CN103865482B - Mineral grinding aid and application thereof - Google Patents
Mineral grinding aid and application thereof Download PDFInfo
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- CN103865482B CN103865482B CN201410112235.XA CN201410112235A CN103865482B CN 103865482 B CN103865482 B CN 103865482B CN 201410112235 A CN201410112235 A CN 201410112235A CN 103865482 B CN103865482 B CN 103865482B
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- grinding aid
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Abstract
The invention discloses a kind of mineral grinding aid, belong to mineral and pulverize field, this mineral grinding aid is grouped into by the following one-tenth counted in mass ratio: water glass 10-40%; Sodium hexametaphosphate 99 5-25%; Trolamine 5-25%; All the other are water.This mineral grinder is preferred for iron ore, gold mine, Pb-Zn deposits, copper mine at the fine grinding in ball milling stage, and when refining, the quality adding described mineral grinding aid is treat the 0.05-1.2% of ore grinding amount.Adopt this mineral grinding aid, under identical raw ore condition, add grinding aid of the present invention, can not considerable influence be produced to ore grade, and the productive rate of concentrate has and significantly promotes, improve more than 13%, the concentrate rate of recovery also significantly promotes, improve more than 39%, mill efficiency significantly improves.The percentage composition that simultaneously in concentrate, particle diameter is less than the particle of 75 μm adds about 10%.In addition, decrease the consumption of electric energy equal energy source, reduce the wearing and tearing frequency of ball-grinding machine.
Description
Technical field
The present invention relates to mineral and grind field, particularly a kind of mineral grinding aid and application thereof.
Background technology
In mineral products field, usually need ore to be carried out pulverizing to reduce the granularity of ore from the ore dressing of the ore of mine excavation, for ore dressing process exposes required mineral surface.
Grinding is a kind of common method of ore grinding.Ore powder is in crushing process, along with the fragmentation of particle, fine particle, at formation illusion macrobead together of reuniting, makes process of lapping become difficulty, the balance even forming grinding and reunite, extra-fine grinding cannot be realized, ore grain size below 10 μm, often increases by 1% in breeze, and its ore grinding time will increase by 2%, the wearing and tearing of power consumption and steel ball liner plate, all corresponding increase by 2%.Thus cause mill efficiency to decline rapidly.In order to improve this situation, this area often adds grinding aid.
Existing grinding aid usually comprises following kind: one is alcohols material, such as ethylene glycol, propylene glycol etc., two is amine substances, as trolamine, tri-isopropanolamine, acid amides etc., three is unsaturated fatty acids materials, such as stearic acid, oleic acid etc., four is salts substances, such as Sodium hexametaphosphate 99, sodium stearate etc., five is mineral substance materials, such as talcum powder, flyash, coke, coal etc., other also comprise the interpolymer, melamine formaldehyde (MF), maleic anhydride derivative etc. of styrenic, and the single or mixture of mentioned kind is as grinding aid often.Although existing grinding aid can improve mill efficiency to a certain extent, its effect is still undesirable, there is very large room for promotion.
Summary of the invention
Goal of the invention of the present invention is: for above-mentioned Problems existing, provides a kind of mineral grinding aid that can significantly improve mill efficiency.
The technical solution used in the present invention is such: a kind of mineral grinding aid, is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99 5-25%; Trolamine 5-25%; All the other are water.
Contriver studies discovery, in mineral powder breakdown mill process, usually can be subject to the effect of different sorts stress, causes material form crackle and expand, is then pulverized.According to lattice Lifei law, the minimum stress needed for brittle rupture is directly proportional to the specific surface energy of material.Obviously, reduce the surface energy of particle, can reduce and make its required stress that ruptures.From the process of ore particles fracture, above-mentioned mineral grinding aid molecule can reduce the external stress needed for crack propagation in the absorption of fresh surface, promotes the expansion of crackle.So say from this point, the chemical substance that can reduce solid surface energy can reduce the intensity of particle, thus can improve crush efficiency or reduce Grin-ding energ7.
