CN103865297A - Floating beads and method for preparing modified floating beads - Google Patents
Floating beads and method for preparing modified floating beads Download PDFInfo
- Publication number
- CN103865297A CN103865297A CN201410124685.0A CN201410124685A CN103865297A CN 103865297 A CN103865297 A CN 103865297A CN 201410124685 A CN201410124685 A CN 201410124685A CN 103865297 A CN103865297 A CN 103865297A
- Authority
- CN
- China
- Prior art keywords
- pearl
- floating beads
- floated
- stirring
- modification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to coating materials for reflecting and insulating light and heat, particularly relates to floating beads and a method for preparing modified floating beads and belongs to the technical field of architectural coatings. A reflective and insulating coating material comprises a reflective coating material and the modified floating beads, wherein the modified floating beads are uniformly dispersed into the reflective coating material. According to the floating beads and the method for preparing the modified floating beads, from economic considerations, ceramic hollow microbeads are replaced with flyash floating beads, then, a good technical effect is obtained; the price of the flyash floating beads is far lower than that of the ceramic hollow microbeads, and although the heat insulating capability of the flyash floating beads is strong, the color of the flyash floating beads is not white enough, thus, the light and heat reflecting properties of the coating material are affected; the color problem of the floating beads is solved by adopting a titanium white spraying process, and the wall adhesion of the floating beads is far greater than that of the ceramic hollow microbeads, so that the floating beads have technical advantages; the reflective coating material can be used separately, can also be used in a manner of being matched with the modified floating beads, has a light and heat reflecting effect during separate use and has a heat reflecting and insulating effect during matched use.
Description
Technical field
The present invention relates to a kind of coating that reflects photo-thermal and isolated photo-thermal, be specifically related to modification and float the preparation method of pearl and float pearl, belong to building coating technical field.
Background technology
Current, reflective heat-insulation paint has obtained applying more and more widely under construction.In general, reflective insulation effect of reflective heat-insulation paint, under same base material strip part, color stuffing plays leading role, and wherein filler is the important component part of coating, is one of key of preparation high-level efficiency reflective heat-insulation paint to its selection.The empty microballon of pottery is a kind of white meal, and its granule interior is hollow, and density is low, and thermal conductivity is little, the incident waves such as the fine reflected light of energy, heat, and the slow heat energy of resistance conducts to interior of articles, and these performances make it to become the first-selected filler of reflective heat-insulation paint.The preparation of current reflective heat-insulation paint, selects this type of filler mostly, but the high-quality ceramic hollow microballon of all size, and still taking import as main, its price is generally higher, larger to coating material production cost impact.
Can extract the fly ash float that obtains being similar to ceramic fine bead from flyash, its outward appearance is greyish white meal, granule interior is hollow, density is low, thermal conductivity is little, with ceramic fine bead comparison, its thermal resistance effect performance approaches, but because surface color is darker, during as filler, in coating along with the increase of its add-on, coating color is deepened rapidly, have a strong impact on effect of film reflection photo-thermal, conventionally in coating preparation process, must be by strong covering power, refractive index is large, the titanium white powder pigment collocation that whiteness is high is used, and suitably strengthen consumption, effectively to hide the color and luster that floats pearl, this adjustment to formulation for coating material has certain limitation.According to the study, in the composition of reflective heat-insulation paint, filler fly ash float proportion is within the specific limits along with the continuous increase of its add-on, the heat rejection thermal characteristics of coating improves gradually, but coating color is also deepened thereupon, make coating film more easily absorb photo-thermal, greatly affect the reflective insulation function of coating.
For addressing this problem, there are some researches show, the titanium dioxide with high refractive index, high whiteness is coated in advance and floats bead surface, make to float pearl particle and have the titanium dioxide crystal phase structure tectum of high refractive index.The pearl that floats through upper method modification combines thermal resistance reflection dual property, as the filler of preparing reflective heat-insulation paint, can effectively strengthen the reflective insulation performance of film.
Existing report titanium salt hydrolysis coating method, is suspended in certain medium by particle, controls the processing condition such as pH, temperature, concentration, makes titanium salt be hydrolyzed into TiO
2deposit to particle surface, after hydrolysis reaction proceeds to a certain degree, filtration, washing, oven dry, roasting, obtain product.As the Chinese invention patent that application number is 02156763.8, a kind of surface TiO of tourmaline powder is disclosed
2coated modifying and whitening method, comprises the following steps: (1), by the tourmaline powder slurrying that adds water, pulp quality is than being tourmaline powder: water=1:6～15; Add 0.1%～1.0% SnCl of tourmaline powder weight simultaneously
2or ZnO; Add acid-conditioning solution pH to 1.5～3.5; (2) tourmalinite slip is heated to 55～95 DEG C, adds titanium salt solution, add NaOH or urea soln simultaneously, to keep slip pH as 2.5～3, in reactor or retort, tourmaline powder is carried out to surface TiO
2precipitation coating reaction, the reaction times is 2～6h; (3) coating reaction product filtered, wash, be dried and roasting.But preparation technology is more tired for this class Chemical coating method, and quality stability is not high, and production process energy consumption is larger.
