CN103931685B - A kind of bacteriostatic agent and preparation and application thereof controlling Domestic Waste Collection fortune process contamination gas discharging - Google Patents
A kind of bacteriostatic agent and preparation and application thereof controlling Domestic Waste Collection fortune process contamination gas discharging Download PDFInfo
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- CN103931685B CN103931685B CN201310017827.9A CN201310017827A CN103931685B CN 103931685 B CN103931685 B CN 103931685B CN 201310017827 A CN201310017827 A CN 201310017827A CN 103931685 B CN103931685 B CN 103931685B
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Abstract
The present invention relates to a kind of bacteriostatic agent and the preparation and application thereof that control Domestic Waste Collection fortune process contamination gas discharging.Bacteriostatic agent of the present invention is plant extraction liquid, and the plant material component of described extract comprises: peppermint, galingal, Chinese honey locust, Radix Glycyrrhizae, Fructus meliae toosendan and vomiting nut.This bacteriostatic agent belongs to natural botanical extraction liquid, and its chemistry, physical property are stablized, friendly to human body environment, pollution-free, without dangerous.Utilize the fungistatic effect of terpane compounds, cloves phenols, saponin, glycyrrhizin, toosendanin and the alkaloids substance contained in peppermint, galingal, Chinese honey locust, Radix Glycyrrhizae, Fructus meliae toosendan, vomiting nut, bacterium in effective suppression rubbish, has good peculiar smell and removes and air sterilizing effect.
Description
Technical field
The invention belongs to environmental protection technical field, be specifically related to a kind of bacteriostatic agent and the preparation and application thereof that control Domestic Waste Collection fortune process contamination gas discharging.
Background technology
Along with expanding economy, the raising of people's living standard, the growth of urban population, the expansion of urban area, the generation of municipal refuse increases year by year.In Shanghai, the Shanghai City house refuse daily output is more than 10,000 tons, and so a large amount of rubbish usually will through garbage-compressing transfer, then receives and be transported to destructor plant.Household garbage-compressing transport process is as the binding site connecting rubbish source of generation and end disposal system, and its effect is more and more obvious, is the requisite link that current municipal refuse is cleared.But, the foul odour that garbage collecting and transferring produces, airborne dust, sewage and the insect pest (mosquitos and flies) thereupon brought, be a troubling problem always, especially receive fortune station from the transfer close to city neighborhood, what the public complained more and strong reaction is foul odour.Therefore, to disturb residents problem for solving waste transportation, it is imperative to seek effective and practicable peculiar smell control technology.
Containing a large amount of carbohydrate, protein and fat in rubbish, multiple smell substance can be produced in anoxic process, mainly contain ammonia (NH
3), hydrogen sulphide (H
2s), methyl mercaptan (CH
3sH), methyl sulfide CH
3sCH
3), trimethylamine ((CH
3)
3n), methyl disulfide (CH
3sSCH
3), indoles (C
8h
5-NHCH
3), acetaldehyde (CH
3cHO), styrene (C
6h
5c
2h
3), lower alcohol and fatty acid etc., the rubbish that the anaerobic fermentation time is longer, also can produce methane isothermal chamber gas.Smell substance belongs to colourless gas mostly, its odor threshold extremely low (mostly being ppb level), have strong impulse stench taste, some also has larger toxicity, and very easily combine with the moisture in air, grit, enter harm health with respiratory system.In order to improve resident living environmental quality, stopping air pollution hidden danger, improve city image, the smell pollution of garbage collecting and transferring process controls to have become one of environmental problem that some areas are urgently to be resolved hurrily at present.
The air pollution control measure of garbage collecting and transferring process mostly is and adopts closure equipment, adopt screening agents such as spraying plant extraction liquid once in a while, these methods serve certain effect to alleviation peculiar smell and dust pollution, but all can not fundamentally eliminate peculiar smell and contamination by dust, smell substance still leaks from gap.Therefore, develop the effective pollution control technology of a kind of garbage collecting and transferring process peculiar smell, meet the development trend of this field Environmental capacity current.
Bacteriostatic agent is often referred to the material of energy bacteria growing inhibiting.Daily bacteriostatic agent spininess is to Escherichia coli, staphylococcus, candida albicans and some fungi, be used for preventive medicine scope, consider bactericidal property simultaneously, be usually used in gynaecologic washing lotion, wet tissue, sanitary napkin, oral-cavity article, hand cleanser, melon and fruit fresh-keeping with sterilization, environment disinfected etc.Two large classes can be divided into by its antimicrobial mechanism.
