CN103910923A - 改性发泡聚乙烯 - Google Patents

改性发泡聚乙烯 Download PDF

Info

Publication number
CN103910923A
CN103910923A CN201410176614.5A CN201410176614A CN103910923A CN 103910923 A CN103910923 A CN 103910923A CN 201410176614 A CN201410176614 A CN 201410176614A CN 103910923 A CN103910923 A CN 103910923A
Authority
CN
China
Prior art keywords
accounts
agent
polyethylene
foamed polyethylene
modified foaming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201410176614.5A
Other languages
English (en)
Inventor
徐春华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Huashida Engineering Plastic Co Ltd
Original Assignee
Suzhou New District Huashida Engineering Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Huashida Engineering Plastic Co Ltd filed Critical Suzhou New District Huashida Engineering Plastic Co Ltd
Priority to CN201410176614.5A priority Critical patent/CN103910923A/zh
Publication of CN103910923A publication Critical patent/CN103910923A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/145—Halogen containing compounds containing carbon, halogen and hydrogen only only chlorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/04—Homopolymers or copolymers of ethene
    • C08J2423/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2429/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2429/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2471/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

本发明公开了一种改性发泡聚乙烯，由发泡聚乙烯塑料及添加剂制成，所述添加剂包括发泡剂、绝热剂、增韧剂、抗冲击该制剂以及分散剂，所述发泡剂为四氯乙烷，所述绝热剂为玻璃纤维，所述增韧剂为聚乙烯醇缩丁醛，所述抗冲击该制剂为乙烯-醋酸乙烯共聚物，所述分散剂为脂肪酸聚乙二醇酯。本发明改性发泡聚乙烯通过在发泡聚乙烯塑料中添加多种添加剂，使得制得的改性发泡聚乙烯质量好，同时具有优异的绝热性、柔软性以及机械强度的特点，并且生产成本较低。

Description

改性发泡聚乙烯
技术领域
本发明涉及塑料，特别是涉及一种改性发泡聚乙烯。
背景技术
发泡聚乙烯，俗称珍珠棉，闭孔式微孔热塑性材料。是一种具有高强缓冲吸震抗震能力的新型环保包装材料，广泛适用于绝热包装、浮力板等产品。但是，随着科技水平的不断提高，市场上所使用的发泡聚乙烯的规格要求不断提高，现有的发泡聚乙烯无法满足市场的使用需求。
发明内容
本发明主要解决的技术问题是提供一种质量好、绝热性好、柔软性好、机械强度高、生产成本较低的改性发泡聚乙烯。
为解决上述技术问题，本发明采用的一个技术方案是：提供一种改性发泡聚乙烯，由发泡聚乙烯塑料及添加剂制成，所述添加剂包括发泡剂、绝热剂、增韧剂、抗冲击该制剂以及分散剂，所述发泡剂为四氯乙烷，所述绝热剂为玻璃纤维，所述增韧剂为聚乙烯醇缩丁醛，所述抗冲击该制剂为乙烯-醋酸乙烯共聚物，所述分散剂为脂肪酸聚乙二醇酯，所述改性发泡聚乙烯各成分所占重量百分比分别为发泡聚乙烯塑料占80.2%-85.5%，四氯乙烷占2.8%-3.9%，玻璃纤维占4.5%-5.7%，聚乙烯醇缩丁醛占2.4%-3.4%，乙烯-醋酸乙烯共聚物占3.2%-4.3%，脂肪酸聚乙二醇酯占1.6%-2.5%。
在本发明一个较佳实施例中，所述的改性发泡聚乙烯各成分所占重量百分比具体为发泡聚乙烯塑料占84.9%，四氯乙烷占2.9%，玻璃纤维占4.6%，聚乙烯醇缩丁醛占2.5%，乙烯-醋酸乙烯共聚物占3.3%，脂肪酸聚乙二醇酯占1.8%。
在本发明一个较佳实施例中，所述的改性发泡聚乙烯各成分所占重量百分比具体为发泡聚乙烯塑料占80.7%，四氯乙烷占3.8%，玻璃纤维占5.6%，聚乙烯醇缩丁醛占3.3%，乙烯-醋酸乙烯共聚物占4.2%，脂肪酸聚乙二醇酯占2.4%。
本发明的有益效果是：本发明改性发泡聚乙烯通过在发泡聚乙烯塑料中添加多种添加剂，使得制得的改性发泡聚乙烯质量好，同时具有优异的绝热性、柔软性以及机械强度的特点，并且生产成本较低。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例仅是本发明的一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其它实施例，都属于本发明保护的范围。
一种改性发泡聚乙烯，由发泡聚乙烯塑料及添加剂制成，所述添加剂包括发泡剂、绝热剂、增韧剂、抗冲击该制剂以及分散剂，所述发泡剂为四氯乙烷，所述绝热剂为玻璃纤维，所述增韧剂为聚乙烯醇缩丁醛，所述抗冲击该制剂为乙烯-醋酸乙烯共聚物，所述分散剂为脂肪酸聚乙二醇酯，所述改性发泡聚乙烯各成分所占重量百分比分别为发泡聚乙烯塑料占80.2%-85.5%，四氯乙烷占2.8%-3.9%，玻璃纤维占4.5%-5.7%，聚乙烯醇缩丁醛占2.4%-3.4%，乙烯-醋酸乙烯共聚物占3.2%-4.3%，脂肪酸聚乙二醇酯占1.6%-2.5%。
进一步地，所述的改性发泡聚乙烯各成分所占重量百分比具体为发泡聚乙烯塑料占84.9%，四氯乙烷占2.9%，玻璃纤维占4.6%，聚乙烯醇缩丁醛占2.5%，乙烯-醋酸乙烯共聚物占3.3%，脂肪酸聚乙二醇酯占1.8%。
进一步地，所述的改性发泡聚乙烯各成分所占重量百分比具体为发泡聚乙烯塑料占80.7%，四氯乙烷占3.8%，玻璃纤维占5.6%，聚乙烯醇缩丁醛占3.3%，乙烯-醋酸乙烯共聚物占4.2%，脂肪酸聚乙二醇酯占2.4%。
本发明改性发泡聚乙烯的有益效果是：本发明改性发泡聚乙烯通过在发泡聚乙烯塑料中添加多种添加剂，使得制得的改性发泡聚乙烯质量好，同时具有优异的绝热性、柔软性以及机械强度的特点，并且生产成本较低。
以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书内容所作的等效结构或等效流程变换，或直接或间接运用在其它相关的技术领域，均同理包括在本发明的专利保护范围内。