Summary of the invention
The present invention will solve the problems of the technologies described above, thereby a kind of reflective heat-insulation paint is provided.This coating has good economy performance, and has function heat insulation and reflection photo-thermal concurrently.
The technical scheme that the present invention addresses the above problem is as follows:
Reflective heat-insulation paint, comprises that reflective coating and modification float pearl, and described modification is floated pearl and is dispersed in described reflective coating; Described reflective heat-insulation paint is made up of method A:
Method A: the water of formula ratio, auxiliary agent are added in container and be stirred to and be uniformly dissolved, add titanium dioxide, barium sulfate, the mica powder of formula ratio, high speed dispersion 8 ~ 10min under 800～1200rpm, rotating speed is reduced to 300 ~ 500rpm, add emulsion to stir again 20 ~ 40min, continue dispersion treatment under the rotating speed of 300 ~ 500rpm, and add the modification of formula ratio to float pearl and ether of cellulose, stir, filter and get final product;
Described auxiliary agent is film coalescence aid, flow agent, thickening material, frostproofer, dispersion agent and defoamer; Described emulsion is organosilicon-modified acrylate emulsion and elastomeric propylene yogurt liquid;
Described in method A, formula is as follows:
Organosilicon-modified acrylate emulsion 26.0 ~ 30.0 mass parts
Elastomeric propylene yogurt liquid 16.0 ~ 20.0 mass parts
Pearl 16.0 ~ 20.0 mass parts are floated in modification
Titanium dioxide 13.0 ~ 18.0 mass parts
Barium sulfate 2.0 ~ 5.0 mass parts
Mica powder 0.8 ~ 1.0 mass parts
Water 16.0 ~ 18.0 mass parts
Film coalescence aid 0.8 ~ 1.2 mass parts
Flow agent 0.1 ~ 0.7 mass parts
Thickening material 0.1 ~ 0.2 mass parts
Frostproofer 1.0 ~ 2.0 mass parts
Dispersion agent 0.5 ~ 0.8 mass parts
Defoamer 0.2 ~ 0.3 mass parts
Ether of cellulose 0.05 mass parts;
Modification described in method A is floated pearl and is made up of method B:
Method B: fly ash float is sent in the efficient powder mixer with fog-spray nozzle, and under stirring at normal temperature, pearl special sizing agent is floated in the modification that quantitatively sprays in advance preparation, 20 ~ 30min is stirred in the complete rear continuation of pulp spraying, discharging, baking at 95 ~ 105 DEG C, cooling, sieving and grading;
Described modification is floated pearl special sizing agent and is made by method C;
Method C comprises the following steps:
1. after titanium dioxide, water and auxiliary agent being mixed, stir;
2. after stirring, drop in shredder and grind, obtain titanium dioxide slurry;
3. titanium dioxide slurry and aqueous epoxy emulsion are mixed to rear stirring, after stirring evenly, obtain titanium dioxide resin slurry;
4. after adding auxiliary agent in titanium dioxide resin slurry, stir, after stirring evenly, obtain modification and float pearl special sizing agent;
Method C step 1. and auxiliary agent 4. formed by the component of following mass parts:
Film coalescence aid 0.8 ~ 1.2 mass parts
Flow agent 0.1 ~ 0.7 mass parts
Thickening material 0.1 ~ 0.2 mass parts
Frostproofer 1.0 ~ 2.0 mass parts
Dispersion agent 0.5 ~ 0.8 mass parts
Defoamer 0.2 ~ 0.3 mass parts.
Film coalescence aid of the present invention, flow agent, thickening material, frostproofer, dispersion agent, defoamer can be all commercially available prod, without special requirement.Lower same.
As above-mentioned design preferably, in method C, step 1. described stirring is the high-speed stirring of carrying out under 1000～2000rpm condition; Step 3. described stirring is that the middling speed of carrying out under 500～1000rpm condition stirs; Step 4. described stirring is the stirring at low speed of carrying out under 100～500rpm condition.
As above-mentioned design preferably, described in method A and method C, titanium dioxide is Rutile type Titanium Dioxide.
As above-mentioned design preferably, in method B, when baking, adopt ebullated bed baking, storing temperature control is 100 ~ 105 DEG C, time control is 25 ~ 35min.
