the contradiction between petroleum resource shortage and urgent need of ecological and environment-friendly textile fibers is solved; and through bioengineering modification, overuse of agricultural fertilizers and insecticides in the planting process is changed, harms of chemical products, residues thereof and toxic and harmful heavy metals in printing and dyeing to human bodies are reduced, wastes are utilized, fibers are regenerated, the environment is cleaned, the cost is reduced and the added value of the product is increased.

Description

Natural green ecological, environmental protective functional fiber textile
Technical field:
The invention discloses a kind of natural green ecological, environmental protective functional fiber textile, be belonging to ecological, environmental protective fiber textile work Skill production technical field.
Background technology:
Society, due to the minimizing day by day of petroleum resources, the requirement of environmental conservation improves day by day, and various countries are to natural green environmental protection The research of fiber textile, application, produce more and more, China the natural color cotton produced, exist through biological engineering modification Produce in planting process and decrease fertilizer and pesticide, the use of the chemical agents such as herbicide.And chemical medicinal residue thing causes environment dirty Dye, the injury to human body, prevent soil property from deteriorating, meet the requirement of the ecological, environmental protective agricultural of " green fiber ", this containing sky So the color cotton of pigment, need not the operations such as bleaching and dyeing during making textile fabric and decreases having in dyeing process Poison, harmful carcinogen, such as formaldehyde, pentachlorophenol, azo dye, luminous agent, softening agent, fluorescent whitening agent, a harmful huge sum of money The pollution belonged to and the residual of the pesticide such as chemicals and parasite killing such as anti-cancer, mothproof, mildew-resistant, and reduce discharge of wastewater and electricity Can, cleaning of environment, reduce cost, improve added value of product.Another kind of acid fiber by polylactic, from Semen Maydis Maninot esculenta crantz. straw etc. The glucose that the starch extracted in natural plants obtains after acid is decomposed, then through lactic acid bacteria, the fermentation of rich selenium germanium Ganderma lucidum generates lactic acid Or cellulose decomposition is prepared lactic acid, lactic acid aggregates into highly purified polylactic acid under suitable condition, is processing through spinning etc. Prepare the rich selenium germanium acid fiber by polylactic being available for weaving, and with arthropodan shells such as natural shrimp Eriocheir sinensis and insecticides, mushroom, The chitin fiber extracted in the lower animal cell wall such as algae or shell cluster fiber, and regenerate bamboo dimension dimension or traditional instrument pulp fibres, should Use in the production process of each operation of spinning.
Summary of the invention:
It is an object of the invention to provide a kind of natural green ecological, environmental protective functional fiber textile.
The technical solution of the present invention is:
A kind of natural green ecological, environmental protective functional fiber textile, is characterized in that: form % by following proportion by weight
Wherein (1) rich selenium germanium Ganoderma natural color synthetic fibre cotton environmental protection antibacterial and deodouring gram demodicid mite mixing nano powder, by following proportion by weight group Become %
(2) rich selenium germanium yeast straw Semen Maydis Maninot esculenta crantz. extract acid fiber by polylactic mixing nano powder, forms % by following proportion by weight
(3) rich selenium germanium spirulina natural plant bagasse hards bamboo fibre mixing nano powder, forms % by following proportion by weight
(4) rich selenium germanium ganoderma spirulina natural antibacterial filter poison release element anion anti electromagnetic wave magnetic therapy mixing nano powder, by following matter Amount part proportioning composition %
Herba Apocyni veneti in embodiment, cures mainly hypertension, headache, dizziness, insomnia, neurasthenia, antibacterial, preventing cold: Fructus Cannabis, Cure mainly fracture, traumatic injury, rheumatalgia, traumatic hemorrhage, expelling wind and activating blood circulation, analgesic hemostatic;Rhizoma Coptidis, heat clearing and damp drying, pathogenic fire purging Removing toxic substances, cure mainly acute conjunctivitis, acute gastrointestinal class bacillary dysentery, control scald: the Radix Astragali, to various bacillus, streptococcus, diplococcus, Staphylococcus, bacillus subtilis all have inhibitory action, to body void spontaneous perspiration edema, chronic nephritis, neurodermatitis obstinate, burst Infections, leukocyte, thrombocytopenia all have better effects;Cypress ethereal oil, is the natural jinx of acarid.
