CN108690473A - The preparation method of rosin acid modified alkyd resin zinc salt antifouling paint - Google Patents
The preparation method of rosin acid modified alkyd resin zinc salt antifouling paint Download PDFInfo
- Publication number
- CN108690473A CN108690473A CN201710610532.0A CN201710610532A CN108690473A CN 108690473 A CN108690473 A CN 108690473A CN 201710610532 A CN201710610532 A CN 201710610532A CN 108690473 A CN108690473 A CN 108690473A
- Authority
- CN
- China
- Prior art keywords
- zinc salt
- alkyd resin
- rosin acid
- modified alkyd
- rosin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 title claims abstract description 51
- 150000003751 zinc Chemical class 0.000 title claims abstract description 38
- 229920000180 alkyd Polymers 0.000 title claims abstract description 37
- 239000003973 paint Substances 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 230000003373 anti-fouling effect Effects 0.000 title claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- 239000000654 additive Substances 0.000 claims abstract description 8
- 230000000996 additive effect Effects 0.000 claims abstract description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000049 pigment Substances 0.000 claims abstract description 6
- 239000006185 dispersion Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 23
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 22
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 22
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 22
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 18
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 11
- 238000009835 boiling Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 9
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 239000011701 zinc Substances 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 150000005846 sugar alcohols Polymers 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 230000018044 dehydration Effects 0.000 claims description 5
- 238000006297 dehydration reaction Methods 0.000 claims description 5
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 5
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 235000021357 Behenic acid Nutrition 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 3
- 239000001530 fumaric acid Substances 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 235000006408 oxalic acid Nutrition 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 229940116226 behenic acid Drugs 0.000 claims description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 2
- 239000002385 cottonseed oil Substances 0.000 claims description 2
- 235000012343 cottonseed oil Nutrition 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 235000019198 oils Nutrition 0.000 claims description 2
- 239000002540 palm oil Substances 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims 1
- AIMMVWOEOZMVMS-UHFFFAOYSA-N cyclopropanecarboxamide Chemical compound NC(=O)C1CC1 AIMMVWOEOZMVMS-UHFFFAOYSA-N 0.000 claims 1
- 235000013847 iso-butane Nutrition 0.000 claims 1
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- 239000002600 sunflower oil Substances 0.000 claims 1
- 235000013311 vegetables Nutrition 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 238000006073 displacement reaction Methods 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract description 2
- 230000005764 inhibitory process Effects 0.000 abstract description 2
- 239000004576 sand Substances 0.000 abstract description 2
- 239000013535 sea water Substances 0.000 abstract description 2
- 159000000000 sodium salts Chemical class 0.000 abstract description 2
- 230000003071 parasitic effect Effects 0.000 abstract 1
- -1 papermaking Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000019484 Rapeseed oil Nutrition 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- DJOWTWWHMWQATC-KYHIUUMWSA-N Karpoxanthin Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1(O)C(C)(C)CC(O)CC1(C)O)C=CC=C(/C)C=CC2=C(C)CC(O)CC2(C)C DJOWTWWHMWQATC-KYHIUUMWSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GTTSNKDQDACYLV-UHFFFAOYSA-N Trihydroxybutane Chemical compound CCCC(O)(O)O GTTSNKDQDACYLV-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000005915 ammonolysis reaction Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 206010016165 failure to thrive Diseases 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002689 maleic acids Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 235000020238 sunflower seed Nutrition 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
- C08G63/48—Polyesters chemically modified by esterification by unsaturated higher fatty oils or their acids; by resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1637—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to coating preparation field, more particularly to a kind of preparation method of rosin acid modified alkyd resin zinc salt antifouling paint is counted, the rosin acid modified alkyd resin zinc salt antifouling paint is composed of the following components in parts by weight:900 ~ 1100 parts of rosin acid modified alkyd resin zinc salt, mix 40 ~ 50 parts of rust resisting pigment, 1 ~ 3 part of coating additive, the above components carry out high speed dispersion or obtain rosin acid modified alkyd resin zinc salt antifouling paint after being sanded in the agitator tank equipped with high speed disperser or in sand mill.Introduce modified rosin acid structure in the present invention has the characteristics that strong adhesive force, flexibility are good, cohesive performance is excellent, quick-drying, and minimum to the pollution of marine environment compared with general coating, more environmentally friendly.Displacement property ionization reaction will occur in the seawater for coating containing zinc salt, dissociate and generate the sodium salt and zinc ion of rosin acid, have inhibition growth to ocean small parasitic biology, also have obvious cleaning protection to ship, dyke, bank base.