Two of object of the present invention is to provide a kind of modified coal ash and floats pearl.Its technical scheme is as follows:
Modification is floated pearl and is made up of method B:
Method B: fly ash float is sent in the efficient powder mixer with fog-spray nozzle, and under stirring at normal temperature, pearl special sizing agent is floated in the modification that quantitatively sprays in advance preparation, 20 ~ 30min is stirred in the complete rear continuation of pulp spraying, discharging, baking at 95 ~ 105 DEG C, cooling, sieving and grading;
Described modification is floated pearl special sizing agent and is made by method C;
Method C comprises the following steps:
1. after titanium dioxide, water and auxiliary agent being mixed, stir;
2. after stirring, drop in shredder and grind, obtain titanium dioxide slurry;
3. titanium dioxide slurry and aqueous epoxy emulsion are mixed to rear stirring, after stirring evenly, obtain titanium dioxide resin slurry;
4. after adding auxiliary agent in titanium dioxide resin slurry, stir, after stirring evenly, obtain modification and float pearl special sizing agent;
Method C step 1. and auxiliary agent 4. formed by the component of following mass parts:
Film coalescence aid 0.8 ~ 1.2 mass parts
Flow agent 0.1 ~ 0.7 mass parts
Thickening material 0.1 ~ 0.2 mass parts
Frostproofer 1.0 ~ 2.0 mass parts
Dispersion agent 0.5 ~ 0.8 mass parts
Defoamer 0.2 ~ 0.3 mass parts.
As technique scheme preferably, in method B, when baking, adopt ebullated bed baking, storing temperature control is 100 ~ 105 DEG C, time control is 25 ~ 35min.
Three of object of the present invention is to provide a kind of flyash modified pearl special sizing agent that floats.Its technical scheme is as follows:
Described modification is floated pearl special sizing agent and is made by method C;
Method C comprises the following steps:
1. after titanium dioxide, water and auxiliary agent being mixed, stir;
2. after stirring, drop in shredder and grind, obtain titanium dioxide slurry;
3. titanium dioxide slurry and aqueous epoxy emulsion are mixed to rear stirring, after stirring evenly, obtain titanium dioxide resin slurry;
4. after adding auxiliary agent in titanium dioxide resin slurry, stir, after stirring evenly, obtain modification and float pearl special sizing agent;
Method C step 1. and auxiliary agent 4. formed by the component of following mass parts:
Film coalescence aid 0.8 ~ 1.2 mass parts
Flow agent 0.1 ~ 0.7 mass parts
Thickening material 0.1 ~ 0.2 mass parts
Frostproofer 1.0 ~ 2.0 mass parts
Dispersion agent 0.5 ~ 0.8 mass parts
Defoamer 0.2 ~ 0.3 mass parts.
As technique scheme preferably, in method C, step 1. described stirring is the high-speed stirring of carrying out under 1000～2000rpm condition; Step 3. described stirring is that the middling speed of carrying out under 500～1000rpm condition stirs; Step 4. described stirring is the stirring at low speed of carrying out under 100～500rpm condition.
As technique scheme preferably, titanium dioxide described in method C is Rutile type Titanium Dioxide.
Thereby four of object of the present invention be to provide a kind of be suitable for catching up with state modification and float pearl collocation and use the reflective coating with reflective insulation function.The alone ability also with good reflection photo-thermal of this reflective coating.The technical scheme of this reflective coating is as follows:
Reflective coating, comprises the component of following mass parts:
Organosilicon-modified acrylate emulsion 26.0 ~ 30.0
Elastomeric propylene yogurt liquid 16.0 ~ 20.0
Titanium dioxide 13.0 ~ 18.0
Barium sulfate 2.0 ~ 5.0
Mica powder 0.8 ~ 1.0
Water 16.0 ~ 18.0.
As technique scheme preferably, described reflective coating also comprises the component of following mass parts:
Film coalescence aid 0.8 ~ 1.2
Flow agent 0.1 ~ 0.7
Thickening material 0.1 ~ 0.2
Frostproofer 1.0 ~ 2.0
Dispersion agent 0.5 ~ 0.8
Defoamer 0.2 ~ 0.3.
As technique scheme preferably, described reflective coating also comprises the component of following mass parts:
Ether of cellulose 0.05.
As technique scheme preferably, described reflective coating is made up of the component of following mass parts:
Organosilicon-modified acrylate emulsion 26.0 ~ 30.0
Elastomeric propylene yogurt liquid 16.0 ~ 20.0
Titanium dioxide 13.0 ~ 18.0
Barium sulfate 2.0 ~ 5.0
Mica powder 0.8 ~ 1.0
Water 16.0 ~ 18.0
Film coalescence aid 0.8 ~ 1.2
Flow agent 0.1 ~ 0.7
Thickening material 0.1 ~ 0.2
Frostproofer 1.0 ~ 2.0
Dispersion agent 0.5 ~ 0.8
Defoamer 0.2 ~ 0.3
Ether of cellulose 0.05.
