CN103892746B - A kind of three layers of Antiskid shower pad - Google Patents
A kind of three layers of Antiskid shower pad Download PDFInfo
- Publication number
- CN103892746B CN103892746B CN201410141962.9A CN201410141962A CN103892746B CN 103892746 B CN103892746 B CN 103892746B CN 201410141962 A CN201410141962 A CN 201410141962A CN 103892746 B CN103892746 B CN 103892746B
- Authority
- CN
- China
- Prior art keywords
- parts
- fiber mesh
- add
- polyoxyethylene
- mesh cloth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to bath mat technical field, particularly relate to a kind of three layers of Antiskid shower pad, described Antiskid shower pad is provided with top layer, supporting layer and bottom three-decker, supporting layer is arranged between top layer and bottom, the bottom of bottom is fixed with multiple sucker, the outside of Antiskid shower pad is sewed with bound edge, and top layer and bottom are fiber mesh cloth, and supporting layer is fish screen cloth.Three layers of Antiskid shower pad of the present invention adopt fiber mesh cloth, fish screen cloth and fiber mesh cloth three layers to be composited, and leak effective, water can not be trapped on bath mat, safe anti-slipping; And fiber mesh cloth and fish screen cloth all have elasticity, sole of comprehensively fitting, silk is sliding submissive, affine comfortable.
Description
Technical field
The present invention relates to bath mat technical field, particularly relate to a kind of three layers of Antiskid shower pad.
Background technology
Present bathroom is mostly be paved into by ceramic tile, is easy to slip when having a bath, and therefore bath mat becomes is one of requisite articles for use in bathroom, and bath mat is used widely.
Application number be 03229556.1 Chinese invention disclose one way of life skid-proof health care bathroom mat, connect bar by reverse side and bond by several piece rectangular bars is parallel and form, in the middle of every bar, leaves hydrophobic gap.There is granular boss in bath mat front, plays health care massage effect, and reverse side is nonslipping spur.
Application number be 200320122296.1 Chinese invention disclose a kind of composite anti-slip bathing cushion, comprise slipmat, the some composite sheet of upper Planar Compound of described slipmat, the composite contact of its slipmat and composite sheet surface coating viscosity glue compound.Its composite sheet can be bamboo chip, also can be wood chip.Its composite sheet can be long strip shape, also can be box-shaped, also can be rhombus, also can be circular.The surrounding of the composite anti-slip bathing cushion described in it is with wrapped belt.
Existing PVC bath mat effect of leaking is bad, and hydropexis, on PVC bath mat, is easy to slip, and safety coefficient is not high yet, and in use procedure, comfort is also poor.Therefore, be necessary that research and development are a kind of leak effective and use comfortable bath mat.
Summary of the invention
The object of the invention is to provide a kind of for the deficiencies in the prior art leak effective and use three layers of comfortable Antiskid shower pad.
To achieve these goals, the present invention adopts following technical scheme: a kind of three layers of Antiskid shower pad, described Antiskid shower pad is provided with top layer, supporting layer and bottom three-decker, supporting layer is arranged between top layer and bottom, the bottom of bottom is fixed with multiple sucker, the outside of Antiskid shower pad is sewed with bound edge, and top layer and bottom are fiber mesh cloth, and supporting layer is fish screen cloth.
The present invention adopts glue or factice recombining process by fiber mesh cloth, fish screen cloth and fiber mesh cloth compound, after carrying out compound to trilaminate material, size on demand cuts, the knitting edge-covering cloth of bath mat surrounding carries out bound edge, to reach the effect of Comfortable attractive.
Three layers of Antiskid shower pad of the present invention adopt fiber mesh cloth, fish screen cloth and fiber mesh cloth three layers to be composited, and leak effective, water can not be trapped on bath mat, safe anti-slipping; And fiber mesh cloth and fish screen cloth all have elasticity, sole of comprehensively fitting, silk is sliding submissive, affine comfortable.
Preferably, the thickness of described fiber mesh cloth is 1 ~ 3mm, and the thickness of described fish screen cloth is 6 ~ 10mm.The thickness of three layers of Antiskid shower pad of the present invention is 8 ~ 16mm, and bath mat should not be too thick, and too thick cost is high, and comfort level is not good enough, also should not be too thin, and too thin meeting causes bath mat elasticity little.
Preferably, described fiber mesh cloth is provided with skin, interlayer and internal layer three-decker, interlayer is arranged between skin and internal layer, outer and internal layer forms through compiling by polyester monofilament, thickness that is outer and internal layer is 0.1 ~ 0.3mm, interlayer is made into by nylon monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness of interlayer is 0.8 ~ 2.4mm, and skin, interlayer and internal layer one is through weaving into fiber mesh cloth.
Fiber mesh cloth of the present invention by outer, interlayer and internal layer one through weaving into fiber mesh cloth, outer and internal layer forms through compiling by polyester monofilament, and interlayer is made into by nylon monofilament, the fiber mesh cloth soft comfortable of braiding, water-retaining capacity is strong, dirtyly can wash by direct clear water.
Preferably, fiber mesh cloth after described braiding adopts dipping solution to process, described dipping solution is made up of the raw material of following weight part: butyl acrylate 12 ~ 18 parts, Isooctyl acrylate monomer 8 ~ 12 parts, vinyl acetate 20 ~ 30 parts, 1.5 ~ 2 parts, vinylformic acid, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.3 ~ 0.5 part, alkylphenol polyoxyethylene 0.1 ~ 0.3 part, deionized water 45 ~ 50 parts, antimonous oxide 3.2 ~ 3.6 parts, n-methylolacrylamide 3.0 ~ 3.5 parts, 0.03 ~ 0.05 part, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate 0.01 ~ 0.02 part, Sodium phosphate dibasic 0.12 ~ 0.24 part, ammonium persulphate 0.04 ~ 0.08 part.
Dipping solution of the present invention selects butyl acrylate and Isooctyl acrylate monomer as soft monomer, vinyl acetate is as hard monomer, vinylformic acid is as function monomer, when the ratio of soft or hard monomer is 20 ~ 30 parts: 30 ~ 20 parts, condensation product in polymerization process is less, the dipping solution obtained is fine and smooth, and strength of glass is maximum.
Dipping solution of the present invention selects the vinylformic acid with double-functional group as function monomer, linear copolymer is cross-linked, improve cohesive strength, simultaneously, along with the increase of vinylformic acid consumption, the water-absorbent of glued membrane also increases, and when vinylformic acid consumption is 1.5 ~ 2 parts, obtained dipping solution over-all properties is best.
