CN1038517C - Multi-purpose detergent and polishing agent and method for prepn. of same - Google Patents
Multi-purpose detergent and polishing agent and method for prepn. of same Download PDFInfo
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- CN1038517C CN1038517C CN93103643A CN93103643A CN1038517C CN 1038517 C CN1038517 C CN 1038517C CN 93103643 A CN93103643 A CN 93103643A CN 93103643 A CN93103643 A CN 93103643A CN 1038517 C CN1038517 C CN 1038517C
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- emulsion
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- optical brightener
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Abstract
The present invention relates to a variable (conversion type) multipurpose decontaminating and polishing agent and a preparation method thereof, which belongs to the technical field of physical chemistry and macromolecular chemistry. The decontaminating and polishing agent is a water in oil (W/O) type emulsion before variation (conversion), and the W/O type emulsion is prepared from 35 to 65% of silicone, 45 to 10% of butyl methacrylate, 0.5 to 1.5% of plasticizing agent, 7 to 4% of emulsifying agent, 3 to 1.5% of oleic acid, 0.1 to 1% of pearling agent, 0.1 to 1% of polymerization initiator and 20 to 15% of antistatic agent (20% of potassium nitrate solution); when the decontaminating and polishing agent needs varying, the prepared emulsion is optionally mixed with water (between 0 and 80DEGC) according to the volume ratio of 1:1 to 1500, and an oil in water (O/W) type self-lighting emulsion can be obtained by variation (conversion).
Description
The present invention relates to physical chemistry and technical field of polymer chemistry and specially refer to a kind of body surface decontamination brightening agent that can use in modification (transition) front and back (promptly being transformed into emulsion oil-in-water) by water-in-oil emulsion; And ability at the rapid polymerization film formation of body surface arranged.
Usually the optical brightener of selling (or glazing is cured) on the market, say from physicochemical meaning to be divided into two types: a class is to be external phase with oil; Water be disperse phase optical brightener (be water-in-oil-type---W/O) another kind of is to be external phase with water; Oil be disperse phase optical brightener (be oil-in-water-type---O/W) manufacturing enterprise is according to the preparation method and the characteristic of this two classes optical brightener, be leather oil, leather wax with these Product Definitions respectively, when the floor is cured or furniture, automobile optical brightener etc. are discussed to preparation method, component, characteristic and the effect of optical brightener in [application of nonionogenic tenside (light industry press)] book, w/o type is described by other relevant document that strictness distinguishes too similarly with O/W type optical brightener as can be seen.
For example: a kind of prescription of automobile polisher and cleaner
[Chemicals handbook (Chemical Industry Press)]
Trolamine 0.75%
Mineral oil 20.86%
Oleic acid 1.87%
Water 75.20%
Earlier that trolamine is soluble in water, again mineral oil and oleic acid are placed another container altogether, make it to mix.Then this fluid mixture is added in the aqueous solution of trolamine and constantly stir, add abrasive at last, continue to be stirred to and be mixed into O/W type optical brightener fully
Illustration as can be seen, at present this series products not have to consider " modification effect " in the preparation application [" Surface Physical chemistry " A.W Adam gloomy (Science Press)] similarly, in pertinent literature, do not relate to " modification effect " this conception of species during the preparation of discussion optical brightener yet.Patent Office of the People's Republic of China number in fact also is a kind of common O/W type optical brightener for a kind of " clean and bright protective agent " that CN90101051.0 provided; therefore the mode that its dilution is used slightly complexity does not also produce the notion that a kind of w/o type optical brightener is introduced dilution in use.In fact just expectation can't produce and a kind ofly can satisfy certain specific needs of user; Can satisfy therewith simultaneously the optical brightener product of other requirement explicitly again.The main drawback of this series products was to be limited at a very narrow use range and being limited on traditional use-pattern in the past---coating and spraying, and do not possess ability at the rapid polymerization film formation of body surface.
The object of the invention is to overcome the defective and the deficiency of above-mentioned prior art, provides a kind of w/o type optical brightener to make it have in the use randomness.This randomness comprises three aspects: one, the present invention can according to the specific needs of user before and after modification of the present invention (transition), be used for any body surface that needs cleaning and brightening use its two, the present invention according to the user require modification (transition) to use the time, modification (transition) is not added the condition that the user is difficult to realize.Its three, the user can be according to practical situation and feasibility with application extension of the present invention to other field.