(1) oxidized form bacteriostatic agent.Common have liquid chlorine, clorox, bromine, ozone, chloramines, chlorated fulminuric acid and salt, hydantoin halides etc.
(2) Non-oxidized bacteriostatic agent.Common have chlorophenols, quaternary ammonium salt, isothiazolinone, Chinese cassia tree aldehydes, heavy metallic salt (as copper sulphate, copper citrate), other organic matter classes (as metronidazole, sevin, fatty acid amine, dodecyl guanidine hydrochloride, quaternary alkylphosphonium salt etc.).
Above bacteriostatic agent many because of extensive use cost higher, antibacterial broad spectrum activity difference or exist secondary pollution (as hypochlorous acid by, liquid chlorine, bromine, chloramines, chlorophenol, heavy metallic salt etc.), thus seldom control for smell pollution in disposal of refuse place.
The mushroom causing waste odor to produce mainly concentrates on strict anaerobes, and to gram-positive bacteria, Gram-negative bacteria, bacterial spore and fungi, acid-producing bacteria, methanogen etc., therefore, choice for use, for the bacteriostatic agent of such bacterium, effectively can control smell pollution.
Summary of the invention
The object of the invention is to overcome defect of the prior art, a kind of bacteriostatic agent that is environmentally friendly, that pollute as the gas with foreign flavor of garbage collecting and transferring process the good plant resource class compound preservative of anaerobic bacteria inhibition is provided, and further provides its preparation method and using method.Bacteriostatic agent of the present invention is for suppressing growing of the anaerobic fermentation bacterium in house refuse, and this bacteriostatic agent distributes control for garbage collecting and transferring process smell substance, avoids the generation of smell substance, and has sterilizing effect concurrently.
The bacteriostatic agent of control Domestic Waste Collection fortune process contamination gas discharging of the present invention is plant extraction liquid, and the plant material component of described extract comprises: peppermint, galingal, Chinese honey locust, Radix Glycyrrhizae, Fructus meliae toosendan and vomiting nut.
More specifically, described plant material presses dry weight basis, comprises the component of following weight portion:
Preferably, described plant material presses dry weight basis, comprises the component of following weight portion:
Described peppermint (Menthahaplocalyx.) is the acrial part of labiate peppermint.
Described galingal (AlpiniaofficinarumHance) is the rhizome of zingiberaceous plant galangal.
Described Chinese honey locust (GleditsiasinensisLam.), has another name called Chinese honey locust, is the fruit of honey locust.
Described Radix Glycyrrhizae (Glycyrrhizaglabra) is the root of Radix Glycyrrhizae plant.
Described Fructus meliae toosendan (FructusMeliaeToosendan) is the ripening fruits of Meliaceae deciduous tree toosendanin.
Described vomiting nut (SemenStrychni) is the mature seed of loganiaceae plant Strychnos nux-vomica.
Plant material of the present invention is dry product or fresh goods, can convert when selecting fresh goods by dry product weight ratio.
Bacteriostatic agent of the present invention is the plant extraction liquid that described plant material obtains through water extraction.
The preparation method of bacteriostatic agent of the present invention comprises the following steps: raw material mixes after crushed in proportion, soak, boiling, cooling, Separation of Solid and Liquid obtain mother liquor, then to carry out after natural stability obtaining antibacterial mother liquor to mother liquor.
More specifically, the preparation method of described bacteriostatic agent comprises the following steps:
1) raw material smashing fineness reaches 10-100 order, mixes in proportion;
2) in a kettle., water plant material being added plant material gross weight (by overall dry weight) 10 ~ 20 times is uniformly mixed, soak 24 ~ 30 hours, boiling 4 ~ 8 hours, boiling temperature 80 ~ 90 DEG C, digestion process distillates point condensing reflux to reactor, is cooled to room temperature and carries out Separation of Solid and Liquid and obtain filtering lower liquid;
3) the lower liquid of filter natural stability 1 ~ 3 day in closed container, is antibacterial mother liquor.
Preferably, in step 1), raw material smashing fineness is 20-80 order.
Preferably, step 2) in, water plant material being added plant material gross weight (by overall dry weight) 13 ~ 14 times is uniformly mixed, and soaks 25 ~ 30 hours, boiling 7 ~ 8 hours.
