Summary of the invention
Therefore, for above content, the invention provides that a kind of water resistant is sliding, anti-ice is sliding, anti-cunning, quality is light, material is soft, sole and upper of a shoe bounding force by force, good springiness, do not need to use glue plastering agent, environmental protection, not yielding, resilience is effective, resistant to elevated temperatures rubber pange footwear, and the preparation method that a kind of these rubber pange footwear are provided, this preparation method's step is simple, save time, and can save larger Financial cost.
For achieving the above object, the present invention is achieved by the following technical solutions: a kind of rubber pange footwear, and comprise sole and be located at the upper of a shoe on sole, described sole comprises the starting material of following weight part:
250~300 parts of natural rubbers
600~700 parts of stone flours
60~80 parts, zinc oxide
3~5 parts of stearic acid
5~10 parts of whipping agents
4~6 parts, sulphur
3~5 parts of vulkacit Ds
Rubber accelerator DM3~5 part
8~10 parts, anti-aging agent
10~11 parts of ointment.
Further improve and be: described sole comprises the starting material of following weight part:
270~290 parts of natural rubbers
650~690 parts of stone flours
70~78 parts, zinc oxide
4~5 parts of stearic acid
7~9 parts of whipping agents
5~6 parts, sulphur
4~5 parts of vulkacit Ds
Rubber accelerator DM4~5 part
9~10 parts, anti-aging agent
10.5~11 parts of ointment.
A preparation method for rubber pange footwear, comprises the following steps:
(1) prepare rubber pange sheet: the starting material of the sole of each weight part claimed in claim 1 are put into rubber mixing machine mixing, obtain rubber pange sheet;
(2) prepare patrix, bed die and shoe last;
(3) rubber pange sheet step (1) being made is put into bed die, shoe last is fixed on to the corresponding position of patrix, at shoe last, puts upper of a shoe outward, foaming at 150~170 ℃, sizing;
(4) delasting head, the demoulding: take out shoe last, patrix and bed die, make integrated rubber pange footwear.
Further improve and be: in described step (1), mixing time is 30~35min.
Further improve and be: the foaming and setting time in described step (3) is 7~10min.
By adopting aforementioned techniques scheme, the invention has the beneficial effects as follows: the step of preparation process of the integrated rubber pange footwear of the present invention is simple, easy to operate, save time, adopt technique of the present invention, in one day, produce 2500 pairs of shoes and only need 20 workmans, compare traditional technique and saved the workman of 60 left and right, saved largely manpower, for enterprise has saved a large amount of Financial cost.The formula of soles environmental protection of rubber pange footwear of the present invention, the sole resilience that adopts such formula to make is effective, has memory effect, after turnover, can return to original shape, bonding force is strong, with upper of a shoe moulding after, the adhesive effect between sole and upper of a shoe is good, is difficult for peeling off, do not need to use glue, free from environmental pollution, simultaneously owing to not using glue, the injury of effectively having avoided glue volatilization to produce human body; In addition, shoes are at high temperature dressed and are difficult for the phenomenon come unstuck, and the anti-neatly of sole, ice slipping prevention, prevent that cunning effect is good, the shoes overall weight making is light, dresses comfortablely, at wintry weather, comparatively dresses severe cold in the situation that, be not easy to rupture, the cold tolerance of shoes is better.
Embodiment
Below with reference to specific embodiment, describe embodiments of the present invention in detail, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure of reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technique means adopting in embodiment is well known to those skilled in the art, the reagent adopting and product are also and can business obtain.The source of agents useful for same, trade(brand)name and be necessary to list its moiety person are all indicated when occurring first.
Embodiment mono-
A kind of rubber pange footwear, comprise sole and be located at the upper of a shoe on sole, described sole comprises the starting material of following weight part: 250 parts of natural rubbers, 600 parts of stone flours, 60 parts, zinc oxide, 3 parts of stearic acid, 5 parts of whipping agents, 4 parts, sulphur, 3 parts of vulkacit Ds, rubber accelerator DM3 part, 8 parts, anti-aging agent, 10 parts of ointment.
A preparation method for rubber pange footwear, comprises the following steps:
(1) prepare rubber pange sheet: the starting material of the sole of above-mentioned each weight part are put into rubber mixing machine mixing, mixing 30min, obtains rubber pange sheet;
(2) prepare patrix, bed die and shoe last;
(3) rubber pange sheet step (1) being made is put into bed die, shoe last is fixed on to the corresponding position of patrix, at shoe last, puts upper of a shoe outward, foaming and setting 7min at 150 ℃;
(4) delasting head, the demoulding: take out shoe last, patrix and bed die, make integrated rubber pange footwear.
Embodiment bis-
A kind of rubber pange footwear, comprise sole and be located at the upper of a shoe on sole, described sole comprises the starting material of following weight part: 270 parts of natural rubbers, 650 parts of stone flours, 4 parts of 70 parts of stearic acid of zinc oxide, 7 parts of whipping agents, 5 parts, sulphur, 4 parts of vulkacit Ds, 4 parts of altaxs, 9 parts, anti-aging agent, 10.5 parts of ointment; The described large end, comprises each component of following weight part: 280 parts of natural rubbers, 670 parts of stone flours, 75 parts, zinc oxide, 4 parts of stearic acid, 8 parts of whipping agents, 5.5 parts, sulphur, 4.5 parts of promotor, rubber accelerator MD4 part, 9.5 parts, anti-aging agent, 11 parts of ointment.
