CN103849036A - Color master batch capable of coloring polyethylene with carbon black - Google Patents
Color master batch capable of coloring polyethylene with carbon black Download PDFInfo
- Publication number
- CN103849036A CN103849036A CN201210594138.XA CN201210594138A CN103849036A CN 103849036 A CN103849036 A CN 103849036A CN 201210594138 A CN201210594138 A CN 201210594138A CN 103849036 A CN103849036 A CN 103849036A
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- Prior art keywords
- carbon black
- masterbatch
- pigmented polyethylene
- coupling agent
- black pigmented
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/006—Additives being defined by their surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a color master batch capable of coloring polyethylene with carbon black. The color master batch capable of coloring polyethylene with carbon black comprises the following components in percentage by mass: 30 to 70% of carbon black, 20 to 60% of polyethylene resin, 3 to 5% of dispersing agent, 0.5 to 3% of coupling agent, 0.1 to 1% of antioxidant, and 0.1 to 1% of phthalocyanine blue. Compared with the prior art, the color master batch capable of coloring polyethylene with carbon black has the beneficial effects that the prepared color master batch shows high blackness during coloring and is also high in dispersing performance, high in concentration, small in additive amount and low in cost; in addition; the process is also simplified, the operation is convenient, and both performance and quality of the product are ensured.
Description
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of Masterbatch by carbon black pigmented polyethylene.
Background technology
Polyethylene (PE) is due to light weight, nontoxic and have excellent dielectric properties, chemical stability and an advantage such as anticorrosive, and cheap, forming process is easy, can be widely used in the industries such as electrical equipment, chemical industry, food, machinery, tubing, particularly polyethylene is as one of main raw material of Material of Plastic Tube in Our Country, features such as, save energy lightweight, corrosion-resistant with it and more and more coming into one's own, Application Areas is also increasing.At present, polyvinyl piping materials part has substituted metal pipe material, and become the second largest plastic pipe kind that consumption is in the world only second to polyvinyl chloride, be widely used in the fields such as the engineerings such as feedwater, agricultural irrigation, combustion gas conveying, blowdown, mine mortar conveying and oil field, chemical industry, post and telecommunications.
In poly a lot of purposes, for painted object need to be used in conjunction with polyethylene and colorant, wherein, conventional colorant comprises that black, white, yellow, blueness, redness and grey etc. are several.That colorant super quantity is attached in resin equably owing to using look mother painted, thereby dispersing property and the coloration efficiency of pigment are greatly improved, there is the advantages such as simple to operate, with low cost, environmentally safe, therefore, in actual applications, polyethylene color great majority adopt look mother painted, simultaneously look female painted also can avoiding because of dyeing specks such as aberration that the reasons such as skewness cause, color spot, look flowers.
Summary of the invention
The object of the present invention is to provide a kind of Masterbatch by carbon black pigmented polyethylene, be mainly used in the painted field of polyvinyl piping materials, and the feature such as it has that tinctorial quality is high, good dispersity, weathering resistance are strong and easy to use.
The technical solution adopted for the present invention to solve the technical problems is: a kind of Masterbatch by carbon black pigmented polyethylene, its component by mass percent proportioning is: carbon black 30%～70%, polyvinyl resin 20%～60%, dispersion agent 3%～5%, coupling agent 0.5%～3%, oxidation inhibitor 0.1%～1%, phthalocyanine blue 0.1%～1%.
Described carbon black is high pigment furnace treated black, particle diameter 10～15nm, specific surface area 200～600m
2/ g, pH value 5～9, DBP absorption value is greater than 1.0mL/g.
Described dispersion agent is the one in low molecular weight polyethylene wax, OP wax and calcium stearate.
Described coupling agent is the one in silane coupling agent, titanate coupling agent, aluminate coupling agent, aluminium titanium composite coupler.
Described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
Described phthalocyanine blue is beta crystal copper phthalocyanine complex compound.
The preparation method of above-mentioned a kind of Masterbatch by carbon black pigmented polyethylene is: each component is prepared burden by weight proportion, then in the high-speed mixer of 1000～3000 revs/min, mix 5～20 minutes, add again in Banbury mixer, 140 ℃～180 ℃ banburyings 5～10 minutes, then pulverize, granulation, drying, pack and obtain a kind of Masterbatch by carbon black pigmented polyethylene of the present invention.
The invention has the beneficial effects as follows, compared with prior art, a kind of Masterbatch by carbon black pigmented polyethylene that the present invention makes carries out when painted, and it has good blackness, and good dispersity, concentration is high, addition is little, and cost is low, has also simplified operation simultaneously, be easy to operate, guaranteed again product performance and quality etc.
Embodiment
Further illustrate technical scheme of the present invention below in conjunction with specific embodiment.
