CN1072299C - Corrugated paper box dampproof glazing agent - Google Patents
Corrugated paper box dampproof glazing agent Download PDFInfo
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- CN1072299C CN1072299C CN96113485A CN96113485A CN1072299C CN 1072299 C CN1072299 C CN 1072299C CN 96113485 A CN96113485 A CN 96113485A CN 96113485 A CN96113485 A CN 96113485A CN 1072299 C CN1072299 C CN 1072299C
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- water
- moisture
- glazing
- paraffin
- silicone oil
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- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
The present invention relates to paint used for preventing moisture and glazing for a corrugated carton, which is prepared from methyl silicone oil, paraffin and oxidized polyethlene wax as water resistant and moisture preventing agents, propene gum resins as brightening agents, water as a solution through reaction at a certain temperature. The present invention has the advantages of bright painted film, rigidity, high durability, good effects of water resistance and moisture prevention, no poison, no odor, no environment pollution, no need of bottoming, one-step successful coating, short drying time, no adhesion, continuous large-scale operation, labor saving, time saving, high production efficiency, long storage period, convenient use, low price and obvious economical and social benefit, and the paint can be coated or sprayed, and can be suitable for all cartons.
Description
The invention belongs to the coating class.Be the coating that is used for moistureproof glazing that uses on the corrugated case in the packaging industry.
Corrugated case is the packing of commodity, and commodity are played very important protective effect in transportation and storage process.Corrugated case is done the moistureproof optical processing of going up; at first make carton have the water of screening, hydrophobic, water-fast, humidity resistance, to delaying carton suction moisture absorption speed, assurance carton compression intensity can normally be brought into play; finally reach the purpose of strong protection commodity, have very important realistic meaning.Secondly, can improve the gloss on carton surface, make color and luster more bright-coloured, strengthen the artistic effect of picture, make product have more attraction.Can also make the carton surface have wear-resisting wiping, chemical resistance, heat-resisting, cold resistance or the like are reduced the loss commodity in transportation, storage.Corrugated case is done the moistureproof optical processing of going up, present two kinds of products of domestic main use, a kind of is oil polish (being polish oil again), productions such as Tianjin printing ink factory.Another kind is an anti-blushing agent, productions such as Wuhan Qiao Kou organic synthesis material factory.The former is an oil-soluble, and solvent is benzene, dimethylbenzene etc., and is bigger to operator's health effect, and environment is had serious pollution, and it is inflammable, and the workman operates inconvenience, and it mainly is mechanically to use, seldom manual the use.The latter is water-soluble, nontoxic, but moisture effect is bad, and brightness is also not enough, and can only use by hand, can not mechanically use.
Also have for moistureproof glazing, on carton, use varnish, boiled wood oil, white lake, methyl-silicone oil, polyvinyl butyral resin, hot melt wax and vinyl chloride resin, acrylic resin, nitro-resin, amino resins etc.Because they all exist such or such problem, so the scope of application is all less.
In recent years, Chinese invention patent CN1082580A provides " protection against the tide of corrugated case glazing and production method thereof ", and raw materials used is formaldehyde, urea, melamine, diffusant and water.CN1040999A provides " moistureproof glazing paint of a kind of paper products and process ", and raw materials used is waste and old polystyrol, dibutyl phthalate, rosin and aromatic hydrocarbons organic solvent.Though these two patents all are the moistureproof glazing paint on the carton, and are raw materials used inconsistent with the present invention, and differ more.
Based on above various reasons, the present invention is to provide a kind of water miscible nontoxic, can mechanically use, can brush by hand again, brightness is big, the product that anti-water moisture effect is good especially.
The present invention is to be anti-water anti-blushing agent with methyl-silicone oil, paraffin, oxidized polyethlene wax, is brightener with the acrylic resin, is thickening, emulsifying agent with rosin, is solvent with water, reacts to form under uniform temperature and pressure.This product strong adhesion, the light of filming, hard durable, anti-water moisture effect is good especially; Its nontoxic odorlessness, non-environmental-pollution; It is applicable to any sold inside the country and export trade carton, and mechanically initial bonding strength is strong the light time, and mechanical usability is good with performance, can use by hand behind its thin up, can be coated with and can spray, and does not all need bottoming, once brushes successfully; Its drying time is short, adhesion, but serialization large-scale operation, and saving of work and time, production efficiency can significantly improve; It is easy to use, and is cheap, economic benefit and obvious social benefit.
