CN103923517A - Preparation method of matt black plasticizing ink - Google Patents
Preparation method of matt black plasticizing ink Download PDFInfo
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- CN103923517A CN103923517A CN201410181727.4A CN201410181727A CN103923517A CN 103923517 A CN103923517 A CN 103923517A CN 201410181727 A CN201410181727 A CN 201410181727A CN 103923517 A CN103923517 A CN 103923517A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000012046 mixed solvent Substances 0.000 claims abstract description 26
- 239000000049 pigment Substances 0.000 claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 24
- 239000006185 dispersion Substances 0.000 claims abstract description 17
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003921 oil Substances 0.000 claims abstract description 15
- 239000000654 additive Substances 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 238000005282 brightening Methods 0.000 claims abstract description 3
- 239000011259 mixed solution Substances 0.000 claims description 32
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 18
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 14
- 235000019198 oils Nutrition 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 10
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 10
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 10
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- NKEQOUMMGPBKMM-UHFFFAOYSA-N 2-hydroxy-2-[2-(2-hydroxy-3-octadecanoyloxypropoxy)-2-oxoethyl]butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COC(=O)CC(O)(C(O)=O)CC(O)=O NKEQOUMMGPBKMM-UHFFFAOYSA-N 0.000 claims description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 7
- 239000004902 Softening Agent Substances 0.000 claims description 7
- 239000001055 blue pigment Substances 0.000 claims description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Natural products OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 4
- 239000001054 red pigment Substances 0.000 claims description 4
- 239000003351 stiffener Substances 0.000 claims description 4
- FJRUWRJAJNEIKD-UHFFFAOYSA-N 2,3-dihydro-1,4-benzodioxine-6,7-diamine Chemical compound O1CCOC2=C1C=C(N)C(N)=C2 FJRUWRJAJNEIKD-UHFFFAOYSA-N 0.000 claims description 2
- IHLDEDLAZNFOJB-UHFFFAOYSA-N 6-octoxy-6-oxohexanoic acid Chemical compound CCCCCCCCOC(=O)CCCCC(O)=O IHLDEDLAZNFOJB-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 239000013530 defoamer Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 239000001069 triethyl citrate Substances 0.000 claims description 2
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims description 2
- 235000013769 triethyl citrate Nutrition 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 239000011347 resin Substances 0.000 abstract description 9
- 229920005989 resin Polymers 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 239000004014 plasticizer Substances 0.000 abstract description 2
- 238000003756 stirring Methods 0.000 abstract 5
- 230000001105 regulatory effect Effects 0.000 abstract 3
- 238000003801 milling Methods 0.000 abstract 2
- 239000003085 diluting agent Substances 0.000 abstract 1
- 238000009736 wetting Methods 0.000 abstract 1
- 229920001944 Plastisol Polymers 0.000 description 7
- 239000004999 plastisol Substances 0.000 description 7
- 238000007639 printing Methods 0.000 description 6
- 239000000523 sample Substances 0.000 description 6
- 241001062009 Indigofera Species 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 210000000795 conjunctiva Anatomy 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000003981 vehicle Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a preparation method of matt black plasticizing ink. The preparation method comprises the following steps: (1) mixing silver powder with gloss oil uniformly in a stirring manner to obtain a regulating material; (2) fully mixing a diluent with part of mixed solvent in a stirring manner, and dissolving the regulating material to prepare a disperse solution; (3) fully mixing pigments with the disperse solution in a stirring manner, and wetting the pigments to prepare first mixed liquor; (4) fully mixing a hardening agent with the remaining mixed solvent in a stirring manner, and dissolving the hardening agent to prepare second mixed liquor; (5) fully mixing the first mixed liquor, the second mixed liquor, the regulating material, plasticizers and optional additives in a stirring manner to obtain mixed feed liquor, and milling to obtain the plasticizing ink. By adopting the preparation method, the surface tension between the pigments and resin can be reduced, the wettability of the pigments and resin can be improved, the ink milling effect can be reinforced, the dispersion time can be reduced, and the ink has good brightening effect and proper viscosity.
Description
Technical field
The invention belongs to the technical field of ink, in particular, the present invention relates to a kind of preparation method of mute black plasticising ink.