Preferably, in step 3), the lower liquid of filter natural stability 2 ~ 3 days in closed container, obtains antibacterial mother liquor.
Further, described step 2) in, Separation of Solid and Liquid utilizes plate and frame filter press to carry out.
Described antibacterial mother liquor can directly as finished product, thin up before use.Or also antibacterial mother liquor can be diluted to mother liquid concentration through water is 0.1% ~ 10%(v%) after as finished product.
Bacteriostatic agent of the present invention, can be used for garbage transporting, handling and stacking time smell pollution control and air sterilizing.
Present invention also offers a kind of garbage transporting, handling and stacking time smell pollution control method, for bacteriostatic agent of the present invention is sprayed on rubbish surface.
Bacteriostatic agent of the present invention, in use, it is 0.1% ~ 10%(v% that antibacterial mother liquor need be diluted with water to mother liquid concentration), be preferably 0.4 ~ 1%, and dilution is used by spray pattern.
The recommendation fountain height of dilution is 0.1 ~ 2L/m
2.
Beneficial outcomes of the present invention is:
The present invention adopts natural botanical extraction liquid, and its chemistry, physical property are stablized, friendly to human body environment, pollution-free, without dangerous.This patent utilizes the fungistatic effect of terpane compounds, cloves phenols, saponin, glycyrrhizin, toosendanin and the alkaloids substance contained in peppermint, galingal, Chinese honey locust, Radix Glycyrrhizae, Fructus meliae toosendan, vomiting nut, bacterium in effective suppression rubbish, has good peculiar smell and removes and air sterilizing effect.
Accompanying drawing explanation
Fig. 1 is the production routine schematic diagram of antibacterial liquid of the present invention.
Embodiment
Below by way of specific instantiation, embodiments of the present invention are described, those skilled in the art the content disclosed by this specification can understand other advantages of the present invention and effect easily.The present invention can also be implemented or be applied by embodiments different in addition, and the every details in this specification also can based on different viewpoints and application, carries out various modification or change not deviating under spirit of the present invention.
Notice, in the following example, the concrete process equipment that indicates or device all adopt conventional equipment in this area or device; All force value and scope all refer to absolute pressure.
In embodiment, the preparation process of each bacteriostatic agent:
1, raw material is ground into fine grained by cracker respectively by table 1, smashing fineness reaches between 10-100 order.
2, raw material step 1 pulverized is transferred to reactor by required weight ratio, and adds the water of 10 ~ 20 times, is uniformly mixed, and soaks 24 ~ 30 hours.
3, boiling 4 ~ 8 hours, boiling temperature 80 ~ 90 DEG C, digestion process distillates point condensing reflux to reactor.
4, be cooled to room temperature, well-done for step 3 material be transferred to solid-liquid separator (plate and frame filter press) and carry out Separation of Solid and Liquid, collect the lower liquid of filter to closed container.
5, step 4 gained is liquid-tight under filtering closes, and natural stability 1 ~ 3 day, is antibacterial mother liquor.
In embodiment, the using method of each bacteriostatic agent:
(1) dilute: according to use needs, water is carried out to the antibacterial mother liquor prepared and is diluted to 0.1% ~ 10% for subsequent use.
(2) antibacterial liquid good for above-mentioned dilution is injected sprinkler.
(3) by 0.1 ~ 2L/m
2fountain height, antibacterial liquid is evenly sprayed to rubbish top layer.
Table 1 proportioning table (following each plant material calculates by dry weight, and unit is kg)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Peppermint | 8 | 7.5 | 8.5 |
| Galingal | 10 | 12 | 11.5 |
| Chinese honey locust | 5 | 6.5 | 7 |
| Radix Glycyrrhizae | 9 | 7 | 8.5 |
| Fructus meliae toosendan | 7 | 8.5 | 9 |
| Vomiting nut | 11 | 12.5 | 13.5 |
Embodiment 1: for garbage transporting process
The preparation of antibacterial mother liquor:
1, above-mentioned raw materials is ground into fine grained by cracker respectively by table 1, smashing fineness reaches between 20-50 order.
2, raw material step 1 pulverized is transferred to reactor by required weight ratio, and adds 750kg water, is uniformly mixed, and soaks 25 hours.
3, boiling 7 hours, boiling temperature 80 ~ 90 DEG C, digestion process distillates point condensing reflux to reactor.