A further object of the present invention is to provide a kind of preparation method of above-mentioned reflective coating, and its technical scheme is as follows:
The preparation method of reflective coating: the water of above-mentioned formula ratio, auxiliary agent are added in container and be stirred to and be uniformly dissolved, add titanium dioxide, barium sulfate, the mica powder of formula ratio, high speed dispersion 8 ~ 10min under 800～1200rpm, rotating speed is reduced to 300 ~ 500rpm, add emulsion to stir again 20 ~ 40min, continue to add under 300 ~ 500rpm low speed to float pearl and ether of cellulose claimed in claim 4, stir, filter, obtain coating finished product; Described auxiliary agent is described film coalescence aid, flow agent, thickening material, frostproofer, dispersion agent and defoamer; Described emulsion is described organosilicon-modified acrylate emulsion and elastomeric propylene yogurt liquid.
The present invention has following technique effect:
1. the present invention from economic considerations, with the alternative ceramic hollow microballon of fly ash float, and obtained good technique effect, the price of fly ash float is far below ceramic hollow microballon, although fly ash float heat-insulating capability is strong, but color is clean not in vain, the photothermal reflectance performance that affects coating, the present invention has adopted titanium dioxide spraying coating process, has solved the color problem of floating pearl, and float pearl at the sticking power of metope much larger than ceramic hollow microballon, advantage possesses skills;
2. reflective coating of the present invention, can be used alone and also can coordinate modification of the present invention to float pearl use, uses separately the effect with reflection photo-thermal, is used in conjunction with the effect with reflective insulation;
3. the method A of coating of the present invention, B, C, not high and easy to operate easy to control for equipment requirements, industrialization cost is low, can greatly promote to produce.
Embodiment
This embodiment is only explanation of the invention, is not limitation of the present invention.Any amendment that those skilled in the art make after having read specification sheets of the present invention, as long as in the protection domain of claim, all will be subject to the protection of patent law.
Pearl special sizing agent is floated in modification, and by method, C makes, and method C comprises the following steps:
1. after titanium dioxide, water and auxiliary agent being mixed, stir;
2. after stirring, drop in shredder and grind, obtain titanium dioxide slurry;
3. titanium dioxide slurry and aqueous epoxy emulsion are mixed to rear stirring, after stirring evenly, obtain titanium dioxide resin slurry;
4. after adding auxiliary agent in titanium dioxide resin slurry, stir, after stirring evenly, obtain modification and float pearl special sizing agent;
In method C, step 1. described stirring is the high-speed stirring of carrying out under 1000～2000rpm condition; Step 3. described stirring is that the middling speed of carrying out under 500～1000rpm condition stirs; Step 4. described stirring is the stirring at low speed of carrying out under 100～500rpm condition.
Pearl is floated in modification, and by method, B makes: fly ash float is sent in the efficient powder mixer with fog-spray nozzle, under stirring at normal temperature, quantitatively spray into above-mentioned modification and float pearl special sizing agent, 20 ~ 30min, discharging are stirred in the complete rear continuation of pulp spraying, at 95 ~ 105 DEG C, baking, cooling, sieving and grading.
Reflective coating, made by following methods: the water of formula ratio, auxiliary agent are added in container and be stirred to and be uniformly dissolved, add titanium dioxide, barium sulfate, the mica powder of formula ratio, under 800～1200rpm, high speed dispersion 8 ~ 10min, is reduced to 300 ~ 500rpm by rotating speed, adds emulsion to stir 20 ~ 40min again, continue to add under 300 ~ 500rpm low speed to float pearl ether of cellulose, stir, filter, obtain coating finished product; Described auxiliary agent is described film coalescence aid, flow agent, thickening material, frostproofer, dispersion agent and defoamer; Described emulsion is described organosilicon-modified acrylate emulsion and elastomeric propylene yogurt liquid.
Heat insulating reflecting coating, comprises that reflective coating and modification float pearl, and described modification is floated pearl and is dispersed in described reflective coating; Described reflective heat-insulation paint is made up of method A:
Method A: the water of formula ratio, auxiliary agent are added in container and be stirred to and be uniformly dissolved, add titanium dioxide, barium sulfate, the mica powder of formula ratio, high speed dispersion 8 ~ 10min under 800～1200rpm, rotating speed is reduced to 300 ~ 500rpm, add emulsion to stir again 20 ~ 40min, continue dispersion treatment under the rotating speed of 300 ~ 500rpm, and add the modification of formula ratio to float pearl and ether of cellulose, stir, filter and get final product;
Described auxiliary agent is film coalescence aid, flow agent, thickening material, frostproofer, dispersion agent and defoamer; Described emulsion is organosilicon-modified acrylate emulsion and elastomeric propylene yogurt liquid.