Background technology
Ink is the important materials for wrapping material printing, and it comprises main component and ancillary component by printing by pattern, the present stock curing ink of literal table, and they mix equably and form the gluey fluid of a kind of viscosity through repeat-rolling.Printing-ink is by dispersed pulpous state colloids mixing of material such as colorant, low-melting ink vehicle and auxiliary agent and solvents.The binder of solvent type ink consists of solid resin and a large amount of volatile organic solvent.After solid resin is dissolved in solvent, colorant is dispersed in binder, ink is printed to printed medium, the rapid volatile dry conjunctiva of solvent.
For ink, general expectation is used and can on printed medium, be produced aesthetic effect and the permanent printing characteristic keeping that simultaneously shows pleasant.The example of these printing characteristics comprises press quality, as optical density (OD), colourity etc.; And weather resistance, as water tolerance, resistance to fadedness, persistence, acidproof and alkaline-resisting etc.Plastisol ink composite is often known as plastisol ink, because the mode applying is utilized the fluid properties of plastisol before heating, by baking or thermofixation, causes the base resin in plastisol to be solidified into solid.In prior art, most plastisol is in the softening agent being dispersed in based on phthalic ester, also passes through in the composition of its polyvinyl chloride (PVC) RESINS that swelling occurs.Polyvinyl chloride (PVC) RESINS plastisol ink is widely used for silk screen printing operation.But due to the consideration of environment, health and safety, the use of these ink is subject to strict restriction just day by day.Therefore guaranteeing, under the prerequisite of ink quality, to develop performance identical with PVC plastisol, but thering is less health and environmental risk; And good dispersity, ink that wettability is good and preparation method thereof becomes the target that those skilled in the art pursue.
Summary of the invention
In order to solve above-mentioned technical problem of the prior art, the object of the present invention is to provide a kind of preparation method of mute black plasticising ink.
In order to realize foregoing invention object, the present invention has adopted following technical scheme:
The preparation method of mute black plasticising ink of the present invention, it comprises silver powder, gloss oil, pigment, stiffening agent, softening agent, thinner and mixed solvent, and optional additive; It is characterized in that: described preparation method comprises the following steps:
(1) silver powder and gloss oil are mixed to adjusted material with alr mode;
(2) thinner and part mixed solvent fully mixed and dissolved with alr mode, making dispersion soln;
(3) dispersion soln pigment and step (2) being prepared, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) stiffening agent fully mixed and dissolved with alr mode with remaining mixed solvent, making the second mixed solution;
(5) the adjusting material that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain, softening agent and optionally additive are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m.
Wherein, described softening agent is selected from one or more in epoxy soybean oil, Octyl adipate, triethyl citrate, citric acid glyceride or DEDB.
Wherein, described mixed solvent consists of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 30～35 weight parts, n-butyl acetate is 15～20 weight parts, and acetone is 15～20 weight parts.
Wherein, described additive is selected from least one in wetting agent, brightening agent, antioxidant, whipping agent, stablizer or defoamer.
Specifically, the silver powder that described mute black plasticising ink contains 3～5 weight parts, the Seiko 1000-800 gloss oil of 10～16.5 weight parts, the black pigment of 70～72 weight parts, the transparent red pigment of 10.0～10.8 parts, the transparent blue pigment of 12.8～13.2 weight parts, the polymethylmethacrylate of 32.0～40.0 weight parts, the Viscoat 295 of 35.0～42.0 weight parts, the glyceryl stearate citrate of 8.0～10.0 weight parts, the mixed solvent of 65～75 weight parts; And additive optionally.
Wherein, described preparation method comprises the following steps:
(1), by the silver powder of 3～5 weight parts, the Seiko 1000-800 gloss oil of 10～16.5 weight parts mixes adjusted material with alr mode;
(2), by the Viscoat 295 of 35.0～42.0 weight parts, the mixed solvent of 30～35 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(3) by the black pigment of 70～72 weight parts, the transparent red pigment of 10.0～10.8 parts, the dispersion soln that the transparent blue pigment of 12.8～13.2 weight parts and step (2) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) by the polymethylmethacrylate of 32.0～40.0 weight parts, the mixed solvent of 35～40 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(5) the adjusting material that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain, glyceryl stearate citrate and optionally additive are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m.