Alkyl phenol ether sulfo-succinic acid ester sodium salt, commodity are called emulsifier os (MS-1), are anion surfactant, have good emulsifying, dispersiveness, wettability, suspension, soil release performance and foaminess.
Alkylphenol polyoxyethylene, commodity are called emulsifier op-10, are nonionogenic tensides, as textile auxiliary, play emulsifying effect.
Polyoxyethylene nonylphenol ether ammonium sulfate, commodity are called emulsifying agent CO-436, and wetting, the dispersion had, emulsifying capacity, can also as the wetting agent of fabric treating.
Sodium lauryl sulphate (SDS) is a kind of anion surfactant, has good emulsifying, dispersion, level dyeing, wetting, antistatic property.
Sodium phosphate dibasic and ammonium persulphate are as initiator, and antimonous oxide is as pH adjusting agent, and deionized water is solvent.
Dipping solution of the present invention adopts butyl acrylate and Isooctyl acrylate monomer as soft monomer, vinyl acetate is as hard monomer, vinylformic acid is as function monomer, alkyl phenol ether sulfo-succinic acid ester sodium salt, alkylphenol polyoxyethylene, polyoxyethylene nonylphenol ether ammonium sulfate and sodium lauryl sulphate are as emulsifying agent, Sodium phosphate dibasic and ammonium persulphate are as initiator, use the fiber mesh cloth snappiness after dipping solution process good, adhesive is little, good flame retardation effect.
Preferably, the preparation method of described dipping solution comprises the steps:
A, in pre-emulsification still, add portions of de-ionized water, stir, under whipped state, add alkylphenol polyoxyethylene and part alkyl phenol ether sulfo-succinic acid ester sodium salt;
B, under whipped state, vinylformic acid and antimonous oxide are added pre-emulsification still;
C, by butyl acrylate, Isooctyl acrylate monomer and vinyl acetate mix after, under whipped state, add pre-emulsification still, add rear continuation stirring 15 ~ 30min, obtain pre-emulsion;
D, in reactor, add remaining deionized water, be warming up to 50 ~ 55 DEG C, stir;
E, n-methylolacrylamide, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate are added in reactor, then add remaining alkyl phenol ether sulfo-succinic acid ester sodium salt, and add the above-mentioned pre-emulsion of part, stir and be warming up to 70 ~ 75 DEG C;
F, under whipped state, add part Sodium phosphate dibasic and part ammonium persulphate, continue to be warming up to 80 ~ 85 DEG C, slowly drip remaining above-mentioned pre-emulsion;
G, under whipped state, add remaining ammonium persulphate and remaining Sodium phosphate dibasic, added once every 15 minutes, after adding, be warming up to 85 ~ 90 DEG C, continue stir and be incubated 20 ~ 40min, then be cooled to less than 60 DEG C, discharging, obtain dipping solution.
Preparation method's step of dipping solution of the present invention is simple, good operability; Adopt butyl acrylate, Isooctyl acrylate monomer, vinyl acetate and vinylformic acid to be polymerized, the stable dipping solution for fiber mesh cloth can be obtained, particularly antimonous oxide is added dipping solution obtained in pre-emulsion and there is better flame retardant effect.The dipping solution that the present invention obtains can make that the fiber mesh cloth snappiness after coating is good, adhesion, and good flame resistance, Alkali resistivity are high, can widely use at field of textiles.
Preferably, the fiber mesh cloth after described dipping solution process is dried and expanding process through first time oven dry, second time successively, and the temperature that first time dries is 80 ~ 100 DEG C, time is 2 ~ 5min, second time bake out temperature is 100 ~ 120 DEG C, and the time is 1 ~ 3min, is 8 ~ 12% through broadwise expanding rate.
Fiber mesh cloth of the present invention is owing to adopting twice oven dry, and bake out temperature gradient increases, and is conducive to the surperficial physical and chemical reaction of fiber mesh cloth, and production efficiency is improved greatly; Because the fiber mesh cloth after drying has carried out expanding process after the heating, the yarn of fiber mesh cloth can be made to define certain prestress, made fiber mesh cloth more smooth simultaneously.
Preferably, described fish screen cloth is provided with upper strata, middle level and lower floor's three-decker, middle level is arranged between the upper and lower, the upper and lower form through compiling by polypropylene filament, the thickness of the upper and lower is 0.2 ~ 0.8mm, middle level is made into by spandex monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness in middle level is 5.6 ~ 8.4mm, and the upper, middle and lower one is through weaving into fish screen cloth.
Fish screen cloth of the present invention is by the upper, middle and lower one through weaving into fiber mesh cloth, and the upper and lower form through compiling by polypropylene filament, and middle level is made into by spandex monofilament, the fish screen cloth soft comfortable of braiding, elasticity is better, and water-retaining capacity is strong, dirtyly can wash by direct clear water.
Preferably, through oil for polypropylene fibre process before described polypropylene filament braiding, described oil for polypropylene fibre is made up of the raw material of following weight part: 50 ~ 70 parts, mineral oil, polyoxyethylene iso stearyl ether phosphate sylvite 1 ~ 5 part, ethoxylated dodecyl alcohol phosphoric acid ester 2 ~ 6 parts, polyoxyethylene nonylphenol ether 3 ~ 7 parts, stearyl alcohol phosphate kalium salt 4 ~ 8 parts, polyoxyethylene glycol bilaurate 6 ~ 10 parts, 3 ~ 5 parts, vinylformic acid; Above-mentioned raw materials makes oil for polypropylene fibre through mix and blend by weight.
Oil for polypropylene fibre of the present invention adopts mineral oil to be smooth agent, polyoxyethylene iso stearyl ether phosphate sylvite, ethoxylated dodecyl alcohol phosphoric acid ester and polyoxyethylene nonylphenol ether are as emulsifying agent, stearyl alcohol phosphate kalium salt is as static inhibitor, polyoxyethylene glycol bilaurate is as collecting agent, and vinylformic acid is as additive; Obtained oil for polypropylene fibre has excellent emulsion's stability, antistatic property and smoothness, and has large oil film strength.
Preferably, through spandex oil agent process before described spandex monofilament braiding, described spandex oil agent is made up of the raw material of following weight part: Ethylhexyl stearate 40 ~ 80 parts, fatty alcohol ethylene oxide propylene oxide copolyether 5 ~ 7 parts, alkylphenol polyoxyethylene 6 ~ 8 parts, hydrogenated castor oil Soxylat A 25-7 5 ~ 7 parts, aliphatic acid polyethenoxy methyl ether 8 ~ 15 parts, potassium alkyl phosphate 1 ~ 3 part, Dodecyl Polyoxyethylene Ether phosphate kalium salt 1 ~ 3 part; Above-mentioned raw materials makes spandex oil agent through mix and blend by weight.