The present invention also aims to provide a kind of multi-usage optical brightener of changeable type
Make it have the ability that after use, can aggregate into one deck polymer cuticula rapidly at body surface
Purpose of the present invention realizes like this: be prepared into by 6.5: 1.5: 0.1 mixed and a kind ofly had modification (transition) function w/o type emulsion to can be used for leather, flooring laminate rigid plastics body surface cleaning and brightening by add lustre to material silicone and methyl-prop diluted acid fourth fat polyaddition initiator of oil phase.With the above-mentioned emulsion that has prepared, by the needs of user, arbitrarily mix by 1: 1～1500 volume ratio (the water temperature requirement is between 0～80 ℃) with water according to oneself, promptly changeable type (transition) is an O/W type luminous breast.Can be widely used in surface decontaminations such as metal, woodenware, pottery, glass (comprising opticglass), paint film, synthetic leather adds lustre to.Can be after the use at the rapid polymerization film formation of body surface.Using method can adopt means such as spraying, coating, flushing as required.The present invention is described in detail below in conjunction with embodiment.
Preparation has a kind of w/o type decontamination brightening agent of modification (transition) ability:
Silicone 35～65%
Methacrylic acid fourth fat 30%～10%
Softening agent 0.5～1.5%
Emulsifying agent 7～4%
Emulsification conditioning agent 3～1.5%
Pearling agent 0.1～1%
Polymerization starter 0.1～1%
20% potassium nitrate solution 24.9%～15%
Wherein silicone can be cured by polyethylene, the polystyrene emulsion substitutes.Methyl-propyl acid fourth fat can be substituted by methymethacrylate, methacrylic acid second fat, methacrylic acid isobutyl fat.Softening agent can adopt tbp, dibutyl phthalate (DBP), tricresyl phosphate fourth oxygen second fat.Emulsifying agent is selected alkylphenol polyoxyethylene, fatty acid ethanol amide, fatty alcohol-polyoxyethylene ether (0-15 to 0-20) for use.Emulsification mediator agent: oleic acid, trolamine.Polymerization starter can adopt two types of auxiliary agents of organic or inorganic, preceding a kind of be Diisopropyl azodicarboxylate, the back a kind of Potassium Persulphate or ammonium persulphate selected for use.The pearly-lustre material can be selected mica titanium or pearl white for use
Embodiment 1: preparation has the w/o type emulsion of modification (transition) ability
The preceding use of modification (transition)]
Silicone 50%
Methacrylic acid fourth fat 30%
Tbp 0.5%
Fatty alcohol-polyoxyethylene ether 5%
Oleic acid 2%
Mica titanium 0.5%
Ammonium persulphate 0.1%
20% potassium nitrate solution 11.9%
Pick w/o type emulsion of the present invention with cotton or hairbrush, the rigid plastics casing surface of wiping examination leather shoes, fur clothing, sneakers or computer, televisor can reach the effect of cleaning and brightening.
Embodiment 2: preparation has the w/o type emulsion of modification (transition) ability
[use modification (transition) back]
Silicone 65%
Methymethacrylate 13%
Dibutyl phthalate (DBP) 0.5%
Alkylphenol polyoxyethylene 5%
Oleic acid 2%
Bismuth hydroxide 0.5%
Ammonium persulphate 0.2%
20% potassium nitrate solution 13.8%
With w/o type emulsion of the present invention and water by 1: 500 volume ratio (the water temperature requirement is between 0～80 ℃) put and mix (hybrid mode does not have particular requirement) in the same container.The liquid that mixes is packed in the atomizer, spray to be cleaned, ornamental body surface.
If object is remaining water droplet after being washed away by water before adding lustre to, can not will object re-use the present invention after drying.
Embodiment 3: preparation has the w/o type emulsion of modification (transition) ability
[use modification (transition) back]
Ployethylene Wax 64%
Methacrylic acid isobutyl fat 10%
Tbp 1.5%
Fatty alcohol-polyoxyethylene ether 6.5%
Trolamine 1%
Bismuth hydroxide 1%
Diisopropyl azodicarboxylate 0.1%
20% potassium nitrate solution 15.9%
With w/o type emulsion of the present invention and water by 1: 1000 volume ratio (the water temperature requirement is between 0～80 ℃) put and mix (hybrid mode does not have particular requirement) in the same container.
Using method one, make-up water pump directly wash vehicle, emmarble metope etc., dry moisture content with cotton then.
Using method two, rinse in the liquid that mixes and twist with towel or cotton and remove a part of moisture content, wiping body surface to be added lustre to is dried moisture content then.
Embodiment 4: preparation has the w/o type emulsion of modification (transition) ability
[use modification (transition) back]
Silicone 61.2%
Methacrylic acid fourth fat 16%
Tbp 1%
Fatty acid ethanol amide 4.5%
Oleic acid 2.5%
Bismuth hydroxide 0.8%
Potassium Persulphate 0.6%
20% potassium nitrate solution 13.4%
W/o type emulsion of the present invention and distilled water (water temperature requires between 0～80 ℃, if ordinary tap water need confirm that water quality is limpid) are mixed by 1: 1000 volume ratio.Camera switching paper (or camera lens cloth) picks the liquid that a little mixes, and wiping optical lens, eyeglass are cleaned with the lens paper (cloth) of not being stained with liquid then.Effect is, can strengthen the light transmission of opticglass, makes optical glass surface produce the anti-water of one deck, the anti-polymer cuticula that goes mouldy.