Wherein, described mixed solvent consists of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 30～35 weight parts,
N-butyl acetate is 15～20 weight parts, and acetone is 15～20 weight parts.
Wherein, the weight ratio of described silver powder and described Seiko 1000-800 gloss oil is 1:3～3:10.
Wherein, the viscosity of described plasticising ink is about 10,000～100,000 centipoises.
Wherein, when the color of described plasticising ink represents with Lab color mode, the scope of L value is that the scope of 29.0～31.5, a value is that the scope of-0.15～0.30, b value is 0.25～1.0.
Compared with prior art, mute black plasticising ink of the present invention has following beneficial effect:
(1), in ink of the present invention, do not contain phthalic ester and polyvinyl chloride resin plasticiser; But its flowing property and prior art are suitable, and there is good preservation stability and good film-forming properties.
(2) adopt dispersing method of the present invention, can reduce the surface tension of pigment and interlaminar resin, improve their wettability, can strengthen the grinding effect of ink, reduce jitter time, and make described ink there is good brightness effect, and suitable viscosity.
(3) ink of the present invention is particularly useful for the silk screen printing of glass, PMMA substrate surface, after ink complete drying, and color light, tack is good, wear resistance good, substantially without oozing out phenomenon.
Embodiment
Below with reference to specific embodiment, the preparation method of mute black plasticising ink of the present invention is described further, to help those skilled in the art to have more complete, accurate and deep understanding to inventive concept of the present invention, technical scheme.Applicant need to declare is that the description of related materials in embodiment, performance and technique etc. is all exemplary, and does not refer to the restriction to invention protection domain.
Embodiment 1
Mute black plasticising ink described in the present embodiment, the component that contains following parts by weight:
The preparation method of the mute black plasticising ink described in the present embodiment comprises the following steps:
(1), by the silver powder of 4.0 weight parts, the Seiko 1000-800 gloss oil of 12.5 weight parts mixes adjusted material with alr mode;
(2), by the Viscoat 295 of 35.0 weight parts, the mixed solvent of 30 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(3) by the Pigment black of 70 weight parts, the pigment transparent red of 10.5 parts, the dispersion soln that the transparent indigo plant of pigment of 13.0 weight parts and step (2) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) by the polymethylmethacrylate of 35.0 weight parts, the mixed solvent of 35 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(5) adjusting material and glyceryl stearate citrate that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m; The viscosity of described ink is about 50,000～80,000 centipoises; When the color of described plasticising ink represents with Lab color mode, the scope of L value is that the scope of 30.2, a value is that the scope of 0.02, b value is 0.52.
Embodiment 2
Mute black plasticising ink described in the present embodiment, the component that contains following parts by weight:
The preparation method of the mute black plasticising ink described in the present embodiment comprises the following steps:
(1), by the silver powder of 4.8 weight parts, the Seiko 1000-800 gloss oil of 15.2 weight parts mixes adjusted material with alr mode;
(2), by the Viscoat 295 of 39.0 weight parts, the mixed solvent of 32 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(3) by the Pigment black of 71.2 weight parts, the pigment transparent red of 10.6 parts, the dispersion soln that the transparent indigo plant of pigment of 13.2 weight parts and step (2) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) by the polymethylmethacrylate of 38.0 weight parts, the mixed solvent of 39 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(5) adjusting material and glyceryl stearate citrate that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m; The viscosity of described ink is about 30,000～60,000 centipoises; When the color of described plasticising ink represents with Lab color mode, the scope of L value is that the scope of 30.0, a value is that the scope of 0.12, b value is 0.38.
Embodiment 3
Mute black plasticising ink described in the present embodiment, the component that contains following parts by weight:
The preparation method of the mute black plasticising ink described in the present embodiment comprises the following steps:
(1), by the silver powder of 4.8 weight parts, the Seiko 1000-800 gloss oil of 15.2 weight parts mixes adjusted material with alr mode;
(2), by the Viscoat 295 of 39.0 weight parts, the mixed solvent of 32 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(3) by the Pigment black of 70.0 weight parts, the pigment transparent red of 10.2 parts, the dispersion soln that the transparent indigo plant of pigment of 12.8 weight parts and step (2) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) by the polymethylmethacrylate of 38.0 weight parts, the mixed solvent of 39 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(5) adjusting material and glyceryl stearate citrate that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m; The viscosity of described ink is about 30,000～60,000 centipoises; When the color of described plasticising ink represents with Lab color mode, the scope of L value is that the scope of 29.7, a value is that the scope of 0.01, b value is 0.58.