Embodiment 1:
A kind of Masterbatch by carbon black pigmented polyethylene, its component by mass percent proportioning is: compound 0.3%, the beta crystal copper phthalocyanine complex compound 0.2% of carbon black 40%, polyvinyl resin 55%, low molecular weight polyethylene wax 3%, silane coupling agent 1.5%, hindered phenol antioxygen 1010 and phosphite ester kind antioxidant 168, wherein, described carbon black is high pigment furnace treated black, particle diameter 10～15nm, specific surface area 200～600m
2/ g, pH value 5～9, DBP absorption value is greater than 1.0mL/g.
Preparation method: each component is prepared burden by weight proportion, then in the high-speed mixer of 1000～3000 revs/min, mix 5～20 minutes, add again in Banbury mixer, 140 ℃～180 ℃ banburyings 5～10 minutes, then pulverize, granulation, drying, pack and obtain a kind of Masterbatch by carbon black pigmented polyethylene of the present invention.
Embodiment 2:
A kind of Masterbatch by carbon black pigmented polyethylene, its component by mass percent proportioning is: compound 1%, the beta crystal copper phthalocyanine complex compound 1% of carbon black 30%, polyvinyl resin 60%, OP wax 5%, titanate coupling agent 3%, hindered phenol antioxygen 1010 and phosphite ester kind antioxidant 168, wherein, described carbon black is high pigment furnace treated black, particle diameter 10～15nm, specific surface area 200～600m
2/ g, pH value 5～9, DBP absorption value is greater than 1.0mL/g.
Preparation method: each component is prepared burden by weight proportion, then in the high-speed mixer of 1000～3000 revs/min, mix 5～20 minutes, add again in Banbury mixer, 140 ℃～180 ℃ banburyings 5～10 minutes, then pulverize, granulation, drying, pack and obtain a kind of Masterbatch by carbon black pigmented polyethylene of the present invention.
Embodiment 3:
A kind of Masterbatch by carbon black pigmented polyethylene, its component by mass percent proportioning is: compound 0.5%, the beta crystal copper phthalocyanine complex compound 0.5% of carbon black 70%, polyvinyl resin 25%, low molecular weight polyethylene wax 3%, aluminium titanium composite coupler 1%, hindered phenol antioxygen 1076 and phosphite ester kind antioxidant 168, wherein, described carbon black is high pigment furnace treated black, particle diameter 10～15nm, specific surface area 200～600m
2/ g, pH value 5～9, DBP absorption value is greater than 1.0mL/g.
Preparation method: each component is prepared burden by weight proportion, then in the high-speed mixer of 1000～3000 revs/min, mix 5～20 minutes, add again in Banbury mixer, 140 ℃～180 ℃ banburyings 5～10 minutes, then pulverize, granulation, drying, pack and obtain a kind of Masterbatch by carbon black pigmented polyethylene of the present invention.
Claims (7)
1. the Masterbatch by carbon black pigmented polyethylene, it is characterized in that, its component by mass percent proportioning is: carbon black 30%～70%, polyvinyl resin 20%～60%, dispersion agent 3%～5%, coupling agent 0.5%～3%, oxidation inhibitor 0.1%～1%, phthalocyanine blue 0.1%～1%.
2. a kind of Masterbatch by carbon black pigmented polyethylene according to claim 1, is characterized in that, described carbon black is high pigment furnace treated black, particle diameter 10～15nm, specific surface area 200～600m
2/ g, pH value 5～9, DBP absorption value is greater than 1.0mL/g.
3. a kind of Masterbatch by carbon black pigmented polyethylene according to claim 1, is characterized in that, described dispersion agent is the one in low molecular weight polyethylene wax, OP wax and calcium stearate.
4. a kind of Masterbatch by carbon black pigmented polyethylene according to claim 1, is characterized in that, described coupling agent is the one in silane coupling agent, titanate coupling agent, aluminate coupling agent, aluminium titanium composite coupler.
5. a kind of Masterbatch by carbon black pigmented polyethylene according to claim 1, is characterized in that, described oxidation inhibitor is hindered phenol antioxygen 1010 or 1076 and the compound of phosphite ester kind antioxidant 168.
6. a kind of Masterbatch by carbon black pigmented polyethylene according to claim 1, is characterized in that, described phthalocyanine blue is beta crystal copper phthalocyanine complex compound.
