CN103857782B

CN103857782B - Powdered detergent composition for clothing, and production method therefor

Info

Publication number: CN103857782B
Application number: CN201280050523.6A
Authority: CN
Inventors: 吉冈佐知子; 上野涉; 冈田京子; 川元贤郎; 川元贤一郎; 割田浩章
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 2011-10-14
Filing date: 2012-09-12
Publication date: 2017-05-17
Anticipated expiration: 2032-09-12
Also published as: JP5432345B2; CN103857782A; WO2013054624A1; JP2013100460A

Abstract

The present invention is a powdered detergent composition for clothing, said composition comprising, in accordance with specific conditions, (A) (A-1) a surfactant including a linear alkylbenzene sulfonate and/or (A-2) an alkyl sulfate, (B) a C12 higher alcohol and/or a C14 higher alcohol, (C) a phosphate, and (D) a solid inorganic compound.

Description

Dress material powder detergent composition and its manufacture method

Technical field

The present invention relates to dress material powder detergent composition and its manufacture method.

Background technology

As the washing methods of medicated clothing, 2 kinds of hand washing washing and washing of drum type washing machine are roughly divided into.Recently as washing machine Popularization, washing of drum type washing machine has the trend of increase, but the demand from from the viewpoint of soil release performance or economy, to hand washing washing Still it is more.In addition, globally, adopting mostly in the few region of water resource can be washed with the hand washing of as far as possible few water washing Wash.

In hand washing washing and washing of drum type washing machine, wherein especially in hand washing washing, in addition to cleaning capacity, during cleaning Foaming rich and cleaning after it is easy to be rinsability be important problem.In hand washing washing, from the wink that washing starts Between sufficiently bubble（Hereinafter also referred to as quick foaming characteristic）It is related to washing easiness, so as to seek quick foaming characteristic.In addition, In the few region of water resource, foam is strongly desired in rinsing process can rapidly disappear, and with a small amount of water washing for rinsing is just completed Wash.However, in the case where the high activating agent of quick foaming characteristic is used in order to improve quick foaming characteristic, rinsability deterioration.Separately Outward, in the case where rinsing is improved, need to use foam easily rinsability good surfactant, but using such table In the case of the activating agent of face, foaming characteristic during cleaning suffers damage significantly.Particularly in the case of hand washing washing, in cleaning Be also possible to add detergent in the case that foaming characteristic is bad, therefore, foaming when taking into account cleaning in hand washing washing rich and Easy to be rinsability after cleaning is important problem.In Japanese Unexamined Patent Publication 2011-89107, disclose and contained with specific condition There are nonionic surfactant, specific anion surfactant and fatty acid that carbon number is 8~18 or its salt Cleanser compositions, the cleaning capacity and foaming characteristic when the cleanser compositions are cleaned is excellent, and in rinsing process Foam rapidly disappears, and rinsing is quickly completed.

On the other hand, all the time, the phosphate such as sodium tripolyphosphate are mainly used as the builder of cleaning agent.Trimerization Sodium phosphate has the very excellent performance such as chelating ability as cleaning agent builder, but, due to phosphorus, therefore, by One of in the reason for the waste water after the cleaning containing it is directly banished and becomes the eutrophication in rivers and creeks or lakes and marhshes.Therefore, The exploitation of the detergent of sodium tripolyphosphate is not used.As the trial for reducing phosphatic compositionss, it is known to international public Open No. 2004/041982, International Publication No. 2011/005904, the compositionss of International Publication No. 2011/005623, but It is, the level that also not up to easily rinsability etc. key property of cleaning capacity, foaming characteristic, foam is satisfied by.Especially, using high In the case of the washings of hardness, if reducing builder component, excellent cleaning capacity, foaming characteristic, foam are difficult to It is easily rinsability.

In addition, having to improve spatter property surfactant, cleaning additive disclosed in Japanese Kohyo 10-500166 Include with the dissolubility of the granular detergent composition in Aqueous wash solution effective dose with 6 DEG C~70 DEG C of fusing point The granular detergent composition of aliphatic alcohol, but do not mention and take into account foaming characteristic（Quick foaming characteristic）Easily rinse with foam Property.Additionally, having comprising anion surfactant, specific nonionic chemical combination disclosed in International Publication No. 1995/35361 The hand washing of the high foaming of thing and the builder in glycine betaine, fatty acid amide, amine oxide, aliphatic alcohol is used Cleaning compositions, but it is easily rinsability not mention foam.

The content of the invention

The present invention relates to a kind of dress material powder detergent composition, it contains following（A）~（D）：

（A）Comprising（A-1）Linear alkylbenzene sulfonate (LAS) is [hereinafter referred to as（A-1）Composition] and（A-2）Alkyl sulfate is [below Referred to as（A-2）Composition] surfactant [hereinafter referred to as（A）Composition], its content is 5~40 mass %；

（B）The higher alcohol that carbon number is 12 higher alcohol and/or carbon number is 14 is [hereinafter referred to as（B）Composition], its Content is 0.1~3 mass %；

（C）Phosphate, its content is 0~8 mass %；And

（D）The inorganic compound of solid is [hereinafter referred to as（D）Composition], its content is 40~90 mass %,

（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] it is 0/10~6.5/3.5,

（A）In composition（A-1）Composition and（A-2）Total quality of composition be 60 mass % more than,

（A-2）Composition with（B）Composition mass ratio [（A-2）Composition/（B）Composition] it is 8/1~60/1.

Moreover, it relates to a kind of dress material powder detergent composition, the dress material powder detergent composition Below coordinating（A）~（D）Form,

（A）Comprising（A-1）Linear alkylbenzene sulfonate (LAS) is [hereinafter referred to as（A-1）Composition] and（A-2）Alkyl sulfate is [below Referred to as（A-2）Composition] surfactant [hereinafter referred to as（A）Composition], its content is 5~40 mass %（Coordinate the ratio in raw material Example）；

（B）The higher alcohol that carbon number is 12 higher alcohol and/or carbon number is 14 is [hereinafter referred to as（B）Composition], its Content is 0.1~3 mass %（Coordinate the ratio in raw material）；

（C）Phosphate, its content is 0~8 mass %（Coordinate the ratio in raw material）；And

（D）The inorganic compound of solid is [hereinafter referred to as（D）Composition], its content is 40~90 mass %（In coordinating raw material Ratio）,

In coordinating raw material（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] for 0/10~ 6.5/3.5,

In coordinating raw material（A-2）Composition with（B）Composition mass ratio [（A-2）Composition/（B）Composition] it is 8/1~60/1.

Moreover, it relates to a kind of hand washing washing methods, the hand washing washing methods is to contain cleaned material contact The rinse water of the dress material powder detergent composition of the invention described above, then hand-washes cleaned material.

Moreover, it relates to a kind of manufacture method of dress material powder detergent composition, the manufacture method is upper The manufacture method of the dress material powder detergent composition of the present invention is stated,

Dress material powder detergent composition contains（A-1）Composition conduct（A）Composition, containing water miscible alkali inorganic salt make For（D）Composition,

The manufacture method has：It is used as by mixing（A-1）The LABS of the acid precursors of composition and conduct （D）The water miscible alkali inorganic salt of composition come in dry type and LABS and water miscible alkali inorganic salt operation,

Before the operation of the dry type neutralization, in operation or after operation, addition（B）Composition, so as to get particle swarm in contain Have（B）Composition,

To contain（B）The particle swarm of composition and other composition mixing.

Specific embodiment

The present invention provides the cleaning capacity that can be maintained when cleaning, and quick foaming characteristic is excellent, and in rinsing process Foam quick disappearance, can be rapidly completed the dress material powder detergent composition and its manufacture method of rinsing.

According to the present invention it is possible to provide reduce the phosphatic usage amount high to carrying capacity of environment, and can maintain clear Cleaning capacity when clean, and quick foaming characteristic is excellent, and foam quick disappearance in rinsing process, rinsing can be rapidly completed Dress material powder detergent composition.The effect of such present invention is in the feelings cleaned, washed with the washings of high rigidity Can also obtain under condition.Additionally, can more uniformly coordinate according to the present invention it is possible to provide（B）The dress material of composition is washed with powder Wash the manufacture method of agent compositionss.

[（A）Composition]

The present invention's（A）Composition is surfactant, is included at least（A-2）The alkyl sulfate of composition.Alternatively, it is also possible to Comprising（A-1）The linear alkylbenzene sulfonate (LAS) of composition and（A-2）The alkyl sulfate of composition.

The present invention's（A-1）Composition is linear alkylbenzene sulfonate (LAS).From from the viewpoint of clean-up performance, foaming characteristic,（A-1） Composition is preferably with the alkyl that carbon number is 10~15.Constitute（A-1）The salt of composition can enumerate the alkali metal of sodium, potassium etc. Alkali salt of salt, alkanolamine and magnesium, calcium etc. etc., from from the viewpoint of clean-up performance, foaming characteristic, dissolubility, preferably Alkali metal salt, further preferred sodium.

The present invention's（A-2）Composition is alkyl sulfate, and the carbon number of alkyl is preferably 10~16, more preferably 12~16, more preferably 12~15.（A-2）Carbon number in the preferred whole alkyl of composition is 12~15 straight chained alkyl Ratio is alkyl sulfate more than 50 mass %.From from the viewpoint of by using the raw material that can be regenerated to reduce environmental pressure, The ratio of the straight chained alkyl in whole alkyl is preferably more than 50 mass %, more than more preferably 70 mass %, more preferably More than more preferably 95 mass %, more than more preferably 97 mass %, it is even more preferably 99 matter more than 90 mass % Amount %, most preferably 100 mass %, i.e.,（A-2）Composition is straight-chain alkyl sulfate.

Constitute（A-2）The salt of composition can enumerate the alkaline earth of alkali metal salt, alkanolamine and magnesium, the calcium of sodium, potassium etc. etc. Slaine etc., from from the viewpoint of clean-up performance, foaming characteristic, dissolubility, preferred as alkali salt, more preferably sodium.

