CN106188820A - A kind of environment-friendly shopping bag plastic master batch of biodegradable - Google Patents
A kind of environment-friendly shopping bag plastic master batch of biodegradable Download PDFInfo
- Publication number
- CN106188820A CN106188820A CN201610717768.XA CN201610717768A CN106188820A CN 106188820 A CN106188820 A CN 106188820A CN 201610717768 A CN201610717768 A CN 201610717768A CN 106188820 A CN106188820 A CN 106188820A
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- parts
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- master batch
- shopping bag
- biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses the environment-friendly shopping bag plastic master batch of a kind of biodegradable, including the component of following mass fraction: heavy calcium carbonate 12 16 parts, liquid paraffin 46 parts, ethylene methyl acrylate copolymer 16 18 parts, linear polyethylene 12 14 parts, high density polyethylene (HDPE) 8 10 parts, Low Density Polyethylene 25 parts, lubricant 25 parts, coupling agent 0.1 5 parts, plasticizer 1 10 parts, dispersant 0.1 5 parts, filler 15 40 parts, 0.5 2 parts of antioxidant, dispersant 0.5 5 parts.The master batch of the present invention adjustment by component so that the starch-based degradable shopping bag with it as master batch has enough intensity and toughness and deflection, meets and uses requirement.
Description
Technical field
The invention belongs to technical field of polymer materials, particularly relate to the environment-friendly shopping bag plastics of a kind of biodegradable
Master batch.
Background technology
The shopping bag that supermarket, market, country fair etc. provide is essentially all employing polystyrene, polyethylene, polypropylene
Make Deng polymeric material, owing to they cannot be degraded, ecological environment is done great damage, threaten the sky of human survival
Between, people are referred to as " white pollution ".To this end, general office of State Council of the People's Republic of China has issued " uses plastics about limiting production and sales
The notice of shopping bag ".According to notice, in view of shopping bag becomes the main source of " white pollution ", from now on various places people civil administration
Mansion, ministries and commissions etc. should forbid producing, selling and uying super-thin plastic shopping bag and carrying out plastic shopping bag Paid Use System.From
On June 1st, 2008 rises, and to carry out plastic shopping bag paid in commodity retail place in all supermarkets, market, country fair etc.
Land use reform, must not provide free plastic shopping bag without exception.Although paid utilization limits a number of shopping bag, but purchases
The pollution problem of thing bag itself does not the most have been resolved.
To this end, people gradually start to study degradable package bag, increasing degradative plastics goods start to emerge in large numbers.
But, current degradation products is constantly present such or such deficiency.The most is to use petroleum-based plastics to gather
Olefin material is that carrier prepares degradative plastics, or uses the polylactic acid-based macromolecular material prepared from natural materials to carry
The biological degradability of high degradative plastics, but, after processing, the heat resistance of material is not enough, it is difficult to the use meeting shopping bag is wanted
Ask, and the cost of polylactic acid is higher.
Summary of the invention
Goal of the invention: the present invention is directed to deficiency of the prior art, proposes the environment-friendly shopping bag of a kind of biodegradable
Plastic master batch.
Technical scheme: the environment-friendly shopping bag plastic master batch of a kind of biodegradable of the present invention, including following matter
The component of amount number:
Heavy calcium carbonate 12-16 part, liquid paraffin 4-6 part, ethylene-methyl acrylate copolymer 16-18 part, linearly gather
Ethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 2-5 part, lubricant 2-5 part, coupling agent 0.1-5
Part, plasticizer 1-10 part, dispersant 0.1-5 part, filler 15-40 part, antioxidant 0.5-2 part, dispersant 0.5-5 part.
Further, including the component of following mass fraction:
Heavy calcium carbonate 14-16 part, liquid paraffin 5-6 part, ethylene-methyl acrylate copolymer 17-18 part, linearly gather
Ethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 3-5 part, lubricant 3-5 part, coupling agent 3-5 part,
Plasticizer 2-10 part, dispersant 3-5 part, filler 20-40 part, antioxidant 1-2 part, dispersant 3-5 part.
Further, including the component of following mass fraction:
Heavy calcium carbonate 15 parts, liquid paraffin 5.5 parts, ethylene-methyl acrylate copolymer 17 parts, linear polyethylene 13
Part, high density polyethylene (HDPE) 9 parts, Low Density Polyethylene 4 parts, lubricant 4 parts, coupling agent 4 parts, plasticizer 6 parts, dispersant 4 parts, fill out
Expect 30 parts, 1 part of antioxidant, dispersant 4 parts.