Embodiment 5: preparation has the w/o type emulsion of modification (transition) ability
[use modification (transition) back]
Polystyrene emulsion 35%
Methacrylic acid isobutyl fat 30%
Tricresyl phosphate fourth oxygen second fat 1.5%
Fatty alcohol-polyoxyethylene ether 5%
Oleic acid 2.5%
Mica titanium 1%
Potassium Persulphate 0.1%
20% potassium nitrate solution 24.9%
W/o type emulsion of the present invention put by 1: 1000～1500 volume ratios (the water temperature requirement is between 0～80 ℃) with water mix (hybrid mode does not have particular requirement) in the same container.Inject the windshield cleanser, cooperate rain brush in automobile is advanced, to clean front windshield, can make glass cleaning, bright.Can make rainwater no longer adsorb windshield glass after using repeatedly repeatedly.
The front points out that the present invention has randomness in use, so the user can go out more using method and enlarge its use range according to the needs conversion in use of the present invention of oneself.For example use modification (transition) back, also can do the cooling fluid of precision cutting lathe, does finishing composition and defoamer in weaving, the printing and dyeing industry.
It is its main contents that the present invention uses as the multi-usage optical brightener, by embodiment as can be known the present invention may be defined as in actual use: a kind of can be before and after modification (transition), be any smooth object surface decontamination ornamental multi-usage optical brightener.By the material difference of the object that added lustre to, it has functions such as softening leather, antirust, anti-oxidant, waterproof, antistatic, reinforcing glass light transmission simultaneously.Final effect is to generate polymeric membrane in the body surface polymerization, improves the body surface reflective light intensity, reduces skin friction coefficient, increases object clarity and decorative effect.
Claims (3)
1, a kind of multi-usage optical brightener of changeable type comprises: (1) silicone, polyethylene wax or polystyrene emulsion: 35～65%; (2) methacrylic acid fourth fat, methacrylic acid second fat or methylacrylic acid isobutyl fat: 30～10%; (3) softening agent: 0.5～1.5%; (4) alkylphenol polyoxyethylene, fatty acid ethanol amide: 7～4%; (5) oleic acid or trolamine: 3～1.5%; (6) pearling agent: 0.1～1%; (7) fine, the Potassium Persulphate of azo two isobutyls, ammonium persulphate: 0.1～1%; (8) 20% potassium nitrate solution: 24.9～15% form emulsion, and emulsion and water mix by 1: 1～1500 volume ratios.
2, the multi-usage optical brightener of a kind of changeable type according to claim 1, it is characterized in that: described softening agent comprises: tributyl phosphate, dibutyl phthalate, tributyloxyethyl phosphate.
3, the multi-usage optical brightener of a kind of changeable type according to claim 1, it is characterized in that: described pearling agent comprises: mica titanium, bismuth hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93103643A CN1038517C (en) | 1993-04-05 | 1993-04-05 | Multi-purpose detergent and polishing agent and method for prepn. of same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93103643A CN1038517C (en) | 1993-04-05 | 1993-04-05 | Multi-purpose detergent and polishing agent and method for prepn. of same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1093389A CN1093389A (en) | 1994-10-12 |
| CN1038517C true CN1038517C (en) | 1998-05-27 |
Family
ID=4984713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93103643A Expired - Fee Related CN1038517C (en) | 1993-04-05 | 1993-04-05 | Multi-purpose detergent and polishing agent and method for prepn. of same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1038517C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1314776C (en) * | 2004-01-15 | 2007-05-09 | 山东大学 | Method for preparing long aftergrow nano luminous material at low temperature |
| CN102070944A (en) * | 2010-11-18 | 2011-05-25 | 苏州美亚美建筑涂料有限公司 | Brightener for paint |
| CN102660197B (en) * | 2012-04-20 | 2014-11-05 | 上海皇宇科技发展有限公司 | Leather brightening agent and leather brightening wet wiper |
| CN104946048A (en) * | 2015-07-03 | 2015-09-30 | 上海皇宇科技发展有限公司 | Nanoscale water-resisting oil-stain-resisting leather surface treatment agent and preparing method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053078A (en) * | 1990-03-07 | 1991-07-17 | 冯宁生 | Clean and bright protective agent |
-
1993
- 1993-04-05 CN CN93103643A patent/CN1038517C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1053078A (en) * | 1990-03-07 | 1991-07-17 | 冯宁生 | Clean and bright protective agent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1093389A (en) | 1994-10-12 |
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