CN104629555A - Novel low-carbon flexible water-based coating and preparation method thereof - Google Patents
Novel low-carbon flexible water-based coating and preparation method thereof Download PDFInfo
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- CN104629555A CN104629555A CN201510029632.5A CN201510029632A CN104629555A CN 104629555 A CN104629555 A CN 104629555A CN 201510029632 A CN201510029632 A CN 201510029632A CN 104629555 A CN104629555 A CN 104629555A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of water-based architectural coatings, in particular to a novel low-carbon flexible water-based coating and a preparation method thereof. The novel low-carbon flexible water-based coating comprises the following raw materials in parts by weight: 30-50 parts of water-based acrylic resin, 10-20 parts of titanium dioxide, 10-20 parts of kaolin, 20-30 parts of nano-calcium carbonate powder, 10-30 parts of emulsion, 3-5 parts of nano-zinc oxide, 1-3 parts of wetting agent, 5-7 parts of dispersing agent and 1-3 parts of bactericide. In the invention, firstly, by virtue of the water-based acrylic resin, the prepared coating has the advantages of low carbon, energy saving, environment protection and the like, and secondly, the nano-zinc oxide and the bactericide, the prepared coating has the advantages of bacterial killing, antitoxin, high aging resistance and good anti-corrosive properties. In addition, the flexible water-based coating and the preparation method thereof have the advantages of simple production process, convenient operation, low manufacturing cost, and easy generalization and use.
Description
Technical field
The present invention relates to aqueous architectural coating technical field, be specifically related to flexible water-borne coatings of novel low carbon and preparation method thereof.
Background technology
21 century is century of environmental protection, resource-saving, economize the energy, pollution-free be main developing direction.The oil-base paint overwhelming majority of current domestic use is solvent based coating, and the maximum shortcoming of these coating is exactly contaminate environment, inflammable and explosive, harmful, and wastes a large amount of resources and the energy.Water-based anticorrosive paint has that price is low, use safety, saving resource and the energy, reduce the advantage such as environmental pollution and public hazards, because becoming the Main way of current development coatings industry, therefore developing free of contamination low-carbon (LC) water-borne coatings will be the focus place of domestic and international coating industry.
Summary of the invention
The object of this invention is to provide a kind of low-carbon (LC), energy-saving and environmental protection, sterilization, gas defence, ageing resistance is high, and preservative property are good, and production technique is simple, easy and simple to handle, flexible water-borne coatings of novel low carbon of low cost of manufacture and preparation method thereof.
In order to solve the problem existing for background technology, the present invention is by the following technical solutions: the flexible water-borne coatings of novel low carbon, proportioning is as follows by weight: water-borne acrylic resin 30-50 part, titanium dioxide 10-20 part, kaolin 10-20 part, nano-calcium carbonate calcium powder 20-30 part, emulsion 10-30 part, nano zine oxide 3-5 part, wetting agent 1-3 part, dispersion agent 5-7 part, sterilant 1-3 part.
Further, described wetting agent is polyxyethylated alkylphenol or wetting agent SNWET-991.
Further, described dispersion agent is polyacrylamide or fatty acid polyglycol ester.
Further, described sterilant is sterilant KLN-15B or sterilant KLN-16B.
Further, described emulsion is organic silicon emulsion RS996AD, KD9 or ACRYLIC EMULSION RS2806, AC-261P or elastic emulsion CN11,2438M.
Present invention also offers the preparation method of the flexible water-borne coatings of novel low carbon, comprise the following steps:
(1), by above-mentioned water-borne acrylic resin, titanium dioxide, kaolin, nano-calcium carbonate calcium powder utilize high speed dispersor to carry out stirring pre-mixing, its mixing time is 20-30 minute, and to reach the fineness of regulation, above-mentioned fineness of materials is separated into 50-70 micron;
(2), by the material after above-mentioned dispersion adopt paint equipment to mix with above-mentioned emulsion, nano zine oxide, wetting agent, dispersion agent, sterilant, to reach the indexs such as the viscosity of regulation, wherein, mixing time is 10-20 minute;
(3) the filter plant coating complete to above-mentioned paint, is adopted to carry out filtration decon;
(4), finished product coating packing sealing.