As（A-1）Composition and（A-2）Beyond composition（A）Composition, can enumerate the sulfur of the ethoxylate of higher alcohol The anionic surface of acid esters salt, alkane sulfonate, alpha-sulfo-fatty acid alkyl ester salt, alpha-alkene sulfonate, soap etc. is lived Property agent；Polyoxyalkene sorbitan fatty acid ester, polyoxyalkylene fatty acid ester, polyoxyalkylene alkyl, polyoxyalkylene alkyl The nonionic of phenyl ether, sucrose fatty acid ester, sorbitan fatty acid ester, fatty acid alkanol amides, alkyl-glucoside etc. Surfactant；The cationic surface of single or double alkylamine and its Polyethylene oxide addition product, single or double long chain alkyl ammonium salt etc. Activating agent；The amphoteric surfactant of carbobetaine, sulfobetaines, hydroxy sulfo lycine etc..Wherein, preferred nonionic table Face activating agent, more preferably polyoxyalkylene alkyl（The carbon number of alkyl：10~15, oxyalkylene, preferably ethylene oxide Average addition molal quantity：1~25, preferably 2~20, more preferably 2~15, more preferably 2~10, more preferably 4~8）.

[（B）Composition]

The present invention's（B）Composition is the higher alcohol that carbon number is 12 and/or the higher alcohol that carbon number is 14, from foaming From the viewpoint of property, defoaming, preferred carbon number is 12 higher alcohol.

[（C）Composition]

The present invention's（C）Composition is phosphate, as phosphate, can enumerate inorganic phosphate, specifically, Ke Yilie Lift the phosphate of more than a kind in orthophosphate, metaphosphate, trimetaphosphate, pyrophosphate and tripolyphosphate. Salt can enumerate the alkali metal salts such as sodium salt, potassium salt.

[（D）Composition]

The present invention's（D）Composition is the inorganic compound of solid, preferably（C）The inorganic chemical of the solid beyond composition Thing, can enumerate the water miscible alkali inorganic salt of carbonate and uncrystalline silicon hydrochlorate etc.；Sulfate, metal chloride, borate Deng water miscible neutral inorganic；The water-insoluble inorganic salt of aluminosilicate, clay mineral etc..（D）Composition be preferably from Water miscible alkali inorganic salt in carbonate and uncrystalline silicon hydrochlorate, the water solublity in sulfate and metal chloride Neutral inorganic and the water-insoluble inorganic salt in aluminosilicate and clay mineral in select more than a kind.Enter One step is preferably selected from more than in carbonate, sulfate and aluminosilicate a kind of inorganic compound, more preferably selected from carbonate With the inorganic compound of more than a kind in sulfate（Also referred to as（D-1）Composition）.

Here, as carbonate, more than a kind can enumerated in alkali metal carbonate salt and bicarbonate alkali metal salt Carbonate.Specifically, a kind for can enumerating in sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate and SODIUM PERCARBONATE Carbonate above.In addition, as uncrystalline silicon hydrochlorate, noncrystalline sodium silicate etc. can be enumerated.

As sulfate, the sulphuric acid of more than a kind can enumerated in alkali metal persulfates and alkali sulfite slaine Salt.Specifically, the sulfate of more than a kind for can enumerating in sodium sulfate and sodium sulfite.In addition, as metal chlorination Thing, can enumerate Sodium Chloride, potassium chloride；As borate, Dexol etc. can be enumerated.

As aluminosilicate, the aluminum of more than a kind can enumerated in crystallinity aluminosilicate, noncrystalline aluminosilicate Silicate.Specifically, chabasie can be enumerated（chabazite）, modenite（mordenite）, erionite （erionite）, faujasite（faujasite）, clinoptilolite（clinoptilolite）Deng natural zeolite, type A zeolite, X Synthetic zeolite of type zeolite, y-type zeolite, zeolite L, Omega type zeolites, P type zeolite, MAP type zeolites etc. etc..In addition, conduct Clay mineral, can enumerate Talcum, pyrophyllite, montmorillonite（Saponite, Strese Hofmann's hectorite., sauconite, stevensite （Stevensite）, montmorillonite, beidellite（Beidellite）, nontronite etc.）, Vermiculitum, Muscovitum（Phlogopite, biotite, ferrum lithium Muscovitum, white mica, paragonite, seladonit, glauconite etc.）, chlorite（Clinochlore, chamosite, nepouite （Nimite）, manganchlorite（pennantite）, mackensite（Sudoite）, Donbasite etc.）, clintonite（Holmesite, Emerylite etc.）, Thulite（thulite）, serpentine minerals（Antigorite, lizardite, choysotile, pictoamesite （amesite）, cronstedtite, berthierine（berthierine）, greenalite, garnierite etc.）, kaolin mineral（Kaolinite Stone, dickite, nacrite, galapectite etc.）Deng.Wherein, from from the viewpoint of flexibility, preferably talc, montmorillonite, bloating tendency cloud Mother, Vermiculitum, choysotile, kaolin mineral etc., further preferred montmorillonite, more preferred montmorillonite.

[dress material powder detergent composition]

The dress material powder detergent composition of the present invention contains 5~40 mass %（A）Composition, from clean-up performance, foaming From the viewpoint of property, defoaming,（A）The content of composition in the composition be preferably 8~30 mass %, more preferably 10~ 27 mass %, more preferably 12~25 mass %, more preferably 12~20 mass %.In addition, the dress material of the present invention is washed with powder Wash agent compositionss to contain（A）More than mass % of composition 5, from from the viewpoint of clean-up performance, foaming characteristic, defoaming, preferably comprise 8 More than quality %, more than further preferably 10 mass %, more preferably contain more than 12 mass %, and, contain（A）Composition Below 40 mass %, from from the viewpoint of clean-up performance, foaming characteristic, defoaming, preferably comprise below 30 mass %, further preferably Below 27 mass %, more preferably contain below 25 mass %, below further preferably 20 mass %.

From from the viewpoint of clean-up performance, foaming characteristic, defoaming, particularly from from the viewpoint of defoaming and spatter property, Wherein from from the viewpoint of defoaming,（A）In composition（A-1）Composition and（A-2）Total quality of composition be 60 mass % with On, it is more than preferably 80 mass %, more than more preferably 85 mass %, more than more preferably 90 mass %, further more excellent Elect as more than 95 mass %.In addition, total quality can be more than 97 mass %, can be more than 99 mass %, further also may be used Think 100 mass %.

（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] it is more than 0/10, preferably 1.2/8.8 more than, more preferably more than 2/8, more preferably more than 2.5/7.5, more preferably more than 3/7, more Preferably more than 3.5/6.5, more preferably more than 4/6.In addition, the mass ratio is below 6.5/3.5, preferably less than 6/4, More preferably below 5.5/4.5, more preferably below 5.2/4.8, more preferably less than 5/5.In addition, from spatter property From the viewpoint of energy, foaming characteristic, defoaming,（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] For 0/10~6.5/3.5, preferably 0/10~6/4, more preferably 1.2/8.8~6/4, more preferably 2/8~6/4, More preferably 2.5/7.5~6/4, more preferably 3/7~5.5/4.5, more preferably 3.5/6.5~5.2/4.8, more Preferably 4/6~5/5.

The dress material of the present invention is contained with powder detergent composition（B）Mass % of composition 0.1~3, from foaming characteristic, defoaming From the viewpoint of,（B）The content of composition is preferably in the composition 0.2~1.5 mass %, more preferably 0.3~1.2 matter Amount %, more preferably 0.5~1 mass %.In addition, the dress material of the present invention is contained with powder detergent composition（B）The matter of composition 0.1 Amount more than %, from from the viewpoint of foaming characteristic, defoaming, preferably comprises more than 0.2 mass %, further preferably 0.3 mass % More than, more preferably contain more than 0.5 mass %, and, contain（B）Below mass % of composition 3, from foaming characteristic, the sight of defoaming Point sets out, and preferably comprises below 1.5 mass %, below further preferably 1.2 mass %, more preferably containing 1 mass % with Under.Particularly from from the viewpoint of foaming characteristic,（B）The content of composition is excellent in the dress material powder detergent composition of the present invention Elect as more than 0.2 mass %, more than more preferably 0.3 mass %, more than more preferably 0.5 mass %.On the other hand, from From the viewpoint of defoaming,（B）The content of composition is preferably 1.5 matter in the dress material powder detergent composition of the present invention Amount below %, below more preferably 1.2 mass %, below more preferably 1 mass %.In addition,（B）The content of composition is at this 1 mass % can be less than in the dress material powder detergent composition of invention, further can also be for below 0.8 mass %.

From from the viewpoint of clean-up performance, foaming characteristic, defoaming,（A-2）Composition with（B）Composition mass ratio [（A-2）Into Point/（B）Composition] it is 8/1~60/1, preferably 10/1~40/1, more preferably 12/1~25/1.In addition, from spatter property From the viewpoint of energy, foaming characteristic, defoaming,（A-2）Composition with（B）Composition mass ratio [（A-2）Composition/（B）Composition] it is 8/1 More than, preferably more than 10/1, more preferably more than 12/1, and, it is less than 60/1, preferably less than 40/1, it is more excellent Elect less than 25/1 as.Particularly from from the viewpoint of defoaming,（A-2）Composition with（B）Composition mass ratio [（A-2）Composition/ （B）Composition] it is preferably more than 10/1, more preferably more than 12/1.On the other hand, from from the viewpoint of foaming characteristic,（A- 2）Composition with（B）Composition mass ratio [（A-2）Composition/（B）Composition] be preferably less than 40/1, more preferably 25/1 with Under.

In the present invention, by making（A）Composition,（B）The content and ratio of composition can be reduced always in particular range Since the phosphatic use level to environment high load capacity that coordinates more in large quantities.In the present invention, from reduction carrying capacity of environment Viewpoint is set out,（C）The content of composition is in the composition 0~8 mass %, in addition, more than 0 mass % and below 8 mass %, to enter One step is preferably below 7 mass %, below more preferably 5 mass %, below more preferably 3 mass %, and more preferably 1 matter Amount below %, more preferably 0 mass %.

The dress material of the present invention is contained with powder detergent composition（D）Mass % of composition 40~90, from productivity ratio, foaming characteristic, From the viewpoint of dissolubility, preferably 45~89 mass %, more preferably 50~87 mass %, more preferably 60~85 matter Amount %, more preferably more preferably 65~85 mass %, more preferably 70~85 mass %, 74~82 mass %.In addition, this The dress material of invention is contained with powder detergent composition（D）More than mass % of composition 40 and below 90 mass %, from productivity ratio, foaming From the viewpoint of property, dissolubility, preferably comprise more than 45 mass %, more than further preferably 50 mass %, more preferably contain Have more than 60 mass %, more preferably containing more than 65 mass %, more preferably containing more than 70 mass %, more preferably contain 74 More than quality %, also, it is preferred that containing below 89 mass %, below further preferably 87 mass %, more preferably containing 85 matter Amount below %, more preferably containing below 82 mass %.Additionally, the dress material of the present invention is preferably comprised with powder detergent composition （D-1）Mass % of inorganic compound 45~85 more than composition, i.e. 1 in carbonate and sulfate kind, further preferably contains There are 50~80 mass %, more preferably containing 55~75 mass %, more preferably containing 60~70 mass %.In addition, the clothing of the present invention Material powder detergent composition contains（D-1）Inorganic compound more than composition, i.e. 1 in carbonate and sulfate kind It is preferred that more than 45 mass %, more than further preferably 50 mass %, more preferably containing more than 55 mass %, more preferably containing Have more than 60 mass %, additionally, it is preferred that containing below 85 mass %, below further preferably 80 mass %, more preferably containing Below 75 mass %, more preferably containing below 70 mass %.

