CN103881576A - Anti-fouling paint - Google Patents

Anti-fouling paint Download PDF

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Publication number
CN103881576A
CN103881576A CN201310518534.9A CN201310518534A CN103881576A CN 103881576 A CN103881576 A CN 103881576A CN 201310518534 A CN201310518534 A CN 201310518534A CN 103881576 A CN103881576 A CN 103881576A
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CN
China
Prior art keywords
parts
fouling paint
paint
paint according
fouling
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310518534.9A
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Chinese (zh)
Inventor
蒋玉俊
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Southeast University
Original Assignee
Southeast University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Southeast University filed Critical Southeast University
Priority to CN201310518534.9A priority Critical patent/CN103881576A/en
Publication of CN103881576A publication Critical patent/CN103881576A/en
Pending legal-status Critical Current

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Abstract

The invention relates to anti-fouling paint which comprises the following components in parts by weight: 10-13 parts of rosin material, 4-7 parts of hydroxyl, 3-6 parts of lactic acid, 12-15 parts of methoxypropanol, 5-8 parts of methylisobutylketone, 3-6 parts of alkyd resin, 12-15 parts of acrylonitrile, 4-6 parts of tricresyl phosphate, 11-16 parts of chlorinated paraffin, 2-6 parts of thickening agent, 5-8 parts of curing agent and 2-7 parts of initiator. The anti-fouling paint has high film strength, excellent mechanical property, hydrolysis resistance and wear resistance, attachment of marine organisms can be effectively avoided, and pollution to a water body is avoided.

Description

A kind of anti-fouling paint
Technical field
The present invention relates to a kind of paint, especially a kind of anti-fouling paint for maritime facilities.
Background technology
As barnacle, marine alga, shellfish etc., to causing adhering in a large number of maritime facilities, ship speed slows down marine organisms, fuel increases, the corrosion such as hull bottom, drilling unit, buoy, bridge pier ulceration, seawater pipeline and aquaculture net cage netting gear stop up, and have brought a large amount of disasters to the process of human development ocean.Marine anti-pollution technology is mainly used in preventing that marine organisms are stained to adhering to of Offshore Units, and existing method mainly contains: taking vinylformic acid organotin ester as base-material from polishing type antifouling varnish, containing the antifouling paint of plant milk extract, low-surface free-energy antifouling paint, antifouling paint taking silicate as stain control agent, conduction anti-soil technology, containing the coating of active biomaterial, taking ion-exchange as basic anti-soil technology, surperficial flocking type antifouling paint, containing the antifouling paint of nanometer inorganic filler, add the antifouling paint of natural silicon crystal.For a long time, most popular is to expect the antifouling antifouling paint as main path of release type taking poison, if organic tributyl tin (TBT), organic copper are the self-polishing coating of poison material.Around material, form marine plant spore and animal larva are had to the concentration of poisons layer of toxic action, thereby play antifouling effect.But this kind of method discharges toxic agent in antifouling, causes water pollution, and can cause biomutation, all be there is to potential safety hazard in marine ecology balance and human health, can be accelerated undoubtedly superseded this today in pay attention to day by day Sustainable development.
Summary of the invention
The object of this invention is to provide one and effectively prevent from halobiontic adhering to but from water body not being produced and being polluted, paint film intensity is high simultaneously, and hydrolytic resistance and wear resisting property be the anti-fouling paint of excellence all.
For achieving the above object, the present invention is achieved by the following technical solutions: a kind of anti-fouling paint, the parts by weight of its each component are: 10~13 parts of rosin material, 4~7 parts of hydroxyls, 3~6 parts of lactic acid, 12~15 parts of methoxypropanol, 5~8 parts of mibks, 3~6 parts of Synolac, 12~15 parts of vinyl cyanide, 4~6 parts of tricresol phosphates, 11~16 parts of clorafins, 2~6 parts of thickening materials, 5~8 parts, solidifying agent, 2~7 parts of initiators.
Further, described rosin material is the sylvate of calcium, magnesium, copper or zinc.
Further, described thickening material is mixed according to the ratio of 1:1 by silica, wilkinite.
Further, described solidifying agent is by zeolite or aliphatic series or aromatic amine, and optimum uses dehydroabietylamine.
Further, described initiator is azo-bis-isobutyl cyanide and so on azo-compound or superoxide.
The invention has the beneficial effects as follows: the invention provides a kind of anti-fouling paint, there is paint film intensity high, excellent mechanical property, anti-hydrolytic performance and abrasion resistance properties, it can effectively prevent halobiontic adhering to, and water body not produced and polluted.
Embodiment
For understanding better the present invention; below by three embodiment, the present invention is done to further concrete elaboration; but unintelligible is limitation of the invention; the foregoing invention content of some nonessential improvement and adjustment do according to to(for) those skilled in the art, be also considered as dropping in protection scope of the present invention.
Embodiment 1
A kind of anti-fouling paint of the present embodiment, the parts by weight of its each component are: 7 parts of the azo-compounds of 13 parts of rosin material, 7 parts of hydroxyls, 6 parts of lactic acid, 15 parts of methoxypropanol, 8 parts of mibks, 6 parts of Synolac, 15 parts of vinyl cyanide, 6 parts of tricresol phosphates, 16 parts of clorafins, 3 parts, silica, 3 parts of swellings, 8 parts of dehydroabietylamines, azo-bis-isobutyl cyanide and so on.
Described rosin material is the sylvate of calcium, magnesium, copper or zinc.
Embodiment 2
A kind of anti-fouling paint of the present embodiment, the parts by weight of its each component are: 10 parts of rosin material, 4 parts of hydroxyls, 3 parts of lactic acid, 12 parts of methoxypropanol, 5 parts of mibks, 3 parts of Synolac, 12 parts of vinyl cyanide, 4 parts of tricresol phosphates, 11 parts of clorafins, 1 part, silica, 1 part of swelling, 5 parts of dehydroabietylamines, peroxidase 12 part.
Described rosin material is the sylvate of calcium, magnesium, copper or zinc.
Embodiment 3
A kind of anti-fouling paint of the present embodiment, the parts by weight of its each component are: 12 parts of rosin material, 5 parts of hydroxyls, 5 parts of lactic acid, 14 parts of methoxypropanol, 6 parts of mibks, 5 parts of Synolac, 13 parts of vinyl cyanide, 5 parts of tricresol phosphates, 14 parts of clorafins, 2 parts, silica, 2 parts of swellings, 6 parts of dehydroabietylamines, 6 parts of superoxide.
Described rosin material is the sylvate of calcium, magnesium, copper or zinc.