Ganoderma is the medicinal fungi of a kind of preciousness, Na2SeO3Selenium accumulation of Ganoderma Lucidum ability is the strongest, and culture medium adds Na2SeO3Concentration with 50mg/kg is advisable, and in can making Ganoderma mycelium, Se content is up to 800mg/kg.Ganoderma, it except containing rich in protein, Outside polysaccharide, vitamin and other active substances, it also has the strongest selenium-rich, the ability of rich germanium, the selenium being enriched be albumen selenium, The Organic Seleniums such as albumen germanium, polysaccharide selenium, holoside Ge, nucleic acid selenium, nucleic acid germanium, organic germanium exist.At present with Ganderma lucidum for carrying Body carries out the bioconversion of selenium, germanium, selenium germanium use fermentation engineering by Ganoderma edible fungi selenium-rich, germanium cultivate selenium, germanium resource micro- Bioconversion, obtain rich in organic selenium, organic germanium Technology application in production.
The nutritive value of spirulina.Protein content is the highest, and its dry powder contains crude protein 60%~70%, and it can become with Natural Transformation Metallothionein, it is to remove the free radical scavenger that human free radical ability is the strongest, and amino acid content is many and complete, particularly contains There are lysine lacking in cereals, threonine.In fat forms, linoleic acid is high with linolenic acid content.It has now been found that Linolenic acid is relevant with regulation blood pressure, synthetic cholesterol, it was found that can anticancer growth, its ratio vitamin carotene carotene content The highest, additionally possibly together with organic germanium selenium, threpsology has more characteristic.The health care of spirulina includes: 1, blood fat reducing; 2, antitumor;3, immunologic function is strengthened;4, radioprotective;5, antioxidation, resisting fatigue.
Selenium is immunologic function strength reinforcing agent.Health is had a major impact by immunologic function, and flu, virus infection, tumor are all Relevant with immunologic function.Immune system such as the army offices and men defended the borderland, and fight capability the strongest surely belong to can kill antibacterial, Virus and the T-lymphocyte of tumor cell, macrophage and NK cell.And selenium has the spy activating this three para-immunities cell Distinguished service energy, improves their lethality, and improves immunity.Therefore lack that people's immunity of selenium is low is susceptible to suffer from tumor.Selenium is The most important defying age element only found.
Organic germanium pharmacological action is mainly manifested in it and has in unique molecular structure the key having three band oxygen, and oral absorption can be to whole body Cell provides substantial amounts of oxygen, improves metabolism, strengthens anti-cancer ability, the generation of anticancer;Also have defying age and beauty treatment Effect, can eliminate climacteric uncomfortable, make skin become ruddy soft and graceful, treatment acne etc..Due to these pharmacological actions of organic germanium, Multiple disease can treated, as chronic disease, hypertension, arthritis, cerebral malacia, cerebral thrombosis, glycosuria can be prevented and treated in clinic The multiple effects such as disease, senile dementia and apoplexy sequela, so being described as " the help germanium of 21st century ", " two Pius XIs The source of life recorded ".
Differential particle diameter after Maifanitum nanotechnology is easy to trace element necessary to dissolution human body through water soaking, with regulation, mends Fill, antagonism people's in-vivo element balances, and it has the water purification function of mystery simultaneously, and it can be to contained by human body 80%, even whole body Moisture become the mineralized water of high-quality, make the blood of thickness be eased, blocked blood vessel is dredged.Maifanitum nanometer skill Postoperative, its specific surface area is very big, so its absorbability is the strongest.The wheat meal of 1% is added in the solution containing 1ppm cyanogen Stone is tested, and measures adsorbable removing 18.2% after 2h, measures adsorbable removing 20.8%, measure adsorbable after 24h after 4h Remove 44%;In the solution containing 0.1ppm cadmium, add the Maifanitum of 10%, after 3h, measure adsorbable removing 43.2%, 24h The adsorbable removing of rear mensuration 61.4%, measures adsorbable removing 84.0%, and heavy metal also has the strongest absorption to filter after 48h Toxic action.
In Maifanitum, main mine material is potassium feldspar, biotite, hornblend, and they are obvious to the harmful components adsorptivity in air Be better than activated carbon, the reason of yet another aspect be Maifanitum Main Ingredients and Appearance in silicon dioxide SiO2, aluminium sesquioxide Al2O3、 Iron sesquioxide Fe2O3, titanium dioxide TiO2, phosphorus pentoxide P2O5, ferrum oxide MgO, calcium oxide CaO, sodium oxide Na2O, potassium oxide K2O etc. meet water can rapidly dissolution to the useful various trace elements manganese Mn of human body, nickel, cobalt Co, zinc Zn, copper Cu, germanium Ge, selenium Se.They both had the active substance of the multiple efficacies of far-infrared negative-ion anti electromagnetic wave, again Energy regulation, supplementary, antagonism people's in-vivo element balance, strengthen health.