7. the preparation method of a kind of Masterbatch by carbon black pigmented polyethylene according to claim 1, it is characterized in that, comprise the following steps: each component is prepared burden by weight proportion, then in the high-speed mixer of 1000～3000 revs/min, mix 5～20 minutes, add again in Banbury mixer, 140 ℃～180 ℃ banburyings 5～10 minutes, then pulverize, granulation, drying, pack and obtain a kind of Masterbatch by carbon black pigmented polyethylene of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594138.XA CN103849036A (en) | 2012-12-04 | 2012-12-04 | Color master batch capable of coloring polyethylene with carbon black |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210594138.XA CN103849036A (en) | 2012-12-04 | 2012-12-04 | Color master batch capable of coloring polyethylene with carbon black |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103849036A true CN103849036A (en) | 2014-06-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210594138.XA Pending CN103849036A (en) | 2012-12-04 | 2012-12-04 | Color master batch capable of coloring polyethylene with carbon black |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104151676A (en) * | 2014-08-28 | 2014-11-19 | 山东鲁燕色母粒有限公司 | Preparation method of polyethylene water supply pipe blue identification specially-use material |
| CN106432881A (en) * | 2016-11-02 | 2017-02-22 | 天津毅兴彩科技有限公司 | Plastic masterbatch |
| CN106496739A (en) * | 2016-11-02 | 2017-03-15 | 天津毅兴彩科技有限公司 | A kind of PE Masterbatch |
| CN106893178A (en) * | 2017-03-10 | 2017-06-27 | 广州润锋化工有限公司 | A kind of special black agglomerate of weather-proof tubing and preparation method thereof |
| CN107619544A (en) * | 2017-09-04 | 2018-01-23 | 珠海市南蓝塑胶科技有限公司 | Blue phase black agglomerate for AS or ABS and preparation method thereof |
| CN107619520A (en) * | 2017-09-04 | 2018-01-23 | 珠海市南蓝塑胶科技有限公司 | For polyethylene or polyacrylic blue phase black agglomerate and preparation method thereof |
| CN107932944A (en) * | 2017-12-18 | 2018-04-20 | 吉林钰邦新型材料有限公司 | A kind of production technology of silico-calcium synthesis hollow package boxboard |
| CN109503923A (en) * | 2018-11-22 | 2019-03-22 | 吉林省塑料研究院 | A kind of silicon carbon black Masterbatch and preparation method thereof |
| CN110527177A (en) * | 2019-09-05 | 2019-12-03 | 佛山市南海皆联科技有限公司 | A kind of low smell food-grade black agglomerate and preparation method thereof |
| CN112063223A (en) * | 2020-09-04 | 2020-12-11 | 华协书画院有限公司 | Method for extracting special carbon black for ink from black rock |
| CN113214555A (en) * | 2021-05-11 | 2021-08-06 | 广东九彩新材料有限公司 | Carbon black master batch with high coloring performance and preparation method thereof |
-
2012
- 2012-12-04 CN CN201210594138.XA patent/CN103849036A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104151676A (en) * | 2014-08-28 | 2014-11-19 | 山东鲁燕色母粒有限公司 | Preparation method of polyethylene water supply pipe blue identification specially-use material |
| CN106432881A (en) * | 2016-11-02 | 2017-02-22 | 天津毅兴彩科技有限公司 | Plastic masterbatch |
| CN106496739A (en) * | 2016-11-02 | 2017-03-15 | 天津毅兴彩科技有限公司 | A kind of PE Masterbatch |
| CN106893178A (en) * | 2017-03-10 | 2017-06-27 | 广州润锋化工有限公司 | A kind of special black agglomerate of weather-proof tubing and preparation method thereof |
| CN107619520B (en) * | 2017-09-04 | 2020-03-17 | 珠海市南蓝塑胶科技有限公司 | Blue-phase black master batch for polyethylene or polypropylene and preparation method thereof |
| CN107619520A (en) * | 2017-09-04 | 2018-01-23 | 珠海市南蓝塑胶科技有限公司 | For polyethylene or polyacrylic blue phase black agglomerate and preparation method thereof |
| CN107619544A (en) * | 2017-09-04 | 2018-01-23 | 珠海市南蓝塑胶科技有限公司 | Blue phase black agglomerate for AS or ABS and preparation method thereof |
| CN107932944A (en) * | 2017-12-18 | 2018-04-20 | 吉林钰邦新型材料有限公司 | A kind of production technology of silico-calcium synthesis hollow package boxboard |
| CN109503923A (en) * | 2018-11-22 | 2019-03-22 | 吉林省塑料研究院 | A kind of silicon carbon black Masterbatch and preparation method thereof |
| CN109503923B (en) * | 2018-11-22 | 2022-01-28 | 吉林省塑料研究院 | Preparation method of silicon-carbon black master batch |
| CN110527177A (en) * | 2019-09-05 | 2019-12-03 | 佛山市南海皆联科技有限公司 | A kind of low smell food-grade black agglomerate and preparation method thereof |
| CN110527177B (en) * | 2019-09-05 | 2022-07-05 | 广东皆联科技有限公司 | Low-odor food-grade black master batch and preparation method thereof |
| CN112063223A (en) * | 2020-09-04 | 2020-12-11 | 华协书画院有限公司 | Method for extracting special carbon black for ink from black rock |
| CN113214555A (en) * | 2021-05-11 | 2021-08-06 | 广东九彩新材料有限公司 | Carbon black master batch with high coloring performance and preparation method thereof |
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Application publication date: 20140611 |