The present invention dress material powder detergent composition can be by described content according to replace with coordinate raw material in Ratio as ratio coordinating（A）Composition,（B）Composition, as needed（C）Composition,（D）Composition and match somebody with somebody as needed The dress material powder detergent composition of the composition of conjunction.In this case（A-1）Composition/（A-2）Composition quality ratio,（A） In composition（A-1）Composition and（A-2）Total quality of composition,（A-2）Composition/（B）The mass ratio of composition also with above range It is identical.In addition, arbitrarily preferred embodiment can select from above range.

In the present compositions can known bleach in the field containing detergent（Bleach-activating etc.）, again Contamination inhibitor, soft agent, reducing agent, fluorescent whitening agent, foam inhibitor, spice, enzyme（Cellulase, protease, pectase, Lipase, glucanase, amylase etc.）, coloring agent etc..

The compositionss of the present invention, the moisture from from the viewpoint of dissolubility, productivity ratio, in compositionss（By JIS K3362:The 2008 heating loss methods recorded）Preferably 0.5~10 mass %, more preferably 1~10 mass %, more preferably For 2~8 mass %, more preferably 3~6 mass %.Based on it is same the reasons why, the present invention compositionss in moisture（By JIS K3362:The 2008 heating loss methods recorded）More than preferably 0.5 mass %, more than more preferably 1 mass %, more preferably More than 2 mass %, it is more than more preferably 3 mass %, also, it is preferred that for below 10 mass %, more preferably 8 mass % with Under, below more preferably 6 mass %.

The compositionss of the present invention, from from the viewpoint of dissolubility, apparent density（Use JIS K3362：The side of 2008 defineds The apparent density that method is determined）Preferably below 1600g/L, more preferably below 1300g/L, more preferably 1000g/L Below.In addition, from convenience or reducing garbage（The storage of product, packaging box used etc.）From the viewpoint of, it is apparent close Degree is preferably more than 300g/L, more preferably more preferably more than 350g/L, more than 400g/L.

The compositionss of the present invention, from from the viewpoint of dissolubility, using JIS Z8801 standard screens be allowed to vibrate 5 minutes it Afterwards, the mean diameter tried to achieve according to the mass fraction obtained by the size of mesh is preferably 150~1000 μm, more preferably 150~800 μm, more preferably 180~600 μm.In addition, the compositionss of the present invention, from from the viewpoint of dissolubility, use JISZ8801 standard screens are allowed to vibrate 5 minutes afterwards, according to the mean diameter that the mass fraction obtained by the size of mesh is tried to achieve Preferably more than 150 μm, more preferably more than 180 μm, also, it is preferred that be less than 1000 μm, more preferably 800 μm with Under, more preferably less than 600 μm.

The present invention compositionss, from clean-up performance, to dress material it is low damaging from the viewpoint of, JIS K3362:2008 notes The pH of the 0.1 mass % aqueous solution determined at 20 DEG C for carrying is preferably 8~12, more preferably 9~11.5, more preferably For 9.5~11, more preferably 10~11.In addition, the compositionss of the present invention, from clean-up performance, to the low abrasive of dress material Viewpoint is set out, JIS K3362:The pH of the 2008 0.1 mass % aqueous solutions determined at 20 DEG C recorded is preferably more than 8, enters one Step is preferably more than 9, more preferably more than 9.5, more preferably more than 10, also, it is preferred that be less than 12, further preferably For less than 11.5, more preferably less than 11.

The compositionss of the present invention, from from the viewpoint of mobility and non-agglomerated, preferably carry out table by surface capping agents Face is modified.

The compositionss of the present invention can be manufactured with known method.It is, for example possible to use in spray drying method, dry type With method, drying-granulating method, dry pigmentation, fluidized bed seasoning, film drying method, extruding pelletization method, rotation comminution granulation, stirring-granulating Method, compacting comminution granulation, surfactant support method or select the method for combining to be manufactured from these.

For example, compositionss of the invention can be by being used as（A）The surfactant of composition, conduct（C）The phosphorus of composition Hydrochlorate, conduct（D）In the mixture of the inorganic compound of composition after addition heating（B）Composition simultaneously is mixed to manufacture.So And, from general（B）Viewpoint and raising that composition equably mixes with other compositions（B）It is excellent from the viewpoint of the operability of composition Select it is previously fabricated containing（B）The particle swarm of composition, the manufacture method mixed with other compositions.That is, compositionss of the invention are preferred By containing（B）The manufacture method that the particle swarm of composition mixes with other compositions is being manufactured.

Contain（B）The particle swarm of composition can be by being used as（A-1）The LABS of the acid precursors of composition and As（D）The water miscible alkali inorganic salt mixing of composition, carry out in dry type and when, addition（B）Composition is manufacturing.The particle swarm is used Contained with powder detergent composition in the dress material of the present invention（A-1）Composition conduct（A）Composition, containing water miscible alkali inorganic salt As（D）The situation of composition.（B）Composition addition can dry type neutralization operation before, it is any in operation and after operation More than one operation or two operations add, from from the viewpoint of the yield of the granule for obtaining, preferably after operation.

Specifically, 1）Can add in water miscible alkali inorganic salt（B）It is mixed with LABS after composition Close, carry out dry type neutralization；2）Add simultaneously in water miscible alkali inorganic salt（B）Composition and LABS or addition Their mixture, carries out dry type neutralization；3）Water miscible alkali inorganic salt and LABS can be mixed, be done After formula neutralization, addition（B）Composition.In these methods, can suitably distribute as needed（C）Composition,（D）Composition is used.

As addition（B）The speed of composition, contains from suppression（B）From the viewpoint of the excessive cohesion of the particle swarm of composition, Preferably with respect to the water miscible alkali inorganic salts of 100kg, will（B）Composition is added with 1~80kg/ minutes, further preferably with 2~ 60kg/ minutes add, and are more preferably added with 3~50kg/ minutes.In addition, as addition（B）The speed of composition, contains from suppression Have（B）From the viewpoint of the excessive cohesion of the particle swarm of composition, preferably with respect to the water miscible alkali inorganic salts of 100kg, will（B）Into Divide and more than minute added with 1kg/, further preferably more than minute added with 2kg/, more preferably added with 3~50kg/ minutes, Also, it is preferred that to add below 80kg/ minutes, further preferably to add below 60kg/ minutes, more preferably with 50kg/ point Add below clock.In addition, as described（B）The adding method of composition, can be carried out continuously or several times.

As water miscible alkali inorganic salt used herein, alkali metal carbonate salt and bicarbonate alkali metal salt are preferably selected from In more than a kind of carbonate, specifically, be preferably selected from sodium carbonate, potassium carbonate, sodium bicarbonate, potassium bicarbonate and cross carbon 1 kind in sour sodium or carbonate of more than two kinds.In water miscible alkali inorganic salt, the easiness from operation is easy with what is obtained Property and LABS reactivity and the operability of detergent addition particle swarm that obtains from the viewpoint of, preferably For sodium carbonate, more preferably light ash.In addition, referring to that the dissolubility of the water relative to 25 DEG C is with regard to the water solublity of alkali inorganic salt More than 0.5g/100g.

The amount of water miscible alkali inorganic salt is preferably than the amount needed for the neutralization of LABS（Neutralization equivalent）It is real More measure in matter, for example, it is preferable to for 1~150 times of neutralization equivalent, more preferably 3~125 times, more preferably 4~ 100 times.In addition, the amount of water miscible alkali inorganic salt is preferably more than 1 times of the neutralization equivalent, more preferably 3 times with On, more preferably more than 4 times, also, it is preferred that for less than 150 times, more preferably less than 125 times, more preferably 100 Below times.

For containing（B）The particle swarm of composition can further add surface modifier carry out surface be modified.As surface Modifying agent, it is possible to use the known surface modifier being usually used during the surface of granule is modified, be adapted to using crystallinity or Noncrystalline aluminosilicate（Zeolite）, calcite, kieselguhr, silicon dioxide etc., preferred zeolite.In addition, the amount phase of surface modifier For the particle swarm before modified of 100 mass parts is preferably 10~40 mass parts, more preferably 15~35 mass parts.Separately Outward, the amount of surface modifier is preferably more than 10 mass parts, more preferably relative to the particle swarm before modified of 100 mass parts More than 15 mass parts, also, it is preferred that being below 40 mass parts, below more preferably 35 mass parts.These surface modifiers Can be（D）Composition.Therefore, contain（B）The particle swarm of composition can contain conduct（D）The aluminosilicate of composition.

In the particle swarm for obtaining（B）The content of composition, from from the viewpoint of the operability of the granule for obtaining, preferably 3.5~20 mass %, more preferably 4~18 mass %, more preferably 5~15 mass %, are even more preferably 5~13 Quality %.In addition, in the particle swarm for obtaining（B）The content of composition, from from the viewpoint of the operability of the granule for obtaining, preferably More than 3.5 mass %, it is more than more preferably 4 mass %, it is more than more preferably 5 mass %, also, it is preferred that for 20 mass % with Under, below more preferably 18 mass %, below more preferably 15 mass %, below more preferably 13 mass %.

LABS with（B）The mass ratio of composition（LABS/（B）Composition）, from the granule for obtaining Operability from the viewpoint of, preferably 1/10~10/1, more preferably 1/4~4/1, more preferably 1/3~3/1, More preferably 2/5~5/2, more preferably 2/3~2/1, more preferably 1/1~3/2.In addition, LABS With（B）The mass ratio of composition（LABS/（B）Composition）, from from the viewpoint of the operability of the granule for obtaining, preferably For more than 1/10, more preferably more than 1/4, more preferably more than 1/3, more preferably more than 2/5, more preferably 2/ More than 3, more preferably more than 1/1, also, it is preferred that for less than 10/1, more preferably less than 4/1, more preferably 3/1 with Under, more preferably less than 5/2, more preferably less than 2/1, more preferably less than 3/2.