Spandex monofilament of the present invention adopts Ethylhexyl stearate as smooth agent, fatty alcohol ethylene oxide propylene oxide copolyether, alkylphenol polyoxyethylene and hydrogenated castor oil Soxylat A 25-7 are as emulsifying agent, potassium alkyl phosphate and Dodecyl Polyoxyethylene Ether phosphate kalium salt are as static inhibitor, and aliphatic acid polyethenoxy methyl ether is as collecting agent; It is good that obtained spandex oil agent has antistatic effect, and use rear spinning property better, the strength loss after precursor twisted weave is little; And stable performance, easy to use, there is good consistency with water.
Preferably, described sucker is made up of the raw material of following weight part: natural rubber 50 ~ 70 parts, polyisoprene rubber 10 ~ 20 parts, terpolymer EP rubber 5 ~ 10 parts, 3 ~ 5 parts, zinc oxide, stearic acid 1 ~ 2 part, polyoxyethylene glycol 1 ~ 2 part, talcum powder 20 ~ 30 parts, naphthenic oil 20 ~ 25 parts, 2-thiol group benzimidazolyl 1.5 ~ 2.5 parts, zinc dibutyl dithiocarbamate 0.1 ~ 0.5 part; Above-mentioned raw materials makes sucker through mixing, shaping by weight.The preparation method of described sucker is the method for preparing rubber that this area is commonly used, and by raw material through mixing, shaping obtained, preparation method does not belong to protection scope of the present invention.
The present invention adopts the raw material such as combination, anti-aging agent 2-thiol group benzimidazolyl, accelerant zinc dibutyl dithiocaarbamate of several different rubber, and obtained sucker quality is soft, smooth surface is smooth, adsorptive power good.
Beneficial effect of the present invention is: the present invention adopts glue or factice recombining process by fiber mesh cloth, fish screen cloth and fiber mesh cloth compound, after carrying out compound to trilaminate material, size on demand cuts, the knitting edge-covering cloth of bath mat surrounding carries out bound edge, to reach the effect of Comfortable attractive.
Three layers of Antiskid shower pad of the present invention adopt fiber mesh cloth, fish screen cloth and fiber mesh cloth three layers to be composited, and leak effective, water can not be trapped on bath mat, safe anti-slipping; And fiber mesh cloth and fish screen cloth all have elasticity, sole of comprehensively fitting, silk is sliding submissive, affine comfortable.
accompanying drawing illustrates:
Fig. 1 is sectional view of the present invention.
Fig. 2 is the perspective view of fiber mesh cloth of the present invention.
Fig. 3 is the perspective view of fish screen cloth of the present invention.
Reference numeral is: 1-top layer, 11-skin, 12-interlayer, 13-internal layer, 2-supporting layer, 21-upper strata, 22-middle level, 23-lower floor, 3-bottom, 4-sucker, 5-bound edge.
embodiment:
For the ease of the understanding of those skilled in the art, below in conjunction with embodiment and accompanying drawing 1 ~ 3, the present invention is further illustrated, and the content that embodiment is mentioned not is limitation of the invention.
Embodiment 1
See Fig. 1 ~ 3, a kind of three layers of Antiskid shower pad, described Antiskid shower pad is provided with top layer 1, supporting layer 2 and bottom 3 three-decker, supporting layer 2 is arranged between top layer 1 and bottom 3, the bottom of bottom 3 is fixed with multiple sucker 4, the outside of Antiskid shower pad is sewed with bound edge 5, and top layer 1 and bottom 3 are fiber mesh cloth, and supporting layer 2 is fish screen cloth.
In the present embodiment, the thickness of described fiber mesh cloth is 1mm, and the thickness of described fish screen cloth is 6mm.
In the present embodiment, described fiber mesh cloth is provided with skin 11, interlayer 12 and internal layer 13 three-decker, interlayer 12 is arranged between outer 11 and internal layer 13, skin 11 and internal layer 13 form through compiling by polyester monofilament, the thickness of skin 11 and internal layer 13 is 0.1mm, interlayer 12 is made into by nylon monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness of interlayer 12 is 0.8mm, and skin 11, interlayer 12 and internal layer 13 one is through weaving into fiber mesh cloth.
In the present embodiment, fiber mesh cloth after described braiding adopts dipping solution to process, and described dipping solution is made up of the raw material of following weight part: butyl acrylate 12 parts, Isooctyl acrylate monomer 8 parts, vinyl acetate 20 parts, 1.5 parts, vinylformic acid, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.3 part, alkylphenol polyoxyethylene 0.1 part, deionized water 45 parts, antimonous oxide 3.2 parts, n-methylolacrylamide 3.0 parts, 0.03 part, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate 0.01 part, Sodium phosphate dibasic 0.12 part, ammonium persulphate 0.04 part.
In the present embodiment, the preparation method of described dipping solution comprises the steps:
A, in pre-emulsification still, add portions of de-ionized water, stir, under whipped state, add alkylphenol polyoxyethylene and part alkyl phenol ether sulfo-succinic acid ester sodium salt;
B, under whipped state, vinylformic acid and antimonous oxide are added pre-emulsification still;
C, by butyl acrylate, Isooctyl acrylate monomer and vinyl acetate mix after, under whipped state, add pre-emulsification still, add rear continuations stirring 15min, obtain pre-emulsion;
D, in reactor, add remaining deionized water, be warming up to 50 DEG C, stir;
E, n-methylolacrylamide, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate are added in reactor, then add remaining alkyl phenol ether sulfo-succinic acid ester sodium salt, and add the above-mentioned pre-emulsion of part, stir and be warming up to 70 DEG C;
F, under whipped state, add part Sodium phosphate dibasic and part ammonium persulphate, continue to be warming up to 80 DEG C, slowly drip remaining above-mentioned pre-emulsion;
G, under whipped state, add remaining ammonium persulphate and remaining Sodium phosphate dibasic, added once every 15 minutes, after adding, be warming up to 85 DEG C, continue stir and be incubated 20min, then be cooled to 55 DEG C, discharging, obtain dipping solution.
In the present embodiment, the fiber mesh cloth after described dipping solution process is dried and expanding process through first time oven dry, second time successively, and the temperature that first time dries is 80 DEG C, time is 2min, second time bake out temperature is 100 DEG C, and the time is 1min, is 8% through broadwise expanding rate.
