CN103898552B - 一种金刚石合成提纯快速电解液 - Google Patents
一种金刚石合成提纯快速电解液 Download PDFInfo
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- CN103898552B CN103898552B CN201410129827.2A CN201410129827A CN103898552B CN 103898552 B CN103898552 B CN 103898552B CN 201410129827 A CN201410129827 A CN 201410129827A CN 103898552 B CN103898552 B CN 103898552B
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- Prior art keywords
- diamond
- electrolysis
- manganese
- cobalt
- nickel
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- 238000005868 electrolysis reaction Methods 0.000 title claims abstract description 20
- 229910003460 diamond Inorganic materials 0.000 title claims abstract description 10
- 239000010432 diamond Substances 0.000 title claims abstract description 10
- 239000007788 liquid Substances 0.000 title claims abstract description 9
- 238000000746 purification Methods 0.000 title claims abstract description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 19
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 10
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 9
- 239000010941 cobalt Substances 0.000 claims abstract description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004411 aluminium Substances 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000010949 copper Substances 0.000 claims abstract description 8
- 229910052802 copper Inorganic materials 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 6
- 239000011572 manganese Substances 0.000 claims abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003792 electrolyte Substances 0.000 claims abstract description 5
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 239000011777 magnesium Substances 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 4
- 239000010703 silicon Substances 0.000 claims abstract description 4
- 239000012452 mother liquor Substances 0.000 claims abstract description 3
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 claims description 3
- 235000013923 monosodium glutamate Nutrition 0.000 claims description 3
- 239000004223 monosodium glutamate Substances 0.000 claims description 3
- 230000007062 hydrolysis Effects 0.000 claims description 2
- 238000006460 hydrolysis reaction Methods 0.000 claims description 2
- 230000007812 deficiency Effects 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 229910001437 manganese ion Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
本发明公开了一种金刚石合成提纯快速电解液，所述的以盐酸体系为电解母液的电解液配方其中铁、镍、钴、锰、铜、铝组成重量百分比，为铁42％、镍49.46％、钴0.07％、锰0.02％、铜0.16％、铝0.3％，硅0.01％、镁0.01％余下为杂质。本发明克服了现有技术的不足，配方设计合理，电解时间较短、金属产物比例高，降低电解成本。
Description
技术领域
本发明涉及金刚石生产电解技术领域，具体属于一种金刚石合成提纯快速电解液。
背景技术
触媒(镍75％锰25％钴5％)合成的金刚石棒料在电溶解时,Ni、Mn、Co分别以离子形式进入电解液。锰离子以氧化物的型式在阳极沉积或以单质锰沉淀在电解槽内,导致阳极导电性能下降,电流效率降低。为消除这些阳极(钛篮)上面的氧化锰,要消耗大量的人力去敲打,用硫酸等化工作。现有技术电解时间较长，成本较高。
发明内容
本发明的目的是提供了一种金刚石合成提纯快速电解液，克服了现有技术的不足，配方设计合理，电解时间较短、金属产物比例高，降低电解成本。
本发明采用的技术方案如下：
一种金刚石合成提纯快速电解液，所述的以盐酸体系为电解母液的电解液配方其中铁、镍、钴、锰、铜、铝组成重量百分比，为铁42％、镍49.46％、钴0.07％、锰0.02％、铜0.16％、铝0.3％，硅0.01％、镁0.01％余下为杂质。
所述的配方中加有味精。
与已有技术相比，本发明的有益效果如下：
本发明电解时间较短、金属产物比例高，降低电解成本。
具体实施方式
一种金刚石合成提纯快速电解液，配方中加有味精，所述的以盐酸体系为电解母液的电解液配方其中铁、镍、钴、锰、铜、铝组成重量百分比，为铁42％、镍49.46％、钴0.07％、锰0.02％、铜0.16％、铝0.3％，硅0.01％、镁0.01％余下为杂质，电解时间较短、金属产物比例高，降低电解成本。
Claims (2)
1.一种金刚石合成提纯快速电解液，其特征在于：所述的以盐酸体系为电解母液的电解液配方其中铁、镍、钴、锰、铜、铝组成重量百分比，为铁42％、镍49.46％、钴0.07％、锰0.02％、铜0.16％、铝0.3％，硅0.01％、镁0.01％余下为杂质。
2.根据权利要求1所述的一种金刚石合成提纯快速电解液，其特征在于：所述的配方中加有味精。
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| CN201410129827.2A CN103898552B (zh) | 2014-04-01 | 2014-04-01 | 一种金刚石合成提纯快速电解液 |
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| CN201410129827.2A CN103898552B (zh) | 2014-04-01 | 2014-04-01 | 一种金刚石合成提纯快速电解液 |
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| Publication Number | Publication Date |
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| CN103898552A CN103898552A (zh) | 2014-07-02 |
| CN103898552B true CN103898552B (zh) | 2016-05-04 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105905892A (zh) * | 2016-06-13 | 2016-08-31 | 安庆市凯立金刚石科技有限公司 | 一种人造金刚石高效提纯电解液 |
| CN106145105A (zh) * | 2016-06-13 | 2016-11-23 | 安庆市凯立金刚石科技有限公司 | 一种金刚石提纯电解液 |
| CN108048914B (zh) * | 2017-12-08 | 2023-11-07 | 郑州人造金刚石及制品工程技术研究中心有限公司 | 一种电解提纯金刚石大单晶合成块的方法 |
| CN112410823A (zh) * | 2020-11-12 | 2021-02-26 | 湖北汇锋钻石有限公司 | 一种金刚石生产电解用电解液 |
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| CN103320845B (zh) * | 2013-07-16 | 2016-03-16 | 安庆市凯立金刚石科技有限公司 | 一种金刚石生产电解用电解液 |
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Effective date of registration: 20190326 Address after: 415301 the three group of Zhu Yuen TA neighborhood committee, two Du Township, Shimenn County, Changde, Hunan Patentee after: Shimenn County Shun Chao Technology Development Co., Ltd. Address before: 246100 Huaining County Industrial Park, Anqing City, Anhui Province Patentee before: Anqing Kaili Technology Co., Ltd. |
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Granted publication date: 20160504 Termination date: 20190401 |