4, be cooled to room temperature, well-done for step 3 material be transferred to plate and frame filter press and carry out Separation of Solid and Liquid, collect the lower liquid of filter to closed container.
5, step 4 gained is liquid-tight under filtering closes, and natural stability 2 days, obtains antibacterial mother liquor.
Get antibacterial mother liquor, with 0.5%(volume ratio) thin up, be dilution articles for use.The antibacterial liquid diluted is filling, is sprayed on 20 square meter rubbish surfaces, fountain height 0.5L/m by spray appliance
2, sprayed once every 1 hour.
Garbage transporting process refers to: cram packer or cargo ship driving process.
Spray use after 8 hours, adopt Ministry of Public Health's staphylococcus aureus examination criteria (GB/T4789.37-2008) to detect, staphylococcus aureus (genus gram-positive bacteria) inhibiting rate reaches more than 93.4%.According to GB/T14675-1993 " the mensuration triangle odor bag method of air quality stench ", to eliminating the unusual smell, effect detects, and the reduced rate of odor concentration reaches more than 95.5%.
Embodiment 2: for rubbish cargo handling process
The preparation of antibacterial mother liquor:
1, above-mentioned raw materials is ground into fine grained by cracker respectively by table 1, smashing fineness reaches between 25-60 order.
2, raw material step 1 pulverized is transferred to reactor by required weight ratio, and adds 810kg water, is uniformly mixed, and soaks 28 hours.
3, boiling 8 hours, boiling temperature 80 ~ 90 DEG C, digestion process distillates point condensing reflux to reactor.
4, be cooled to room temperature, well-done for step 3 material be transferred to plate and frame filter press and carry out Separation of Solid and Liquid, collect the lower liquid of filter to closed container.
5, step 4 gained is liquid-tight under filtering closes, and natural stability 2 days, obtains antibacterial mother liquor.
Get antibacterial mother liquor, in 0.4% ratio (volume ratio) thin up, be dilution antibacterial liquid finished product.The antibacterial liquid diluted is filling, when rubbish loads and unloads, is sprayed on rubbish surface, fountain height 1.5L/m with spray appliance simultaneously
2.
Rubbish handling operation process of the present invention refers to: rubbish is in entrucking and unload, or the transfer process of loading onto ship and unloading a ship.When rubbish shifts, namely in rubbish surface sprinkling.
Spray use after 8 hours, adopt Ministry of Public Health's staphylococcus aureus examination criteria (GB/T4789.37-2008) to detect, staphylococcus aureus (genus gram-positive bacteria) inhibiting rate reaches more than 94.2%.According to GB/T14675-1993 " the mensuration triangle odor bag method of air quality stench ", to eliminating the unusual smell, effect detects, and the reduced rate of odor concentration reaches more than 96.1%.According to GB/T2761-2006 " indoor air purification product clean-up effect assay method " to the total plate count deactivation service check in the air of operation area, result shows, and in air, the clearance of total plate count is 96.5%.
Embodiment 3: for dumping process
The preparation of antibacterial mother liquor:
1, above-mentioned raw materials is ground into fine grained by cracker respectively by table 1, smashing fineness reaches between 30-80 order.
2, raw material step 1 pulverized is transferred to reactor by required weight ratio, and adds 900kg water, is uniformly mixed, and soaks 30 hours.
3, boiling 8 hours, boiling temperature 80 ~ 90 DEG C, digestion process distillates point condensing reflux to reactor.
4, be cooled to room temperature, well-done for step 3 material be transferred to plate and frame filter press and carry out Separation of Solid and Liquid, collect the lower liquid of filter to closed container.
5, step 4 gained is liquid-tight under filtering closes, and natural stability 3 days, obtains antibacterial mother liquor.
Get antibacterial mother liquor, by 1% percent by volume thin up, be dilution antibacterial liquid finished product.The antibacterial liquid diluted is filling, is sprayed on 20 square meter rubbish surfaces, fountain height 1.0L/m by spray appliance
2, every day sprays once.
During use, every day sprays once, sprays after 3 days continuously, and adopt Ministry of Public Health's staphylococcus aureus examination criteria (GB/T4789.37-2008) to detect, staphylococcus aureus (genus gram-positive bacteria) inhibiting rate reaches more than 93.3%.According to GB/T14675-1993 " the mensuration triangle odor bag method of air quality stench ", to eliminating the unusual smell, effect detects, and the reduced rate of odor concentration reaches more than 95.8%.According to GB/T2761-2006 " indoor air purification product clean-up effect assay method " to the total plate count deactivation service check in the air of operation area, result shows, and in air, the clearance of total plate count is 96.2%.