In the present embodiment, described fish screen cloth is provided with upper strata 21, middle level 22 and lower floor 23 three-decker, middle level 22 is arranged between upper strata 21 and lower floor 23, upper strata 21 and lower floor 23 form through compiling by polypropylene filament, the thickness of upper strata 21 and lower floor 23 is 0.2mm, middle level 22 is made into by spandex monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness in middle level 22 is 5.6mm, and upper strata 21, middle level 22 and lower floor 23 one are through weaving into fish screen cloth.
In the present embodiment, through oil for polypropylene fibre process before described polypropylene filament braiding, described oil for polypropylene fibre is made up of the raw material of following weight part: 50 parts, mineral oil, polyoxyethylene iso stearyl ether phosphate sylvite 1 part, ethoxylated dodecyl alcohol phosphoric acid ester 2 parts, polyoxyethylene nonylphenol ether 3 parts, stearyl alcohol phosphate kalium salt 4 parts, polyoxyethylene glycol bilaurate 6 parts, 3 parts, vinylformic acid; Above-mentioned raw materials makes oil for polypropylene fibre through mix and blend by weight.
In the present embodiment, through spandex oil agent process before described spandex monofilament braiding, described spandex oil agent is made up of the raw material of following weight part: Ethylhexyl stearate 40 parts, fatty alcohol ethylene oxide propylene oxide copolyether 5 parts, alkylphenol polyoxyethylene 6 parts, hydrogenated castor oil Soxylat A 25-7 5 parts, aliphatic acid polyethenoxy methyl ether 8 parts, potassium alkyl phosphate 1 part, Dodecyl Polyoxyethylene Ether phosphate kalium salt 1 part; Above-mentioned raw materials makes spandex oil agent through mix and blend by weight.
In the present embodiment, described sucker 4 is made up of the raw material of following weight part: natural rubber 50 parts, polyisoprene rubber 10 parts, terpolymer EP rubber 5 parts, 3 parts, zinc oxide, stearic acid 1 part, polyoxyethylene glycol 1 part, talcum powder 20 parts, naphthenic oil 20 parts, 2-thiol group benzimidazolyl 1.5 parts, zinc dibutyl dithiocarbamate 0.1 part; Above-mentioned raw materials makes sucker through mixing, shaping by weight.
Embodiment 2
The difference of the present embodiment and above-described embodiment 1 is: the thickness of described fiber mesh cloth is 2mm, and the thickness of described fish screen cloth is 7mm.
In the present embodiment, described fiber mesh cloth is provided with skin 11, interlayer 12 and internal layer 13 three-decker, interlayer 12 is arranged between outer 11 and internal layer 13, skin 11 and internal layer 13 form through compiling by polyester monofilament, the thickness of skin 11 and internal layer 13 is 0.2mm, interlayer 12 is made into by nylon monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness of interlayer 12 is 1.6mm, and skin 11, interlayer 12 and internal layer 13 one is through weaving into fiber mesh cloth.
In the present embodiment, fiber mesh cloth after described braiding adopts dipping solution to process, and described dipping solution is made up of the raw material of following weight part: butyl acrylate 14 parts, Isooctyl acrylate monomer 9 parts, vinyl acetate 22 parts, 1.6 parts, vinylformic acid, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.4 part, alkylphenol polyoxyethylene 0.1 part, deionized water 46 parts, antimonous oxide 3.3 parts, n-methylolacrylamide 3.1 parts, 0.04 part, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate 0.02 part, Sodium phosphate dibasic 0.15 part, ammonium persulphate 0.05 part.
In the present embodiment, the preparation method of described dipping solution comprises the steps:
A, in pre-emulsification still, add portions of de-ionized water, stir, under whipped state, add alkylphenol polyoxyethylene and part alkyl phenol ether sulfo-succinic acid ester sodium salt;
B, under whipped state, vinylformic acid and antimonous oxide are added pre-emulsification still;
C, by butyl acrylate, Isooctyl acrylate monomer and vinyl acetate mix after, under whipped state, add pre-emulsification still, add rear continuations stirring 18min, obtain pre-emulsion;
D, in reactor, add remaining deionized water, be warming up to 51 DEG C, stir;
E, n-methylolacrylamide, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate are added in reactor, then add remaining alkyl phenol ether sulfo-succinic acid ester sodium salt, and add the above-mentioned pre-emulsion of part, stir and be warming up to 71 DEG C;
F, under whipped state, add part Sodium phosphate dibasic and part ammonium persulphate, continue to be warming up to 81 DEG C, slowly drip remaining above-mentioned pre-emulsion;
G, under whipped state, add remaining ammonium persulphate and remaining Sodium phosphate dibasic, added once every 15 minutes, after adding, be warming up to 86 DEG C, continue stir and be incubated 25min, then be cooled to 50 DEG C, discharging, obtain dipping solution.
In the present embodiment, the fiber mesh cloth after described dipping solution process is dried and expanding process through first time oven dry, second time successively, and the temperature that first time dries is 85 DEG C, time is 3min, second time bake out temperature is 105 DEG C, and the time is 2min, is 9% through broadwise expanding rate.
In the present embodiment, described fish screen cloth is provided with upper strata 21, middle level 22 and lower floor 23 three-decker, middle level 22 is arranged between upper strata 21 and lower floor 23, upper strata 21 and lower floor 23 form through compiling by polypropylene filament, the thickness of upper strata 21 and lower floor 23 is 0.4mm, middle level 22 is made into by spandex monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness in middle level 22 is 6.2mm, and upper strata 21, middle level 22 and lower floor 23 one are through weaving into fish screen cloth.
In the present embodiment, through oil for polypropylene fibre process before described polypropylene filament braiding, described oil for polypropylene fibre is made up of the raw material of following weight part: 55 parts, mineral oil, polyoxyethylene iso stearyl ether phosphate sylvite 2 parts, ethoxylated dodecyl alcohol phosphoric acid ester 3 parts, polyoxyethylene nonylphenol ether 4 parts, stearyl alcohol phosphate kalium salt 5 parts, polyoxyethylene glycol bilaurate 7 parts, 4 parts, vinylformic acid; Above-mentioned raw materials makes oil for polypropylene fibre through mix and blend by weight.
In the present embodiment, through spandex oil agent process before described spandex monofilament braiding, described spandex oil agent is made up of the raw material of following weight part: Ethylhexyl stearate 50 parts, fatty alcohol ethylene oxide propylene oxide copolyether 6 parts, alkylphenol polyoxyethylene 7 parts, hydrogenated castor oil Soxylat A 25-7 6 parts, aliphatic acid polyethenoxy methyl ether 10 parts, potassium alkyl phosphate 2 parts, Dodecyl Polyoxyethylene Ether phosphate kalium salt 2 parts; Above-mentioned raw materials makes spandex oil agent through mix and blend by weight.
