CN103881195A - Antistatic anti-aging polyethylene master batch and preparation method thereof - Google Patents
Antistatic anti-aging polyethylene master batch and preparation method thereof Download PDFInfo
- Publication number
- CN103881195A CN103881195A CN201210560812.2A CN201210560812A CN103881195A CN 103881195 A CN103881195 A CN 103881195A CN 201210560812 A CN201210560812 A CN 201210560812A CN 103881195 A CN103881195 A CN 103881195A
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- Prior art keywords
- master batch
- polyethylene master
- resistant polyethylene
- antistatic
- ageing
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses antistatic anti-aging polyethylene master batch and a preparation method thereof. The master batch comprises following components by weight: 20-50% of polyethylene resin, 10-40% of an antistatic agent, 15-20% of a light stabilizer, 10-40% of a filling material, 1-3% of an antioxidant, 0.5-2% of a coupling agent, 1-3% of a dispersant and 0.1-1% of other auxiliary agents. Beneficial effects of the master batch and the preparation method are that: compared with the prior art, the master batch has an antistatic function and an anti-aging function, and is good in processing performance, low in cost and convenient to use; the master batch maintains high material tensile strength, impact strength and heat resistance; and the surface resistance of a polyethylene product adopting the master batch can reach 107-109 ohm*m.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of antistatic ageing-resistant polyethylene master batch and preparation method thereof.
Background technology
Polyethylene (PE) has light weight, the feature that nontoxic, forming process is easy, the ratio of performance to price is high, is all widely used in a lot of fields, is the general-purpose plastics of consumption second in the world.But polyethylene is more aging, particularly illumination or in the situation that being heated aging speed faster, there is extremely important meaning so improve polyethylene ageing-resistant performance.Because polyethylene belongs to electrically insulating material, its surface easily produces static, brings potential safety hazard to actual production simultaneously.
Summary of the invention
The object of the present invention is to provide a kind of antistatic property lasting, efficient and there is antistatic ageing-resistant polyethylene master batch of good ageing-resistant performance and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: antistatic ageing-resistant polyethylene master batch, its component by mass percent proportioning is: polyvinyl resin 20%～50%, static inhibitor 10%～40%, photostabilizer 15%～20%, filler 10%～40%, oxidation inhibitor 1%～3%, coupling agent 0.5%～2%, dispersion agent 1%～3%, other auxiliary agent 0.1%～1%.
Described static inhibitor is stearic acid monoglycerides, stearyl trimethyl quaternary ammonium salt, stearamide propyl hydroxyethyl quaternary amine nitrate, to one or more the mixture in Nonylphenoxy propyl sulfonic acid sodium, alkyl two (α-ethylol amine phosphoric acid ester), alkyl dicarboxyl ammonium methyl second lactone.
Described photostabilizer is the one in hindered amines Polymeric stabilizer, Benzotriazole Ultraviolet Stabilizer, benzophenone UV light absorber, two (3,5-di-tert-butyl-4-hydroxyl benzyl phosphonic acids mono ethyl ester) nickel.
Described filler is nano level talcum powder.
Described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
Described coupling agent is silane coupling agent or aluminium titanium composite coupler.
Described dispersion agent is low-molecular polyethylene wax.
Other described auxiliary agent is softening agent and colorant.
The preparation method of above-mentioned antistatic ageing-resistant polyethylene master batch, comprises the following steps:
(1) take by weight ratio filler and coupling agent, add in super mixer and mix, temperature is 80 DEG C～100 DEG C, mixing time is 10～30 minutes, obtain the filler that surface activation process is good, then add the polyvinyl resin, static inhibitor, photostabilizer, oxidation inhibitor, dispersion agent and other auxiliary agent that take by weight ratio, continue to mix 15～20 minutes;
(2) add twin screw extruder to carry out melting mixing the above-mentioned material mixing, then extrude, cooling, granulation, dry, packaging, obtain antistatic ageing-resistant polyethylene master batch of the present invention.
The invention has the beneficial effects as follows, compared with prior art, the antistatic ageing-resistant polyethylene master batch that the present invention makes, with antistatic and ageing-resistant function, and good processability, with low cost, easy to use, and maintain higher tensile strength of material, shock strength and resistance toheat, can reach 10 in the surface resistivity that is applied to polyethylene products
7～10
9Ω m.
Embodiment
Further illustrate technical scheme of the present invention below in conjunction with specific embodiment.