Contain in manufacture（B）In the particle swarm of composition, stirring granulating machine is preferably used, as batch-wise stirring-granulating Machine, can enumerate LODIGE blenders（MATSUBO Corporation are manufactured）, ploughshare mixer（Ploughshare Mixer）（Pacific Machinery ＆ Engineering Co., Ltd. manufactures）, vertical comminutor（Powrex Corp. are manufactured）, homogenizer（Deep river work Industry Co., Ltd. manufactures）, Gericke blenders（Mingzhi Machinery Co., Ltd. manufactures）Deng.As the stirring granulating machine of continuous way, Continuous way LODIGE blender can be enumerated（Speed stirrer；Holdup time is long）, or as homogenizer（It is detained Time is shorter）CB Recycler（Loedige is manufactured）、Turbulizer（Hosokawa Micron Corporation Manufacture）, Schugi blenders（Powrex Corp. are manufactured）, jet-impingement blender（FLOW JET MIXER）（Powder grinds a plant formula Commercial firm manufactures）Deng.

Manufacture method above is to contain in manufacture dress material powder detergent composition of the invention（A-1）Composition conduct （A）Composition, containing water miscible alkali inorganic salt conduct（D）The method of the compositionss of composition.And, if with the present invention clothing The relation of the composition of material powder detergent composition is illustrated, then the manufacture method tool of dress material powder detergent composition Have：It is used as by mixing（A-1）The LABS of the acid precursors of composition and conduct（D）The water miscible alkali of composition is inorganic Salt carrys out dry type neutralization（A-1）The operation of the acid precursors of composition and water miscible alkali inorganic salt, before the operation of the dry type neutralization, work In sequence or after operation, addition（B）Composition, so as to get particle swarm in contain（B）Composition, will contain（B）Described of composition Particle swarm and other composition mixing.

In the method, LABS can use final group equivalent to dress material powder detergent composition A part in（A-1）The amount of composition.In addition,（B）Composition is preferably used equivalent to dress material powder detergent composition In final composition（B）The amount of the total amount of composition.In addition, water miscible inorganic salt can also be used being washed with powder equivalent to dress material Wash the amount of a part of water-soluble inorganic salt in the final composition of agent compositionss.Respectively with dress material powder detergent composition Final composition a part amount using in the case of LABS or water miscible inorganic salt, surplus with contain （B）The particle swarm of composition is mixed.

The present invention relates to a kind of hand washing washing methods, the hand washing washing methods is to make cleaned material contact containing above-mentioned The rinse water of the dress material powder detergent composition of invention, then hand-washes cleaned material.Use as the dress material using the present invention The hand washing washing methods of powder detergent composition, can enumerate the dress material made as cleaned material（Can also include cloth and silk with Outer fiber product）Contact, the dipping rinse water by obtained in the dress material powder detergent composition of the present invention, is hand-washed Method.If time of contact and/or dip time are long, cleaning performance is high, by contacting and/or impregnating 5~15 minutes, can be with Obtain good effect.If placed 5~15 minutes in the especially dirty direct coating composition in part, higher effect can be obtained Really.Rinse water uses the compositionss containing the present invention and the rinse water of water.Rinse water preferably with the compositionss/water of the present invention= Obtained from the compositionss and water of 10/1~1/3,000, more preferably 1/1~1/2, the 000 mass ratio mixing present invention. Relative to dress material（Cleaned material）Quality, the quality of rinse water is preferably 2~100 times, more preferably 3~50 times, more More preferably 5~25 times.In addition, relative to dress material（Cleaned material）Quality, the quality of rinse water be preferably 2 times with On, more preferably more than 3 times, more preferably more than 5 times, also, it is preferred that be less than 100 times, more preferably 50 times with Under, more preferably less than 25 times.If the dress material due to fully washing the rinse water for contacting involved in the present invention by rubbing with the hands with handss, Good cleaning capacity not only can be obtained, and galore bubbled, therefore, visually preferably it.After the hand washing washed by rubbing with the hands etc., Dress material is taken out from rinse water（Cleaned material）, wring out removing water or remove water using dewaterer, it is allowed to impregnated in again newly Water [hereinafter referred to as washings] in.Washings can be the water, or flowing water of the savings such as wash basin.Washings relative to The quality of cleaned material, on the basis of rinsing the total amount of washings used, preferably 2~1,000 times, more preferably 5 ~500 times, be still more preferably 10~100 times.In addition, quality of the washings relative to dress material, to rinse rinsing used On the basis of the total amount of water, preferably more than 2 times, more preferably more than 5 times, more preferably more than 10 times, also, it is preferred that being Less than 1,000 times, more preferably less than 500 times, more preferably less than 100 times.Be allowed in the stage for impregnating washings by It is dissolved in washings again in surfactant on dress material etc. is residued in, accordingly, it can be seen that foaming.If repeatedly The operation, then do not bubble, and terminates rinsing.In general washing by hand washing, such as in the situation using common detergent Under, it usually needs more than 5 times, can just terminate rinsing with less than 3 times in the present invention, can just be tied with considerably less washings Beam is rinsed.

In the present invention, it is preferred to use the rinse water of the compositionss containing the present invention and water as rinse water, rinsed with water The cleaned material hand-washed.That is, hand washing washing methods of the invention preferably has：Hand washing contacted the dress material containing the present invention and used The operation of the cleaned material of the rinse water of powder detergent composition and water；With the work of the cleaned material hand-washed with water rinsing Sequence.In the present invention, used in the modulation of rinse water hardness of water and/or the hardness of water for rinsing, from cleaning capacity From the viewpoint of rinsability, preferably 1 ° DH~50 ° DH, more preferably 2 ° DH~50 ° DH, more preferably 3 ° DH~ 50 ° of DH, more preferably 5 ° DH~50 ° DH, more preferably 8 ° DH~50 ° DH, more preferably 10 ° DH~50 ° DH.Separately Outward, used in the modulation of rinse water hardness of water and/or the hardness of water for rinsing, from cleaning capacity and rinsability sight Point set out, preferably 1 ° more than DH, more preferably 2 ° more than DH, more preferably 3 ° more than DH, more preferably 5 ° DH with On, more preferably 8 ° more than DH, more preferably 10 ° more than DH, also, it is preferred that being 50 ° of below DH.

Embodiments of the present invention illustrated below.

<1>A kind of dress material powder detergent composition, wherein, containing following（A）~（D）：

（A）Comprising（A-1）Linear alkylbenzene sulfonate (LAS) is [hereinafter referred to as（A-1）Composition] and（A-2）Alkyl sulfate is [below Referred to as（A-2）Composition] surfactant [hereinafter referred to as（A）Composition], its content is more than 5 mass % and below 40 mass %；

（B）The higher alcohol that carbon number is 12 higher alcohol and/or carbon number is 14 is [hereinafter referred to as（B）Composition], its Content is more than 0.1 mass % and below 3 mass %；

（C）Phosphate, its content is 0~8 mass %；And

（D）The inorganic compound of solid is [hereinafter referred to as（D）Composition], its content be 40 mass % more than and 90 mass % with Under,

（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] it is 0/10~6.5/3.5, preferably For 0/10~6/4,

<2>As described above<1>Described dress material powder detergent composition, wherein, contain（A）It is more than mass % of composition 8, Further containing more than 10 mass %, further containing 12 mass % more than, and, contain（A）Below mass % of composition 40, enter one Step containing below 30 mass %, further containing 27 mass % below, further containing 25 mass % below.

<3>As described above<1>Or<2>Described dress material powder detergent composition, wherein, contain（B）The matter of composition 0.2 Amount more than %, further containing 0.3 mass % more than, further containing 0.5 mass % more than, and, further containing 1.5 mass % Hereinafter, further containing 1.2 mass % below, further containing 1 mass % below.

<4>As described above<1>~<3>Any one of dress material powder detergent composition, wherein, contain（C）Into Divide below 7 mass %, preferably comprise below 5 mass %, below further preferably 3 mass %, even more preferably containing 0 matter Amount %.

<5>As described above<1>~<3>Any one of dress material powder detergent composition, wherein, contain（D）Into It is more than point 45 mass %, further containing 50 mass % more than, further containing 60 mass % more than, further containing 65 mass % with On, further containing 70 mass % more than, further containing 74 mass % more than, and, contain（D）Below mass % of composition 89, enter One step contains below 87 mass %, further containing 85 mass % below, further containing 82 mass % below.

<6>A kind of dress material powder detergent composition, wherein, dress material powder detergent composition coordinates following 's（A）~（D）Form,

（C）Phosphate, its content is 0~8 mass %；And

In coordinating raw material（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] for 0/10~ 6.5/3.5, preferably 0/10~6/4,

<7>As described above<6>Described dress material powder detergent composition, wherein, in coordinating raw material,（A）The ratio of composition Example for more than 8 mass %, it is more than more preferably 10 mass %, it is more than more preferably 12 mass %, and, be 30 mass % with Under, below more preferably 27 mass %, below more preferably 25 mass %.

<8>As described above<6>Or<7>Described dress material powder detergent composition, wherein, in coordinating raw material,（B）Composition Ratio be 0.2 mass % more than, it is more than more preferably 0.3 mass %, it is more than more preferably 0.5 mass %, and, be Below 1.5 mass %, below more preferably 1.2 mass %, below more preferably 1 mass %.

<9>As described above<6>~<8>Any one of dress material powder detergent composition, wherein, coordinate raw material In,（C）The ratio of composition is below 7 mass %, below preferably 5 mass %, below more preferably 3 mass %, further more Preferably 0 mass %.

<10>As described above<6>~<9>Any one of dress material powder detergent composition, wherein, coordinate raw material In,（D）The ratio of composition is more than 45 mass %, more than more preferably 50 mass %, more than more preferably 60 mass %, more Plus more than preferably 65 mass %, it is more than more preferably 70 mass %, it is more than more preferably 74 mass %, and, it is 89 matter Amount below %, below more preferably 87 mass %, below more preferably 85 mass %, below more preferably 82 mass %.

<11>As described above<1>~<10>Any one of dress material powder detergent composition, wherein,（A-1）Into Point with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] be 1.2/8.8~6/4, preferably 2/8~6/4, enter one Step is preferably 2.5/7.5~6/4, and more preferably 3/7~5.5/4.5, more preferably 3.5/6.5~5.2/4.8 are more excellent Elect 4/6~5/5 as.

<12>As described above<1>~<11>Any one of dress material powder detergent composition, wherein,（A）Composition In（A-1）Composition and（A-2）Total quality of composition is more than 80 mass %, more than preferably 85 mass %, further preferably More than 90 mass %, even more preferably for 95 mass % more than, even more preferably for 97 mass % more than, it is further more excellent Elect as more than 99 mass %.