In the present embodiment, described sucker 4 is made up of the raw material of following weight part: natural rubber 55 parts, polyisoprene rubber 12 parts, terpolymer EP rubber 6 parts, 4 parts, zinc oxide, stearic acid 2 parts, polyoxyethylene glycol 2 parts, talcum powder 22 parts, naphthenic oil 21 parts, 2-thiol group benzimidazolyl 1.8 parts, zinc dibutyl dithiocarbamate 0.2 part; Above-mentioned raw materials makes sucker through mixing, shaping by weight.
Embodiment 3
The difference of the present embodiment and above-described embodiment 1 is: the thickness of described fiber mesh cloth is 2mm, and the thickness of described fish screen cloth is 8mm.
In the present embodiment, described fiber mesh cloth is provided with skin 11, interlayer 12 and internal layer 13 three-decker, interlayer 12 is arranged between outer 11 and internal layer 13, skin 11 and internal layer 13 form through compiling by polyester monofilament, the thickness of skin 11 and internal layer 13 is 0.2mm, interlayer 12 is made into by nylon monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness of interlayer 12 is 1.6mm, and skin 11, interlayer 12 and internal layer 13 one is through weaving into fiber mesh cloth.
In the present embodiment, fiber mesh cloth after described braiding adopts dipping solution to process, and described dipping solution is made up of the raw material of following weight part: butyl acrylate 15 parts, Isooctyl acrylate monomer 10 parts, vinyl acetate 25 parts, 1.7 parts, vinylformic acid, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.4 part, alkylphenol polyoxyethylene 0.2 part, deionized water 47 parts, antimonous oxide 3.4 parts, n-methylolacrylamide 3.2 parts, 0.05 part, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate 0.01 part, Sodium phosphate dibasic 0.18 part, ammonium persulphate 0.06 part.
In the present embodiment, the preparation method of described dipping solution comprises the steps:
A, in pre-emulsification still, add portions of de-ionized water, stir, under whipped state, add alkylphenol polyoxyethylene and part alkyl phenol ether sulfo-succinic acid ester sodium salt;
B, under whipped state, vinylformic acid and antimonous oxide are added pre-emulsification still;
C, by butyl acrylate, Isooctyl acrylate monomer and vinyl acetate mix after, under whipped state, add pre-emulsification still, add rear continuations stirring 22min, obtain pre-emulsion;
D, in reactor, add remaining deionized water, be warming up to 52 DEG C, stir;
E, n-methylolacrylamide, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate are added in reactor, then add remaining alkyl phenol ether sulfo-succinic acid ester sodium salt, and add the above-mentioned pre-emulsion of part, stir and be warming up to 72 DEG C;
F, under whipped state, add part Sodium phosphate dibasic and part ammonium persulphate, continue to be warming up to 82 DEG C, slowly drip remaining above-mentioned pre-emulsion;
G, under whipped state, add remaining ammonium persulphate and remaining Sodium phosphate dibasic, added once every 15 minutes, after adding, be warming up to 87 DEG C, continue stir and be incubated 30min, then be cooled to 45 DEG C, discharging, obtain dipping solution.
In the present embodiment, the fiber mesh cloth after described dipping solution process is dried and expanding process through first time oven dry, second time successively, and the temperature that first time dries is 90 DEG C, time is 3min, second time bake out temperature is 110 DEG C, and the time is 3min, is 10% through broadwise expanding rate.
In the present embodiment, described fish screen cloth is provided with upper strata 21, middle level 22 and lower floor 23 three-decker, middle level 22 is arranged between upper strata 21 and lower floor 23, upper strata 21 and lower floor 23 form through compiling by polypropylene filament, the thickness of upper strata 21 and lower floor 23 is 0.5mm, middle level 22 is made into by spandex monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness in middle level 22 is 7mm, and upper strata 21, middle level 22 and lower floor 23 one are through weaving into fish screen cloth.
In the present embodiment, through oil for polypropylene fibre process before described polypropylene filament braiding, described oil for polypropylene fibre is made up of the raw material of following weight part: 60 parts, mineral oil, polyoxyethylene iso stearyl ether phosphate sylvite 3 parts, ethoxylated dodecyl alcohol phosphoric acid ester 4 parts, polyoxyethylene nonylphenol ether 5 parts, stearyl alcohol phosphate kalium salt 6 parts, polyoxyethylene glycol bilaurate 8 parts, 3 parts, vinylformic acid; Above-mentioned raw materials makes oil for polypropylene fibre through mix and blend by weight.
In the present embodiment, through spandex oil agent process before described spandex monofilament braiding, described spandex oil agent is made up of the raw material of following weight part: Ethylhexyl stearate 60 parts, fatty alcohol ethylene oxide propylene oxide copolyether 5 parts, alkylphenol polyoxyethylene 6 parts, hydrogenated castor oil Soxylat A 25-7 5 parts, aliphatic acid polyethenoxy methyl ether 12 parts, potassium alkyl phosphate 1 part, Dodecyl Polyoxyethylene Ether phosphate kalium salt 3 parts; Above-mentioned raw materials makes spandex oil agent through mix and blend by weight.
In the present embodiment, described sucker 4 is made up of the raw material of following weight part: natural rubber 60 parts, polyisoprene rubber 15 parts, terpolymer EP rubber 7 parts, 3 parts, zinc oxide, stearic acid 1 part, polyoxyethylene glycol 1 part, talcum powder 25 parts, naphthenic oil 22 parts, 2-thiol group benzimidazolyl 2 parts, zinc dibutyl dithiocarbamate 0.3 part; Above-mentioned raw materials makes sucker through mixing, shaping by weight.
Embodiment 4
The difference of the present embodiment and above-described embodiment 1 is: the thickness of described fiber mesh cloth is 3mm, and the thickness of described fish screen cloth is 9mm.
In the present embodiment, described fiber mesh cloth is provided with skin 11, interlayer 12 and internal layer 13 three-decker, interlayer 12 is arranged between outer 11 and internal layer 13, skin 11 and internal layer 13 form through compiling by polyester monofilament, the thickness of skin 11 and internal layer 13 is 0.3mm, interlayer 12 is made into by nylon monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness of interlayer 12 is 2.4mm, and skin 11, interlayer 12 and internal layer 13 one is through weaving into fiber mesh cloth.