Description
Technical field
The present invention relates to coating preparation field, more particularly to a kind of system of rosin acid modified alkyd resin zinc salt antifouling paint
Preparation Method.
Background technology
Hull, harbour, drilling platforms etc. are located at the attachment that the part under water line is vulnerable to bacterium and marine organisms at present
It is stained, a large amount of waste that adheres to not only increases the dead weight of ship, reduces the load-carrying of ship, while the resistance that will greatly increase hull
Power causes the speed of a ship or plane of ship to reduce the increase with fuel consumption.And fall off after fouling organism death, it is also possible to be inhaled into equipment
Pipeline in, cause the blocking of pipeline.The breeding of fouling organism can also cause the corrosion protective layer of ship or off-shore structure
Damage, accelerates the corrosion of metal component, reduces the service life of ship and marine structure.Usually all it is to be applied in these parts
Antifouling paint prevents marine organisms from adhering to, the marine antifouling coating of traditional tin system due to marine eco-environment pollution compared with
Greatly, it has been forbidden to use.Rosin is widely used in soap, papermaking, paint and rubber etc. as a kind of important industrial chemicals
Industry.The modification of rosin, the reaction active groups such as general conjugated double bond, carboxyl using in rosin molecular structure, by addition,
Hydrogenation, polymerization, ammonolysis, at reactions such as salt, esterifications maleic rosin, disproportionated rosin, hydrogenated rosin, newtrex, pine is made in disproportionation
The deep processed products such as fragrant amine, abietate and various rosin esters.
Invention content
In order to make up the above deficiency, the present invention discloses a kind of preparation side of rosin acid modified alkyd resin zinc salt antifouling paint
Method, rosin modified alkyd resin refers to the addition modifying agent rosin in the preparation process of alkyd resin, made of chemical reaction
Modified resin.Due to the modification of rosin, the resin is made to be soluble in esters solvent, the adhesive force of paint film can be increased, reduced paint film and rise
Wrinkle improves durability, alkali resistance and the gloss of paint film, reduces viscosity;Paint film release solvent is also very fast, does rate and improves, parches and adding
Soon, and to the less pollution of marine environment.
The present invention is achieved through the following technical solutions:A kind of system of rosin acid modified alkyd resin zinc salt antifouling paint
Preparation Method, which is characterized in that count in parts by weight, the rosin acid modified alkyd resin zinc salt antifouling paint is by following components group
At:900 ~ 1100 parts of rosin acid acid modified alcoholic tree zinc salt mixes 40 ~ 50 parts of rust resisting pigment, 1 ~ 3 part of coating additive.
Preferably, it is prepared by following processing steps:
Step 1:Rosin acid refines
Ethanol water is added in rosin, adds the aqueous solution of sodium hydroxide, is heated to boiling, return stirring reaction 3 ~ 4
Hour, activated carbon decolorizing, filtering is added, filtrate is cooled to 0 ~ 4 DEG C, is slowly dropped into aqueous hydrochloric acid solution, filters again, obtain slightly
Yellow solid is washed with water to neutrality.
Step 2:The preparation of rosin acid modified alkyd resin zinc salt
Refined rosin acid, polyalcohol, substance and solvent containing oleic acid are added in a kettle, is warming up to 90 ~ 100 DEG C, instead
0.5 ~ 1h is answered, alkyl dicarboxylic aid then is added and dry oxidation zinc stirs evenly, is heated to boiling, dehydration 1h;Increase temperature
Degree reacts 2 ~ 4h to 210 ~ 220 DEG C, measures acid value as 80 hereinafter, up to rosin acid modified alkyd resin zinc salt.
Step 3:The preparation of rosin acid modified alkyd resin zinc salt antifouling paint
By 900 ~ 1100 parts of the rosin acid modified alkyd resin zinc salt, 40 ~ 50 parts of rust resisting pigment, 1 ~ 3 part of coating additive are mixed,
Dispersion is sanded to 40 μm of granularity hereinafter, to obtain the final product.