Tourmaline has two important features, i.e. pyroelectricity and piezoelectricity.It produces pyroelectric effect and pressure under certain conditions Electrical effect, existence based on both effects, when temperature and pressure produces change, even the most small change, also can draw Playing electric heating difference and voltage difference between tourmaline crystal, this electrostatic potential difference can be up to 1.0 × 106Ev electrostatic potential is poor, thus Forming electric field, high-tension electricity, be the air ionization in electric field, the electronics hit is had by tourmaline nanocrystalline powders two ends After the permanent positive and negative polarity having contacts with the hydrone of the hydrone in common water, air or skin surface, just can produce wink Between discharge ionisation effect, by hydrone electrolysis for H+And OH-。H+The electronics discharged with tourmaline nano powder end be combined and It is neutralized into H atom, and OH-Be combined with other molecules and can continuously generate hydroxyl group anion (H3O2)-.During this Water, either alkaline water or acid water are all to present to benefit human body.Alkalescent water greatly reduces the viscosity of blood, When people suck this numerous anion, enter internal, the anion carried can be transported to whole body and respectively organize, blood can be strengthened Liquid circulates, and enhances metabolism, and improves immunity of organisms.
Zeolite has three big characteristics: one, adsorptivity;Two, catalyst;Three, ion exchangeable.Zeolite is natural volcano mine Stone, has unique complicated crystalline texture.Trickle pipeline and vestibule it is filled with inside zeolite, more complicated than Nidus Vespae.Through section Scholar calculates, if one gram of zeolite all opens pipeline and vestibule, paves, has the specific surface area of 2000 square metres.Cause This, utilize big surface area can adsorb anaphylactogen, heavy metal and harmful toxins etc..It addition, zeolite is minority in the middle of nature One of mineral with negative charge, so, to the internal heavy metal with positive electricity, blood poison, intestinal poison, lymph poison, cell toxicant Adsorption consumingly is had with free radical.Russia, the U.S. and Japan's nuclear leakage event all utilize Zeolite absorption radio chemistry Material and other harmful toxins.
Day by day reducing and the raising day by day of environmental protection requirement due to petroleum resources at present, various countries are to ecological environment-friendly type textile fabric Research, produce and apply more and more.Color cotton i.e. natural colorful cotton fibre, and a kind of New Regenerated Cellulosic Fibers, it Be native cellulose be raw material, use dedicated solvent (N methyhnorpholine-N-oxide, NMMO or solion) the most molten Solve the viscose rayon being spun into after cellulose, because the more common viscose fiber of its process technology has an improvement it is considered to be 21 century " green fiber ".This fibre spinning processing is different from common viscose fiber spinning process, uses and dry squirts method, generally selects The fiber of timber or other plant is raw material, first that wood planing is in blocks, prepares a kind of content of cellulose through steaming and decocting rinsing and is more than 96.5%.The wood pulps of the degree of polymerization higher degree more than 600, then with N-methylmorpholine-N-oxide (NMMO) be Solvent, after pulp is sufficiently mixed with NMMO, makes pulp fully dissolve, adds certain additive and stabilizer, passes through After filter, deaeration, form certain density spinning liquid, then it is extruded from spinneret orifice, be spun into solvent-laden aqueous coagulation bath In, Precipitation cellulose also forms fiber, the most scrubbed, stretches, is dried, crimps, the processing such as cut-out, and i.e. being formed can Cellulose fibre for weaving.