Comparative example 1
Mute black plasticising ink described in the present embodiment, the component that contains following parts by weight:
The preparation method of the mute black plasticising ink described in the present embodiment comprises the following steps:
(1), by the silver powder of 4.0 weight parts, the Seiko 1000-800 gloss oil of 12.5 weight parts mixes adjusted material with alr mode;
(2), by the Viscoat 295 of 35.0 weight parts, the mixed solvent of 30 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(3) by the Pigment black of 70 weight parts, the pigment transparent red of 10.5 parts, the dispersion soln that the transparent indigo plant of pigment of 13.0 weight parts and step (2) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) by the polymethylmethacrylate of 35.0 weight parts, the mixed solvent of 35 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(5) adjusting material and dibutyl phthalate that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m; The viscosity of described ink is about 50,000～80,000 centipoises; When the color of described plasticising ink represents with Lab color mode, the scope of L value is that the scope of 30.2, a value is that the scope of 0.02, b value is 0.52.
Adopt conventional method for printing screen that the ink described in embodiment 1-3 and comparative example 1 is printed on glass and PMMA base material; Then at the temperature of 120 ± 1 ℃, carry out first baking; Then at the temperature of 150 ± 1 ℃, carry out second baking; After ink complete drying, the pattern adhesion property that above-mentioned ink printing obtains is stablized, wear resistance is good, presents mute black.
Each 20g of ink sample that gets embodiment 1-3 and comparative example 1 is placed in the thermostat container of 40 ℃, detects the stability in storage of ink sample at the temperature improving; Utilize probe to detect sample at interval of 12 hours, to determine that sample becomes the enough thick and time that cannot carry out silk screen printing, characterizes the time of stability in storage.Result shows: the ink sample of embodiment of the present invention can reach 25-35 days at the storage stability improving at temperature, suitable with comparative example.
In the present invention; for the ordinary skill in the art described; specific embodiment is just exemplarily described the present invention; obviously specific implementation of the present invention is not subject to the restrictions described above; as long as adopted the improvement of the various unsubstantialities that method of the present invention design and technical scheme carry out; or without improving, design of the present invention and technical scheme are directly applied to other occasion, all within protection scope of the present invention.
Claims (10)
1. a preparation method for mute black plasticising ink, described ink comprises silver powder, gloss oil, pigment, stiffening agent, softening agent, thinner and mixed solvent, and optional additive; It is characterized in that: described preparation method comprises the following steps:
(1) silver powder and gloss oil are mixed to adjusted material with alr mode;
(2) thinner and part mixed solvent fully mixed and dissolved with alr mode, making dispersion soln;
(3) dispersion soln pigment and step (2) being prepared, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) stiffening agent fully mixed and dissolved with alr mode with remaining mixed solvent, making the second mixed solution;
(5) the adjusting material that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain, softening agent and optionally additive are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m.
2. the preparation method of mute black plasticising ink according to claim 1, is characterized in that: described softening agent is selected from one or more in epoxy soybean oil, Octyl adipate, triethyl citrate, citric acid glyceride or DEDB.
3. the preparation method of mute black plasticising ink according to claim 1, is characterized in that: described mixed solvent consists of propyl carbinol, n-butyl acetate and acetone.
4. the preparation method of mute black plasticising ink according to claim 1, is characterized in that: described additive is selected from least one in wetting agent, brightening agent, antioxidant, whipping agent, stablizer or defoamer.
5. the preparation method of mute black plasticising ink according to claim 1, it is characterized in that: the silver powder that described ink contains 3～5 weight parts, the Seiko 1000-800 gloss oil of 10～16.5 weight parts, the black pigment of 70～72 weight parts, the transparent red pigment of 10.0～10.8 parts, the transparent blue pigment of 12.8～13.2 weight parts, the polymethylmethacrylate of 32.0～40.0 weight parts, the Viscoat 295 of 35.0～42.0 weight parts, the glyceryl stearate citrate of 8.0～10.0 weight parts, the mixed solvent of 65～75 weight parts; And additive optionally.