In the present embodiment, fiber mesh cloth after described braiding adopts dipping solution to process, and described dipping solution is made up of the raw material of following weight part: butyl acrylate 16 parts, Isooctyl acrylate monomer 11 parts, vinyl acetate 28 parts, 1.8 parts, vinylformic acid, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.5 part, alkylphenol polyoxyethylene 0.2 part, deionized water 48 parts, antimonous oxide 3.5 parts, n-methylolacrylamide 3.3 parts, 0.03 part, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate 0.02 part, Sodium phosphate dibasic 0.21 part, ammonium persulphate 0.07 part.
In the present embodiment, the preparation method of described dipping solution comprises the steps:
A, in pre-emulsification still, add portions of de-ionized water, stir, under whipped state, add alkylphenol polyoxyethylene and part alkyl phenol ether sulfo-succinic acid ester sodium salt;
B, under whipped state, vinylformic acid and antimonous oxide are added pre-emulsification still;
C, by butyl acrylate, Isooctyl acrylate monomer and vinyl acetate mix after, under whipped state, add pre-emulsification still, add rear continuations stirring 25min, obtain pre-emulsion;
D, in reactor, add remaining deionized water, be warming up to 53 DEG C, stir;
E, n-methylolacrylamide, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate are added in reactor, then add remaining alkyl phenol ether sulfo-succinic acid ester sodium salt, and add the above-mentioned pre-emulsion of part, stir and be warming up to 73 DEG C;
F, under whipped state, add part Sodium phosphate dibasic and part ammonium persulphate, continue to be warming up to 83 DEG C, slowly drip remaining above-mentioned pre-emulsion;
G, under whipped state, add remaining ammonium persulphate and remaining Sodium phosphate dibasic, added once every 15 minutes, after adding, be warming up to 88 DEG C, continue stir and be incubated 35min, then be cooled to 40 DEG C, discharging, obtain dipping solution.
In the present embodiment, the fiber mesh cloth after described dipping solution process is dried and expanding process through first time oven dry, second time successively, and the temperature that first time dries is 95 DEG C, time is 4min, second time bake out temperature is 115 DEG C, and the time is 2min, is 11% through broadwise expanding rate.
In the present embodiment, described fish screen cloth is provided with upper strata 21, middle level 22 and lower floor 23 three-decker, middle level 22 is arranged between upper strata 21 and lower floor 23, upper strata 21 and lower floor 23 form through compiling by polypropylene filament, the thickness of upper strata 21 and lower floor 23 is 0.6mm, middle level 22 is made into by spandex monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness in middle level 22 is 7.8mm, and upper strata 21, middle level 22 and lower floor 23 one are through weaving into fish screen cloth.
In the present embodiment, through oil for polypropylene fibre process before described polypropylene filament braiding, described oil for polypropylene fibre is made up of the raw material of following weight part: 65 parts, mineral oil, polyoxyethylene iso stearyl ether phosphate sylvite 4 parts, ethoxylated dodecyl alcohol phosphoric acid ester 5 parts, polyoxyethylene nonylphenol ether 6 parts, stearyl alcohol phosphate kalium salt 7 parts, polyoxyethylene glycol bilaurate 9 parts, 4 parts, vinylformic acid; Above-mentioned raw materials makes oil for polypropylene fibre through mix and blend by weight.
In the present embodiment, through spandex oil agent process before described spandex monofilament braiding, described spandex oil agent is made up of the raw material of following weight part: Ethylhexyl stearate 70 parts, fatty alcohol ethylene oxide propylene oxide copolyether 6 parts, alkylphenol polyoxyethylene 7 parts, hydrogenated castor oil Soxylat A 25-7 6 parts, aliphatic acid polyethenoxy methyl ether 13 parts, potassium alkyl phosphate 2 parts, Dodecyl Polyoxyethylene Ether phosphate kalium salt 2 parts; Above-mentioned raw materials makes spandex oil agent through mix and blend by weight.
In the present embodiment, described sucker 4 is made up of the raw material of following weight part: natural rubber 65 parts, polyisoprene rubber 18 parts, terpolymer EP rubber 8 parts, 4 parts, zinc oxide, stearic acid 2 parts, polyoxyethylene glycol 2 parts, talcum powder 28 parts, naphthenic oil 23 parts, 2-thiol group benzimidazolyl 2.2 parts, zinc dibutyl dithiocarbamate 0.4 part; Above-mentioned raw materials makes sucker through mixing, shaping by weight.
Embodiment 4
The difference of the present embodiment and above-described embodiment 1 is: the thickness of described fiber mesh cloth is 3mm, and the thickness of described fish screen cloth is 10mm.
In the present embodiment, described fiber mesh cloth is provided with skin 11, interlayer 12 and internal layer 13 three-decker, interlayer 12 is arranged between outer 11 and internal layer 13, skin 11 and internal layer 13 form through compiling by polyester monofilament, the thickness of skin 11 and internal layer 13 is 0.3mm, interlayer 12 is made into by nylon monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness of interlayer 12 is 2.4mm, and skin 11, interlayer 12 and internal layer 13 one is through weaving into fiber mesh cloth.
In the present embodiment, fiber mesh cloth after described braiding adopts dipping solution to process, and described dipping solution is made up of the raw material of following weight part: butyl acrylate 18 parts, Isooctyl acrylate monomer 12 parts, vinyl acetate 30 parts, 2 parts, vinylformic acid, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.5 part, alkylphenol polyoxyethylene 0.3 part, deionized water 50 parts, antimonous oxide 3.6 parts, n-methylolacrylamide 3.5 parts, 0.04 part, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate 0.01 part, Sodium phosphate dibasic 0.24 part, ammonium persulphate 0.08 part.
In the present embodiment, the preparation method of described dipping solution comprises the steps:
A, in pre-emulsification still, add portions of de-ionized water, stir, under whipped state, add alkylphenol polyoxyethylene and part alkyl phenol ether sulfo-succinic acid ester sodium salt;
B, under whipped state, vinylformic acid and antimonous oxide are added pre-emulsification still;
C, by butyl acrylate, Isooctyl acrylate monomer and vinyl acetate mix after, under whipped state, add pre-emulsification still, add rear continuations stirring 30min, obtain pre-emulsion;
D, in reactor, add remaining deionized water, be warming up to 55 DEG C, stir;
E, n-methylolacrylamide, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate are added in reactor, then add remaining alkyl phenol ether sulfo-succinic acid ester sodium salt, and add the above-mentioned pre-emulsion of part, stir and be warming up to 75 DEG C;
F, under whipped state, add part Sodium phosphate dibasic and part ammonium persulphate, continue to be warming up to 85 DEG C, slowly drip remaining above-mentioned pre-emulsion;
G, under whipped state, add remaining ammonium persulphate and remaining Sodium phosphate dibasic, added once every 15 minutes, after adding, be warming up to 90 DEG C, continue stir and be incubated 40min, then be cooled to 35 DEG C, discharging, obtain dipping solution.
