CN104341918A - Wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material - Google Patents
Wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material Download PDFInfo
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- CN104341918A CN104341918A CN201410591560.9A CN201410591560A CN104341918A CN 104341918 A CN104341918 A CN 104341918A CN 201410591560 A CN201410591560 A CN 201410591560A CN 104341918 A CN104341918 A CN 104341918A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material. The wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material is prepared from the raw materials in parts by weight: 70-73 parts of acrylic resin, 15-18 parts of keto-aldehyde resin KR-120, 11-14 parts of styrene-acrylic emulsion, 14-17 parts of meerschaum powder, 6-9 parts of bentonite, 3.3-3.6 parts of dibutyl zirconium dilaurate, 1-2 parts of aluminum caprylate, 1.1-1.4 parts of mono-alkoxy titanate coupling agent, 0.5-0.8 part of defoamer, 0.8-1.2 parts of leveling agent, 0.5-0.8 part of mildew preventive, 1.5-1.8 parts of pigment and 52-55 parts of solvent. The wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material disclosed by the invention has excellent wear-resistant, anti-fouling and corrosion-resistant performance and is high in adhesion.
Description
Technical field
The present invention relates to technical field of coatings, particularly relate to the antifouling corrosion resistant coating of a kind of wear resistant high-adhesion.
Background technology
Ocean environment is very harsh corrosive environment, ship housing is in such environment for a long time, corrode extremely serious, simultaneously, marine organisms are with chemical bonding, diffusion, the modes such as electrostatic interaction are attached to ship housing surface, to peel off, the modes such as shearing come off from ship housing surface, and the coating of ship housing is peeled off from ship housing, the havoc integrity of hull, great safety is brought to safety of navigation, in addition, boats and ships are pulling in shore, in navigation process, foreign matter in inevitable and harbour and ocean produces and rubs, and coating is as ship housing the first layer " umbrella ", main anticorrosion of ship housing, wear-resisting, antifouling, corrosion-resistant means, therefore, develop a kind of high adhesive force and wear-resisting, antifouling, corrosion resistant coating is very necessary.
Summary of the invention
The technical problem that basic background technology exists, the present invention proposes the antifouling corrosion resistant coating of a kind of wear resistant high-adhesion, have excellent wear-resisting, antifouling, corrosion resistance nature, and sticking power is high.
The antifouling corrosion resistant coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: acrylic resin 70-73 part, ketone resin KR-120 15-18 part, benzene emulsion 11-14 part, sepiolite powder 14-17 part, wilkinite 6-9 part, di lauric dibutyl zirconium 3.3-3.6 part, aluminium octoate 1-2 part, monoalkoxy type titanate coupling agent 1.1-1.4 part, defoamer 0.5-0.8 part, advection agent 0.8-1.2 part, mould inhibitor 0.5-0.8 part, pigment 1.5-1.8 part, solvent 52-55 part.
Preferably, the weight ratio of acrylic resin, ketone resin KR-120, benzene emulsion is 71-72:16-17:12-13.
Preferably, its raw material comprises by weight: acrylic resin 71-72 part, ketone resin KR-120 16-17 part, benzene emulsion 12-13 part, sepiolite powder 15-16 part, wilkinite 7-8 part, di lauric dibutyl zirconium 3.4-3.5 part, aluminium octoate 1.5-1.8 part, monoalkoxy type titanate coupling agent 1.2-1.3 part, defoamer 0.6-0.7 part, advection agent 0.9-1.1 part, mould inhibitor 0.6-0.7 part, pigment 1.6-1.7 part, solvent 53-54 part.
Preferably, its raw material comprises by weight: acrylic resin 71.5 parts, ketone resin KR-120 16.5 parts, benzene emulsion 12.5 parts, sepiolite powder 15.5 parts, wilkinite 7.5 parts, di lauric dibutyl zirconium 3.45 parts, aluminium octoate 1.6 parts, monoalkoxy type titanate coupling agent 1.25 parts, defoamer 0.65 part, advection agent 1 part, mould inhibitor 0.65 part, pigment 1.65 parts, solvent 53.5 parts.