More than provided modification and floated the preparation method that pearl special sizing agent, modification float pearl, reflective coating and heat insulating reflecting coating, aforesaid method depends on formula.For clearer the content of expressing embodiment, the present invention expresses different embodiment by providing the form of different ingredients.It is to be understood that, each formula should be considered in conjunction with aforesaid method, an independent true content that formula is not specific embodiment.In aforesaid method, related parameter has been all the parameter in zone of reasonableness, from the inventor's concrete practice, as long as in these zone of reasonableness, the fluctuation of parameter is little to influential effect of the present invention, therefore in this embodiment, does not do specified otherwise.In addition, various auxiliary agents involved in the present invention can be commercially available auxiliary agents, also little on impact of the present invention, therefore also do not do special considering.The routine operation of this area does not do specified otherwise yet in addition, as occurred corroding or to dissolve the raw material that floats pearl coating layer in the formula of coating; Float the fragmentation of pearl coating layer if there is modification and need to check whether coating layer is completely curing after toasting, and also will consider whether be that stirring velocity is too fast.
Embodiment mono-
In method C, step 1. and auxiliary agent 4. formed by following component, by mass parts:
Film coalescence aid 0.8
Flow agent 0.1
Thickening material 0.1
Frostproofer 1.0
Dispersion agent 0.5
Defoamer 0.2.
The formula of reflective coating is as follows, by mass parts:
Organosilicon-modified acrylate emulsion 26.0
Elastomeric propylene yogurt liquid 16.0
Titanium dioxide 13.0
Barium sulfate 2.0
Mica powder 0.8
Water 16.0
Film coalescence aid 0.8
Flow agent 0.1
Thickening material 0.1
Frostproofer 1.0
Dispersion agent 0.5
Defoamer 0.2
Ether of cellulose 0.05.
The formula of heat insulating reflecting coating is as follows, by mass parts:
Organosilicon-modified acrylate emulsion 26.0
Elastomeric propylene yogurt liquid 16.0
Pearl 16.0 is floated in modification
Titanium dioxide 13.0
Barium sulfate 2.0
Mica powder 0.8
Water 16.0
Film coalescence aid 0.8
Flow agent 0.1
Thickening material 0.1
Frostproofer 1.0
Dispersion agent 0.5
Defoamer 0.2
Ether of cellulose 0.05.
Embodiment bis-
In method C, step 1. and auxiliary agent 4. formed by following component, by mass parts:
Film coalescence aid 0.9
Flow agent 0.2
Thickening material 0.12
Frostproofer 1.2
Dispersion agent 0.56
Defoamer 0.22
The formula of reflective coating is as follows:
Organosilicon-modified acrylate emulsion 27.0
Elastomeric propylene yogurt liquid 17.0
Titanium dioxide 14.0
Barium sulfate 2.0
Mica powder 0.84
Water 16.5
Film coalescence aid 0.9
Flow agent 0.2
Thickening material 0.12
Frostproofer 1.2
Dispersion agent 0.56
Defoamer 0.22
Ether of cellulose 0.05.
The formula of heat insulating reflecting coating is as follows:
Organosilicon-modified acrylate emulsion 27.0
Elastomeric propylene yogurt liquid 17.0
Pearl 17.0 is floated in modification
Titanium dioxide 14.0
Barium sulfate 2.0
Mica powder 0.84
Water 16.5
Film coalescence aid 0.9
Flow agent 0.2
Thickening material 0.12
Frostproofer 1.2
Dispersion agent 0.56
Defoamer 0.22
Ether of cellulose 0.05.
Embodiment tri-
In method C, step 1. and auxiliary agent 4. formed by following component, by mass parts:
Film coalescence aid 1.0
Flow agent 0.3
Thickening material 0.15
Frostproofer 1.2
Dispersion agent 0.6
Defoamer 0.25
The formula of reflective coating is as follows:
Organosilicon-modified acrylate emulsion 28.0
Elastomeric propylene yogurt liquid 18.0
Titanium dioxide 15.0
Barium sulfate 2.5
Mica powder 0.88
Water 16.5
Film coalescence aid 1.0
Flow agent 0.3
Thickening material 0.15
Frostproofer 1.2
Dispersion agent 0.56
Defoamer 0.26
Ether of cellulose 0.05.