<13>As described above<1>~<12>Any one of dress material powder detergent composition, wherein,（A-2）Into Point with（B）Composition mass ratio [（A-2）Composition/（B）Composition] it is 10/1~40/1, preferably 12/1~25/1.

<14>A kind of dress material powder detergent composition, wherein, containing following（A）~（D）：

（A）Comprising（A-1）Linear alkylbenzene sulfonate (LAS) is [hereinafter referred to as（A-1）Composition] and（A-2）Alkyl sulfate is [below Referred to as（A-2）Composition] surfactant [hereinafter referred to as（A）Composition], its content be 5 mass % more than, preferably 8 mass % with On, it is more than more preferably 10 mass %, it is more than more preferably 12 mass %, and, it is preferably 30 matter below 40 mass % Amount below %, below more preferably 27 mass %, below more preferably 25 mass %；

（B）The higher alcohol that carbon number is 12 higher alcohol and/or carbon number is 14, preferably carbon number are 12 Higher alcohol is [hereinafter referred to as（B）Composition], its content be 0.1 mass % more than, it is more than preferably 0.2 mass %, more preferably 0.3 It is more than quality %, it is more than more preferably 0.5 mass %, and, it is below 3 mass %, it is more excellent below preferably 1.5 mass % Elect as below 1.2 mass %, below more preferably 1 mass %；

（C）Phosphate, preferably inorganic phosphate are [hereinafter referred to as（C）Composition], its content be 0~8 mass %, preferably 7 It is even more preferably 0 mass % below more preferably 3 mass % below more preferably 5 mass % below quality %；With And

（D）The inorganic compound of solid, preferably（C）The inorganic compound of the solid beyond composition, its content is 40 matter Amount more than %, it is more than preferably 45 mass %, it is more than more preferably 50 mass %, it is more than more preferably 60 mass %, and, it is Below 90 mass %, below preferably 89 mass %, below more preferably 87 mass %, below more preferably 85 mass %,

（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] it is more than 0/10, preferably 1.2/8.8 more than, more preferably more than 2/8, more preferably more than 2.5/7.5, more preferably more than 3/7, it is more excellent Elect more than 3.5/6.5 as, more preferably more than 4/6, and, it is below 6.5/3.5, preferably less than 6/4, more preferably 5.5/4.5 it is following, more preferably below 5.2/4.8, more preferably less than 5/5,

（A）In composition（A-1）Composition and（A-2）Total quality of composition is more than 60 mass % preferably 80 mass % More than, it is more than more preferably 85 mass %, it is more than more preferably 90 mass %, even more preferably for 95 mass % more than,

（A-2）Composition with（B）Composition mass ratio [（A-2）Composition/（B）Composition] for more than 8/1, preferably 10/1 with On, more preferably more than 12/1, and, it is less than 60/1, preferably less than 40/1, more preferably less than 25/1.

<15>A kind of dress material powder detergent composition, wherein, the dress material with powder detergent composition coordinate with Under（A）~（D）Form,

（A）Comprising（A-1）Linear alkylbenzene sulfonate (LAS) is [hereinafter referred to as（A-1）Composition] and（A-2）Alkyl sulfate is [below Referred to as（A-2）Composition] surfactant [hereinafter referred to as（A）Composition], its content is more than 5 mass %（Coordinate the ratio in raw material Example）, it is more than more preferably 8 mass %, it is more than more preferably 10 mass %, it is more than more preferably 12 mass %, and, it is Below 40 mass %（Coordinate the ratio in raw material）, below more preferably 30 mass %, below more preferably 27 mass %, more Plus below preferably 25 mass %；

（B）The higher alcohol that carbon number is 12 higher alcohol and/or carbon number is 14, preferably carbon number are 12 Higher alcohol is [hereinafter referred to as（B）Composition], its content is more than 0.1 mass %（Coordinate the ratio in raw material）, more preferably 0.2 It is more than quality %, it is more than more preferably 0.3 mass %, it is more than more preferably 0.5 mass %, and, it is 3 mass %（Coordinate former Ratio in material）Hereinafter, more preferably below 1.5 mass %, below more preferably 1.2 mass %, more preferably 1 matter Amount below %；

（C）Phosphate is [hereinafter referred to as（C）Composition], its content is 0~8 mass %（Coordinate the ratio in raw material）, preferably It is even more preferably 0 mass % below more preferably 3 mass % below more preferably 5 mass % below 7 mass %； And

（D）The inorganic compound of solid, preferably（C）The inorganic compound of the solid beyond composition is [hereinafter referred to as（D）Into Point], its content is 40 mass %（Coordinate the ratio in raw material）More than, it is more than more preferably 45 mass %, more preferably 50 It is more than quality %, it is more than more preferably 60 mass %, and, it is 90 mass %（Coordinate the ratio in raw material）Hereinafter, more preferably Below 89 mass %, below more preferably 87 mass %, below more preferably 85 mass %,

In coordinating raw material（A-1）Composition with（A-2）Composition mass ratio [（A-1）Composition/（A-2）Composition] for 0/10 with On, preferably more than 1.2/8.8, more preferably more than 2/8, more preferably more than 2.5/7.5, more preferably 3/7 with On, more preferably more than 3.5/6.5, more preferably more than 4/6, and, it is below 6.5/3.5, preferably less than 6/4, More preferably below 5.5/4.5, more preferably below 5.2/4.8, more preferably less than 5/5,

In coordinating raw material（A-2）Composition with（B）Composition mass ratio [（A-2）Composition/（B）Composition] it is more than 8/1, it is excellent Elect more than 10/1, more preferably more than 12/1 as, and, it is less than 60/1, preferably less than 40/1, more preferably 25/1 Below.

<16>As described above<1>~<15>Any one of dress material powder detergent composition, wherein,（A-2）Into In point, it is more than 50 mass % preferably 70 mass % that the carbon number in whole alkyl is the ratio of 12~15 straight chained alkyl More than, it is more than more preferably 90 mass %, it is more than more preferably 99 mass %, more preferably 100 mass %.

<17>As described above<10>~<16>Any one of dress material powder detergent composition, wherein,（A-1）Into Point and（A-2）Beyond composition（A）Composition is polyoxyalkylene alkyl（The carbon number of alkyl：10~15, it is oxyalkylene, excellent Elect the average addition molal quantity of ethylene oxide as：1~25, preferably 2~20, more preferably 2~15, more preferably 2 ~10, more preferably 4~8）.

<18>As described above<1>~<17>Any one of dress material powder detergent composition, wherein,（C）Composition For inorganic phosphate.

<19>As described above<1>~<18>Any one of dress material powder detergent composition, wherein,（D）Composition It is from water miscible alkali inorganic salt, the water in sulfate and metal chloride in carbonate and uncrystalline silicon hydrochlorate In the neutral inorganic of dissolubility and the water-insoluble inorganic salt in aluminosilicate and clay mineral select a kind with On, it is preferably selected from more than in carbonate and sulfate a kind.

<20>As described above<1>~<19>Any one of dress material powder detergent composition, wherein, in compositionss Moisture（By JIS K3362:The 2008 heating loss methods recorded）More than 1 mass %, it is more than more preferably 2 mass %, It is more than more preferably 3 mass %, and, it is below 10 mass %, below more preferably 8 mass %, more preferably 6 mass % Below.

<21>As described above<1>~<20>Any one of dress material powder detergent composition, wherein, JIS K3362:The pH of the 2008 0.1 mass % aqueous solutions determined at 20 DEG C recorded is more than 8, more preferably more than 9, more Preferably more than 9.5, more preferably more than 10, and, it is less than 12, more preferably less than 11.5, more preferably 11 Below.

<22>One kind hand washing washing methods, wherein, the hand washing washing methods is contacted containing above-mentioned to make cleaned material<1> ~<21>Any one of dress material powder detergent composition rinse water, then hand-wash cleaned material.

<23>As described above<22>Described hand washing washing methods, wherein, rinse water contains the compositionss and water, and uses Water rinses the cleaned material hand-washed, and the hardness of water used of the hardness of water and/or rinsing used in the modulation of rinse water is 1 ° of DH~50 ° DH.

<24>As described above<22>Or<23>Described hand washing washing methods, wherein, the water used in the modulation of rinse water Hardness and/or rinsing hardness of water used is preferably 1 ° of DH~50 ° DH, more preferably 2 ° DH~50 ° DH, more preferably For 3 ° of DH~50 ° DH, more preferably 5 ° DH~50 ° DH, more preferably 10 ° DH~50 ° DH.

<25>Compositionss as dress material powder detergent purposes, wherein, the compositionss contain following（A）~ （D）：

（C）Phosphate, its content is 0~8 mass %；And

<26>Compositionss as hand washing washing powder detergent purposes, wherein, the compositionss contain following（A） ~（D）：

（C）Phosphate, its content is 0~8 mass %；And

<27>A kind of manufacture method of dress material powder detergent composition, it is above-mentioned<1>~<21>Any one of institute The manufacture method of the dress material powder detergent composition stated, wherein, the dress material powder detergent composition contains（A-1） Composition conduct（A）Composition, containing water miscible alkali inorganic salt conduct（D）Composition,

The manufacture method of the dress material powder detergent composition has：By mixing（A-1）The acid precursors of composition and Water miscible alkali inorganic salt carrys out dry type neutralization（A-1）The operation of the acid precursors of composition and water miscible alkali inorganic salt,

<28>As described above<27>The manufacture method of described dress material powder detergent composition, wherein, contain（B）Composition Particle swarm in（B）The content of composition is preferably 3.5~20 mass %, more preferably 4~18 mass %, more preferably 5~15 mass %, more preferably 5~13 mass %.

<29>As described above<27>Or<28>The manufacture method of described dress material powder detergent composition, wherein,（A-1） The acid precursors of composition with（B）Composition mass ratio [（A-1）The acid precursors of composition/（B）Composition] 1/10~10/1 is preferably, enter one Step is preferably 1/4~4/1, more preferably 1/3~3/1, is even more preferably 2/5~5/2, is even more preferably 2/3 ~2/1, it is still more preferably 1/1~3/2.

<30>As described above<27>~<29>Any one of dress material powder detergent composition manufacture method, its In, contain（B）The particle swarm of composition be the dry type neutralization operation before, any one operation after operation neutralization step or More than two operations add（B）The granule that composition is obtained.

Embodiment

Below example is the explanation carried out to the enforcement of the present invention.Embodiment is to saying that the illustration of the present invention is carried out It is bright, it is not intended to limit the present invention.