The prescription of corrugated paper box dampproof glazing agent (percentage by weight) is as follows:
Methyl-silicone oil 1～10
Paraffin 5～10
Oxidized polyethlene wax 1～10
Acrylic resin 2～15
Rosin 2～15
Morpholine 2～10
Stearic acid 1～10
NaOH 2～8
Hydrochloric acid 1～8
Water 83～4
Production technology: NaOH, morpholine, stearic acid, rosin and water, in reactor, be heated to dissolving fully together, add methyl-silicone oil, paraffin, oxidized polyethlene wax and acrylic resin, cooling when question response is complete, add appropriate hydrochloric acid and be neutralized to neutrality, promptly get this product.
Reaction principle:
A, B, four kinds of materials of C, D all are very effective emulsifying agents, and they can be original water-fast methyl-silicone oil, paraffin, oxidized polyethlene wax and acrylic resin emulsification.When this emulsion is coated on the corrugated case, the moisture content volatilization, methyl-silicone oil, paraffin, oxidized polyethlene wax and acrylic resin particulate interpenetrate, and diffusion, coalescently are cross-linked into continuous, transparent, bright film.Because this film light, so has good glossiness-giving effect; Because this film is water insoluble, and has hydrophobicity, so remarkable anti-water moisture effect is just arranged.
Technical indicator:
| Project | Index |
| Outward appearance | There is not mechanical impurity, uniformly material |
| Smell | Free from extraneous odour |
| PH | 7 |
| Adhesive force (level) | 2 |
| Heat resistance (℃) | The no change of filming below 60 ℃ |
| Resistance to water | Titration did not have infiltration in 24 hours |
| Drying time (minute) | Surface drying: 10～15, do solid work＜60 |
Embodiment 1:
Prescription:
The title percentage by weight
Methyl-silicone oil 10
Paraffin 10
Oxidized polyethlene wax 5
Acrylic resin 8
Rosin 5
Morpholine 3
Stearic acid 3
NaOH 6
Hydrochloric acid 2
Water 48
Technology: get NaOH 6kg, stearic acid 3kg, morpholine 3kg, rosin 5kg, water 48kg are in reactor, and heating is dissolved it fully, wait to dissolve complete back and add methyl-silicone oil 10kg, paraffin 10kg, oxidized polyethlene wax 5kg, acrylic resin 8kg, heating makes complete emulsification, treat to lower the temperature when emulsification is complete, the hydrochloric acid that adds about 2kg is neutralized to PH=7, promptly gets this product.
Embodiment 2:
Prescription:
The title percentage by weight
Methyl-silicone oil 10
Paraffin 8
Oxidized polyethlene wax 6
Acrylic resin 15
Rosin 5
Morpholine 5
Stearic acid 4
NaOH 7
Hydrochloric acid 2
Water 2
Technology: get NaOH 7kg, stearic acid 4kg, morpholine 3kg, rosin 5kg, water 40kg are in reactor, and heating is dissolved it fully, wait to dissolve complete back and add methyl-silicone oil 10kg, paraffin 8kg, oxidized polyethlene wax 6kg, acrylic resin 15kg, heating makes complete emulsification, treat to lower the temperature when emulsification is complete, the hydrochloric acid that adds about 2kg is neutralized to PH=7, promptly gets this product.
List of references:
1, CN 1082580A lustering and damp-proof agent for corrugated paper box and production method thereof
2, moistureproof glazing paint of CN 1040999A paper products and process
3, CN 1087150A carton or paper products fire retarding damp-proof agent and preparation method
4, CN 1081453A technology toilet paper brightening protecting agent.
5, the moistureproof boxboard manufacturing technique method of CN 1080679A
6, CN 1079756A light powder (Lacquer finish powder) and preparation method thereof
7, CN 1081193A multipurpose brightener and manufacture method thereof
8, CN 1087660A cleaning polishing agent
9, CN 1057850A cleaning and polishing powder
10, the transparent liquid cleaning wax polish of CN 1061234A
11, CN 1062362A quick-dried polishing rosin oil
12, CN 1076478A dirt-removing polishing agent and preparation method thereof
13, the glazing paint of CN 1044824A glazing paper straw hat
14, CN 85106004A " emulsion type " brightener.