Further, described coupling agent is silane coupler or aluminate coupling agent.
Further, described dispersant is grafting EBA dispersant.
Further, described lubricant is stearic acid, oleamide or erucyl amide
Further, the one or more combination thing during described plasticizer is ethylene glycol, glycerol, carbamide.
Beneficial effect: the master batch of the present invention adjustment by component so that the starch-based degradable shopping bag with it as master batch
There is enough intensity and toughness and deflection, meet and use requirement.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described:
Embodiment 1
A kind of environment-friendly shopping bag plastic master batch of biodegradable, including the component of following mass fraction:
Heavy calcium carbonate 12 parts, liquid paraffin 4 parts, ethylene-methyl acrylate copolymer 16 parts, linear polyethylene 12
Part, high density polyethylene (HDPE) 8 parts, Low Density Polyethylene 2 parts, lubricant 2 parts, coupling agent 0.1 part, plasticizer 1 part, dispersant
0.1 part, filler 15 parts, 0.5 part of antioxidant, dispersant 0.5 part.
Described coupling agent is silane coupler or aluminate coupling agent.
Described dispersant is grafting EBA dispersant.
Described lubricant is stearic acid, oleamide or erucyl amide
Described plasticizer is the one or more combination thing in ethylene glycol, glycerol, carbamide.
Embodiment 2
A kind of environment-friendly shopping bag plastic master batch of biodegradable, including the component of following mass fraction:
Heavy calcium carbonate 16 parts, liquid paraffin 6 parts, ethylene-methyl acrylate copolymer 18 parts, linear polyethylene 14
Part, high density polyethylene (HDPE) 10 parts, Low Density Polyethylene 5 parts, lubricant 5 parts, coupling agent 5 parts, plasticizer 10 parts, dispersant
5 parts, filler 40 parts, 2 parts of antioxidant, dispersant 5 parts.
Described coupling agent is silane coupler or aluminate coupling agent.
Described dispersant is grafting EBA dispersant.
Described lubricant is stearic acid, oleamide or erucyl amide
Described plasticizer is the one or more combination thing in ethylene glycol, glycerol, carbamide.
Embodiment 3
A kind of environment-friendly shopping bag plastic master batch of biodegradable, including the component of following mass fraction:
Heavy calcium carbonate 15 parts, liquid paraffin 5.5 parts, ethylene-methyl acrylate copolymer 17 parts, linear polyethylene 13
Part, high density polyethylene (HDPE) 9 parts, Low Density Polyethylene 4 parts, lubricant 4 parts, coupling agent 4 parts, plasticizer 6 parts, dispersant 4 parts, fill out
Expect 30 parts, 1 part of antioxidant, dispersant 4 parts.
Described coupling agent is silane coupler or aluminate coupling agent.
Described dispersant is grafting EBA dispersant.
Described lubricant is stearic acid, oleamide or erucyl amide
Described plasticizer is the one or more combination thing in ethylene glycol, glycerol, carbamide.
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, though
So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people being familiar with this specialty
Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above makes a little change or modification
For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention
Any simple modification, equivalent variations and the modification being made above example, all still falls within the range of technical solution of the present invention.
Claims (7)
1. the environment-friendly shopping bag plastic master batch of a biodegradable, it is characterised in that: include the component of following mass fraction:
Heavy calcium carbonate 12-16 part, liquid paraffin 4-6 part, ethylene-methyl acrylate copolymer 16-18 part, linearly gather
Ethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 2-5 part, lubricant 2-5 part, coupling agent 0.1-5
Part, plasticizer 1-10 part, dispersant 0.1-5 part, filler 15-40 part, antioxidant 0.5-2 part, dispersant 0.5-5 part.
The environment-friendly shopping bag plastic master batch of a kind of biodegradable the most according to claim 1, it is characterised in that: include
The component of following mass fraction:
Heavy calcium carbonate 14-16 part, liquid paraffin 5-6 part, ethylene-methyl acrylate copolymer 17-18 part, linearly gather
Ethylene 12-14 part, high density polyethylene (HDPE) 8-10 part, Low Density Polyethylene 3-5 part, lubricant 3-5 part, coupling agent 3-5 part,
Plasticizer 2-10 part, dispersant 3-5 part, filler 20-40 part, antioxidant 1-2 part, dispersant 3-5 part.