, with the use of following compositions, with following methods dress material powder detergent composition is modulated shown in table 1,2, Carry out following evaluation.In showing the result in table 1,2.

·LAS：Sodium alkyl benzene sulfonate（With the manufacture of Guang Chunyao operations Co., Ltd., straight chained alkyl（Carbon number be 12~ 14）Benzene sulfonic acid sodium salt）

·AS：The carbon number of alkyl is 12~14 alkyl sulfate（Kao Corp manufactures, EMAL10P, all The ratio of the straight chained alkyl in alkyl is 100 mass %）

Nonionic surfactant 1：It is the oxidation of 12~14 average 6mol of primary alconol addition to the carbon number of alkyl The polyoxyethylene alkyl ether of ethylene（Kao Corp, Emulgen108）

Nonionic surfactant 2：It is the oxidation of 12~14 average 20mol of primary alconol addition to the carbon number of alkyl The polyoxyethylene alkyl ether of ethylene（Kao Corp, Emulgen121）

C12 alcohol：Lauryl alcohol（Kao Corp manufactures, KALCOL2098）

C14 alcohol：Myristyl alcohol（Kao Corp manufactures, KALCOL4098）

C10 alcohol：Decanol（Kao Corp manufactures, KALCOL1098）

C16 alcohol：Spermol（Kao Corp manufactures, KALCOL6098）

Sodium tripolyphosphate：Sodium tripolyphosphate（ShiShimonoseki Mitsui Chemicals, Inc manufactures）

Sodium carbonate：Weight ash（Central Glass Co., Ltd. are manufactured）

Sodium bicarbonate：Sodium bicarbonate（Wako Pure Chemical Industries, Ltd. manufactures）

Noncrystalline sodium silicate：Sodium silicate（Wako Pure Chemical Industries, Ltd. manufactures）

Type A zeolite：“ZEOBUILDER”（ZEOBUILDER companies manufacture, median particle diameter：3.0μm）

Sodium sulfate：Anhydrous neutral Natrii Sulfas（Shikoku Chem manufactures）

Sodium Chloride：Sodium Chloride（Wako Pure Chemical Industries, Ltd. manufactures）

Layered clay mineral：Laundrosil DGA212（S ü d-chemie companies manufacture）

Bleach-activating：GA-10B（Dong chemical conversion industries Co., Ltd. manufactures）

Sodium polyacrylate：40 mass % aqueous sodium polyacrylates are used in the way of effective ingredient becomes the value in table （Kao Corp manufactures, Oligomer D, matter average molecular weight：10000）.

Fluorescent dye：Tinopal（BASF Japan Co., Ltd. are manufactured）

Enzyme：Protease granules（Kao Corp manufactures, KAP）

Embodiment 1~14, comparative example 1~11

Using LODIGE blenders（Song Banjiyan Co., Ltd. manufactures, capacity 20L）With the manufacture detergent combination of 5kg units Thing.According to table 1,2, above-mentioned LODIGE blenders mixture of sodium carbonate, sodium sulfate, sodium bicarbonate, chlorine are passed through with the amount that table 1,2 is recorded Change sodium, noncrystalline sodium silicate, AS, LAS.Liquid charging stock was added with 2 minutes with the amount described in table 1,2（Water, non-ionic surface are lived Property agent, aqueous sodium polyacrylate）.In addition, nonionic surfactant is added with the state for being heated to 40 DEG C.Further, will Sieved with 1180 μm of sieves by the granule for obtaining blender work pelletize in 1 minute, sieve top grade Fitzmill DKA-6 （Hosokawa Micron Corporation are manufactured）Carry out pulverization process.Mixed in the granule for obtaining using cylinder mixer Enter higher alcohol, zeolite, bleach-activating, layered clay mineral, enzyme and spice.In addition, higher alcohol is being heated to 40 DEG C of state Addition.Thus obtained embodiment 1~14, the apparent density of the granule of comparative example 1~11 be 700~1100g/L, mean diameter For 180~600 μm, the pH of 0.1 mass % aqueous solution is 10~11.

By the commercially available undershirts of 2.5kg, [GUNZE Ltd. are manufactured（YG1614 crew neck L-size, cotton 100%）] use washing machine （Panasonic manufactures NA-F70PB1 ' 2008）89.5mg/L is scaled with 20 DEG C of water temperature, with Calcium Carbonate（Deutschland hardness is 5 ° DH）The removing inorganic agent [wash conditions of hard water repeated washing 5 times：Water yield 54L, washes 12 minutes, rinses 2 times（Water storage is rinsed）, it is de- Water 5 minutes].Now, used nonionic surfactant with 0.5g/L（The average addition on the primary alconol that carbon number is 12 has The surfactant of 6mol ethylene oxides）, noncrystalline sodium silicate, sodium carbonate is with 1:1:3（Mass ratio）Mixed mixing Thing.Afterwards, it is 20 DEG C, the hard water of 89.5mg/L is scaled with Calcium Carbonate using water temperature, uses dual grooved washing machine（HITACHI systems Make, PS-H35L ' 2008）, carry out flowing water rinsing.Rinsed when rinsing is stopped foam being wholly absent, make to remove to spontaneously dry The undershirt for having removed inorganic agent and cleansing is dried, and is used with undershirt as evaluation.

（1）Foaming characteristic is evaluated

In standard circular wash basin（The diameter of bottom surface（Internal diameter）The cylinder propylene container of 25cm, high 15cm）Middle injection 3L Water temperature is 20 DEG C, the hard water of 179mg/L is scaled with Calcium Carbonate（Deutschland hardness is 10 ° of DH）（In 1.58g calcium chloride CaCl₂· 2H₂O and 1.45g magnesium sulfate MgSO₄·6H₂Adding ion exchange water in O becomes the mixed liquor of 10L, Ca/Mg=6/4（Mole Than））.Next addition powder detergent composition makes（A）Become 750ppm into subtotaling, and be allowed to dissolve.Next, heating （60℃）Modulation oil shown in following, in the way of 3 as 1g（Per 1 about 0.33g）Use dropper（φ：2mm）Drip to undershirt On collar, the undershirt is put into wherein, and the state with thorough impregnation in cleaning solution is placed 15 minutes.After placement, by one Collar on part undershirt washes 50 times by rubbing with the hands（By rubs mutually between collar and make a round trip（About 1 second）It is scaled 1 time）.Afterwards, no Undershirt is taken out, in the state of direct impregnation is in the water foam height is measured.Standard circular wash basin is being divided from from the point of view of plane For 4 parts（Fan-shaped 4 deciles）Each region in, measure foam height from the water surface from outside with ruler etc., survey at one in each region （At total 4）Foam height, calculate its meansigma methods.Then, carry out same evaluation by 3 people, using the meansigma methodss of this 3 people as Evaluation criterion.

In the case that in matting, quick foaming characteristic is bad, it is understood that be difficult to crumple, in addition, visually recognizing clear Clean power not enough, sometimes can be in order that foaming characteristic well adds detergent to increase foam.Therefore, washing each time can be increased Wash the usage amount of agent.Chinese women to 25~39 years old（N=20）The investigation with regard to foaming characteristic is carried out, as a result, in foam height For in the case of more than 0.5cm, 35% women is answered to meet, and 80% women is answered and met during more than 1.0cm, 1.5cm with 90% women is answered to meet when upper.From the result, foam height during cleaning is preferably more than 1.0cm.

* oil is modulated

By mass % of lauric acid 1, mass % of myristic acid 7.1, mass % of pentadecanoic acid 5.3, mass % of Palmic acid 14.2,17 Mass % of alkanoic acid 1, mass % of stearic acid 3.6, mass % of Oleic acid 17.8, mass % of glycerol trioleate 30, Palmic acid n-hexadecyl Mass % of ester 5, mass % of Squalene 15 are heated to about 60 DEG C, and the mixed mixture of uniform dissolution is used as modulation oil.

（2）Rinsability evaluation

In standard circular wash basin（The diameter of bottom surface（Internal diameter）The columned propylene container of 25cm, high 15cm）Middle work It is 20 DEG C, the hard water of 179mg/L is scaled with Calcium Carbonate for washings injection 5L water temperature（Used in evaluating with above-mentioned foaming characteristic The hard water similarly modulated）, put into the undershirt of 3 coil bucklings in above-mentioned foaming characteristic is evaluated.Undershirt is rubbed in washings After opening, the collar part for having carried the undershirt kneaded open per part carries it from water-bath（Carry from water-bath to wash basin about The height of 5cm is until clothes is integrally extracted）, it is placed again into afterwards in water-bath.By such up and down motion to per 1 undershirt weight After multiple 10 rinsings, it is 100~140% left relative to undershirt to make the water content of undershirt in the coil buckling undershirt on wash basin 10cm The right side, the liquid level state of the washings observed after 3 undershirt rinsings, dehydrations just terminate, according to following scales, evaluates drift Washing property.

Fraction：

6：In liquid level, on the whole residual foam is highly the foam of more than 1cm.

5：In liquid level residual foam on the whole（Less than 1cm）.

4：In liquid level 1/2 or so remains foam（Less than 1cm）.

3：In liquid level 1/4 or so remains foam（Less than 1cm）.

2：Tiny foam is remained on liquid level.

1：Without residual foam on liquid level.

If foam is easily rinsability bad during rinsing process, in order to need to carry out repeatedly rinsing so as to secondary to lather collapse Number can increase.Its result can waste substantial amounts of water.From such a viewpoint, few, the above-mentioned fraction of foam during preferred rinsing More preferably less than 3 points, more preferably less than 2 points, more preferably 1 point.

Embodiment 17

In LODIGE blender FKM-130D（Song Banjiyan Co., Ltd. manufactures, capacity 130L, jacketed）Middle input 21.97kg sodium carbonate（Light ash：Central Glass Co., Ltd.s manufacture, 100 μm of median particle diameter）, with main wing 55rpm（Fu Lao Moral number Fr.：0.85, peripheral speed：1.44m/s）, chopping wing 3600rpm（Peripheral speed 30m/s）, jacket temperature be 40 DEG C Under the conditions of mix 1 minute.

While make blender work under conditions of same as described above, while adding 3.25kg to be heated in 0.48 minute 60 DEG C of C12 alcohol（Lauryl alcohol, Kao Corp's manufacture, KALCOL2098）.Then, make to stir under conditions of same as described above Mix machine to work 1 minute, mixed.