The formula of heat insulating reflecting coating is as follows:
Organosilicon-modified acrylate emulsion 28.0
Elastomeric propylene yogurt liquid 18.0
Pearl 18.0 is floated in modification
Titanium dioxide 15.0
Barium sulfate 2.5
Mica powder 0.88
Water 16.5
Film coalescence aid 1.0
Flow agent 0.3
Thickening material 0.15
Frostproofer 1.2
Dispersion agent 0.56
Defoamer 0.26
Ether of cellulose 0.05.
Embodiment tetra-
In method C, step 1. and auxiliary agent 4. formed by following component, by mass parts:
Film coalescence aid 1.1
Flow agent 0.6
Thickening material 0.18
Frostproofer 1.8
Dispersion agent 0.7
Defoamer 0.28.
The formula of reflective coating is as follows, by mass parts:
Organosilicon-modified acrylate emulsion 29.0
Elastomeric propylene yogurt liquid 19.0
Titanium dioxide 17.0
Barium sulfate 4.0
Mica powder 0.9
Water 17.5
Film coalescence aid 1.2
Flow agent 0.6
Thickening material 0.18
Frostproofer 1.8
Dispersion agent 0.7
Defoamer 0.28
Ether of cellulose 0.05.
The formula of heat insulating reflecting coating is as follows, by mass parts:
Organosilicon-modified acrylate emulsion 29.0
Elastomeric propylene yogurt liquid 19.0
Pearl 19.0 is floated in modification
Titanium dioxide 17.0
Barium sulfate 4.0
Mica powder 0.9
Water 17.5
Film coalescence aid 1.2
Flow agent 0.6
Thickening material 0.18
Frostproofer 1.8
Dispersion agent 0.7
Defoamer 0.28
Ether of cellulose 0.05.
Embodiment five
In method C, step 1. and auxiliary agent 4. formed by following component, by mass parts:
Film coalescence aid 1.2
Flow agent 0.7
Thickening material 0.2
Frostproofer 2.0
Dispersion agent 0.8
Defoamer 0.3
The formula of reflective coating is as follows, by mass parts:
Organosilicon-modified acrylate emulsion 30
Elastomeric propylene yogurt liquid 20.0
Titanium dioxide 18.0
Barium sulfate 5.0
Mica powder 1.0
Water 18.0
Film coalescence aid 1.2
Flow agent 0.7
Thickening material 0.2
Frostproofer 2.0
Dispersion agent 0.8
Defoamer 0.3
Ether of cellulose 0.05.
The formula of heat insulating reflecting coating is as follows:
Organosilicon-modified acrylate emulsion 30.0
Elastomeric propylene yogurt liquid 20.0
Pearl 20.0 is floated in modification
Titanium dioxide 18.0
Barium sulfate 5.0
Mica powder 1.0
Water 18.0
Film coalescence aid 1.2
Flow agent 0.7
Thickening material 0.2
Frostproofer 2.0
Dispersion agent 0.8
Defoamer 0.3
Ether of cellulose 0.05.
Claims (7)
1. the preparation method of pearl is floated in modification, it is characterized in that: fly ash float is sent in the efficient powder mixer with fog-spray nozzle, under stirring at normal temperature, pearl special sizing agent is floated in the modification that quantitatively sprays into preparation in advance, and 20 ~ 30min, discharging are stirred in the complete rear continuation of pulp spraying, baking at 95 ~ 105 DEG C, cooling, sieving and grading, pearl is floated in the modification that is different size;
Described modification is floated pearl special sizing agent and is prepared by the following method:
After being mixed, titanium dioxide, water and grinding aid stir;
After stirring, drop in shredder and grind, obtain titanium dioxide slurry;
Titanium dioxide slurry and aqueous epoxy emulsion are mixed to rear stirring, after stirring evenly, obtain titanium dioxide resin slurry;
Add auxiliary agent in titanium dioxide resin slurry after, stir, after stirring evenly, obtain modification and float pearl special sizing agent;
Described auxiliary agent is made up of the component of following mass parts:
Film coalescence aid 0.8 ~ 1.2
Flow agent 0.1 ~ 0.7
Thickening material 0.1 ~ 0.2
Frostproofer 1.0 ~ 2.0
Dispersion agent 0.5 ~ 0.8
Defoamer 0.2 ~ 0.3.
2. the preparation method of pearl is floated in modification according to claim 1, it is characterized in that: when baking, adopt ebullated bed baking, storing temperature control is 100 ~ 105 DEG C.
3. the preparation method of pearl is floated in modification according to claim 1 and 2, it is characterized in that: step 1. described stirring is the high-speed stirring of carrying out under 1000～2000rpm condition.