Adopt olefin(e) acid resin, ketone resin KR-120 as filmogen in the present invention, significantly improve wear-resisting and sticking power of the present invention, also make the present invention have good antifouling, corrosion resistance nature simultaneously, the auxiliary benzene emulsion added is rare by benzene second and the cruel monomer of acrylic acid obtains through emulsion copolymerization, substantially increases antifouling property of the present invention and corrosion resistance nature; Sepiolite powder, bentonitic interpolation further increase wear resisting property of the present invention, sticking power and corrosion resistance nature; And di lauric dibutyl zirconium and linolic acid aluminium are combined to form curing system, greatly improve curing speed of the present invention, and the in-situ hybridization that organic and inorganic occurs in the curing process is cross-linked to form three-dimensional netted crosslinking structure, because sepiolite powder, wilkinite have very high specific surface area, impel crosslinking structure extremely tight, improve antifouling corrosion resistance of the present invention further.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The antifouling corrosion resistant coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: acrylic resin 73 parts, ketone resin KR-120 15 parts, benzene emulsion 14 parts, sepiolite powder 17 parts, wilkinite 6 parts, di lauric dibutyl zirconium 3.6 parts, aluminium octoate 1 part, monoalkoxy type titanate coupling agent 1.4 parts, defoamer 0.5 part, advection agent 1.2 parts, mould inhibitor 0.5 part, pigment 1.8 parts, solvent 52 parts.
Embodiment 2
The antifouling corrosion resistant coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: acrylic resin 70 parts, ketone resin KR-120 18 parts, benzene emulsion 11 parts, sepiolite powder 14 parts, wilkinite 9 parts, di lauric dibutyl zirconium 3.3 parts, aluminium octoate 2 parts, monoalkoxy type titanate coupling agent 1.1 parts, defoamer 0.8 part, advection agent 0.8 part, mould inhibitor 0.8 part, pigment 1.5 parts, solvent 55 parts.
Embodiment 3
The antifouling corrosion resistant coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: acrylic resin 72 parts, ketone resin KR-120 16 parts, benzene emulsion 13 parts, sepiolite powder 16 parts, wilkinite 7 parts, di lauric dibutyl zirconium 3.5 parts, aluminium octoate 1.5 parts, monoalkoxy type titanate coupling agent 1.3 parts, defoamer 0.6 part, advection agent 1.1 parts, mould inhibitor 0.6 part, pigment 1.7 parts, solvent 53 parts.
Embodiment 4
The antifouling corrosion resistant coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: acrylic resin 71 parts, ketone resin KR-120 17 parts, benzene emulsion 12 parts, sepiolite powder 15 parts, wilkinite 8 parts, di lauric dibutyl zirconium 3.4 parts, aluminium octoate 1.8 parts, monoalkoxy type titanate coupling agent 1.2 parts, defoamer 0.7 part, advection agent 0.9 part, mould inhibitor 0.7 part, pigment 1.6 parts, solvent 54 parts.
Embodiment 5
The antifouling corrosion resistant coating of a kind of wear resistant high-adhesion that the present invention proposes, its raw material comprises by weight: acrylic resin 71.5 parts, ketone resin KR-120 16.5 parts, benzene emulsion 12.5 parts, sepiolite powder 15.5 parts, wilkinite 7.5 parts, di lauric dibutyl zirconium 3.45 parts, aluminium octoate 1.6 parts, monoalkoxy type titanate coupling agent 1.25 parts, defoamer 0.65 part, advection agent 1 part, mould inhibitor 0.65 part, pigment 1.65 parts, solvent 53.5 parts.
Carry out performance test to embodiment 1-5, select the commercially available acrylic coating of certain money as a control group, its result is as follows:
| Test item | Embodiment 1-5 mean value | Control group | Establishing criteria |
| Sticking power | 1 grade | 1 grade | GB/T9286-1998 |
| Hardness | H | HB | GB/T6739-2006 |
| Shock-resistant (kgcm) | 62 | 55 | GB/T1732-1993 |
| Salt fog resistance (h) | 288 | 192 | GB/T1771-1991 |
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (4)
1. the antifouling corrosion resistant coating of wear resistant high-adhesion, is characterized in that, its raw material comprises by weight: acrylic resin 70-73 part, ketone resin KR-12015-18 part, benzene emulsion 11-14 part, sepiolite powder 14-17 part, wilkinite 6-9 part, di lauric dibutyl zirconium 3.3-3.6 part, aluminium octoate 1-2 part, monoalkoxy type titanate coupling agent 1.1-1.4 part, defoamer 0.5-0.8 part, advection agent 0.8-1.2 part, mould inhibitor 0.5-0.8 part, pigment 1.5-1.8 part, solvent 52-55 part.