Preferably, in step 1:The volume fraction of the ethyl alcohol is 75% ~ 90%, and the sodium hydroxide is water-soluble
The concentration of liquid and hydrochloric acid is 1 ~ 3mol/L, and the molar ratio of the rosin, sodium hydroxide and hydrochloric acid is 10:1:1.2, rosin, ethyl alcohol
Mass ratio with activated carbon is 100:150~170:1~3.
Preferably, in step 2:The solvent is one kind in toluene or n-butanol, and the polyalcohol is season
One kind in penta tetrol, glycerine or trihydroxy methyl propane, the substance containing oleic acid are behenic acid, castor oil, sunflower seeds
One kind in oil, palm oil, cottonseed oil or rapeseed oil, the alkyl dicarboxylic aid are in succinic acid, maleic acid, fumaric acid or oxalic acid
It is one or more;The rosin acid, polyalcohol, the substance containing oleic acid, alkyl dicarboxylic aid and dry oxidation zinc weight ratio be
100:35~45:45~55:25~35:0.02~0.03.
The beneficial effects of the invention are as follows:Modified rosin acid structure is introduced in the present invention, and compared with general coating, there is attachment
The features such as power is strong, flexibility is good, cohesive performance is excellent, quick-drying, and it is minimum to the pollution of marine environment, it is more environmentally friendly.Containing zinc salt
Displacement property ionization reaction will occur in the seawater for coating, dissociate and generate the sodium salt and zinc ion of rosin acid, small to ocean to post
Raw biology has inhibition growth, also has obvious cleaning protection to ship, dyke, bank base.
Description of the drawings
Fig. 1 is the hanging test of the embodiment of the present invention 1.
Specific implementation mode
Below by embodiment, the present invention will be further described, but the scope of the invention is not limited.
Embodiment 1:
Rosin acid refines:The ethyl alcohol 800ml that volume fraction is 75% is added in 300g rosin, adds the 2mol/L of 50ml
Sodium hydrate aqueous solution is heated to boiling, and return stirring reacts 3.5 hours, and 6g activated carbon decolorizings, filtering, filtrate cooling is added
To 0 ~ 4 DEG C, 60ml 2mol/L aqueous hydrochloric acid solutions are slowly dropped into, are filtered again, yellowish solid is obtained, are washed with water to neutrality.
The preparation of rosin acid modified alkyd resin zinc salt:To equipped with blender, thermometer, straight pipe condensation pipe, water-oil separating
1013g rosin acids, 421g glycerine and 506g behenic acids are added in the reaction kettle of device, is warming up to 95 DEG C, reacts 35 minutes, then
320g fumaric acid, 2.3g oxalic acid and 0.253g dry oxidation zinc is added to stir evenly, is heated to boiling, dehydration 1h;It increases
Temperature is to 220 DEG C, then reacts 3h, measures acid value as 80 hereinafter, up to rosin acid modified alkyd resin zinc salt.
The preparation of rosin acid modified alkyd resin zinc salt antifouling paint:
Rosin acid modified alkyd resin zinc salt 1000g is added into the coating material production tank equipped with high speed dispersor, mixes antirust face
Expect 45g, coating additive 2g, carry out high speed dispersion, survey fineness at 40 μm hereinafter, to obtain the final product.
Performance test:
Adhesive force(Grade):It is evaluated as 1 by GB/T1720-1989 standards;
Flexibility(mm):It is evaluated as 1 by GB/T1731-1993 standards;
Viscosity(Pa.s):It is evaluated as 40 ~ 50 by GB/T1723-1993 standards;
Impact strength(kg.cm):It is evaluated as 45 ± 5 by GB/T1732-1993 standards;
Artificial ageing resistance(600h):It is evaluated by GB/T1865-2009 standards, no blistering, peeling, crackle;
Salt spray test(1000h):By GB/T1771-2007 standards evaluate, it is no blistering, without cracking, without rust staining;
Hardening time (25C, relative humidity 70%):Biao Gan≤0.5h;The h of Shi Gan≤4;
Hanging test situation
As shown in Figure 1, the environmentally friendly antifouling paint produced as base-material using modified rosin acid zinc salt composite polypropylene acid resin was passed through to day
Hanging test is done according to marine terminal 7 times, and every 2 square metres of application is stored 3 years, is had no that microorganism adheres to, is closed on maritime waters
Biology has no growth failure.
