CN103058577A - Liquid compound reinforced type cement grinding aid and preparation method thereof - Google Patents
Liquid compound reinforced type cement grinding aid and preparation method thereof Download PDFInfo
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- CN103058577A CN103058577A CN2013100188406A CN201310018840A CN103058577A CN 103058577 A CN103058577 A CN 103058577A CN 2013100188406 A CN2013100188406 A CN 2013100188406A CN 201310018840 A CN201310018840 A CN 201310018840A CN 103058577 A CN103058577 A CN 103058577A
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Abstract
The invention discloses a liquid compound reinforced type cement grinding aid. The liquid compound reinforced type cement grinding aid is prepared by the following ingredients in part by weight: 5 to 15 parts of reinforced compounds, 20 to 40 parts of grinding aiding compound, 0.1 to 1 part of silicon-contained compound, 10 to 50 parts of stable compounds, and the balance of water. The invention also discloses a preparation method of the liquid compound reinforced type cement grinding aid. The preparation method comprises the following steps: 1, adding water to a reacting kettle, and heating to reach 50 to 60 DEG C; 2, sequentially adding the reinforced component and the silicon-contained compound, and stirring for 30 minutes; 3, adding the stabile component and the grinding aiding component, and stirring for 10 minutes; and 4, adjusting the pH (Potential Of Hydrogen) of the solution to 8 to 9, and stirring for 10 minutes. The cement grinding aid disclosed by the invention can improve the physical and mechanical performances, and is low in dosage and free from harmful ingredients such as chlorine salt; and the preparation method of the cement grinding aid is simple in technological preparation and low in cost.
Description
Technical field
The present invention relates to composite enhanced cement grinding aid of a kind of liquid state and preparation method thereof.
Background technology
According to statistics, in Cement industry, the energy that grinding process consumes about 97% becomes heat energy and wastes, and only has seldom part energy for increasing the specific surface area of material.Therefore, energy-saving and cost-reducing is the urgent task of current cement production enterprise, and compares with the approach of other energy-saving and emission-reduction in the cement production process, and using cement grinding aid to improve mill efficiency is the most direct effective means.In grinding process, add a small amount of cement grinding aid, can consume under the identical condition with mill power in the fineness of cement and increase output, also can consume the specific surface area that increases cement under the identical condition with mill power at cement output, thereby improve intensity and the quality of cement.Therefore, adopting cement grinding aid is the effective measure that improve cement grinding efficient, reduce unit power consumption, and very large technical economic benefit is arranged.
Yet liquid cement grinding additive of the prior art is composited with the pure chemistry compositions such as trolamine or industrial waste.Existing grinding aid Performance Ratio is more single, to improve mill output or to increase strength of cement as main, can not be the more cost of cement production enterprise saving merely.
Summary of the invention
The object of the present invention is to provide composite enhanced cement grinding aid of a kind of liquid state and preparation method thereof, the grinding aid and the concrete admixture that are prepared by the method have good adaptability, and concrete use properties and weather resistance are had no adverse effects.
For reaching above-mentioned purpose, solution of the present invention is:
The composite enhanced cement grinding aid of a kind of liquid state, formulated by weight by following batching: enhancement component 5-15 part, grinding aid component 20-40 part, siliceous compound 0.1-1 part is stablized component 10-50 part, and all the other are water.
The preparation method of the composite enhanced cement grinding aid of a kind of liquid state may further comprise the steps:
Step 1, in reactor, injected water is heated to 50-60 ℃;
Step 2 adds enhancement component and siliceous compound successively, stirs 30 minutes;
Step 3 adds and stablizes component and grinding aid component, stirs 10 minutes;
Step 4, regulator solution pH value stirred 10 minutes to 8-9, namely got liquid composite enhanced cement grinding aid.
Further, enhancement component is one or more in Sulfothiorine, urea, water glass, sodium-acetate, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, Sunmorl N 60S, the sodium aluminate, is used for the activity of excited cement adulterant, improves strength of cement.
Further, the grinding aid component is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, tri-isopropanolamine, ethylene glycol, glycerol, glycol ether, Diethylene Glycol, di-alcohol α-amino isopropyl alcohol, molasses, the tetrahydroxy ethyl hexyl diamines, be used for eliminating the electrostatic effect of cement clinker and adulterant thereof, improve mill efficiency, optimize cement size grading and distribute.
Further, siliceous compound is block silicone oil, improves the intensity of cement, has obvious excitation.
Further, stable component is one or more in sulfonated lignin, sulfamate, the sulfonated acetone formaldehyde condensation products, improves the adaptability of cement grinding aid and concrete admixture, improves the over-all properties of cement.
After adopting such scheme, the liquid composite enhanced cement grinding aid of the present invention's preparation compared with prior art has the following advantages:
One, the cement grinding aid product does not relate to villaumite, has guaranteed that concrete has good weather resistance.
Two, add enhancement component in the cement grinding aid product, it is obvious to ordinary Portland cement and composite Portland cement enhancement, can when to mix industrial solid castoff be main blended material more, guarantee to improve more than the cement 28d ultimate compression strength 3MPa.
Three, add in the cement grinding aid product and stablize component, greatly improved cement physical properties and mechanical property.
Four, the present invention fills a prescription simple and technological operation is simplified, and the grinding aid grinding aid reinforced effects of production is good.
Embodiment
Below in conjunction with specific embodiment the present invention is described in detail.