While make blender work under conditions of same as described above, while adding what is be pre-mixed to add in 1.4 minutes The LABS of heat to 60 DEG C（The carbon number of straight chained alkyl is 10~14, mean molecule quantity 322）3.12kg with 98% Sulphuric acid 0.31kg.In addition, above-mentioned LAS is by SO₃Obtained in gas sulfonation method, containing the sulphuric acid of 1.5 mass % in LAS.

After LAS additions, then, make blender work at identical conditions 3.0 minutes, complete neutralization reaction and pelletize Operation.In addition, starting to add the ventilation carried out in machine for 0.5 minute after LAS（300L/min, 25 DEG C）.

<Surface-modification processes>

When neutralization reaction and granulation operations is completed, then, the type A zeolite as surface modifier is added 3.25kg, makes blender and ventilation work carry out surface modification treatment in 1 minute under conditions of same as described above, obtains pelletize Product.

The pelletize product for obtaining are that mean diameter is 158 μm, the granule rate on 1000 μm of sieves（1000 μm of ON are designated as in table）For 4.0 mass %, the granule rate under 125 μm of sieves（125 μm of PASS are designated as in table）For 25.5 mass %, apparent density for 815g/L Grain.

With GYRO Shifter GS-B2-25（The manufacture of Co., Ltd. of moral longevity work institute, 1180 μm of mesh footpath）To 19.4kg tables The modified pelletize product in face carry out progressive operation.The granule on the sieve after progressive operation is reclaimed, is reinstated with 0.6kgA types zeolite one Fitzmill DKA-6（HosokawaMicron Corporation are manufactured, peripheral speed 60m/s）Crushed, by what is obtained Ground product mixes with the granule under the sieve after progressive operation, obtains detergent addition particle swarm 1.

The detergent addition particle swarm 1 for obtaining is that mean diameter is 134 μm, and the granule rate on 1000 μm of sieves is 0.7 matter Amount %, 125 μm of lower granule rates of sieve are 45.5 mass %, and apparent density is 821g/L, and breaking load is the granule of 110gf, granule Cohesiveness reduce excellent physical property granule.

With following method manufacture dress material powder detergent compositions, so as to be mixed with the detergent addition use for obtaining The composition of particle swarm 1 and following compositions is as shown in table 4.

·LAS-Na：Sodium alkyl benzene sulfonate（With the manufacture of Guang Chunyao operations Co., Ltd., straight chained alkyl（Carbon number is 12 ~14）Benzene sulfonic acid sodium salt）

·AS-Na：The carbon number of alkyl is 12~14 alkyl sulfate（Kao Corp manufactures, EMAL10P, The ratio of the straight chained alkyl in whole alkyl is 100 mass %）

Sodium carbonate：Weight ash（Central Glass Co., Ltd. are manufactured）

Type A zeolite：“ZEOBUILDER”（ZEOBUILDER companies manufacture）

Sodium sulfate：Anhydrous neutral Natrii Sulfas（Shikoku Chem manufactures）

Using LODIGE blenders（Song Banjiyan Co., Ltd. manufactures, capacity 20L）And cylinder mixer, with 5kg units Detergent composition for clothing shown in manufacture table 4.

Specifically, by above-mentioned LODIGE blenders mixture of sodium carbonate, sodium sulfate, noncrystalline sodium silicate, LAS-Na, AS-Na.Thereafter, liquid charging stock is added（Aqueous sodium polyacrylate, water）.By the compound particles for obtaining GYRO Shifter GS-B2-25（The manufacture of Co., Ltd. of moral longevity work institute, 1180 μm of mesh footpath）Carry out progressive operation.Reclaim on the sieve after progressive operation Granule, use Fitzmill DKA-6（Hosokawa Micron Corporation are manufactured, peripheral speed 60m/s）Carry out powder It is broken, the ground product for obtaining is mixed with the granule under the sieve after progressive operation.Further, the granule for obtaining in the progressive operation Used in cylinder mixer（Capacity 75L）The detergent addition particle swarm 1, type A zeolite that mixing is obtained with the manufacture method And spice, obtain detergent composition for clothing.

Embodiment 18~20

By with the identical method of embodiment 17, obtain the detergent addition particle swarm 2~4 of table 3, further, pass through With the detergent composition for clothing that the identical method of embodiment 17 manufactures table 4.

Embodiment 21

In LODIGE blender FKM-130D（Song Banjiyan Co., Ltd. manufactures, capacity 130L, jacketed）Middle input 19.80kg sodium carbonate（Light ash：Central Glass Co., Ltd.s manufacture, 100 μm of median particle diameter）, in main wing 55rpm（Fu Lao Moral number Fr.：0.85, peripheral speed：1.44m/s）, chopping wing 3600rpm（Peripheral speed 30m/s）, jacket temperature be 40 DEG C Under the conditions of mix 1 minute.

While make blender work under conditions of same as described above, while adding what is be pre-mixed to add in 1.6 minutes The LABS of heat to 60 DEG C（The carbon number of straight chained alkyl is 10~14, and mean molecule quantity is 322）3.69kg and 98% sulphuric acid 0.28kg.In addition, above-mentioned LAS is by SO₃Obtained in gas sulfonation method, containing the sulfur of 1.5 mass % in LAS Acid.

After LAS additions, then, make blender work at identical conditions 3.5 minutes, complete neutralization reaction and pelletize Operation.In addition, starting to add the ventilation carried out in machine for 0.5 minute after LAS（300L/min, 25 DEG C）.

While make blender work under conditions of same as described above, while adding 1.63kg to be heated in 0.23 minute 60 DEG C of C12 alcohol（Lauryl alcohol, Kao Corp's manufacture, KALCOL2098）.Then, make to stir under conditions of same as described above Mix machine to work 1 minute, mixed.

<Surface-modification processes>

When neutralization reaction and granulation operations is completed, then, type A zeolite 6.5kg as surface modifier is added, In main wing 55rpm（Froude number Fr.：0.85, peripheral speed：1.44m/s）, chopping wing 1800rpm（Peripheral speed 15m/s）'s Make its work carry out surface modification treatment in 1 minute under stirring condition, obtain pelletize product.

The pelletize product for obtaining are that mean diameter is 208 μm, and the granule rate on 1000 μm of sieves is 5.6 mass %, under 125 μm of sieves Granule rate be 19.3 mass %, apparent density for 684g/L granule.

With GYRO Shifter GS-B2-25（The manufacture of Co., Ltd. of moral longevity work institute, 1180 μm of mesh footpath）To 19.4kg tables The pelletize product that face was modified carry out progressive operation.The granule on the sieve after progressive operation is reclaimed, is reinstated with 0.6kgA types zeolite one Fitzmill DKA-6（Hosokawa Micron Corporation are manufactured, peripheral speed 60m/s）Crushed, will be obtained Ground product mix with the granule under the sieve after progressive operation, obtain detergent addition particle swarm 5.Further, by with reality Apply the identical method of example 17 manufacture detergent composition for clothing.

Embodiment 22~24

By with the identical method of embodiment 21, obtain the detergent addition particle swarm 5~8 of table 3.Further, pass through With the detergent composition for clothing that the identical method of embodiment 17 manufactures table 4.

Contain（B）The breaking load of the detergent addition particle swarm of composition is low, and operability is excellent, can be easily manufactured The detergent composition for clothing of the present invention.The raw material addition in the manufacturing process of embodiment 17~24 is represented in table 3, is washed Wash composition, the physical property of detergent addition particle swarm, the pelletize product of agent addition particle swarm（It is denoted in the table as intermediate granulation product） Physical property.Each physical property is measured with following method.

Apparent density is measured with the method for JIS K3362 defineds.The apparent density of pelletize product is to use GYRO Shifter（The manufacture of Co., Ltd. of moral longevity work institute, 1180 μm of mesh footpath）It is classified, after removing more than 1180 μm of particle swarm Apparent density；The apparent density of detergent addition particle swarm, using GYRO Shifter（Moral longevity work institute Co. Ltd. system Make, 1180 μm of mesh footpath）It is classified, by more than 1180 μm of particle swarm Fitzmill DKA-6（Hosokawa Micron Corporation is manufactured, peripheral speed 60m/s）Crushed, by the granule under the sieve after the ground product for obtaining and progressive operation Group is mixed, using thus obtained mixture as detergent addition particle swarm, as its apparent density.

For mean diameter, it is measured by following method.

（1）For the granule that mean diameter is more than 125 μm, using the standard screen of JIS Z8801-1（Mesh footpath be 2000~ 125μm）It is allowed to vibrate 5 minutes afterwards, median particle diameter is calculated according to the mass fraction obtained by the size of mesh.In more detail Say, using mesh footpath be 125 μm, 180 μm, 250 μm, 355 μm, 500 μm, 710 μm, 1000 μm, 1400 μm, 9 grades of 2000 μm Sieve and flange, the sieve little from mesh footpath starts to overlap successively on flange, adds from 2000 μm of topmost of sieve The particle swarm of 100g, closes the lid, and is installed on Ro-Tap types sieve agitator（HEIKO makes manufactured, raps 156 beats/min, Rock 290 beats/min）, afterwards measure residues in the quality of each sieve and the particle swarm on flange within 5 minutes for vibration, calculates each The mass ratio of the particle swarm on sieve（%）.The particle swarm for starting to add up in order on the little sieve in mesh footpath from flange Mass ratio, will add up to the particle diameter for becoming 50% as mean diameter.

（2）For mean diameter be 80 μm less than 125 μm of granule, using mesh footpath be 45 μm, 63 μm, 90 μm, 125 μm, 180 μm, 250 μm, 355 μm, 500 μm, 710 μm, 1000 μm, 1400 μm, 12 grades of 2000 μm of sieve and flange enter The same measure of row, calculates mean diameter.

（3）For granule of the mean diameter less than 80, using laser diffraction/scattering formula particle size distribution device LA-920 （Hole field makes the manufacture of Co., Ltd. of institute）, the particle swarm is scattered in the solvent of the insoluble particle swarm, by the intermediate value for measuring Particle diameter is used as mean diameter.

In addition, in the present invention, using the mean diameter of pelletize product particle swarm and detergent addition particle swarm as whole The mean diameter of granule.

For breaking load, it is measured by following method.

The sample of 50mL is filled uniformly with the cylinder of a diameter of 40mm, with the load that piston applies 1kg, 3 points is stood Clock, is thus shaped to cylindrical shape by particle swarm.The sample after molding is taken out from cylinder, using flow graph（RHEOTECH Co. Manufacture）Measure makes the sample of the molding crumble required power.The power is defined as into breaking load.The value of the generally breaking load is got over Little, then the cohesiveness of particle swarm is less, and coherency is also less, and free mobility is more excellent, therefore, operability is excellent.