The eco-environmental prote of this fiber is mainly reflected in the several aspects during producing and using;1, manufacture raw material and select speed Raw woods, derives from nature, renewable, has sustainable developability.2, the production technology of this fiber compared with viscose process Flow process shortens dramatically, and only includes pulp mixing, heat of solution, filtration, extruding spinning, stretches, washes, the technique such as is dried.Save Gone substantial amounts of process technique in viscose fiber manufacture process, as alkalized, squeeze, pulverizing, experienced, Hemerocallis citrina Baroni, maturation and multiple Miscellaneous last handling process etc., decreases the discharge of the energy consumption in production process and refuse;Production and processing uses circulating enclosed, NMMO solvent can be with efficient recovery and recycling, and solvent NMMO itself is nontoxic, therefore can be used for the life of regenerated fiber Product effect on environment is little.3, this fiber is a kind of regenerated celulose fibre, and the physics and chemistry not only with native cellulose fibre is special Property and excellent wearability, have again some synthetic fibers characteristic, meet people's back to nature, advocate natural demand.Natural Color cotton can be with blend kinder healthcare face fabric, Fructus Cannabis blending leisure fabric, silk fiber blended or interwoven fabric etc. plus tool Have the characteristic of environmental protection, be widely used in underwear, underwear, T-shirt, bra, vest, socks, shirt, nightwear and towel, The underlinen such as cotton blanket, bath towel, sheet, bathing gown, towelling coverlet with and household textile products, be particularly suitable for infant clothing and Articles for use.It addition, develop a series of high-tech color cotton textile, if colorful cotton fibre is with natural gray cotton, natural color Color cotton is soft, moisture absorption is ventilative, warmth retention property is good, and its product color is soft, simple and tasteful, quality is pure, comfortable and easy to wear, Meet people compel to ask recover one's original simplicity, phychology that color is natural, add there is the characteristic of natural green environmental protection so being widely used in each Plant in the making of yarn woven fabric.
Bamboo fibre is the nearly 10 years a kind of tencels occurred.The maximum feature of bamboo fibre is natural antibacterial, this be probably by Containing caused by natural antibacterial ingredient " bamboo quinone " in bamboo.But bamboo fiber through slurrying, dipping, aging, yellow, How a series of chemical treatments and the courses of reaction such as dissolving, maturation, regeneration, ensure that this antibiotic substance does not run off and do not changes Learning change, be the final products mechanism that remain to keep good anti-microbial property, the acid fiber by polylactic of production is from Semen Maydis, and Maninot esculenta crantz. is sweet The starch extracted in some straws such as dish, corn and fiber obtains glucose after acid is decomposed, more raw through lactic acid bacteria fermentation Becoming acid, or cellulose decomposition is prepared lactic acid, lactic acid aggregates into highly purified polylactic acid under proper condition, then through spinning etc. Work prepares the acid fiber by polylactic being available for weaving.
Owing to Poly-L-lactic acid has crystallinity, fusing point is higher, and fibre property has practicality, and its synthesis uses indirect polymerized Method, first has Lactate to obtain lactide, the most on-job polylactic acid, therefore the acid fiber by polylactic produced at present is poly-levorotatory lactide fibre Dimension, D-lactic acid content is typically more than 97%.
The spinning process of acid fiber by polylactic has solvent volatilization and fusion method two kinds.The solvent that solvent volatilization spinning is commonly used is chlorine and toluene Mixed liquor, its spinning technique flow process is: Poly-L-lactic acid → dissolving → aging → filtration → metering → extrusion → molten evaporation → fibre Dimension shaping → stretching → winding → fibrous finished product.The melt-spinning technology of Poly-L-lactic acid fusion method spinning technique and polyester seemingly, but Melt temperature is lower than polyester fiber, and its spinning technique flow process is;Poly-L-lactic acid → vacuum drying → melt extruded → filtration → meter Molding → coiled fiber finished product is extruded → cooled down to amount → spinneret.The fiber power performance that solvent evaporation method prepares relatively melts the good of method, spins The fiber knitted has higher intensity.
In today that petroleum resources are day by day exhausted, acid fiber by polylactic is the tencel material solving this problem, but polylactic acid The maximum feature of fiber is still the feature of its environmental protection;1, acid fiber by polylactic is with some reproducible agronomic crop fibres Straw is raw material, and all amyloid crops even common plant can be converted to polylactic acid, and raw material can be planted, one Determine in degree prevented also from soil erosion.2, acid fiber by polylactic has good biocompatibility and biological degradability, Ke Yijing Hydrolysis, enzymolysis, ultimately generate CO2And H2O.Therefore the garbage of fibre can be degraded voluntarily;Free from environmental pollution.3、 The whole production process of acid fiber by polylactic can accomplish environmentally safe, and therefore, acid fiber by polylactic can deserve to be called real green Color fibre.