Embodiment 1:
A kind of antistatic ageing-resistant polyethylene master batch, its component by mass percent proportioning is: compound 2%, silane coupling agent 1.5%, low-molecular polyethylene wax 2%, other auxiliary agent 0.5% of polyvinyl resin 21%, stearic acid monoglycerides 25%, hindered amines Polymeric stabilizer 18%, nano level talcum powder 30%, hindered phenol antioxygen 1010 and phosphite ester kind antioxidant 168.Wherein, other described auxiliary agent is softening agent and colorant.
Preparation method: (1) takes nano level talcum powder and silane coupling agent by weight ratio, add in super mixer and mix, temperature is 80 DEG C～100 DEG C, mixing time is 10～30 minutes, obtain the nano level talcum powder that surface activation process is good, then the compound, low-molecular polyethylene wax and other auxiliary agent that add the polyvinyl resin, stearic acid monoglycerides, hindered amines Polymeric stabilizer, hindered phenol antioxygen 1010 and the phosphite ester kind antioxidant 168 that take by weight ratio, continue to mix 15～20 minutes; (2) add twin screw extruder to carry out melting mixing the above-mentioned material mixing, then extrude, cooling, granulation, dry, packaging, obtain antistatic ageing-resistant polyethylene master batch of the present invention.
Embodiment 2:
A kind of antistatic ageing-resistant polyethylene master batch, its component by mass percent proportioning is: compound 3%, aluminium titanium composite coupler 1%, low-molecular polyethylene wax 2%, other auxiliary agent 1% of polyvinyl resin 30%, stearyl trimethyl quaternary ammonium salt 15%, benzophenone UV light absorber 20%, nano level talcum powder 28%, hindered phenol antioxygen 1076 and phosphite ester kind antioxidant 168.Wherein, other described auxiliary agent is softening agent and colorant.
Preparation method: (1) takes nano level talcum powder and aluminium titanium composite coupler by weight ratio, add in super mixer and mix, temperature is 80 DEG C～100 DEG C, mixing time is 10～30 minutes, obtain the nano level talcum powder that surface activation process is good, then the compound, low-molecular polyethylene wax and other auxiliary agent that add the polyvinyl resin, stearyl trimethyl quaternary ammonium salt, benzophenone UV light absorber, hindered phenol antioxygen 1076 and the phosphite ester kind antioxidant 168 that take by weight ratio, continue to mix 15～20 minutes; (2) add twin screw extruder to carry out melting mixing the above-mentioned material mixing, then extrude, cooling, granulation, dry, packaging, obtain antistatic ageing-resistant polyethylene master batch of the present invention.
Claims (9)
1. an antistatic ageing-resistant polyethylene master batch, it is characterized in that, its component by mass percent proportioning is: polyvinyl resin 20%～50%, static inhibitor 10%～40%, photostabilizer 15%～20%, filler 10%～40%, oxidation inhibitor 1%～3%, coupling agent 0.5%～2%, dispersion agent 1%～3%, other auxiliary agent 0.1%～1%.
2. antistatic ageing-resistant polyethylene master batch according to claim 1, it is characterized in that, described static inhibitor is stearic acid monoglycerides, stearyl trimethyl quaternary ammonium salt, stearamide propyl hydroxyethyl quaternary amine nitrate, to one or more the mixture in Nonylphenoxy propyl sulfonic acid sodium, alkyl two (α-ethylol amine phosphoric acid ester), alkyl dicarboxyl ammonium methyl second lactone.
3. antistatic ageing-resistant polyethylene master batch according to claim 1, it is characterized in that, described photostabilizer is the one in hindered amines Polymeric stabilizer, Benzotriazole Ultraviolet Stabilizer, benzophenone UV light absorber, two (3,5-di-tert-butyl-4-hydroxyl benzyl phosphonic acids mono ethyl ester) nickel.
4. antistatic ageing-resistant polyethylene master batch according to claim 1, is characterized in that, described filler is nano level talcum powder.
5. antistatic ageing-resistant polyethylene master batch according to claim 1, is characterized in that, described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
6. antistatic ageing-resistant polyethylene master batch according to claim 1, is characterized in that, described coupling agent is silane coupling agent or aluminium titanium composite coupler.
7. antistatic ageing-resistant polyethylene master batch according to claim 1, is characterized in that, described dispersion agent is low-molecular polyethylene wax.
8. antistatic ageing-resistant polyethylene master batch according to claim 1, is characterized in that, other described auxiliary agent is softening agent and colorant.