Using GYRO Shifter GS-B2-25（The manufacture of Co., Ltd. of moral longevity work institute, 1180 μm of mesh footpath）It is classified, Use Fitzmill DKA-6（Hosokawa Micron Corporation are manufactured, peripheral speed 60m/s）By more than 1180 μm Particle swarm is crushed, and the ground product for obtaining is mixed with the particle swarm under the sieve after progressive operation.Thus obtained mixture is made For detergent addition particle swarm, as its breaking load.

Table 3：

Table 4：

LAS-Na in the * 1 detergent addition particle swarm and LAS-Na mixed with detergent addition particle swarm, matter Amount % is based on its total amount.

Sodium carbonate in * 2 detergent addition particle swarms（Light ash）And the carbonic acid mixed with detergent addition particle swarm Sodium（Weight ash）, quality % is based on its total amount.

Zeolite in * 3 detergent addition particle swarms and the zeolite mixed with detergent addition particle swarm, quality % base In its total amount.

Sodium sulfate in * 4 detergent addition particle swarms and the sodium sulfate mixed with detergent addition particle swarm, matter Amount % is based on its total amount.

The dress material powder detergent composition of table 4 all shows frothing capacity, the rinsing performance equal with embodiment 4.

Claims

1. a kind of dress material powder detergent composition, wherein,

Containing following (A)~(D)：

(A) surfactant comprising (A-1) linear alkylbenzene sulfonate (LAS) and (A-2) alkyl sulfate, hereinafter referred to as (A) Composition, its content is 5~40 mass %, below (A-1) linear alkylbenzene sulfonate (LAS) is referred to as into (A-1) composition, below by (A-2) Alkyl sulfate is referred to as (A-2) composition；

(B) higher alcohol that carbon number is 12 higher alcohol and/or carbon number is 14, hereinafter referred to as (B) composition, it contains Measure as 0.1~3 mass %；

(C) phosphate, its content is 0~8 mass %；And

(D) inorganic compound of solid, hereinafter referred to as (D) composition, its content is 40~90 mass %,

(A-1) composition and mass ratio (A-1) composition/(A-2) composition of (A-2) composition are 0/10~6.5/3.5,

(A) total quality of (A-1) composition in composition and (A-2) composition is more than 80 mass %,

(A-2) composition and mass ratio (A-2) composition/(B) composition of (B) composition are 10/1~36/1.

2. dress material powder detergent composition as claimed in claim 1, wherein,

(C) phosphate containing 0~3 mass %.

3. a kind of dress material powder detergent composition, wherein,

The dress material powder detergent composition coordinates following (A)~(D) to form,

(A) surfactant comprising (A-1) linear alkylbenzene sulfonate (LAS) and (A-2) alkyl sulfate, hereinafter referred to as (A) Composition, used as the ratio coordinated in raw material, its use level is 5~40 mass %, below claims (A-1) linear alkylbenzene sulfonate (LAS) For (A-1) composition, below (A-2) alkyl sulfate is referred to as into (A-2) composition；

(B) higher alcohol that carbon number is 12 higher alcohol and/or carbon number is 14, hereinafter referred to as (B) composition, as Coordinate the ratio in raw material, its use level is 0.1~3 mass %；

(C) phosphate, used as the ratio coordinated in raw material, its use level is 0~8 mass %；And

(D) inorganic compound of solid, hereinafter referred to as (D) composition, used as the ratio coordinated in raw material, its use level is 40 ~90 mass %,

(A-1) composition and mass ratio (A-1) composition/(A-2) composition of (A-2) composition in raw material is coordinated to be 0/10~6.5/ 3.5,

(A-2) composition and mass ratio (A-2) composition/(B) composition of (B) composition in raw material is coordinated to be 10/1~36/1.

4. dress material powder detergent composition as claimed in claim 3, wherein,

Used as the ratio coordinated in raw material, (C) phosphate for coordinating 0~3 mass % is formed.

5. the dress material powder detergent composition as any one of Claims 1 to 4, wherein,

(A-2) composition be the ratio of the straight chained alkyl that the carbon number in whole alkyl is 12~15 be more than 50 mass % alkane Base sulfate.

6. the dress material powder detergent composition as any one of Claims 1 to 4, wherein,

(A-1) composition and (A) composition beyond (A-2) composition are polyoxyalkylene alkyl, wherein, the carbon number of the alkyl For 10~15, the average addition molal quantity of oxyalkylene is 2~10.

7. the dress material powder detergent composition as any one of Claims 1 to 4, wherein,

(B) content of composition is in the composition 0.3~1.2 mass %.

8. the dress material powder detergent composition as any one of Claims 1 to 4, wherein,

(B) content of composition is in the composition for more than 0.3 mass % and below 1 mass %.

9. the dress material powder detergent composition as any one of Claims 1 to 4, wherein,

(B) content of composition is in the composition for more than 0.3 mass % and below 0.8 mass %.

10. the dress material powder detergent composition as any one of Claims 1 to 4, wherein,

(C) composition be a kind in orthophosphate, metaphosphate, trimetaphosphate, pyrophosphate and tripolyphosphate with On phosphate.

The 11. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D) composition is to select from water miscible alkali inorganic salt, water miscible neutral inorganic and water-insoluble inorganic salt More than a kind,

Wherein, the water miscible alkali inorganic salt is selected from carbonate and uncrystalline silicon hydrochlorate, the water miscible neutral inorganic Selected from sulfate and metal chloride, the water-insoluble inorganic salt is selected from aluminosilicate and clay mineral.

The 12. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D) content of composition is 45~89 mass %.

The 13. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D) content of composition is 50~87 mass %.

The 14. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D) content of composition is 60~85 mass %.

The 15. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D) content of composition is 65~85 mass %.

The 16. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D) content of composition is 70~85 mass %.

The 17. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D) content of composition is 74~82 mass %.

The 18. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D-1) containing 45~85 mass % is selected from the inorganic compound of more than a kind in carbonate and sulfate.

The 19. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D-1) containing 50~80 mass % is selected from the inorganic compound of more than a kind in carbonate and sulfate.

The 20. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

Containing the inorganic of more than a kind of (D-1) more than 50 mass % and below 70 mass % in carbonate and sulfate Compound.

The 21. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

(D-1) containing 55~75 mass % is selected from the inorganic compound of more than a kind in carbonate and sulfate.

The 22. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

Containing the inorganic of more than a kind of (D-1) more than 60 mass % and below 70 mass % in carbonate and sulfate Compound.

23. dress material powder detergent compositions as claimed in claim 11, wherein,

Carbonate is the carbonate of more than a kind in alkali metal carbonate salt and bicarbonate alkali metal salt.

24. dress material powder detergent compositions as claimed in claim 11, wherein,

Sulfate is the sulfate of more than a kind in alkali metal persulfates and alkali sulfite slaine.

25. dress material powder detergent compositions as claimed in claim 11, wherein,

Aluminosilicate is the aluminosilicate of more than a kind in crystallinity aluminosilicate, noncrystalline aluminosilicate.

The 26. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

By JIS K 3362:Moisture in the compositionss that the 2008 heating loss methods recorded are obtained is 1~10 mass %.

The 27. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

JIS K 3362:The pH of the 2008 0.1 mass % aqueous solutions determined at 20 DEG C recorded is 8~12.

The 28. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

JIS K 3362:The pH of the 2008 0.1 mass % aqueous solutions determined at 20 DEG C recorded is 9~11.5.

The 29. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

JIS K 3362:The pH of the 2008 0.1 mass % aqueous solutions determined at 20 DEG C recorded is 9.5~11.

The 30. dress material powder detergent compositions as any one of Claims 1 to 4, wherein,

JIS K 3362:The pH of the 2008 0.1 mass % aqueous solutions determined at 20 DEG C recorded is 10~11.

A kind of 31. hand washing washing methods, wherein,

The hand washing washing methods is cleaned material is contacted containing the dress material powder any one of claims 1 to 30 The rinse water of composition of detergent, then hand-washes cleaned material.

32. hand washing washing methods as claimed in claim 31, wherein,

Hardness of water used in the modulation of rinse water and/or the hardness of water for rinsing are 1 ° of DH~50 ° DH.

33. hand washing washing methods as claimed in claim 31, wherein,

Rinse water contains the compositionss and water, and the cleaned material hand-washed with water rinsing, used in the modulation of rinse water Hardness of water and/or for rinsing hardness of water be 1 ° of DH~50 ° DH.

The 34. hand washing washing methods as any one of claim 31~33, wherein,

Hardness of water used in the modulation of rinse water and/or the hardness of water for rinsing are 8 ° of DH~50 ° DH.

The 35. hand washing washing methods as any one of claim 31~33, wherein,

Hardness of water used in the modulation of rinse water and/or the hardness of water for rinsing are 10 ° of DH~50 ° DH.

A kind of 36. manufacture methods of dress material powder detergent composition, it is the clothing any one of claims 1 to 30 The manufacture method of material powder detergent composition, wherein,

Dress material powder detergent composition contains (A-1) composition as (A) composition, containing water miscible alkali inorganic salt conduct (D) composition,

The manufacture method of the dress material powder detergent composition has：By mixing as the acid precursors of (A-1) composition LABS and the water miscible alkali inorganic salt as (D) composition come in dry type and LABS and water solublity Alkali inorganic salt operation,

Before the operation of dry type neutralization, in operation or after operation, add (B) composition, so as to get particle swarm in contain (B) Composition,

Will be containing the particle swarm of (B) composition and other composition mixing.

37. manufacture methods as claimed in claim 36, wherein,

Water miscible alkali inorganic salt is the carbonate of more than a kind in alkali metal carbonate salt and bicarbonate alkali metal salt.

38. manufacture methods as described in claim 36 or 37, wherein,

The content of (B) composition in the particle swarm containing (B) composition is 3.5~20 mass %.

39. manufacture methods as described in claim 36 or 37, wherein,

Used as LABS and the mass ratio of (B) composition, LABS/(B) composition is 1/10~10/1.

40. manufacture methods as described in claim 36 or 37, wherein,

The speed of addition (B) composition is alkali inorganic salt water miscible relative to 100kg, and (B) composition is added with 1~80kg/ minutes Plus.

41. manufacture methods as described in claim 36 or 37, wherein,

The speed of addition (B) composition is alkali inorganic salt water miscible relative to 100kg, and (B) composition is added with 2~60kg/ minutes Plus.

42. manufacture methods as described in claim 36 or 37, wherein,

The speed of addition (B) composition is alkali inorganic salt water miscible relative to 100kg, and (B) composition is added with 3~50kg/ minutes Plus.