Claims (1)
1. corrugated paper box dampproof glazing agent is characterized in that the percentage by weight that raw material is formed is:
Methyl-silicone oil 1-10%
Paraffin 5-10%
Oxidized polyethlene wax 1-10%
Acrylic resin 2-15%
Rosin 2-15%
Morpholine 2-10%
Stearic acid 1-10%
NaOH 2-8%
Hydrochloric acid 1-8%
Water 83-4%
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96113485A CN1072299C (en) | 1996-12-27 | 1996-12-27 | Corrugated paper box dampproof glazing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96113485A CN1072299C (en) | 1996-12-27 | 1996-12-27 | Corrugated paper box dampproof glazing agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1157870A CN1157870A (en) | 1997-08-27 |
| CN1072299C true CN1072299C (en) | 2001-10-03 |
Family
ID=5121873
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96113485A Expired - Fee Related CN1072299C (en) | 1996-12-27 | 1996-12-27 | Corrugated paper box dampproof glazing agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1072299C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104863013A (en) * | 2015-04-24 | 2015-08-26 | 句容市鼎盛纸箱包装有限公司 | Carton lustering agent and preparation method thereof |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101666058B (en) * | 2009-09-23 | 2011-05-04 | 际华三五零二职业装有限公司 | Method for preparing damp-proof oil for military corrugated case |
| CN102433797A (en) * | 2011-10-24 | 2012-05-02 | 吴江市天源塑胶有限公司 | Moisture-proof coating for paper products |
| CN102676051B (en) * | 2011-11-14 | 2014-11-05 | 张宝荣 | Protection liquid for calligraphy and paintings |
| CN104404822A (en) * | 2014-11-06 | 2015-03-11 | 合肥东彩印刷科技有限公司 | Waterproof flame-retardant paint for cartons |
| CN104805731A (en) * | 2015-04-24 | 2015-07-29 | 句容市鼎盛纸箱包装有限公司 | Moisture-proof agent for carton and preparation method of moisture-proofing agent |
| CN105350395A (en) * | 2015-09-25 | 2016-02-24 | 句容市兴武包装有限公司 | Corrugated carton polish agent and preparation method therefor |
| CN106283860A (en) * | 2016-08-08 | 2017-01-04 | 苏州莱奥生物技术有限公司 | A kind of carton water-repellent paint |
| CN107097460A (en) * | 2017-04-10 | 2017-08-29 | 滁州卷烟材料厂 | It is a kind of that there is the moistureproof corrugated case with anti-dust performance |
| CN107354807B (en) * | 2017-06-22 | 2019-01-29 | 杭州特种纸业有限公司 | A kind of waterproof insulation vulcan fibre and preparation method thereof |
| WO2022088150A1 (en) * | 2020-10-31 | 2022-05-05 | 河北比尔尼克新材料科技股份有限公司 | Water-based carton waterproof coating, preparation method therefor and use thereof |
| CN112609512B (en) * | 2020-12-08 | 2022-08-23 | 浙江下沙荣成包装有限公司 | Corrugated paper and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079790A (en) * | 1992-06-06 | 1993-12-22 | 大竹县国营出口包装装璜厂 | Dampproof agent for paper products |
| CN1087150A (en) * | 1993-04-28 | 1994-05-25 | 潘则林 | Carton or paper products fire retarding damp-proof agent and preparation method |
-
1996
- 1996-12-27 CN CN96113485A patent/CN1072299C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079790A (en) * | 1992-06-06 | 1993-12-22 | 大竹县国营出口包装装璜厂 | Dampproof agent for paper products |
| CN1087150A (en) * | 1993-04-28 | 1994-05-25 | 潘则林 | Carton or paper products fire retarding damp-proof agent and preparation method |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104863013A (en) * | 2015-04-24 | 2015-08-26 | 句容市鼎盛纸箱包装有限公司 | Carton lustering agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1157870A (en) | 1997-08-27 |
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