2. the antifouling corrosion resistant coating of wear resistant high-adhesion according to claim 1, it is characterized in that, the weight ratio of acrylic resin, ketone resin KR-120, benzene emulsion is 71-72:16-17:12-13.
3. the antifouling corrosion resistant coating of wear resistant high-adhesion according to claim 1 or 2, it is characterized in that, its raw material comprises by weight: acrylic resin 71-72 part, ketone resin KR-12016-17 part, benzene emulsion 12-13 part, sepiolite powder 15-16 part, wilkinite 7-8 part, di lauric dibutyl zirconium 3.4-3.5 part, aluminium octoate 1.5-1.8 part, monoalkoxy type titanate coupling agent 1.2-1.3 part, defoamer 0.6-0.7 part, advection agent 0.9-1.1 part, mould inhibitor 0.6-0.7 part, pigment 1.6-1.7 part, solvent 53-54 part.
4. the antifouling corrosion resistant coating of wear resistant high-adhesion according to any one of claim 1-3, it is characterized in that, its raw material comprises by weight: acrylic resin 71.5 parts, ketone resin KR-12016.5 part, benzene emulsion 12.5 parts, sepiolite powder 15.5 parts, wilkinite 7.5 parts, di lauric dibutyl zirconium 3.45 parts, aluminium octoate 1.6 parts, monoalkoxy type titanate coupling agent 1.25 parts, defoamer 0.65 part, advection agent 1 part, mould inhibitor 0.65 part, pigment 1.65 parts, solvent 53.5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410591560.9A CN104341918A (en) | 2014-10-28 | 2014-10-28 | Wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410591560.9A CN104341918A (en) | 2014-10-28 | 2014-10-28 | Wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material |
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| Publication Number | Publication Date |
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| CN104341918A true CN104341918A (en) | 2015-02-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410591560.9A Pending CN104341918A (en) | 2014-10-28 | 2014-10-28 | Wear-resistant, high-adhesion, anti-fouling and corrosion-resistant coating material |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104845473A (en) * | 2015-04-29 | 2015-08-19 | 广德嘉宝莉化工有限公司 | High-strength, shock-resistant and abrasion-resistant mechanical paint |
| CN104861800A (en) * | 2015-04-28 | 2015-08-26 | 桐城市新丰彩印包装有限公司 | High adhesion and corrosion resistant decontamination coating |
| CN105038539A (en) * | 2015-06-30 | 2015-11-11 | 芜湖县双宝建材有限公司 | High-strength and high-adhesion environmentally-friendly antifouling coating |
| CN107779046A (en) * | 2017-11-01 | 2018-03-09 | 安徽宝岛新能源发展有限公司 | Electric automobile Wear-resistant corrosion-resistant coating |
| CN107841230A (en) * | 2017-11-01 | 2018-03-27 | 安徽宝岛新能源发展有限公司 | A kind of preparation method of electric automobile Wear-resistant corrosion-resistant coating |
| CN108285712A (en) * | 2018-02-27 | 2018-07-17 | 合肥择浚电气设备有限公司 | A kind of electrical equipment surface anticorrosive coating and preparation method thereof |
-
2014
- 2014-10-28 CN CN201410591560.9A patent/CN104341918A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861800A (en) * | 2015-04-28 | 2015-08-26 | 桐城市新丰彩印包装有限公司 | High adhesion and corrosion resistant decontamination coating |
| CN104845473A (en) * | 2015-04-29 | 2015-08-19 | 广德嘉宝莉化工有限公司 | High-strength, shock-resistant and abrasion-resistant mechanical paint |
| CN105038539A (en) * | 2015-06-30 | 2015-11-11 | 芜湖县双宝建材有限公司 | High-strength and high-adhesion environmentally-friendly antifouling coating |
| CN107779046A (en) * | 2017-11-01 | 2018-03-09 | 安徽宝岛新能源发展有限公司 | Electric automobile Wear-resistant corrosion-resistant coating |
| CN107841230A (en) * | 2017-11-01 | 2018-03-27 | 安徽宝岛新能源发展有限公司 | A kind of preparation method of electric automobile Wear-resistant corrosion-resistant coating |
| CN108285712A (en) * | 2018-02-27 | 2018-07-17 | 合肥择浚电气设备有限公司 | A kind of electrical equipment surface anticorrosive coating and preparation method thereof |
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Application publication date: 20150211 |
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| WD01 | Invention patent application deemed withdrawn after publication |