Above-mentioned have between surface-active its composition of mineral grinding aid mutually work in coordination with, surface energy can be eliminated, reduce the reunion of fine particle in process of lapping, after employing grouping screening measure, granularity can be met the requirements of mineral and send to choosing point in time, the mineral making granularity not reach requirement are got back to grinding machine and are regrinded, and both improve concentrate grade like this, turn improve the mill efficiency of grinding machine and the rate of recovery of concentrate.Meanwhile, also just decrease energy consumption, reduce the wearing and tearing frequency of ball-grinding machine.
As preferred technical scheme, this mineral grinding aid is grouped into by the following one-tenth counted in mass ratio:
Water glass 20%; Sodium hexametaphosphate 99 10%; Trolamine 10%; All the other are water.
Adopt the grinding aid that the component of this ratio obtains, the rate of recovery of its mill efficiency and concentrate is higher.
As preferred technical scheme, this mineral grinding aid is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99: 5-25%; Trolamine: 5-25%; Tripoly phosphate sodium STPP 3 ~ 10%; All the other are water.
On the basis of aforementioned three kinds of compositions, add the tripoly phosphate sodium STPP of proper ratio, mill efficiency and the concentrate rate of recovery can be improved further.
As further preferred technical scheme, this mineral grinding aid is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99: 5-25%; Trolamine: 5-25%; Tripoly phosphate sodium STPP 3 ~ 10%; Multi-amidocyanogen sodium phosphate 3 ~ 10%; All the other are water.
On the basis of aforementioned four kinds of compositions, add the polyamino Alendronate of proper ratio, mill efficiency and the concentrate rate of recovery can be improved further.
As further preferred technical scheme, this mineral grinding aid is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99: 5-25%; Trolamine: 5-25%; Tripoly phosphate sodium STPP 3 ~ 10%; Multi-amidocyanogen sodium phosphate 3 ~ 10%; Calcium lignin sulphonate 1 ~ 5%; All the other are water.
On the basis of aforementioned five kinds of compositions, add the calcium lignin sulphonate of proper ratio, mill efficiency and the concentrate rate of recovery can reach more excellent.
Water glass of the present invention is preferably liquid sodium silicate.
The present invention also provides the application of above-mentioned mineral grinding aid, and the technical scheme of employing is: described mineral grinding aid is used for iron ore, gold mine, Pb-Zn deposits, copper mine at the fine grinding in ball milling stage.
As preferred technical scheme: when refining, the quality adding described mineral grinding aid is treat the 0.05-1.2% of ore grinding amount.
In sum, owing to have employed technique scheme, the invention has the beneficial effects as follows: under identical raw ore condition, add grinding aid of the present invention, considerable influence can not be produced to ore grade, and the productive rate of concentrate has and significantly promotes, improve more than 13%, the concentrate rate of recovery also significantly promotes, improve more than 39%, mill efficiency significantly improves.The particle that in concentrate, particle diameter is less than 75 μm simultaneously, namely the percentage composition of the particle of "-75 μm " adds about 10%.In addition, decrease the consumption of electric energy equal energy source, reduce the wearing and tearing frequency of ball-grinding machine.
Embodiment
The present invention is described in detail below.
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1:
A kind of mineral grinding aid, its preparation method is: by by mass percentage 10% liquid sodium silicate, the Sodium hexametaphosphate 99 of 5%, the trolamine of 5%, all the other be water, and in stirred pot, stirring 120 minutes, stirs, to obtain final product.
Embodiment 2:
By the liquid sodium silicate of 20wt%, the Sodium hexametaphosphate 99 of 10wt%, the trolamine of 10wt%, all the other are water, stir 120 minutes, stir as solvent in stirred pot.
Embodiment 3:
By the liquid sodium silicate of 30wt%, the Sodium hexametaphosphate 99 of 20wt%, the trolamine of 20wt%, all the other are water, stir 120 minutes, stir as solvent in stirred pot.