6. the preparation method of mute black plasticising ink according to claim 5, is characterized in that: described preparation method comprises the following steps:
(1), by the silver powder of 3～5 weight parts, the Seiko 1000-800 gloss oil of 10～16.5 weight parts mixes adjusted material with alr mode;
(2), by the Viscoat 295 of 35.0～42.0 weight parts, the mixed solvent of 30～35 weight parts fully mixes and dissolves with alr mode, makes dispersion soln;
(3) by the black pigment of 70～72 weight parts, the transparent red pigment of 10.0～10.8 parts, the dispersion soln that the transparent blue pigment of 12.8～13.2 weight parts and step (2) prepare, fully mixes and soaks with alr mode, makes the first mixed solution;
(4) by the polymethylmethacrylate of 32.0～40.0 weight parts, the mixed solvent of 35～40 weight parts fully mixes and dissolves with alr mode, makes the second mixed solution;
(5) the adjusting material that the second mixed solution that the first mixed solution step (3) being obtained, step (4) obtain, step (1) obtain, glyceryl stearate citrate and optionally additive are fully mixed to get mixed liquor with alr mode;
(6) mixed liquor step (5) being obtained adopts sand mill to grind, and obtains the ink that fineness is less than 5 μ m.
7. the preparation method of mute black plasticising ink according to claim 6, is characterized in that: described mixed solvent consists of propyl carbinol, n-butyl acetate and acetone; And described propyl carbinol is 30～35 weight parts, n-butyl acetate is 15～20 weight parts, and acetone is 15～20 weight parts.
8. the preparation method of mute black plasticising ink according to claim 6, is characterized in that: the weight ratio of described silver powder and described Seiko 1000-800 gloss oil is 1:3～3:10.
9. the preparation method of mute black plasticising ink according to claim 6, is characterized in that: the viscosity of described plasticising ink is about 10,000～100,000 centipoises.
10. the preparation method of mute black plasticising ink according to claim 6, it is characterized in that: when the color of described plasticising ink represents with Lab color mode, the scope of L value is that the scope of 29.0～31.5, a value is that the scope of-0.15～0.30, b value is 0.25～1.0.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830146A (en) * | 2015-05-22 | 2015-08-12 | 苏州安洁科技股份有限公司 | Preparation method of silver grey environment-friendly ink for silk-screen printing |
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| JP2009185186A (en) * | 2008-02-07 | 2009-08-20 | Fujifilm Corp | Ink composition, inkjet-recording method, printed matter, and molded printed matter |
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| CN102863849A (en) * | 2012-09-29 | 2013-01-09 | 苏州安洁科技股份有限公司 | IR (infrared) purple ink |
| CN103013225A (en) * | 2012-12-25 | 2013-04-03 | 广州慧谷工程材料有限公司 | IML gloss oil and IML printing ink and preparation method and application thereof |
| CN103666098A (en) * | 2013-12-05 | 2014-03-26 | 湖南互力达涂料科技有限公司 | Aqueous UV gravure varnish |
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2014
- 2014-04-30 CN CN201410181727.4A patent/CN103923517B/en not_active Expired - Fee Related
Patent Citations (5)
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| JP2009185186A (en) * | 2008-02-07 | 2009-08-20 | Fujifilm Corp | Ink composition, inkjet-recording method, printed matter, and molded printed matter |
| CN101760073A (en) * | 2010-01-29 | 2010-06-30 | 蓝思科技（湖南）有限公司 | Colored translucent printing ink |
| CN102863849A (en) * | 2012-09-29 | 2013-01-09 | 苏州安洁科技股份有限公司 | IR (infrared) purple ink |
| CN103013225A (en) * | 2012-12-25 | 2013-04-03 | 广州慧谷工程材料有限公司 | IML gloss oil and IML printing ink and preparation method and application thereof |
| CN103666098A (en) * | 2013-12-05 | 2014-03-26 | 湖南互力达涂料科技有限公司 | Aqueous UV gravure varnish |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830146A (en) * | 2015-05-22 | 2015-08-12 | 苏州安洁科技股份有限公司 | Preparation method of silver grey environment-friendly ink for silk-screen printing |
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| CN103923517B (en) | 2016-01-20 |
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