Embodiment one
The composite enhanced cement grinding aid of a kind of liquid state, formulated by weight by following batching: 8 parts of sodium-acetates, 15 parts of trolamines, 8 parts of ethylene glycol, 0.5 part of block silicone oil, 30 parts of sulfamates, all the other are water.In reactor, above-mentioned raw materials is carried out proportioning by weight, carry out the composite composite enhanced cement grinding aid that namely obtains by process of preparing of the present invention.This invention product incorporation in cement is 0.05% of cement (comprising mineral admixture) weight.Take by weighing cement raw material 5kg and 2.5g grinding aid, the cement physical and mechanical properties changed before and after the comparative analysis grinding aid used, and through test ball mill grinding 25 minutes, cement testing the results are shown in Table shown in one.
Embodiment two
The composite enhanced cement grinding aid of a kind of liquid state, formulated by weight by following batching: 8 parts of sodium-acetates, 5 parts in Sulfothiorine, 10 parts of trolamines, 18 parts of di-alcohol α-amino isopropyl alcohols, 0.3 part of block silicone oil, 35 parts of sulfamates, all the other are water.In reactor, above-mentioned raw materials is carried out proportioning by weight, carry out the composite composite enhanced cement grinding aid that namely obtains by process of preparing of the present invention.This invention product incorporation in cement is 0.03% of cement (comprising mineral admixture) weight.Take by weighing cement raw material 5kg and 1.5g grinding aid, the cement physical and mechanical properties changed before and after the comparative analysis grinding aid used, and through test ball mill grinding 25 minutes, cement testing the results are shown in Table shown in one.
Embodiment three
The composite enhanced cement grinding aid of a kind of liquid state, formulated by weight by following batching: 3 parts of tripoly phosphate sodium STPPs, 10 parts of sodium-acetates, 15 parts of diethanolamine, 6 parts of tetrahydroxy ethyl hexyl diamines, 0.2 part of block silicone oil, 10 parts of xylogen iodates, 20 parts of sulfamates, all the other are water.In reactor, above-mentioned raw materials is carried out proportioning by weight, carry out the composite composite enhanced cement grinding aid that namely obtains by process of preparing of the present invention.This invention product incorporation in cement is 0.03% of cement (comprising mineral admixture) weight.Take by weighing cement raw material 5kg and 2.5g grinding aid, the cement physical and mechanical properties changed before and after the comparative analysis grinding aid used, and through test ball mill grinding 25 minutes, cement testing the results are shown in Table shown in one.
Embodiment four
The composite enhanced cement grinding aid of a kind of liquid state, formulated by weight by following batching: 10 parts of sodium-acetates, 18 parts of di-alcohol α-amino isopropyl alcohols, 12 parts of ethylene glycol, 0.3 part of block silicone oil, 25 parts of sulfamates, 10 parts of sulfonated acetone formaldehyde condensation products, all the other are water.In reactor, above-mentioned raw materials is carried out proportioning by weight, carry out the composite composite enhanced cement grinding aid that namely obtains by process of preparing of the present invention.This invention product incorporation in cement is 0.03% of cement (comprising mineral admixture) weight.Take by weighing cement raw material 5kg and 1.5g grinding aid, the cement physical and mechanical properties changed before and after the comparative analysis grinding aid used, and through test ball mill grinding 25 minutes, cement testing the results are shown in Table shown in one.
Cement physical and mechanical properties contrast before and after table one grinding aid uses
(percentage ratio is mass percent)
Claims (6)
1. composite enhanced cement grinding aid of liquid state is characterized in that: formulated by weight by following batching: enhancement component 5-15 part, and grinding aid component 20-40 part, siliceous compound 0.1-1 part is stablized component 10-50 part, and all the other are water.
2. the composite enhanced cement grinding aid of a kind of liquid state as claimed in claim 1, it is characterized in that: enhancement component is one or more in Sulfothiorine, urea, water glass, sodium-acetate, tripoly phosphate sodium STPP, Sodium hexametaphosphate 99, Sunmorl N 60S, the sodium aluminate.
3. the composite enhanced cement grinding aid of a kind of liquid state as claimed in claim 1, it is characterized in that: the grinding aid component is one or more in Monoethanolamine MEA BASF, diethanolamine, trolamine, tri-isopropanolamine, ethylene glycol, glycerol, glycol ether, Diethylene Glycol, di-alcohol α-amino isopropyl alcohol, molasses, the tetrahydroxy ethyl hexyl diamines.
4. the composite enhanced cement grinding aid of a kind of liquid state as claimed in claim 1, it is characterized in that: siliceous compound is block silicone oil.
5. the composite enhanced cement grinding aid of a kind of liquid state as claimed in claim 1, it is characterized in that: stable component is one or more in sulfonated lignin, sulfamate, the sulfonated acetone formaldehyde condensation products.
6. the preparation method of the composite enhanced cement grinding aid of a kind of liquid state as claimed in claim 1 is characterized in that: may further comprise the steps:
Step 1, in reactor, injected water is heated to 50-60 ℃;
Step 2 adds enhancement component and siliceous compound successively, stirs 30 minutes;
Step 3 adds and stablizes component and grinding aid component, stirs 10 minutes;
Step 4, regulator solution pH value stirred 10 minutes to 8-9, namely got liquid composite enhanced cement grinding aid.
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Application publication date: 20130424 |