Embodiment 4:
By the liquid sodium silicate of 40wt%, the Sodium hexametaphosphate 99 of 25wt%, the trolamine of 25wt%, all the other are water, stir 120 minutes, stir as solvent in stirred pot.
Embodiment 5:
By the liquid sodium silicate of 20wt%, the Sodium hexametaphosphate 99 of 10wt%, the trolamine of 10wt%, tripoly phosphate sodium STPP 3wt%, multi-amidocyanogen sodium phosphate 3wt%, calcium lignin sulphonate 1wt% all the other be water, in stirred pot, stir 120 minutes as solvent, stir.
Embodiment 6:
By the liquid sodium silicate of 20wt%, the Sodium hexametaphosphate 99 of 10wt%, the trolamine of 10wt%, tripoly phosphate sodium STPP 6wt%, multi-amidocyanogen sodium phosphate 6wt%, calcium lignin sulphonate 2wt%, all the other are water, stir 120 minutes, stir as solvent in stirred pot.
Embodiment 7:
By the liquid sodium silicate of 20wt%, the Sodium hexametaphosphate 99 of 10wt%, the trolamine of 10wt%, tripoly phosphate sodium STPP 10wt%, multi-amidocyanogen sodium phosphate 10wt%, calcium lignin sulphonate 5wt%, all the other are water, stir 120 minutes, stir as solvent in stirred pot.
Embodiment 8
The experiment of ore fine grinding
By the grinding aid prepared by embodiment 1-7, add to and treat that in mill powdered iron ore, (consumption is 0.5% of powdered iron ore quality) carries out fine grinding contrast experiment.Test-results is as shown in table 1.
Table 1 combines the ore grinding result of grinding aid
As shown in Table 1, add before and after grinding aid under identical raw ore condition, can not considerable influence be produced to ore grade, and the productive rate of concentrate has and significantly promotes, improve more than 13%, the concentrate rate of recovery also significantly promotes, improve more than 39%, mill efficiency significantly improves.The particle that in concentrate, particle diameter is less than 75 μm simultaneously, namely the percentage composition of the particle of "-75 μm " adds about 10%.
Claims (7)
1. a mineral grinding aid, is characterized in that, is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99 5-25%; Trolamine 5-25%; All the other are water.
2. mineral grinding aid as claimed in claim 1, is characterized in that, be grouped into by the following one-tenth counted in mass ratio:
Water glass 20%; Sodium hexametaphosphate 99 10%; Trolamine 10%; All the other are water.
3. a mineral grinding aid, is characterized in that, is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99: 5-25%; Trolamine: 5-25%; Tripoly phosphate sodium STPP 3 ~ 10%; All the other are water.
4. a mineral grinding aid, is characterized in that, is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99: 5-25%; Trolamine: 5-25%; Tripoly phosphate sodium STPP 3 ~ 10%; Multi-amidocyanogen sodium phosphate 3 ~ 10%; All the other are water.
5. a mineral grinding aid, is characterized in that, is grouped into by the following one-tenth counted in mass ratio:
Water glass 10-40%; Sodium hexametaphosphate 99: 5-25%; Trolamine: 5-25%; Tripoly phosphate sodium STPP 3 ~ 10%; Multi-amidocyanogen sodium phosphate 3 ~ 10%; Calcium lignin sulphonate 1 ~ 5%; All the other are water.
6. the application of the mineral grinding aid described in claim 1-4 any one, is characterized in that: described mineral grinding aid is used for iron ore, gold mine, Pb-Zn deposits, copper mine at the fine grinding in ball milling stage.