Embodiment 2:
Rosin acid refines:The ethyl alcohol 715ml that volume fraction is 85% is added in 300g rosin, adds the 1mol/L of 100ml
Sodium hydrate aqueous solution is heated to boiling, and return stirring reacts 3 hours, and 3g activated carbon decolorizings, filtering is added, and filtrate is cooled to 0
~ 4 DEG C, the 1mol/L aqueous hydrochloric acid solutions of 120ml are slowly dropped into, are filtered again, yellowish solid is obtained, are washed with water to neutrality.
The preparation of rosin acid modified alkyd resin zinc salt:To equipped with blender, thermometer, straight pipe condensation pipe, water-oil separating
1013g rosin acids, 355g glycerine and 456g castor oil are added in the reaction kettle of device, is warming up to 90 DEG C, reacts 30 minutes, then
304g maleic acids are added and 0.203g dry oxidation zinc stirs evenly, are heated to boiling, dehydration 1h;Temperature is increased to 210
DEG C, then 2h is reacted, acid value is measured as 80 hereinafter, up to rosin acid modified alkyd resin zinc salt.
The preparation of rosin acid modified alkyd resin zinc salt antifouling paint:
Rosin acid modified alkyd resin zinc salt 900g is added into sand mill, mixes rust resisting pigment 40g, coating additive 1g, carries out
It is sanded, surveys fineness at 40 μm hereinafter, to obtain the final product.
Embodiment 3:
Rosin acid refines:The ethyl alcohol 676ml that volume fraction is 90% is added in 300g rosin, adds the 3mol/L of 33ml
Sodium hydrate aqueous solution is heated to boiling, and return stirring reacts 4 hours, and 9g activated carbon decolorizings, filtering is added, and filtrate is cooled to 0
~ 4 DEG C, the 3mol/L aqueous hydrochloric acid solutions of 40ml are slowly dropped into, are filtered again, yellowish solid is obtained, are washed with water to neutrality.
The preparation of rosin acid modified alkyd resin zinc salt:To equipped with blender, thermometer, straight pipe condensation pipe, water-oil separating
1013g rosin acids, 455g trihydroxy methyls propane and 557g rapeseed oils are added in the reaction kettle of device, is warming up to 100 DEG C, reaction
Then 1h is added 354g succinic acid and 0.304g dry oxidation zinc stirs evenly, is heated to boiling, dehydration 1h;Increase temperature
Degree is to 215 DEG C, then reacts 4h, measures acid value as 80 hereinafter, up to rosin acid modified alkyd resin zinc salt.
The preparation of rosin acid modified alkyd resin zinc salt antifouling paint:
Rosin acid acid modified alcoholic resin zinc salt 1100g is added into the coating material production tank equipped with high speed dispersor, mixes antirust face
Expect 50g, coating additive 3g, carry out high speed dispersion, survey fineness at 40 μm hereinafter, to obtain the final product.
In addition to technical characteristic described in specification, remaining technical characteristic is technology known to those skilled in the art.
Claims (4)
1. a kind of preparation method of rosin acid modified alkyd resin zinc salt antifouling paint, which is characterized in that count in parts by weight, institute
It is composed of the following components to state rosin acid modified alkyd resin zinc salt antifouling paint:Rosin acid modified alkyd resin zinc salt 900 ~ 1100
Part, mix 40 ~ 50 parts of rust resisting pigment, 1 ~ 3 part of coating additive.
2. the preparation method of rosin acid modified alkyd resin zinc salt antifouling paint according to claim 1, which is characterized in that
It is prepared by following processing steps:
Step 1:Rosin acid refines
Ethanol water is added in rosin, adds the aqueous solution of sodium hydroxide, is heated to boiling, return stirring reaction 3 ~ 4
Hour, activated carbon decolorizing, filtering is added, filtrate is cooled to 0 ~ 4 DEG C, instills aqueous hydrochloric acid solution, filters again, obtain yellowish
Solid, be washed with water to neutrality to get.
Step 2:The preparation of rosin acid modified alkyd resin zinc salt
Refined rosin acid, polyalcohol, substance and solvent containing oleic acid are added into reaction kettle, is warming up to 90 ~ 100 DEG C, instead
0.5 ~ 1h is answered, alkyl dicarboxylic aid then is added and dry oxidation zinc stirs evenly, is heated to boiling, dehydration 1h, then increase
Temperature reacts 2 ~ 4h to 210 ~ 220 DEG C, measures acid value as 80 hereinafter, up to rosin acid modified alkyd resin zinc salt.