The present invention has following beneficial effect: flexible water-borne coatings of novel low carbon of the present invention and preparation method thereof, first water-borne acrylic resin is adopted, there is the advantage such as low-carbon (LC), energy-saving and environmental protection, next adopts nano zine oxide, sterilant etc., there is the advantage such as sterilization, gas defence, ageing resistance is high, and preservative property are good.In addition, this flexible water-borne coatings and preparation method thereof production technique is simple, easy and simple to handle, low cost of manufacture, is easy to promote and use.
Embodiment
Embodiment one:
The flexible water-borne coatings of novel low carbon, proportioning is as follows by weight: water-borne acrylic resin 30 parts, titanium dioxide 10 parts, kaolin 10 parts, nano-calcium carbonate calcium powder 20 parts, emulsion 10 parts, nano zine oxide 3 parts, wetting agent 1 part, dispersion agent 5 parts, 1 part, sterilant.Wherein, described wetting agent is polyxyethylated alkylphenol or wetting agent SNWET-991; Described dispersion agent is polyacrylamide or fatty acid polyglycol ester; Described sterilant is sterilant KLN-15B or sterilant KLN-16B; Described emulsion is organic silicon emulsion RS996AD, KD9 or ACRYLIC EMULSION RS2806, AC-261P or elastic emulsion CN11,2438M.
The preparation method of the flexible water-borne coatings of novel low carbon, comprises the following steps:
(1), by above-mentioned water-borne acrylic resin, titanium dioxide, kaolin, nano-calcium carbonate calcium powder utilize high speed dispersor to carry out stirring pre-mixing, its mixing time is 20 minutes, and to reach the fineness of regulation, above-mentioned fineness of materials is separated into 50 microns;
(2), by the material after above-mentioned dispersion adopt paint equipment to mix with above-mentioned emulsion, nano zine oxide, wetting agent, dispersion agent, sterilant, to reach the indexs such as the viscosity of regulation, wherein, mixing time is 10 minutes;
(3) the filter plant coating complete to above-mentioned paint, is adopted to carry out filtration decon; Owing to there being the impurity such as a small amount of thick slag in the coating that paint is complete, filter plant is therefore adopted to make it purification;
(4), finished product coating packing sealing.
Embodiment two:
The flexible water-borne coatings of novel low carbon, proportioning is as follows by weight: water-borne acrylic resin 40 parts, titanium dioxide 15 parts, kaolin 15 parts, nano-calcium carbonate calcium powder 25 parts, emulsion 20 parts, nano zine oxide 4 parts, wetting agent 2 parts, dispersion agent 6 parts, 2 parts, sterilant.Wherein, described wetting agent is polyxyethylated alkylphenol or wetting agent SNWET-991; Described dispersion agent is polyacrylamide or fatty acid polyglycol ester; Described sterilant is sterilant KLN-15B or sterilant KLN-16B; Described emulsion is organic silicon emulsion RS996AD, KD9 or ACRYLIC EMULSION RS2806, AC-261P or elastic emulsion CN11,2438M.
The preparation method of the flexible water-borne coatings of novel low carbon, comprises the following steps:
(1), by above-mentioned water-borne acrylic resin, titanium dioxide, kaolin, nano-calcium carbonate calcium powder utilize high speed dispersor to carry out stirring pre-mixing, its mixing time is 25 minutes, and to reach the fineness of regulation, above-mentioned fineness of materials is separated into 60 microns;
(2), by the material after above-mentioned dispersion adopt paint equipment to mix with above-mentioned emulsion, nano zine oxide, wetting agent, dispersion agent, sterilant, to reach the indexs such as the viscosity of regulation, wherein, mixing time is 15 minutes;
(3) the filter plant coating complete to above-mentioned paint, is adopted to carry out filtration decon;
(4), finished product coating packing sealing.In the present embodiment, other is all identical with embodiment one.