4. the preparation method of pearl is floated in modification according to claim 1 and 2, it is characterized in that: step 3. described stirring is that the constant speed of carrying out under 500～1000rpm condition stirs.
5. the preparation method of pearl is floated in modification according to claim 1 and 2, it is characterized in that: step 4. described stirring is the stirring at low speed of carrying out under 100～500rpm condition.
6. the preparation method of pearl special sizing agent is floated in modification according to claim 1 and 2, it is characterized in that: described titanium dioxide is Rutile type Titanium Dioxide.
7. pearl is floated in the modification being made by method described in above-mentioned arbitrary claim.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410124685.0A CN103865297B (en) | 2014-03-31 | 2014-03-31 | The preparation method of modification drift pearl and drift pearl |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410124685.0A CN103865297B (en) | 2014-03-31 | 2014-03-31 | The preparation method of modification drift pearl and drift pearl |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103865297A true CN103865297A (en) | 2014-06-18 |
| CN103865297B CN103865297B (en) | 2015-12-02 |
Family
ID=50904336
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410124685.0A Active CN103865297B (en) | 2014-03-31 | 2014-03-31 | The preparation method of modification drift pearl and drift pearl |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103865297B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104762007A (en) * | 2015-04-29 | 2015-07-08 | 肖先波 | Energy-saving texture thermal insulation coating used for building external wall |
| CN104860630A (en) * | 2015-04-29 | 2015-08-26 | 肖先波 | Environmental protection paint for building exterior wall |
| CN105368233A (en) * | 2015-12-18 | 2016-03-02 | 盐城工学院 | Composite thermal insulation coating and preparation method thereof |
| CN110408241A (en) * | 2019-08-12 | 2019-11-05 | 镇江市丹徒区蓝带保温材料厂 | A kind of modification floating bead preparation method that reflective insulation performance is good |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1061983A (en) * | 1963-10-15 | 1967-03-15 | Walter Thorley | Protective surface coating |
| KR20040022985A (en) * | 2002-09-10 | 2004-03-18 | 이석주 | An Adiabatic Paint |
| CN1508196A (en) * | 2002-12-18 | 2004-06-30 | 中国矿业大学（北京校区） | Tourmaline powder surface TiO2 cladding, modifying and brightening method |
| CN1916092A (en) * | 2006-09-08 | 2007-02-21 | 河北工业大学 | Insulating mold coating, and prepartion method |
| CN1927954A (en) * | 2006-09-12 | 2007-03-14 | 陈建华 | Filling and insulating mould coating of titanium dioxide coating fly ash float and preparation method thereof |
| CN102352160A (en) * | 2011-11-17 | 2012-02-15 | 上海材料研究所 | Water-based thermal-insulation paint for cement encaustic tiles and roofs and preparation method thereof |
| KR20120036550A (en) * | 2010-10-08 | 2012-04-18 | 유림특수화학 주식회사 | Eco-friendly paint coating composition with good adhesion and sound absorption and products with coating film using the same |
| CN102888175A (en) * | 2011-07-20 | 2013-01-23 | 上海纳米技术及应用国家工程研究中心有限公司 | Surface modification floating bead-containing heat-insulation powdery coating and preparation method thereof |
| CN103173079A (en) * | 2013-02-26 | 2013-06-26 | 安徽真信涂料有限公司 | Exterior wall coating material of high-stability paint film and preparation method of exterior wall coating material |
| CN103332884A (en) * | 2013-06-09 | 2013-10-02 | 南通苏宝建筑节能科技有限公司 | Colorful heat insulation coating mortar as well as manufacturing method and application thereof |
-
2014
- 2014-03-31 CN CN201410124685.0A patent/CN103865297B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1061983A (en) * | 1963-10-15 | 1967-03-15 | Walter Thorley | Protective surface coating |
| KR20040022985A (en) * | 2002-09-10 | 2004-03-18 | 이석주 | An Adiabatic Paint |
| CN1508196A (en) * | 2002-12-18 | 2004-06-30 | 中国矿业大学（北京校区） | Tourmaline powder surface TiO2 cladding, modifying and brightening method |
| CN1916092A (en) * | 2006-09-08 | 2007-02-21 | 河北工业大学 | Insulating mold coating, and prepartion method |
| CN1927954A (en) * | 2006-09-12 | 2007-03-14 | 陈建华 | Filling and insulating mould coating of titanium dioxide coating fly ash float and preparation method thereof |
| KR20120036550A (en) * | 2010-10-08 | 2012-04-18 | 유림특수화학 주식회사 | Eco-friendly paint coating composition with good adhesion and sound absorption and products with coating film using the same |
| CN102888175A (en) * | 2011-07-20 | 2013-01-23 | 上海纳米技术及应用国家工程研究中心有限公司 | Surface modification floating bead-containing heat-insulation powdery coating and preparation method thereof |