The environment-friendly shopping bag plastic master batch of a kind of biodegradable the most according to claim 1, it is characterised in that: include
The component of following mass fraction:
Heavy calcium carbonate 15 parts, liquid paraffin 5.5 parts, ethylene-methyl acrylate copolymer 17 parts, linear polyethylene 13
Part, high density polyethylene (HDPE) 9 parts, Low Density Polyethylene 4 parts, lubricant 4 parts, coupling agent 4 parts, plasticizer 6 parts, dispersant 4 parts, fill out
Expect 30 parts, 1 part of antioxidant, dispersant 4 parts.
The environment-friendly shopping bag plastic master batch of a kind of biodegradable the most according to claim 1, it is characterised in that: described
Coupling agent is silane coupler or aluminate coupling agent.
The environment-friendly shopping bag plastic master batch of a kind of biodegradable the most according to claim 1, it is characterised in that: described
Dispersant is grafting EBA dispersant.
The environment-friendly shopping bag plastic master batch of a kind of biodegradable the most according to claim 1, it is characterised in that: described
Lubricant is stearic acid, oleamide or erucyl amide.
The environment-friendly shopping bag plastic master batch of a kind of biodegradable the most according to claim 1, it is characterised in that: described
Plasticizer is the one or more combination thing in ethylene glycol, glycerol, carbamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610717768.XA CN106188820A (en) | 2016-08-25 | 2016-08-25 | A kind of environment-friendly shopping bag plastic master batch of biodegradable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610717768.XA CN106188820A (en) | 2016-08-25 | 2016-08-25 | A kind of environment-friendly shopping bag plastic master batch of biodegradable |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106188820A true CN106188820A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610717768.XA Pending CN106188820A (en) | 2016-08-25 | 2016-08-25 | A kind of environment-friendly shopping bag plastic master batch of biodegradable |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189219A (en) * | 2017-06-30 | 2017-09-22 | 南宁东印时代广告有限公司 | Shopping bag |
| CN107686588A (en) * | 2017-09-30 | 2018-02-13 | 安徽省天乐塑业有限公司 | A kind of high-intensity polyethylene film |
| CN117603522A (en) * | 2024-01-23 | 2024-02-27 | 四川腾达峰橡塑科技有限公司 | Full-biodegradation plastic master batch and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1756766A (en) * | 2003-03-03 | 2006-04-05 | 澳大利亚聚合物股份有限公司 | Dispersing agents in nanocomposites |
| CN103819803A (en) * | 2012-11-16 | 2014-05-28 | 无锡市黄盛包装制品有限公司 | Preparation method of plastic master batch for degradable environment-friendly shopping bag |
| CN103881195A (en) * | 2012-12-21 | 2014-06-25 | 青岛欣展塑胶有限公司 | Antistatic anti-aging polyethylene master batch and preparation method thereof |
-
2016
- 2016-08-25 CN CN201610717768.XA patent/CN106188820A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1756766A (en) * | 2003-03-03 | 2006-04-05 | 澳大利亚聚合物股份有限公司 | Dispersing agents in nanocomposites |
| CN103819803A (en) * | 2012-11-16 | 2014-05-28 | 无锡市黄盛包装制品有限公司 | Preparation method of plastic master batch for degradable environment-friendly shopping bag |
| CN103881195A (en) * | 2012-12-21 | 2014-06-25 | 青岛欣展塑胶有限公司 | Antistatic anti-aging polyethylene master batch and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189219A (en) * | 2017-06-30 | 2017-09-22 | 南宁东印时代广告有限公司 | Shopping bag |
| CN107686588A (en) * | 2017-09-30 | 2018-02-13 | 安徽省天乐塑业有限公司 | A kind of high-intensity polyethylene film |
| CN117603522A (en) * | 2024-01-23 | 2024-02-27 | 四川腾达峰橡塑科技有限公司 | Full-biodegradation plastic master batch and preparation method and application thereof |
| CN117603522B (en) * | 2024-01-23 | 2024-03-29 | 四川腾达峰橡塑科技有限公司 | Full-biodegradation plastic master batch and preparation method and application thereof |
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Application publication date: 20161207 |
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