Step 3:The preparation of rosin acid modified alkyd resin zinc salt antifouling paint
By 900 ~ 1100 parts of the rosin acid modified alkyd resin zinc salt, 40 ~ 50 parts of rust resisting pigment, 1 ~ 3 part of coating additive are mixed,
Dispersion is sanded to 40 μm of granularity hereinafter, to obtain the final product.
3. the preparation method of rosin acid modified alkyd resin zinc salt antifouling paint according to claim 2, which is characterized in that
In step 1:The volume fraction of the ethanol water is 75% ~ 90%, the sodium hydrate aqueous solution and aqueous hydrochloric acid solution
Concentration is 1 ~ 3mol/L, and the molar ratio of the rosin, sodium hydroxide and hydrochloric acid is 10:1:1.2, rosin, ethyl alcohol and activated carbon
Mass ratio is 100:150~170:1~3.
4. the preparation method of rosin acid modified alkyd resin zinc salt antifouling paint according to claim 2, which is characterized in that
In step 2:The solvent is one kind in toluene or n-butanol, and the polyalcohol is pentaerythrite, glycerine or trihydroxy
One kind in methylpropane, the substance containing oleic acid are behenic acid, castor oil, sunflower oil, palm oil, cottonseed oil or vegetable seed
One kind in oil, the alkyl dicarboxylic aid are one or more in succinic acid, maleic acid, fumaric acid or oxalic acid;The rosin
Acid, polyalcohol, the substance containing oleic acid, alkyl dicarboxylic aid and dry oxidation zinc weight ratio be 100:35~45:45~55:25~35:
0.02~0.03。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710610532.0A CN108690473B (en) | 2017-07-25 | 2017-07-25 | Preparation method of rosin acid modified alkyd resin zinc salt antifouling paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710610532.0A CN108690473B (en) | 2017-07-25 | 2017-07-25 | Preparation method of rosin acid modified alkyd resin zinc salt antifouling paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108690473A true CN108690473A (en) | 2018-10-23 |
| CN108690473B CN108690473B (en) | 2020-07-17 |
Family
ID=63843961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710610532.0A Active CN108690473B (en) | 2017-07-25 | 2017-07-25 | Preparation method of rosin acid modified alkyd resin zinc salt antifouling paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108690473B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112409896A (en) * | 2020-12-04 | 2021-02-26 | 广西民族大学 | Preparation method of long-oil alkyd resin anticorrosive enamel with high corrosion potential |
| CN114479582A (en) * | 2020-10-27 | 2022-05-13 | 中石化石油工程技术服务有限公司 | Copper-free antifouling paint for coastal oil and gas pipeline in static environment and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1396154A (en) * | 2001-07-16 | 2003-02-12 | 中国医药研究开发中心 | Sulfonated dehydroabietate and its preparing process and application |
| JP2005255873A (en) * | 2004-03-12 | 2005-09-22 | Harima Chem Inc | Varnish composition for gravure printing ink |
| CN103881576A (en) * | 2013-10-29 | 2014-06-25 | 东南大学 | Anti-fouling paint |
| CN105949447A (en) * | 2016-06-03 | 2016-09-21 | 滁州市龙飞化工有限公司 | Alkyd resin for polyurethane paint |
| CN106008937A (en) * | 2016-06-28 | 2016-10-12 | 石媛 | Production method of light-colored rosin modified alkyd resin |
-
2017
- 2017-07-25 CN CN201710610532.0A patent/CN108690473B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1396154A (en) * | 2001-07-16 | 2003-02-12 | 中国医药研究开发中心 | Sulfonated dehydroabietate and its preparing process and application |
| JP2005255873A (en) * | 2004-03-12 | 2005-09-22 | Harima Chem Inc | Varnish composition for gravure printing ink |
| CN103881576A (en) * | 2013-10-29 | 2014-06-25 | 东南大学 | Anti-fouling paint |
| CN105949447A (en) * | 2016-06-03 | 2016-09-21 | 滁州市龙飞化工有限公司 | Alkyd resin for polyurethane paint |
| CN106008937A (en) * | 2016-06-28 | 2016-10-12 | 石媛 | Production method of light-colored rosin modified alkyd resin |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114479582A (en) * | 2020-10-27 | 2022-05-13 | 中石化石油工程技术服务有限公司 | Copper-free antifouling paint for coastal oil and gas pipeline in static environment and preparation method thereof |
| CN114479582B (en) * | 2020-10-27 | 2023-08-11 | 中石化石油工程技术服务有限公司 | Copper-free antifouling paint for use in static environment of offshore oil and gas pipeline and preparation method thereof |