In the present embodiment, the fiber mesh cloth after described dipping solution process is dried and expanding process through first time oven dry, second time successively, and the temperature that first time dries is 100 DEG C, time is 5min, second time bake out temperature is 120 DEG C, and the time is 3min, is 12% through broadwise expanding rate.
In the present embodiment, described fish screen cloth is provided with upper strata 21, middle level 22 and lower floor 23 three-decker, middle level 22 is arranged between upper strata 21 and lower floor 23, upper strata 21 and lower floor 23 form through compiling by polypropylene filament, the thickness of upper strata 21 and lower floor 23 is 0.8mm, middle level 22 is made into by spandex monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness in middle level 22 is 8.4mm, and upper strata 21, middle level 22 and lower floor 23 one are through weaving into fish screen cloth.
In the present embodiment, through oil for polypropylene fibre process before described polypropylene filament braiding, described oil for polypropylene fibre is made up of the raw material of following weight part: 70 parts, mineral oil, polyoxyethylene iso stearyl ether phosphate sylvite 5 parts, ethoxylated dodecyl alcohol phosphoric acid ester 6 parts, polyoxyethylene nonylphenol ether 7 parts, stearyl alcohol phosphate kalium salt 8 parts, polyoxyethylene glycol bilaurate 10 parts, 5 parts, vinylformic acid; Above-mentioned raw materials makes oil for polypropylene fibre through mix and blend by weight.
In the present embodiment, through spandex oil agent process before described spandex monofilament braiding, described spandex oil agent is made up of the raw material of following weight part: Ethylhexyl stearate 80 parts, fatty alcohol ethylene oxide propylene oxide copolyether 7 parts, alkylphenol polyoxyethylene 8 parts, hydrogenated castor oil Soxylat A 25-7 7 parts, aliphatic acid polyethenoxy methyl ether 15 parts, potassium alkyl phosphate 3 parts, Dodecyl Polyoxyethylene Ether phosphate kalium salt 3 parts; Above-mentioned raw materials makes spandex oil agent through mix and blend by weight.
In the present embodiment, described sucker 4 is made up of the raw material of following weight part: natural rubber 70 parts, polyisoprene rubber 20 parts, terpolymer EP rubber 10 parts, 5 parts, zinc oxide, stearic acid 1 part, polyoxyethylene glycol 1 part, talcum powder 30 parts, naphthenic oil 25 parts, 2-thiol group benzimidazolyl 2.5 parts, zinc dibutyl dithiocarbamate 0.5 part; Above-mentioned raw materials makes sucker through mixing, shaping by weight.
Above-described embodiment is the present invention's preferably implementation, and in addition, the present invention can also realize by alternate manner, and any apparent replacement is all within protection scope of the present invention without departing from the inventive concept of the premise.
Claims (8)
1. three layers of Antiskid shower pad, it is characterized in that: described Antiskid shower pad is provided with top layer, supporting layer and bottom three-decker, supporting layer is arranged between top layer and bottom, the bottom of bottom is fixed with multiple sucker, the outside of Antiskid shower pad is sewed with bound edge, top layer and bottom are fiber mesh cloth, and supporting layer is fish screen cloth;
Described fiber mesh cloth is provided with skin, interlayer and internal layer three-decker, interlayer is arranged between skin and internal layer, outer and internal layer forms through compiling by polyester monofilament, thickness that is outer and internal layer is 0.1 ~ 0.3mm, interlayer is made into by nylon monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, the thickness of interlayer is 0.8 ~ 2.4mm, and skin, interlayer and internal layer one is through weaving into fiber mesh cloth;
Fiber mesh cloth after braiding adopts dipping solution to process, described dipping solution is made up of the raw material of following weight part: butyl acrylate 12 ~ 18 parts, Isooctyl acrylate monomer 8 ~ 12 parts, vinyl acetate 20 ~ 30 parts, 1.5 ~ 2 parts, vinylformic acid, alkyl phenol ether sulfo-succinic acid ester sodium salt 0.3 ~ 0.5 part, alkylphenol polyoxyethylene 0.1 ~ 0.3 part, deionized water 45 ~ 50 parts, antimonous oxide 3.2 ~ 3.6 parts, n-methylolacrylamide 3.0 ~ 3.5 parts, 0.03 ~ 0.05 part, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate 0.01 ~ 0.02 part, Sodium phosphate dibasic 0.12 ~ 0.24 part, ammonium persulphate 0.04 ~ 0.08 part.
2. a kind of three layers of Antiskid shower pad according to claim 1, it is characterized in that: the thickness of described fiber mesh cloth is 1 ~ 3mm, the thickness of described fish screen cloth is 6 ~ 10mm.
3. a kind of three layers of Antiskid shower pad according to claim 1, is characterized in that: the preparation method of described dipping solution comprises the steps:
A, in pre-emulsification still, add portions of de-ionized water, stir, under whipped state, add alkylphenol polyoxyethylene and part alkyl phenol ether sulfo-succinic acid ester sodium salt;
B, under whipped state, vinylformic acid and antimonous oxide are added pre-emulsification still;
C, by butyl acrylate, Isooctyl acrylate monomer and vinyl acetate mix after, under whipped state, add pre-emulsification still, add rear continuation stirring 15 ~ 30min, obtain pre-emulsion;
D, in reactor, add remaining deionized water, be warming up to 50 ~ 55 DEG C, stir;
E, n-methylolacrylamide, polyoxyethylene nonylphenol ether ammonium sulfate, sodium lauryl sulphate are added in reactor, then add remaining alkyl phenol ether sulfo-succinic acid ester sodium salt, and add the above-mentioned pre-emulsion of part, stir and be warming up to 70 ~ 75 DEG C;
F, under whipped state, add part Sodium phosphate dibasic and part ammonium persulphate, continue to be warming up to 80 ~ 85 DEG C, slowly drip remaining above-mentioned pre-emulsion;
G, under whipped state, add remaining ammonium persulphate and remaining Sodium phosphate dibasic, added once every 15 minutes, after adding, be warming up to 85 ~ 90 DEG C, continue stir and be incubated 20 ~ 40min, then be cooled to less than 60 DEG C, discharging, obtain dipping solution.