9. the preparation method of antistatic ageing-resistant polyethylene master batch according to claim 1, is characterized in that, comprises the following steps:
(1) take by weight ratio filler and coupling agent, add in super mixer and mix, temperature is 80 DEG C～100 DEG C, mixing time is 10～30 minutes, obtain the filler that surface activation process is good, then add the polyvinyl resin, static inhibitor, photostabilizer, oxidation inhibitor, dispersion agent and other auxiliary agent that take by weight ratio, continue to mix 15～20 minutes;
(2) add twin screw extruder to carry out melting mixing the above-mentioned material mixing, then extrude, cooling, granulation, dry, packaging, obtain antistatic ageing-resistant polyethylene master batch of the present invention.
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| CN201210560812.2A CN103881195A (en) | 2012-12-21 | 2012-12-21 | Antistatic anti-aging polyethylene master batch and preparation method thereof |
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| CN201210560812.2A CN103881195A (en) | 2012-12-21 | 2012-12-21 | Antistatic anti-aging polyethylene master batch and preparation method thereof |
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Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106188820A (en) * | 2016-08-25 | 2016-12-07 | 芜湖市天雄新材料科技有限公司 | A kind of environment-friendly shopping bag plastic master batch of biodegradable |
| CN106349548A (en) * | 2016-09-12 | 2017-01-25 | 苏州清丰兴业塑胶有限公司 | Ultraviolet-light-resistant polyethylene functional master batch |
| CN106398100A (en) * | 2016-09-30 | 2017-02-15 | 美的集团股份有限公司 | Anti-static and easy-to-clean material and preparation method thereof |
| CN106398101A (en) * | 2016-09-30 | 2017-02-15 | 美的集团股份有限公司 | Antistatic easy-to-clean material and preparation method thereof |
| CN106479109A (en) * | 2016-09-30 | 2017-03-08 | 美的集团股份有限公司 | A kind of antistatic non-sticky putty material and preparation method thereof |
| CN108359161A (en) * | 2018-03-16 | 2018-08-03 | 青岛中隆科技股份有限公司 | A kind of environmentally-friendly EPE pearl wool master batch and preparation method thereof |
| CN108440820A (en) * | 2018-03-15 | 2018-08-24 | 苏州新区特氟龙塑料制品厂 | A kind of novel antistatic environmentally-friendly plastic |
| CN109335270A (en) * | 2018-08-27 | 2019-02-15 | 浙江正庄实业有限公司 | Antiultraviolet antistatic emulsion pumps and preparation method thereof |
| CN109335269A (en) * | 2018-08-27 | 2019-02-15 | 浙江正庄实业有限公司 | Degradable oil pump of antiultraviolet and preparation method thereof |
| CN109553839A (en) * | 2018-12-20 | 2019-04-02 | 合肥旭弘塑胶制品有限公司 | A kind of anti-static plastic master batch |
| CN109824963A (en) * | 2019-03-08 | 2019-05-31 | 上海魔核新材料科技有限公司 | A kind of anti-aging master batch |
| CN110092924A (en) * | 2019-05-31 | 2019-08-06 | 朱登年 | Antibacterial polyethylene master batch and its production technology |
| CN110591204A (en) * | 2019-09-28 | 2019-12-20 | 武汉鑫恒顺科技有限公司 | Antistatic weather-resistant anti-adhesion color master batch for PE (polyethylene) film |
| CN110885502A (en) * | 2019-12-13 | 2020-03-17 | 天津金发新材料有限公司 | Low-emission precipitation-resistant antistatic talcum powder filled polypropylene material and preparation method thereof |
| CN111057292A (en) * | 2019-12-30 | 2020-04-24 | 纳琳威纳米科技南通有限公司 | Nanometer anti-aging master batch |
| CN111205545A (en) * | 2020-03-20 | 2020-05-29 | 宿迁联盛科技股份有限公司 | Method for preventing auxiliary agent in polyethylene aging-resistant master batch from being separated out |
| CN112225970A (en) * | 2020-09-26 | 2021-01-15 | 九天起宏(江苏)检测有限公司 | Modified polyethylene insulating material and preparation method thereof |
| CN112812427A (en) * | 2020-12-31 | 2021-05-18 | 苏州度辰新材料有限公司 | Photoluminescent color-changing polyolefin master batch and preparation method thereof |