Claims (3)

1.一种改性发泡聚乙烯，由发泡聚乙烯塑料及添加剂制成，其特征在于：所述添加剂包括发泡剂、绝热剂、增韧剂、抗冲击该制剂以及分散剂，所述发泡剂为四氯乙烷，所述绝热剂为玻璃纤维，所述增韧剂为聚乙烯醇缩丁醛，所述抗冲击该制剂为乙烯-醋酸乙烯共聚物，所述分散剂为脂肪酸聚乙二醇酯，所述改性发泡聚乙烯各成分所占重量百分比分别为发泡聚乙烯塑料占80.2%-85.5%，四氯乙烷占2.8%-3.9%，玻璃纤维占4.5%-5.7%，聚乙烯醇缩丁醛占2.4%-3.4%，乙烯-醋酸乙烯共聚物占3.2%-4.3%，脂肪酸聚乙二醇酯占1.6%-2.5%。
2.根据权利要求1所述的改性发泡聚乙烯，其特征在于，所述的改性发泡聚乙烯各成分所占重量百分比具体为发泡聚乙烯塑料占84.9%，四氯乙烷占2.9%，玻璃纤维占4.6%，聚乙烯醇缩丁醛占2.5%，乙烯-醋酸乙烯共聚物占3.3%，脂肪酸聚乙二醇酯占1.8%。
3.根据权利要求1所述的改性发泡聚乙烯，其特征在于，所述的改性发泡聚乙烯各成分所占重量百分比具体为发泡聚乙烯塑料占80.7%，四氯乙烷占3.8%，玻璃纤维占5.6%，聚乙烯醇缩丁醛占3.3%，乙烯-醋酸乙烯共聚物占4.2%，脂肪酸聚乙二醇酯占2.4%。
CN201410176614.5A 2014-04-29 2014-04-29 改性发泡聚乙烯 Pending CN103910923A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410176614.5A CN103910923A (zh) 2014-04-29 2014-04-29 改性发泡聚乙烯

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410176614.5A CN103910923A (zh) 2014-04-29 2014-04-29 改性发泡聚乙烯

Publications (1)

Publication Number Publication Date
CN103910923A true CN103910923A (zh) 2014-07-09

Family

ID=51036959

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410176614.5A Pending CN103910923A (zh) 2014-04-29 2014-04-29 改性发泡聚乙烯

Country Status (1)