Acid fiber by polylactic has merged the feature of natural fiber and synthetic fibers, and the advantage of both unions, has many excellent Performance.Acid fiber by polylactic is aliphatic poly ester fiber, its physical property and chemical property and direction adoption PETP (PET), poly-similar to fibers such as stupid dioctyl phthalate propylene diester (PTT), polybutylene terephthalates (PBT), performance between Between polyester fiber and polyesteramide fibre.Intensity, growth, hygroscopicity and dyeability are all close with them, have good Elasticity, crimpiness and anti-wrinkle shrink-proof performance, acid fiber by polylactic compares with the partial properties of polyester and Fypro, and polylactic acid is fine Dimension has preferable wicking, and wet transmitting performance is better than polyester fiber, has absorbing sweat, perspiration functions, has good wearing comfort, The dyeability of acid fiber by polylactic is poorer than general textile fabric, generally uses disperse dyes, but without High Temperature High Pressure.Polylactic acid Fiber has the features such as antibacterial, mildew-resistant, odorless;Its combustibility is low, is formed without cigarette during burning, even if burning also will not produce Poison, harmful material.Acid fiber by polylactic has certain ultraviolet resistance, sun-resistant, against weather, after 50h is exposed to the sun in outdoor, Intensity still can retain about 55%.
Chitin (Chitin), also known as chitin, chitin, is widely present in arthropodan shell and the bacterium such as shrimp, Eriocheir sinensis and insecticide In the zootic cell wall such as class, algae, it is that on the earth, storage is only second to a kind of natural polymer of cellulose and renewable money Source, is the most positively charged alkaline polysaccharide being found up to now in nature.Pure chitin water, diluted acid, diluted alkaline with And general organic solvent is difficult to dissolve, process through concentrated base, after acetyl group therein is transformed into amino, reformed into solubility Chitin, also known as chitosan or chitosan, chitosan (Chitosan) is the product that chitin deacetylase degree reaches more than 75% Thing, is the most important derivant of chitin.Typically now described chitin, refers to chitosan in most cases, and carapace Matter is the general designation of chitin and chitosan.It is spun into fiber with the chitin spinning liquid examination of cold sulphuric acid preparation 6%~10%.Use chitin Sulphonic acid ester uses the spinning technique of viscose fiber to make fiber.
At present, the most commonly used weaving chitin or the method for chitin fiber are wet mouldings, and its process route is general It it is two classes: 1 → chitin (chitosan) → dissolving → spinning solution → filtration → deaeration → metering → spinning → mono-bath → drawing-off → bis-baths → sizing → washing → be dried → fiber;2 chitins (chitosan) modification → spinning solution → filtration → deaeration → metering → spinning → coagulating bath → stretch oneself and yawn → shape → wash → be dried → fiber.The fiber strength that the latter prepares is higher than the former, The change of other performances is little.
Chitin fiber is compared with viscose fiber, and dry strong high, wet the most close, crimpiness is good;Chitin fiber rate of growth is high, just Beginning modulus is similar to terylene, and tenacity of fibre is big, and wear-resisting, smooth surface, resilience is poor, and cohesive force is poor, and mantle friction is little, can The property spun is poor.Hygroscopicity is close with viscose fiber, and hygroscopicity is good, has excellent moisture absorption and moisture-keeping functions, and its regain is 13.5%~15.8%, this is because the amino of chitin and hydroxyl have the highest hydrophilic.
Chitin and derivant thereof are positively charged natural polymers, and macromole has the structure of similar human bone collagen tissue. Chemical property and biological property are close with tissue so that it is biological activity and biocompatibility are excellent, have no side effect, its system There is not exclusive problem in product and human body, have prevent aging, blood pressure lowering and cholesterol, regulation physiological function, antibacterial, deodorant, Antiinflammatory, stopping blooding, ease pain, promote wound healing and the function such as cure the wound, washing nor affects on its antibiotic property.Therefore chitin fiber Good prospect is had on medical.Chitin fiber long filament can be used for making medical absorbent surgical sutures year.The most especially It is that the U.S. manufactures artificial skin, absorbable suture, hemodialysis membrane, medicine with Japan mainly by chitin and chitosan Corrosion inhibiter and various medical dressing etc..