| CN113831637A (en) * | 2021-09-16 | 2021-12-24 | 宿迁联盛科技股份有限公司 | Anti-aging master batch for flat filament product and preparation method thereof |
| CN115286860A (en) * | 2022-09-15 | 2022-11-04 | 青岛赛诺新材料有限公司 | Polyethylene master batch and preparation method and application thereof |
-
2012
- 2012-12-21 CN CN201210560812.2A patent/CN103881195A/en active Pending
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106188820A (en) * | 2016-08-25 | 2016-12-07 | 芜湖市天雄新材料科技有限公司 | A kind of environment-friendly shopping bag plastic master batch of biodegradable |
| CN106349548A (en) * | 2016-09-12 | 2017-01-25 | 苏州清丰兴业塑胶有限公司 | Ultraviolet-light-resistant polyethylene functional master batch |
| CN106479109A (en) * | 2016-09-30 | 2017-03-08 | 美的集团股份有限公司 | A kind of antistatic non-sticky putty material and preparation method thereof |
| CN106398100A (en) * | 2016-09-30 | 2017-02-15 | 美的集团股份有限公司 | Anti-static and easy-to-clean material and preparation method thereof |
| CN106479109B (en) * | 2016-09-30 | 2020-04-24 | 美的集团股份有限公司 | Antistatic non-dusting material and preparation method thereof |
| CN106398100B (en) * | 2016-09-30 | 2020-02-21 | 美的集团股份有限公司 | Antistatic easy-cleaning material and preparation method thereof |
| CN106398101A (en) * | 2016-09-30 | 2017-02-15 | 美的集团股份有限公司 | Antistatic easy-to-clean material and preparation method thereof |
| CN108440820A (en) * | 2018-03-15 | 2018-08-24 | 苏州新区特氟龙塑料制品厂 | A kind of novel antistatic environmentally-friendly plastic |
| CN108359161A (en) * | 2018-03-16 | 2018-08-03 | 青岛中隆科技股份有限公司 | A kind of environmentally-friendly EPE pearl wool master batch and preparation method thereof |
| CN109335269A (en) * | 2018-08-27 | 2019-02-15 | 浙江正庄实业有限公司 | Degradable oil pump of antiultraviolet and preparation method thereof |
| CN109335270A (en) * | 2018-08-27 | 2019-02-15 | 浙江正庄实业有限公司 | Antiultraviolet antistatic emulsion pumps and preparation method thereof |
| CN109335269B (en) * | 2018-08-27 | 2024-03-15 | 浙江正庄实业有限公司 | Ultraviolet-proof degradable oil pump and preparation method thereof |
| CN109335270B (en) * | 2018-08-27 | 2024-01-12 | 浙江正庄实业有限公司 | Ultraviolet-proof and antistatic emulsion pump and preparation method thereof |
| CN109553839A (en) * | 2018-12-20 | 2019-04-02 | 合肥旭弘塑胶制品有限公司 | A kind of anti-static plastic master batch |
| CN109824963A (en) * | 2019-03-08 | 2019-05-31 | 上海魔核新材料科技有限公司 | A kind of anti-aging master batch |
| CN110092924A (en) * | 2019-05-31 | 2019-08-06 | 朱登年 | Antibacterial polyethylene master batch and its production technology |
| CN110591204A (en) * | 2019-09-28 | 2019-12-20 | 武汉鑫恒顺科技有限公司 | Antistatic weather-resistant anti-adhesion color master batch for PE (polyethylene) film |
| CN110885502A (en) * | 2019-12-13 | 2020-03-17 | 天津金发新材料有限公司 | Low-emission precipitation-resistant antistatic talcum powder filled polypropylene material and preparation method thereof |
| CN111057292A (en) * | 2019-12-30 | 2020-04-24 | 纳琳威纳米科技南通有限公司 | Nanometer anti-aging master batch |
| CN111205545A (en) * | 2020-03-20 | 2020-05-29 | 宿迁联盛科技股份有限公司 | Method for preventing auxiliary agent in polyethylene aging-resistant master batch from being separated out |
| CN112225970A (en) * | 2020-09-26 | 2021-01-15 | 九天起宏(江苏)检测有限公司 | Modified polyethylene insulating material and preparation method thereof |
| CN112812427A (en) * | 2020-12-31 | 2021-05-18 | 苏州度辰新材料有限公司 | Photoluminescent color-changing polyolefin master batch and preparation method thereof |
| CN113831637A (en) * | 2021-09-16 | 2021-12-24 | 宿迁联盛科技股份有限公司 | Anti-aging master batch for flat filament product and preparation method thereof |
| CN115286860A (en) * | 2022-09-15 | 2022-11-04 | 青岛赛诺新材料有限公司 | Polyethylene master batch and preparation method and application thereof |
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Application publication date: 20140625 |