| CN112409896A (en) * | 2020-12-04 | 2021-02-26 | 广西民族大学 | Preparation method of long-oil alkyd resin anticorrosive enamel with high corrosion potential |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108690473B (en) | 2020-07-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101241747B1 (en) | Antifouling coating composition, antifouling coating film formed using the composition, coated object having the coating film on the surface, and method of antifouling treatment by formation of the coating film | |
| KR101963670B1 (en) | Antifouling coating composition | |
| US20130273116A1 (en) | Anti-fouling composition comprising an aerogel | |
| CN103289007B (en) | A kind of zinc acrylate resin/resin of copper preparation method of improvement | |
| EP1272570A1 (en) | Antifouling paint composition comprising rosin and enzyme | |
| CN102224209A (en) | Antifouling coating composition, antifouling coating film, and method of preventing fouling of base | |
| KR102656962B1 (en) | Antifouling paint composition, antifouling film, antifouling film attachment base material, manufacturing method thereof, and repair method | |
| CN103122187A (en) | Ionic liquid modified marine antifouling paint | |
| CN103360904A (en) | Tar-free epoxy resin coating and its preparation method | |
| CN105295585A (en) | Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint | |
| CN102807797A (en) | Efficient marine antifouling coating and broad-spectrum controlled-release antifouling agent for same | |
| CN101696340A (en) | Strippable anti-fouling paint | |
| CN108690473A (en) | The preparation method of rosin acid modified alkyd resin zinc salt antifouling paint | |
| CN104761991A (en) | Environmental-protection type multi-element collaborative marine anti-fouling coating | |
| CN104403448A (en) | Nano cuprous oxide and nano silver compounded sea anti-fouling paint | |
| KR20180081779A (en) | Antifouling coating composition, antifouling coating film, antifouling base, and method of manufacturing antifouling base | |
| CN105837733A (en) | Capsaicin [(12-acryloyl-oxy)-dehydroabietate]-acrylic acid copolymer, and preparation and application thereof | |
| CN111253821B (en) | High-solid-content copper-free linear self-polishing marine antifouling paint | |
| CN104610851A (en) | Preparation method of anti-fouling coating | |
| CN108610892A (en) | A kind of ocean steel construction anticorrosion and antifouling water paint and preparation method thereof | |
| CN104530985A (en) | Rosin metal salt resin as well as preparation method and application thereof | |
| CN104530986B (en) | Rosin organic acid metal salt resin with acrylate metal salt resin chemical architectural feature and performance and preparation method thereof and purposes | |
| CN103038293A (en) | Antifouling coating | |
| CN102125038B (en) | Anti-fouling agent containing paeonolum and nicotine structure and preparation method thereof | |
| CN106118299A (en) | A kind of preparation method of Graphene Capsaicin synthesis shipbottom paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation of rosin acid modified alkyd resin zinc salt antifouling coating Effective date of registration: 20201120 Granted publication date: 20200717 Pledgee: Heze rural commercial bank Limited by Share Ltd. Pledgor: KEYAO CHEMICAL Co.,Ltd. Registration number: Y2020980008271 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20211207 Granted publication date: 20200717 Pledgee: Heze rural commercial bank Limited by Share Ltd. Pledgor: KEYAO CHEMICAL CO.,LTD. Registration number: Y2020980008271 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation of rosin acid modified alkyd resin zinc salt antifouling coating Effective date of registration: 20211207 Granted publication date: 20200717 Pledgee: Heze rural commercial bank Limited by Share Ltd. Pledgor: KEYAO CHEMICAL CO.,LTD. Registration number: Y2021990001154 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20221206 Granted publication date: 20200717 Pledgee: Heze rural commercial bank Limited by Share Ltd. Pledgor: KEYAO CHEMICAL CO.,LTD. Registration number: Y2021990001154 |
|
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation of rosin acid modified alkyd resin zinc salt antifouling coating Effective date of registration: 20221209 Granted publication date: 20200717 Pledgee: Heze rural commercial bank Limited by Share Ltd. Pledgor: KEYAO CHEMICAL CO.,LTD. Registration number: Y2022980026485 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right |