Claims (5)

1. an anti-fouling paint, it is characterized in that, the parts by weight of its each component are: 10~13 parts of rosin material, 4~7 parts of hydroxyls, 3~6 parts of lactic acid, 12~15 parts of methoxypropanol, 5~8 parts of mibks, 3~6 parts of Synolac, 12~15 parts of vinyl cyanide, 4~6 parts of tricresol phosphates, 11~16 parts of clorafins, 2~6 parts of thickening materials, 5~8 parts, solidifying agent, 2~7 parts of initiators.
2. a kind of anti-fouling paint according to claim 1, is characterized in that, described rosin material is the sylvate of calcium, magnesium, copper or zinc.
3. a kind of anti-fouling paint according to claim 1, is characterized in that, described thickening material is mixed according to the ratio of 1:1 by silica, wilkinite.
4. a kind of anti-fouling paint according to claim 1, is characterized in that, described solidifying agent is by zeolite or aliphatic series or aromatic amine, and optimum uses dehydroabietylamine.
5. a kind of anti-fouling paint according to claim 1, is characterized in that, described initiator is azo-bis-isobutyl cyanide and so on azo-compound or superoxide.
CN201310518534.9A 2013-10-29 2013-10-29 Anti-fouling paint Pending CN103881576A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310518534.9A CN103881576A (en) 2013-10-29 2013-10-29 Anti-fouling paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310518534.9A CN103881576A (en) 2013-10-29 2013-10-29 Anti-fouling paint

Publications (1)

Publication Number Publication Date
CN103881576A true CN103881576A (en) 2014-06-25

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310518534.9A Pending CN103881576A (en) 2013-10-29 2013-10-29 Anti-fouling paint

Country Status (1)

Country Link
CN (1) CN103881576A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231694A (en) * 2014-09-29 2014-12-24 无锡康柏斯机械科技有限公司 Anti-fouling toughening paint for marine boats
CN106752691A (en) * 2016-11-30 2017-05-31 河池市技术开发中心 A kind of anti-fouling paint for metallurgical machinery surface
CN108690473A (en) * 2017-07-25 2018-10-23 山东科耀化工有限公司 The preparation method of rosin acid modified alkyd resin zinc salt antifouling paint
JP2021518475A (en) * 2018-03-20 2021-08-02 ヨツン アクティーゼルスカブ Composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1386799A (en) * 2002-05-27 2002-12-25 周贻皓 Anti-fouling paint composition for ship and its preparing process
JP2004528437A (en) * 2001-03-16 2004-09-16 ユハ ナチュラル ペイント コーポレーション リミテッド Natural oil-based resin composition, method for producing the same, and natural paint composition based on the same
CN101967316A (en) * 2010-09-08 2011-02-09 中国乐凯胶片集团公司 Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint
CN102408763A (en) * 2011-11-22 2012-04-11 吴江市天源塑胶有限公司 Method for preparing anti-fouling paint for ship bottom
CN103013307A (en) * 2012-11-29 2013-04-03 益阳祥瑞科技有限公司 Antifouling topping paint for boat

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004528437A (en) * 2001-03-16 2004-09-16 ユハ ナチュラル ペイント コーポレーション リミテッド Natural oil-based resin composition, method for producing the same, and natural paint composition based on the same
CN1386799A (en) * 2002-05-27 2002-12-25 周贻皓 Anti-fouling paint composition for ship and its preparing process
CN101967316A (en) * 2010-09-08 2011-02-09 中国乐凯胶片集团公司 Nontoxic antifouling paint for oceanographic ship and facilities and method for preparing paint
CN102408763A (en) * 2011-11-22 2012-04-11 吴江市天源塑胶有限公司 Method for preparing anti-fouling paint for ship bottom
CN103013307A (en) * 2012-11-29 2013-04-03 益阳祥瑞科技有限公司 Antifouling topping paint for boat

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104231694A (en) * 2014-09-29 2014-12-24 无锡康柏斯机械科技有限公司 Anti-fouling toughening paint for marine boats
CN106752691A (en) * 2016-11-30 2017-05-31 河池市技术开发中心 A kind of anti-fouling paint for metallurgical machinery surface
CN108690473A (en) * 2017-07-25 2018-10-23 山东科耀化工有限公司 The preparation method of rosin acid modified alkyd resin zinc salt antifouling paint
JP2021518475A (en) * 2018-03-20 2021-08-02 ヨツン アクティーゼルスカブ Composition
JP7372933B2 (en) 2018-03-20 2023-11-01 ヨツン アクティーゼルスカブ Composition

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Application publication date: 20140625

RJ01 Rejection of invention patent application after publication