Above embodiment illustrates, patent of the present invention has good eradicating efficacy to waste odor, and fungistatic effect is obvious, has good bactericidal effect simultaneously.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (8)
1. one kind controls the bacteriostatic agent of Domestic Waste Collection fortune process contamination gas discharging, for plant extraction liquid, the plant material component of described plant extraction liquid comprises: peppermint, galingal, Chinese honey locust, Radix Glycyrrhizae, Fructus meliae toosendan and vomiting nut, and described bacteriostatic agent adopts the method comprised the following steps to obtain:
1) raw material smashing fineness reaches 10-100 order, mixes in proportion;
2) in a kettle., water plant material being added plant material gross dry weight 10 ~ 20 times is uniformly mixed, and soaks 24 ~ 30 hours, boiling 4 ~ 8 hours, boiling temperature 80 ~ 90 DEG C, digestion process distillates point condensing reflux to reactor, is cooled to room temperature and carries out Separation of Solid and Liquid and obtain filtering lower liquid;
3) the lower liquid of filter natural stability 1 ~ 3 day in closed container, obtains antibacterial mother liquor.
2. control the bacteriostatic agent of Domestic Waste Collection fortune process contamination gas discharging as claimed in claim 1, it is characterized in that, described plant material presses dry weight basis, comprises the component of following weight portion:
3. control the bacteriostatic agent of Domestic Waste Collection fortune process contamination gas discharging as claimed in claim 1, it is characterized in that, described plant material presses dry weight basis, comprises the component of following weight portion:
4. the preparation method of bacteriostatic agent as described in claim as arbitrary in claim 1-3, comprises the following steps:
1) raw material smashing fineness reaches 10-100 order, mixes in proportion;
2) in a kettle., water plant material being added plant material gross dry weight 10 ~ 20 times is uniformly mixed, and soaks 24 ~ 30 hours, boiling 4 ~ 8 hours, boiling temperature 80 ~ 90 DEG C, digestion process distillates point condensing reflux to reactor, is cooled to room temperature and carries out Separation of Solid and Liquid and obtain filtering lower liquid;
3) the lower liquid of filter natural stability 1 ~ 3 day in closed container, obtains antibacterial mother liquor.
5. the preparation method of bacteriostatic agent as claimed in claim 4, is characterized in that, step 2) in, water plant material being added plant material gross dry weight 13 ~ 14 times is uniformly mixed, and soak time is 25 ~ 30 hours, and digestion time is 7 ~ 8 hours.
6. the preparation method of bacteriostatic agent as described in claim as arbitrary in claim 4-5, is characterized in that, step 3) after also comprise: it is 0.1% ~ 10% that antibacterial mother liquor is diluted to mother liquor volumetric concentration through water.
7. bacteriostatic agent as described in claim as arbitrary in claim 1-3 be used for garbage transporting, handling and stacking time smell pollution control and the purposes of air sterilizing.
8. garbage transporting, handling and stacking time a smell pollution control method, for the bacteriostatic agent described in arbitrary for claim 1-3 claim is sprayed on rubbish surface.
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| CN105944496A (en) * | 2016-05-12 | 2016-09-21 | 赵月 | Indoor air purifying agent |
| CN110465167A (en) * | 2019-08-06 | 2019-11-19 | 北京市畜牧总站 | A kind of deodorizing methods of scale chicken house |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102090417A (en) * | 2010-12-22 | 2011-06-15 | 韶关蓝威消毒药业有限公司 | Preparation method of living disinfectant |
| CN102240409A (en) * | 2011-05-27 | 2011-11-16 | 胡镜 | Plant source extraction deodorant and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102090417A (en) * | 2010-12-22 | 2011-06-15 | 韶关蓝威消毒药业有限公司 | Preparation method of living disinfectant |
| CN102240409A (en) * | 2011-05-27 | 2011-11-16 | 胡镜 | Plant source extraction deodorant and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 中草药抗菌抑菌作用在食品保鲜中的应用;章薇等;《肉类工业》;20090725(第7期);第52-54页 * |
| 中草药源农药的研究与应用;严振等;《中国中药杂志》;20051130;第30卷(第21期);第1714-1717页 * |
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