4. a kind of three layers of Antiskid shower pad according to claim 1, it is characterized in that: the fiber mesh cloth after described dipping solution process is dried and expanding process through first time oven dry, second time successively, the temperature that first time dries is 80 ~ 100 DEG C, time is 2 ~ 5min, second time bake out temperature is 100 ~ 120 DEG C, time is 1 ~ 3min, is 8 ~ 12% through broadwise expanding rate.
5. a kind of three layers of Antiskid shower pad according to claim 1, it is characterized in that: described fish screen cloth is provided with upper strata, middle level and lower floor's three-decker, middle level is arranged between the upper and lower, the upper and lower form through compiling by polypropylene filament, the thickness of the upper and lower is 0.2 ~ 0.8mm, middle level is made into by spandex monofilament and forms X decussate texture or be parallel to each other structure or IXI alternating structure, and the thickness in middle level is 5.6 ~ 8.4mm, and the upper, middle and lower one is through weaving into fish screen cloth.
6. a kind of three layers of Antiskid shower pad according to claim 5, it is characterized in that: through oil for polypropylene fibre process before described polypropylene filament braiding, described oil for polypropylene fibre is made up of the raw material of following weight part: 50 ~ 70 parts, mineral oil, polyoxyethylene iso stearyl ether phosphate sylvite 1 ~ 5 part, ethoxylated dodecyl alcohol phosphoric acid ester 2 ~ 6 parts, polyoxyethylene nonylphenol ether 3 ~ 7 parts, stearyl alcohol phosphate kalium salt 4 ~ 8 parts, polyoxyethylene glycol bilaurate 6 ~ 10 parts, 3 ~ 5 parts, vinylformic acid; Above-mentioned raw materials makes oil for polypropylene fibre through mix and blend by weight.
7. a kind of three layers of Antiskid shower pad according to claim 5, it is characterized in that: through spandex oil agent process before described spandex monofilament braiding, described spandex oil agent is made up of the raw material of following weight part: Ethylhexyl stearate 40 ~ 80 parts, fatty alcohol ethylene oxide propylene oxide copolyether 5 ~ 7 parts, alkylphenol polyoxyethylene 6 ~ 8 parts, hydrogenated castor oil Soxylat A 25-7 5 ~ 7 parts, aliphatic acid polyethenoxy methyl ether 8 ~ 15 parts, potassium alkyl phosphate 1 ~ 3 part, Dodecyl Polyoxyethylene Ether phosphate kalium salt 1 ~ 3 part; Above-mentioned raw materials makes spandex oil agent through mix and blend by weight.
8. a kind of three layers of Antiskid shower pad according to claim 1, is characterized in that: described sucker is made up of the raw material of following weight part: natural rubber 50 ~ 70 parts, polyisoprene rubber 10 ~ 20 parts, terpolymer EP rubber 5 ~ 10 parts, 3 ~ 5 parts, zinc oxide, stearic acid 1 ~ 2 part, polyoxyethylene glycol 1 ~ 2 part, talcum powder 20 ~ 30 parts, naphthenic oil 20 ~ 25 parts, 2-thiol group benzimidazolyl 1.5 ~ 2.5 parts, zinc dibutyl dithiocarbamate 0.1 ~ 0.5 part; Above-mentioned raw materials makes sucker through mixing, shaping by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410141962.9A CN103892746B (en) | 2014-04-10 | 2014-04-10 | A kind of three layers of Antiskid shower pad |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410141962.9A CN103892746B (en) | 2014-04-10 | 2014-04-10 | A kind of three layers of Antiskid shower pad |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103892746A CN103892746A (en) | 2014-07-02 |
| CN103892746B true CN103892746B (en) | 2016-04-20 |
Family
ID=50984572
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410141962.9A Active CN103892746B (en) | 2014-04-10 | 2014-04-10 | A kind of three layers of Antiskid shower pad |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103892746B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110592756A (en) * | 2019-10-15 | 2019-12-20 | 肇庆市高要区长河毛纺有限公司 | Functional moisture absorption quick-drying blended yarn |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202641468U (en) * | 2012-06-28 | 2013-01-02 | 何春城 | Terylene three-dimensional ground mat |
| CN203159853U (en) * | 2013-01-17 | 2013-08-28 | 常熟市双润织造有限公司 | Bamboo charcoal fiber net cloth |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002266223A (en) * | 2001-03-15 | 2002-09-18 | Toyobo Co Ltd | Three-dimensional netted structure |
-
2014
- 2014-04-10 CN CN201410141962.9A patent/CN103892746B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202641468U (en) * | 2012-06-28 | 2013-01-02 | 何春城 | Terylene three-dimensional ground mat |
| CN203159853U (en) * | 2013-01-17 | 2013-08-28 | 常熟市双润织造有限公司 | Bamboo charcoal fiber net cloth |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103892746A (en) | 2014-07-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102424069B1 (en) | Shape enhancing garments with discontinuous elastic polymer composition | |
| CN110066635B (en) | Graphene-coated conductive heat storage fabric and preparation process thereof | |
| CN103892746B (en) | A kind of three layers of Antiskid shower pad | |
| CN106996039B (en) | A kind of preparation method of durable flame-retardant silk fabric | |
| KR100959637B1 (en) | Funtional fabrics process using silk yarn or silk union cloth and product by that process | |
| CN110158255A (en) | An a kind of step decoration method of cool feeling air layer bed necessaries fabric | |
| JP2009102752A (en) | Method for producing textile product and textile product | |
| CN201782525U (en) | Ultrastrong-water absorbing slow-rebound anti-skidding foot bath mat | |
| CN112677593A (en) | Anti-seepage bed sheet | |
| CN204095225U (en) | A kind of novel soft nonwoven | |
| JP2018071030A (en) | Woven fabric | |
| CN105040483A (en) | Non-slip fabric | |
| CN209058504U (en) | A kind of high comfortably adjustable 3D multifunctinoal health cushion | |
| CN208857449U (en) | A kind of antistatic non-woven cloth | |
| CN109938564A (en) | A kind of anti-fold carpet | |
| US20240065489A1 (en) | Washable mat material and system | |
| JPS61119780A (en) | Tile carpet | |
| CN209915582U (en) | Super-soft warm-keeping anti-skid bed sheet | |
| CN109267321A (en) | A kind of preparation method of antibacterial bath mats | |
| CN219856255U (en) | Warm sense anti-slip urine isolation pad | |
| CN213308894U (en) | 3D absorbent pad | |
| CN218028692U (en) | Floor product with surface fiber woven structure | |
| CN218477192U (en) | Cloth with foaming particles | |
| CN209032882U (en) | A kind of compound core body of band solid elastic | |
| CN208910711U (en) | A kind of dedicated pure cotton non-woven fabrics of wings of sanitary towel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |