CN103881341B - Tung oil derivative-modified unsaturated polyester resin composition and preparation method thereof - Google Patents
Tung oil derivative-modified unsaturated polyester resin composition and preparation method thereof Download PDFInfo
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- CN103881341B CN103881341B CN201410139738.6A CN201410139738A CN103881341B CN 103881341 B CN103881341 B CN 103881341B CN 201410139738 A CN201410139738 A CN 201410139738A CN 103881341 B CN103881341 B CN 103881341B
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- unsaturated polyester
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Abstract
The invention discloses a tung oil derivative-modified unsaturated polyester resin composition and a preparation method thereof. The preparation method comprises the steps: by taking a tung oil derivative and general type unsaturated polyester resin as primary materials, adding a certain amount of an antioxidant, a thermal stabilizer, a light stabilizer, a mildew preventive and a defoaming agent, stirring and mixing uniformly at a normal temperature to prepare the tung oil derivative-modified unsaturated polyester resin composition. After being added with an initiator and an accelerant, the composition is heated for reacting and curing to form a co-mixing structure composite of tung oil derivative monomer and an unsaturated polyester macromolecule, so that problems such as bad air-drying performance, poor adhesion force, poor flexibility, poor impact resistance, and the like, of the existing unsaturated polyester resin paint are solved, and therefore, the tung oil derivative-modified unsaturated polyester resin composition can be used as thermocuring paint for being applied to the fields such as buildings, cars, chemical engineering, and the like. The method has the advantages of being low in production cost, simple and convenient to operate, short in production period, small in environmental pollution, and the like.
Description
Technical field
The present invention relates to the field of chemical synthesis, be specially a kind of derivative modified unsaturated polyester resin compositions of Oleum Verniciae fordii and preparation method thereof.
Background technology
Unsaturated polyester resin (Unsaturated Polyester
Resin, UPR) be thermosetting resin, be usually by unsaturated dibasic acid and dihydroxylic alcohols polycondensation, there is ester bond and the chain macromolecule compound of unsaturated double-bond.Its production technology is simple, raw material is easy to get, and combination property is good, has high rigidity, high richness, and weatherability, resistance to water, oil resistivity are good, and glossiness is high, and electric insulating quality is excellent, and light weight and the advantage such as cheap, be one of important coating film-forming resin.But it is bad to use universal UPR to there is air-drying property when preparing coating, the shortcomings such as adhesive force, pliability and shock resistance are poor.Along with constantly expanding and the enhancing day by day of people's environmental consciousness of production field, common UPR cannot adapt to the demand of social development.
Study on the modification for unsaturated polyester resin improves the problem existed when unsaturated polyester (UP) prepares coating at present, is mainly modified with polyurethane or base polyurethane prepolymer for use as, acrylic resin, organosilicon, nano material and vegetable oil.Wherein, crude vegetal has wide material sources, strong, degradable various in style, cheap, alternative and the plurality of advantages such as renewable, so, plant oil modified unsaturated polyester resin is increasingly paid attention to by people.
In vegetable oil, soybean oil, oleum lini, Oleum Ricini, Semen Maydis oil, Oleum Verniciae fordii is used also to be had been reported that by the method for chemosynthesis modified unsaturated polyester resin.The method is to add a certain amount of above-mentioned vegetable oil in unsaturated polyester resin building-up process, and its response time is long, complex operation, and reaction temperature is high, easily cause vegetable oil self that being polymerized between double bond and double bond occurs, thus do not reach the Expected Results of modification, affect product quality.At present, there is not yet document report with the method for Oleum Verniciae fordii derivative blended modified unsaturated polyester resin compositions.
Summary of the invention
Technical problem solved by the invention is to provide a kind of derivative modified unsaturated polyester resin compositions of Oleum Verniciae fordii and preparation method thereof, to solve the shortcoming in above-mentioned background technology.
Technical problem solved by the invention realizes by the following technical solutions:
The derivative modified unsaturated polyester resin compositions of Oleum Verniciae fordii, its constituent and content ratio are as follows:
Unsaturated polyester resin:
100 g；
Oleum Verniciae fordii derivant:
1～12 g；
Antioxidant:
0.3～0.5 g；
Heat stabilizer:
0.3～0.8 g；
Light stabilizer:
0.3～1.5 g；
Antifungus agent:
0.3～0.6 g；
Defoamer:
0.2～0.5 g.
In the present invention, one or more during described Oleum Verniciae fordii derivant is eleostearic acid, methyl eleostearate (ME), epoxidation methyl eleostearate (EME), eleostearic acid monoglyceride (EAM), paulownia horse adduct (MEMAA) and Oleum Verniciae fordii polylol (TOAEP).
In the present invention, described antioxidant is antioxidant 1010；Described heat stabilizer is zinc stearate；Described light stabilizer is 2-hydroxyl-4-dodecyl-benzophenone；Described antifungus agent is copper 8-quinolinolate；Described defoamer is JF-1102 organic silicon defoamer.
The preparation method of the derivative modified unsaturated polyester resin compositions of Oleum Verniciae fordii based on above-mentioned composition and content, idiographic flow is: add unsaturated polyester resin and Oleum Verniciae fordii derivant in reaction vessel, it is stirred, it is sequentially added into antioxidant, heat stabilizer, light stabilizer, antifungus agent, defoamer simultaneously, after being uniformly mixed, i.e. prepares the derivative modified unsaturated polyester resin compositions of thermohardening type Oleum Verniciae fordii.
Beneficial effect:
The present invention utilizes fast drying that Oleum Verniciae fordii derivant had, adhesive force is strong, pliability and the feature such as impact resistance is good, unsaturated polyester resin is modified by the compatibility utilizing Oleum Verniciae fordii derivant and unsaturated polyester resin good, thus improve and increase the combination property after unsaturated polyester resin solidification, can obtain a kind of air-drying property good, adhesive force is strong, pliability and the good unsaturated polyester resin coating of shock resistance.The derivative modified unsaturated polyester resin compositions of Oleum Verniciae fordii has the features such as good continuous operation, fast setting and high adhesion force, can be applied to the fields such as building, automobile and chemical industry as heat curing coating.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, name example and describe the present invention.
Case study on implementation 1
100 g unsaturated polyester resin materials are added in reaction vessel, add the eleostearic acid of 10 g, add the antioxidant 1010 of 0.4 g, the heat stabilizer zinc stearate of 0.4 g, the light stabilizer 2-hydroxyl-4-dodecyl-benzophenone of 0.4 g, the antifungus agent copper 8-quinolinolate of 0.4 g, the JF-1102 organic silicon defoamer of 0.2 g, above material is placed in mixing reactor, is uniformly mixed under room temperature, i.e. prepare thermohardening type eleostearic acid modified unsaturated polyester resin compositions.Said composition is after adding 1 g benzoyl peroxide and 1 g DMA, on film to horse oralia, and film forming after being solidified by thermal response, obtain modified UPR-1.
Case study on implementation 2-9
Method according to embodiment 1, change the kind of modifying agent Oleum Verniciae fordii derivant, the consumption of modifying agent, the consumption of antioxidant, the consumption of heat stabilizer, the consumption of light stabilizer, the consumption of antifungus agent, the consumption of defoamer respectively, having obtained case study on implementation 2-9, concrete consumption is shown in Table 1.
Table 1 Oleum Verniciae fordii derivative modified unsaturated polyester resin compositions formula table
The method synthesis technique is simple, is suitable to continuous prodution, can obtain a kind of having that drying time is fast, adhesive force strong, flexility and the good product of the combination property such as shock resistance is good.The present invention carries out sample preparation by above-mentioned case study on implementation and tests its performance the unsaturated polyester resin compositions that obtained Oleum Verniciae fordii is derivative modified, and sample preparation is carried out by national standard method with test: surface drying time test is carried out according to the regulation in " paint film, putty membrane assay method drying time " GB 1728-79；Pliability test is carried out according to the regulation in " paint film flexibility method of testing " GB/T 1731-93；Adhesive force test is carried out according to the regulation in " paint film adhesion algoscopy " GB/T 9286-88；Impact strength test is carried out according to the regulation in " paint film impact resistance algoscopy " GB 1732-79.Test result is shown in Table 2。
Table 2 Oleum Verniciae fordii derivative modified unsaturated polyester resin compositions test result
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.Skilled person will appreciate that of the industry; the present invention is not restricted to the described embodiments; the principle that the present invention is simply described described in above-described embodiment and description; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements both fall within scope of the claimed invention.Claimed scope is defined by appending claims and equivalent thereof.
Claims (2)
1. the derivative modified unsaturated polyester resin compositions of Oleum Verniciae fordii, it is characterised in that the derivative modified unsaturated polyester of described Oleum Verniciae fordii
Ester resin composition consists of composition and content ratio forms:
Unsaturated polyester resin: 100g；
Oleum Verniciae fordii derivant: 1～12g；Described Oleum Verniciae fordii derivant is eleostearic acid, methyl eleostearate, epoxidation methyl eleostearate, paulownia
One or more in acid monoglyceride and Oleum Verniciae fordii polylol；
Antioxidant 1010: 0.3～0.5g；
Heat stabilizer zinc stearate: 0.3～0.8g；
Light stabilizer 2-hydroxyl-4-dodecyl-benzophenone: 0.3～1.5g；
Antifungus agent copper 8-quinolinolate: 0.3～0.6g；
Defoamer: 0.2～0.5g.
The preparation method of the derivative modified unsaturated polyester resin compositions of Oleum Verniciae fordii the most according to claim 1, its feature exists
In, its idiographic flow is: adds unsaturated polyester resin and Oleum Verniciae fordii derivant in reaction vessel, is stirred, the most successively
Add antioxidant, heat stabilizer, light stabilizer, antifungus agent, defoamer, after being uniformly mixed, i.e. prepare thermohardening type paulownia
The derivative modified unsaturated polyester resin compositions of oil.
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| CN201410139738.6A CN103881341B (en) | 2014-04-04 | 2014-04-04 | Tung oil derivative-modified unsaturated polyester resin composition and preparation method thereof |
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| CN201410139738.6A CN103881341B (en) | 2014-04-04 | 2014-04-04 | Tung oil derivative-modified unsaturated polyester resin composition and preparation method thereof |
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| CN103881341A CN103881341A (en) | 2014-06-25 |
| CN103881341B true CN103881341B (en) | 2017-01-11 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86108060A (en) * | 1986-12-06 | 1988-07-13 | 北京师范大学 | Tung oil modified unsaturated polyester paint and synthesis method |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5367794A (en) * | 1976-11-29 | 1978-06-16 | Hitachi Chem Co Ltd | Resin composition |
| JPS5792030A (en) * | 1980-11-30 | 1982-06-08 | Matsushita Electric Works Ltd | Manufacture of laminate |
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2014
- 2014-04-04 CN CN201410139738.6A patent/CN103881341B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86108060A (en) * | 1986-12-06 | 1988-07-13 | 北京师范大学 | Tung oil modified unsaturated polyester paint and synthesis method |
Non-Patent Citations (1)
| Title |
|---|
| "Novel Materials from Unsaturated Polyester Resin/Styrene/Tung Oil Blends with High Impact Strengths and Enhanced Mechanical Properties";Kunal Das et al;《Journal of Applied Polymer Science》;20100827;第119卷;第2174-2182页 * |
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