A preparation method for rubber pange footwear, comprises the following steps:
(1) prepare rubber pange sheet: the starting material of the sole of above-mentioned each weight part are put into rubber mixing machine mixing, mixing how long 30min, obtains rubber pange sheet;
(2) prepare patrix, bed die and shoe last;
(3) rubber pange sheet step (1) being made is put into bed die, shoe last is fixed on to the corresponding position of patrix, at shoe last, puts upper of a shoe outward, foaming and setting 8min at 160 ℃;
(4) delasting head, the demoulding: take out shoe last, patrix and bed die, make integrated rubber pange footwear.
Embodiment tri-
A kind of rubber pange footwear, comprise sole and be located at the upper of a shoe on sole, described sole comprises the starting material of following weight part: 290 parts of natural rubbers, 690 parts of stone flours, 78 parts, zinc oxide, 5 parts of stearic acid, 9 parts of whipping agents, 6 parts, sulphur, 5 parts of vulkacit Ds, rubber accelerator DM5 part, 10 parts, anti-aging agent, 11 parts of ointment.
A preparation method for rubber pange footwear, comprises the following steps:
(1) prepare rubber pange sheet: the starting material of the sole of above-mentioned each weight part are put into rubber mixing machine mixing, mixing how long 30min, obtains rubber pange sheet;
(2) prepare patrix, bed die and shoe last;
(3) rubber pange sheet step (1) being made is put into bed die, shoe last is fixed on to the corresponding position of patrix, at shoe last, puts upper of a shoe outward, foaming and setting 9min at 170 ℃;
(4) delasting head, the demoulding: take out shoe last, patrix and bed die, make integrated rubber pange footwear.
Embodiment tetra-
A kind of rubber pange footwear, comprise sole and be located at the upper of a shoe on sole, described sole comprises the starting material of following weight part: 295 parts of natural rubbers, 650 parts of stone flours, 76 parts, zinc oxide, 3 parts of stearic acid, 8 parts of whipping agents, 4 parts, sulphur, 3.5 parts of vulkacit Ds, 3.5 parts of altaxs, 8 parts, anti-aging agent, 10 parts of ointment; Described big-sole formula comprises each component of following weight part: 300 parts of natural rubbers, 700 parts of stone flours, 5 parts of 80 parts of stearic acid of zinc oxide, 10 parts of whipping agents, 6 parts, sulphur, 5 parts of promotor, rubber accelerator MD5 part, 10 parts, anti-aging agent, 11 parts of ointment.
A preparation method for rubber pange footwear, comprises the following steps:
(1) prepare rubber pange sheet: the starting material of the sole of above-mentioned each weight part are put into rubber mixing machine mixing, mixing how long 30min, obtains rubber pange sheet;
(2) prepare patrix, bed die and shoe last;
(3) rubber pange sheet step (1) being made is put into bed die, shoe last is fixed on to the corresponding position of patrix, at shoe last, puts upper of a shoe outward, foaming and setting 10min at 165 ℃;
(4) delasting head, the demoulding: take out shoe last, patrix and bed die, make integrated rubber pange footwear.
Wherein, in the present invention, in described formula of soles, the content of each component all can be realized object of the present invention in following scope: 250~300 parts of natural rubbers, 600~700 parts of stone flours, 60~80 parts, zinc oxide, 3~5 parts of stearic acid, 5~10 parts of whipping agents, 4~6 parts, sulphur, 3~5 parts of vulkacit Ds, 3~5 parts of altaxs, 8~10 parts, anti-aging agent, 10~11 parts of ointment.Temperature in described high temperature foaming, fixating shape step is controlled within the scope of 150~170 ℃ and all can realizes object of the present invention.The large end of sole of the present invention and the formula at the middle end can be the same, also difference to some extent, and the component of its formula and component concentration all can be realized object of the present invention in above-mentioned scope.
The step of preparation process of inventing integrated rubber pange footwear is simple, easy to operate, save time, adopt technique of the present invention, in one day, produce 2500 pairs of shoes and only need 20 workmans, compare traditional technique and saved the workman of 60 left and right, saved largely manpower, for enterprise has saved a large amount of Financial cost.The formula of soles environmental protection of rubber pange footwear of the present invention, the sole resilience that adopts such formula to make is effective, has memory effect, after turnover, can return to original shape, bonding force is strong, with upper of a shoe moulding after, the adhesive effect between sole and upper of a shoe is good, is difficult for peeling off, do not need to use glue, free from environmental pollution, simultaneously owing to not using glue, the injury of effectively having avoided glue volatilization to produce human body; In addition, shoes are at high temperature dressed and are difficult for the phenomenon come unstuck, and the anti-neatly of sole, ice slipping prevention, prevent that cunning effect is good, the shoes overall weight making is light, dresses comfortablely, at wintry weather, comparatively dresses severe cold in the situation that, be not easy to rupture, the cold tolerance of shoes is better.
Rubber pange footwear of the present invention are carried out to physical and mechanical properties test, and it the results are shown in Table one.
Table one physical and mechanical properties test result
Above record, only, for utilizing the embodiment of this origination techniques content, modification, variation that any those skilled in the art use this creation to do, all belong to the scope of the claims that this creation is advocated, and be not limited to those disclosed embodiments.