Below in conjunction with embodiment, the present invention is further described:
Specific implementation method:
Embodiment 1: a kind of natural green ecological, environmental protective functional fiber textile, is characterized in that: form % by following proportion by weight
Wherein (1) rich selenium germanium Ganoderma natural color synthetic fibre cotton environmental protection antibacterial and deodouring gram demodicid mite mixing nano powder, by following proportion by weight group Become %
(5) rich selenium germanium yeast straw Semen Maydis Maninot esculenta crantz. extract acid fiber by polylactic mixing nano powder, forms % by following proportion by weight
(6) rich selenium germanium spirulina natural plant bagasse hards bamboo fibre mixing nano powder, forms % by following proportion by weight
(7) rich selenium germanium ganoderma spirulina natural antibacterial filter poison release element anion anti electromagnetic wave magnetic therapy mixing nano powder, by following matter Amount part proportioning composition %
Embodiment 2: a kind of natural green ecological, environmental protective functional fiber textile, is characterized in that: form % by following proportion by weight
Embodiment 3: a kind of natural green ecological, environmental protective functional fiber textile, is characterized in that: form % by following proportion by weight
Embodiment 4: a kind of natural green ecological, environmental protective functional fiber textile, is characterized in that: form % by following proportion by weight

Claims (1)

1. a natural green ecological, environmental protective functional fiber textile, is characterized in that: form % by following proportion by weight
Wherein (1) rich selenium germanium Ganoderma natural color synthetic fibre cotton environmental protection antibacterial and deodouring gram demodicid mite mixing nano powder, by following proportion by weight Composition %
(2) rich selenium germanium yeast straw Semen Maydis Maninot esculenta crantz. extract acid fiber by polylactic mixing nano powder, forms % by following proportion by weight
(3) rich selenium germanium spirulina natural plant bagasse hards bamboo fibre mixing nano powder, forms % by following proportion by weight
(4) rich selenium germanium ganoderma spirulina natural antibacterial filter poison release element anion anti electromagnetic wave magnetic therapy mixing nano powder, by following Proportion by weight composition %
CN201610349359.9A 2016-05-17 2016-05-17 Natural, green, ecological and environment-friendly functional fiber textile Pending CN105970345A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385598A (en) * 2017-07-25 2017-11-24 安徽亚源印染有限公司 A kind of military fabric of anti-infrared high abrasion high tenacity
CN108070913A (en) * 2017-12-01 2018-05-25 镇江星运科技有限公司 A kind of manufacturing method and manufacturing method of fabric of kingfisher melt multifunctional textile fiber
CN115216854A (en) * 2022-06-06 2022-10-21 李庆生 Environment-friendly antibacterial ganoderma lucidum fiber and preparation method thereof

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CN101703319A (en) * 2009-09-25 2010-05-12 成钢 Wool fibre fabric sweat shirt (pants) with functions of powerful antibiosis, cancer prevention and life prolonging by utilizing nano silver, selenium and germanium
CN101949067A (en) * 2010-06-02 2011-01-19 陈欣荣 Anti-ultraviolet anti-sunburn nano elemental fabric body-building protective clothes
CN102817102A (en) * 2012-08-14 2012-12-12 成钢 Multi-functional nano-biological composite active material healthcare and rehabilitation patient clothes
CN103397397A (en) * 2013-08-06 2013-11-20 陈欣荣 Summer element fiber body-building protective suit for ship repairing and building personnel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101703319A (en) * 2009-09-25 2010-05-12 成钢 Wool fibre fabric sweat shirt (pants) with functions of powerful antibiosis, cancer prevention and life prolonging by utilizing nano silver, selenium and germanium
CN101949067A (en) * 2010-06-02 2011-01-19 陈欣荣 Anti-ultraviolet anti-sunburn nano elemental fabric body-building protective clothes
CN102817102A (en) * 2012-08-14 2012-12-12 成钢 Multi-functional nano-biological composite active material healthcare and rehabilitation patient clothes
CN103397397A (en) * 2013-08-06 2013-11-20 陈欣荣 Summer element fiber body-building protective suit for ship repairing and building personnel

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107385598A (en) * 2017-07-25 2017-11-24 安徽亚源印染有限公司 A kind of military fabric of anti-infrared high abrasion high tenacity
CN108070913A (en) * 2017-12-01 2018-05-25 镇江星运科技有限公司 A kind of manufacturing method and manufacturing method of fabric of kingfisher melt multifunctional textile fiber
CN115216854A (en) * 2022-06-06 2022-10-21 李庆生 Environment-friendly antibacterial ganoderma lucidum fiber and preparation method thereof
CN115216854B (en) * 2022-06-06 2023-08-15 李庆生 Environment-friendly antibacterial ganoderma lucidum fiber and preparation method thereof

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