7. apply as claimed in claim 6, it is characterized in that: when refining, the quality adding described mineral grinding aid is treat the 0.05-1.2% of ore grinding amount.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410112235.XA CN103865482B (en) | 2014-03-25 | 2014-03-25 | Mineral grinding aid and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410112235.XA CN103865482B (en) | 2014-03-25 | 2014-03-25 | Mineral grinding aid and application thereof |
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| CN103865482A CN103865482A (en) | 2014-06-18 |
| CN103865482B true CN103865482B (en) | 2015-08-19 |
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| CN201410112235.XA Expired - Fee Related CN103865482B (en) | 2014-03-25 | 2014-03-25 | Mineral grinding aid and application thereof |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104449569A (en) * | 2014-11-18 | 2015-03-25 | 桂林华越环保科技有限公司 | Mineral powder grinding aid |
| CN104449567B (en) * | 2014-11-18 | 2017-01-04 | 桂林华越环保科技有限公司 | A kind of breeze grinding aid being exclusively used in vertical grinding system |
| CN104479629B (en) * | 2014-11-19 | 2016-06-22 | 沈阳建筑大学 | A kind of Coaseries kaolin powder grinding aid |
| CN105733505B (en) * | 2014-12-09 | 2018-02-13 | 河南绿金矿业科技有限公司 | It is a kind of to have gold mine ore grinding grinding aid for helping leaching to act on and preparation method thereof concurrently |
| CN106513154A (en) * | 2016-11-03 | 2017-03-22 | 江苏省冶金设计院有限公司 | Ore-grinding magnetic separation additive and application thereof |
| CN107353875A (en) * | 2017-07-05 | 2017-11-17 | 鞍钢集团矿业有限公司 | A kind of iron ore grinding aid and its application method |
| CN108465551A (en) * | 2018-03-07 | 2018-08-31 | 鞍钢集团矿业有限公司 | Add the magnetic iron ore secondary grinding technique of grinding aid sodium tripolyphosphate |
| CN108993694A (en) * | 2018-07-05 | 2018-12-14 | 鞍钢集团矿业有限公司 | A kind of hematite grinding aid and application method |
| CN113213790B (en) * | 2021-06-03 | 2022-07-01 | 厦门美益建材有限公司 | Low hydration heat portland cement and preparation method thereof |
| CN116144324A (en) * | 2023-02-23 | 2023-05-23 | 湖南格林朗科技有限公司 | Synergistic liquid special for mineral separation and preparation method and application thereof |
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| CN1451624A (en) * | 2002-04-19 | 2003-10-29 | 尹小林 | Industrial waste residue activating grinding aid |
| CN101892031A (en) * | 2010-06-10 | 2010-11-24 | 赵淼 | Powder grinding addictive for coal-series hard kaoline |
| CN101942679A (en) * | 2010-10-25 | 2011-01-12 | 江苏技术师范学院 | Method for preparing, pre-treating and dispersing superfine copper powder |
| CN102108015A (en) * | 2011-03-09 | 2011-06-29 | 烟台大学 | Multi-functional environment-friendly grinding aid |
| WO2012102180A1 (en) * | 2011-01-27 | 2012-08-02 | 株式会社 フジミインコーポレーテッド | Polishing material and polishing composition |
| CN103058577A (en) * | 2013-01-18 | 2013-04-24 | 科之杰新材料集团有限公司 | Liquid compound reinforced type cement grinding aid and preparation method thereof |
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2014
- 2014-03-25 CN CN201410112235.XA patent/CN103865482B/en not_active Expired - Fee Related
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1451624A (en) * | 2002-04-19 | 2003-10-29 | 尹小林 | Industrial waste residue activating grinding aid |
| CN101892031A (en) * | 2010-06-10 | 2010-11-24 | 赵淼 | Powder grinding addictive for coal-series hard kaoline |
| CN101942679A (en) * | 2010-10-25 | 2011-01-12 | 江苏技术师范学院 | Method for preparing, pre-treating and dispersing superfine copper powder |
| WO2012102180A1 (en) * | 2011-01-27 | 2012-08-02 | 株式会社 フジミインコーポレーテッド | Polishing material and polishing composition |
| CN102108015A (en) * | 2011-03-09 | 2011-06-29 | 烟台大学 | Multi-functional environment-friendly grinding aid |
| CN103058577A (en) * | 2013-01-18 | 2013-04-24 | 科之杰新材料集团有限公司 | Liquid compound reinforced type cement grinding aid and preparation method thereof |
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Granted publication date: 20150819 Termination date: 20170325 |