Country Link
CN (1) CN103910923A (zh)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237877A (zh) * 2015-10-26 2016-01-13 陈鹤忠 高分子纳米户外用防滑板及其制备方法
CN105542282A (zh) * 2016-01-26 2016-05-04 苏州羽帆新材料科技有限公司 一种保温抗冲击环保材料及其制备方法
CN106566050A (zh) * 2016-10-31 2017-04-19 江苏昊晟塑业科技有限公司 用于汽车内饰的发泡材料
CN107880368A (zh) * 2017-12-26 2018-04-06 骆苏君 一种改性聚乙烯及其加工工艺
CN107987363A (zh) * 2017-12-26 2018-05-04 骆苏君 一种聚乙烯及其制备方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109427A (zh) * 1985-01-02 1986-07-23 诺贝尔炸药公司 导电聚乙烯泡沫
CN101495561A (zh) * 2006-08-02 2009-07-29 超科有限公司 可光致交联的聚烯烃组合物
CN102206358A (zh) * 2011-04-06 2011-10-05 东莞市鸿捷环保科技有限公司 一种挤出物理发泡聚乙烯开孔发泡球的制备方法
US20110272620A1 (en) * 2008-05-16 2011-11-10 Saudi Basic Industries Corporation Physically Blown Polyethylene Foam
CN102276893A (zh) * 2011-05-25 2011-12-14 厦门三德信电子科技有限公司 一种高性能发泡聚乙烯板材及其制备方法
CN102807700A (zh) * 2012-07-27 2012-12-05 苏州市兴吴工程塑胶有限公司 一种发泡聚乙烯塑料的配方
CN103408830A (zh) * 2013-07-08 2013-11-27 陈志冲 一种具有隔音作用的板材

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85109427A (zh) * 1985-01-02 1986-07-23 诺贝尔炸药公司 导电聚乙烯泡沫
CN101495561A (zh) * 2006-08-02 2009-07-29 超科有限公司 可光致交联的聚烯烃组合物
US20110272620A1 (en) * 2008-05-16 2011-11-10 Saudi Basic Industries Corporation Physically Blown Polyethylene Foam
CN102206358A (zh) * 2011-04-06 2011-10-05 东莞市鸿捷环保科技有限公司 一种挤出物理发泡聚乙烯开孔发泡球的制备方法
CN102276893A (zh) * 2011-05-25 2011-12-14 厦门三德信电子科技有限公司 一种高性能发泡聚乙烯板材及其制备方法
CN102807700A (zh) * 2012-07-27 2012-12-05 苏州市兴吴工程塑胶有限公司 一种发泡聚乙烯塑料的配方
CN103408830A (zh) * 2013-07-08 2013-11-27 陈志冲 一种具有隔音作用的板材

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
殷锦捷等: "PE/EVA共混改性材料力学性能的研究", 《上海塑料》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105237877A (zh) * 2015-10-26 2016-01-13 陈鹤忠 高分子纳米户外用防滑板及其制备方法
CN105237877B (zh) * 2015-10-26 2018-07-31 陈鹤忠 高分子纳米户外用防滑板及其制备方法
CN105542282A (zh) * 2016-01-26 2016-05-04 苏州羽帆新材料科技有限公司 一种保温抗冲击环保材料及其制备方法
CN106566050A (zh) * 2016-10-31 2017-04-19 江苏昊晟塑业科技有限公司 用于汽车内饰的发泡材料
CN107880368A (zh) * 2017-12-26 2018-04-06 骆苏君 一种改性聚乙烯及其加工工艺
CN107987363A (zh) * 2017-12-26 2018-05-04 骆苏君 一种聚乙烯及其制备方法

Similar Documents

Publication Publication Date Title
CN103910923A (zh) 改性发泡聚乙烯
WO2013101767A3 (en) Biomodal high-density polyethylene resins and compositions with improved properties and methods of making and using the same
WO2015069380A3 (en) Mineral reinforced thermoplastic polymer compositions with improved properties
CN103333392A (zh) 一种天然抗菌珍珠棉
CN103740065B (zh) 一种薄膜开关用pet树脂组合物及其制备方法
CN102850702A (zh) 一种改性聚四氟乙烯的配方
CN104844938A (zh) 一种耐高温环保水杯及其制备方法
CN103360667A (zh) 高强度轻质防火铝塑板用无卤阻燃高分子芯层材料及其制备方法
CN102807700A (zh) 一种发泡聚乙烯塑料的配方
CN102532720A (zh) 一种微发泡聚丙烯复合材料及其制备方法
CN105367938A (zh) 一种新型pvc环保发泡板材
CN103305003A (zh) 一种改性聚苯硫醚塑料的配方
CN103360710A (zh) 超高冲击聚苯乙烯的配方
CN103740047A (zh) 超钢聚甲醛塑料
CN103232646A (zh) 一种聚苯乙烯塑料板
CN105440503A (zh) 一种阻燃pvc防水卷材
CN105585790A (zh) 用于衣柜的木塑复合板配方
CN104072907A (zh) 一种用于耐磨室内地板的pvc型材及其生产方法
CN103254529A (zh) 阻燃改性pvc材料及其制备方法
CN104327785A (zh) 一种阻燃聚氨酯密封胶
CN103497400B (zh) 一种聚乙烯泡棉胶带基材
CN104163982A (zh) 一种环保发泡聚丙烯材料及其制备方法
CN102898740B (zh) 聚氯乙烯防水卷材
CN104387674A (zh) 一种可阻燃抗老化泡沫材料
CN204326445U (zh) 玄武岩发泡防水、防火地板

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C12 Rejection of a patent application after its publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20140709