| CN102352160A (en) * | 2011-11-17 | 2012-02-15 | 上海材料研究所 | Water-based thermal-insulation paint for cement encaustic tiles and roofs and preparation method thereof |
| CN103173079A (en) * | 2013-02-26 | 2013-06-26 | 安徽真信涂料有限公司 | Exterior wall coating material of high-stability paint film and preparation method of exterior wall coating material |
| CN103332884A (en) * | 2013-06-09 | 2013-10-02 | 南通苏宝建筑节能科技有限公司 | Colorful heat insulation coating mortar as well as manufacturing method and application thereof |
Non-Patent Citations (3)
| Title |
|---|
| 李文丹等: "TiO2包覆粉煤灰漂珠外墙隔热涂料的研究", 《化工新型材料》, vol. 35, no. 09, 15 September 2007 (2007-09-15) * |
| 王谷峰等: "建筑保温隔热弹性乳胶漆的研制", 《现代涂料与涂装》, vol. 14, no. 11, 20 November 2011 (2011-11-20) * |
| 陆洪彬等: "新型太阳热反射隔热涂料的研制", 《太阳能学报》, vol. 29, no. 12, 28 December 2008 (2008-12-28) * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104762007A (en) * | 2015-04-29 | 2015-07-08 | 肖先波 | Energy-saving texture thermal insulation coating used for building external wall |
| CN104860630A (en) * | 2015-04-29 | 2015-08-26 | 肖先波 | Environmental protection paint for building exterior wall |
| CN105368233A (en) * | 2015-12-18 | 2016-03-02 | 盐城工学院 | Composite thermal insulation coating and preparation method thereof |
| CN110408241A (en) * | 2019-08-12 | 2019-11-05 | 镇江市丹徒区蓝带保温材料厂 | A kind of modification floating bead preparation method that reflective insulation performance is good |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103865297B (en) | 2015-12-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103937314B (en) | The preparation method of modification drift pearl special sizing agent and modification drift pearl special sizing agent | |
| CN103865352A (en) | Reflective coating material and preparation method thereof | |
| CN105331231B (en) | A kind of energy-saving ring fidelity stone-type composite dope and preparation method thereof and construction method | |
| CN103865297B (en) | The preparation method of modification drift pearl and drift pearl | |
| CN102911579B (en) | A kind of heat reflection-obstruct composite type energy-saving coating material and preparation method thereof | |
| CN1916092A (en) | Insulating mold coating, and prepartion method | |
| CN104177940B (en) | The colorful environmental protection coating material of sunlight heat reflective insulation water-water and production method thereof | |
| CN105131764B (en) | A kind of reflective insulation texture paint and preparation method thereof | |
| CN103865344B (en) | Reflective heat-insulation paint | |
| CN109280462A (en) | A kind of environmental protection flame retardant building coating and preparation method thereof | |
| CN105368233A (en) | Composite thermal insulation coating and preparation method thereof | |
| CN110527384A (en) | Application of the expanded and vitrified small ball in water burnt-in sand base paint, water burnt-in sand base paint, preparation method and water burnt-in sand coating | |
| CN107057490A (en) | A kind of external wall elastic coating with reflective insulation effect and preparation method thereof | |
| CN105017955A (en) | Heat-shielding thermal-insulation paint | |
| CN107815215A (en) | A kind of water-based stone-like coating formula and water-based imitative stone terrace | |
| CN104151965A (en) | Exterior wall coating with solar heat reflecting function and preparation method of exterior wall coating | |
| CN101585685B (en) | Attapulgite water proof putty powder | |
| CN107793915A (en) | Radiation shielding coating and production method | |
| CN104194436B (en) | A kind of inner-outer wall elastic water-proof texture coating and preparation technology thereof | |
| CN107674574A (en) | Children's interior wall coating and production method | |
| CN107226675A (en) | A kind of preparation method of the fire-retardant building materials of novel energy-conserving | |
| CN104152043A (en) | Thermal-insulation and heat-preservation paint | |
| CN109161284A (en) | Aqueous reflective heat-insulation paint | |
| CN105967214B (en) | A kind of preparation method of spherical nanometer calcium carbonate | |
| CN107699125A (en) | Interior wall coating and production method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: 313000 Zhejiang city of Huzhou province Daixi shangqiang Industrial Park Patentee after: Huzhou Green Building Materials Development Co., Ltd. Address before: 313023 Zhejiang Province, Huzhou city Wuxing District Daixi Town Industrial Park Venture Road No. 30 Patentee before: HUZHOU GREEN BUILDING MATERIALS DEVELOPMENT CO., LTD. |