Embodiment three:
The flexible water-borne coatings of novel low carbon, proportioning is as follows by weight: water-borne acrylic resin 50 parts, titanium dioxide 20 parts, kaolin 20 parts, nano-calcium carbonate calcium powder 30 parts, emulsion 30 parts, nano zine oxide 5 parts, wetting agent 3 parts, dispersion agent 7 parts, 3 parts, sterilant.Wherein, described wetting agent is polyxyethylated alkylphenol or wetting agent SNWET-991; Described dispersion agent is polyacrylamide or fatty acid polyglycol ester; Described sterilant is sterilant KLN-15B or sterilant KLN-16B; Described emulsion is organic silicon emulsion RS996AD, KD9 or ACRYLIC EMULSION RS2806, AC-261P or elastic emulsion CN11,2438M.
The preparation method of the flexible water-borne coatings of novel low carbon, comprises the following steps:
(1), by above-mentioned water-borne acrylic resin, titanium dioxide, kaolin, nano-calcium carbonate calcium powder utilize high speed dispersor to carry out stirring pre-mixing, its mixing time is 30 minutes, and to reach the fineness of regulation, above-mentioned fineness of materials is separated into 70 microns;
(2), by the material after above-mentioned dispersion adopt paint equipment to mix with above-mentioned emulsion, nano zine oxide, wetting agent, dispersion agent, sterilant, to reach the indexs such as the viscosity of regulation, wherein, mixing time is 20 minutes;
(3) the filter plant coating complete to above-mentioned paint, is adopted to carry out filtration decon;
(4), finished product coating packing sealing.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, other amendments that those of ordinary skill in the art make technical scheme of the present invention or equivalently to replace, only otherwise depart from the spirit and scope of technical solution of the present invention, all should be encompassed in the middle of right of the present invention.
Claims (6)
1. the flexible water-borne coatings of novel low carbon, it is characterized in that, proportioning is as follows by weight: water-borne acrylic resin 30-50 part, titanium dioxide 10-20 part, kaolin 10-20 part, nano-calcium carbonate calcium powder 20-30 part, emulsion 10-30 part, nano zine oxide 3-5 part, wetting agent 1-3 part, dispersion agent 5-7 part, sterilant 1-3 part.
2. the flexible water-borne coatings of novel low carbon according to claim 1, it is characterized in that, described wetting agent is polyxyethylated alkylphenol or wetting agent SNWET-991.
3. the flexible water-borne coatings of novel low carbon according to claim 1, it is characterized in that, described dispersion agent is polyacrylamide or fatty acid polyglycol ester.
4. the flexible water-borne coatings of novel low carbon according to claim 1, it is characterized in that, described sterilant is sterilant KLN-15B or sterilant KLN-16B.
5. the flexible water-borne coatings of novel low carbon according to claim 1, is characterized in that, described emulsion is organic silicon emulsion RS996AD, KD9 or ACRYLIC EMULSION RS2806, AC-261P or elastic emulsion CN11,2438M.
6. the preparation method of the flexible water-borne coatings of novel low carbon according to claim 1, is characterized in that, comprise the following steps:
(1), by above-mentioned water-borne acrylic resin, titanium dioxide, kaolin, nano-calcium carbonate calcium powder utilize high speed dispersor to carry out stirring pre-mixing, its mixing time is 20-30 minute, and to reach the fineness of regulation, above-mentioned fineness of materials is separated into 50-70 micron;
(2), by the material after above-mentioned dispersion adopt paint equipment to mix with above-mentioned emulsion, nano zine oxide, wetting agent, dispersion agent, sterilant, to reach the indexs such as the viscosity of regulation, wherein, mixing time is 10-20 minute;
(3) the filter plant coating complete to above-mentioned paint, is adopted to carry out filtration decon;
(4), finished product coating packing sealing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510029632.5A CN104629555A (en) | 2015-01-21 | 2015-01-21 | Novel low-carbon flexible water-based coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510029632.5A CN104629555A (en) | 2015-01-21 | 2015-01-21 | Novel low-carbon flexible water-based coating and preparation method thereof |
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| CN104629555A true CN104629555A (en) | 2015-05-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510029632.5A Pending CN104629555A (en) | 2015-01-21 | 2015-01-21 | Novel low-carbon flexible water-based coating and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893473A (en) * | 2015-06-18 | 2015-09-09 | 张家港市山牧新材料技术开发有限公司 | Environment-friendly compound paint |
| CN107142009A (en) * | 2017-06-27 | 2017-09-08 | 陆文韬 | A kind of environment-friendlywater-based water-based paint |
| CN111793395A (en) * | 2020-05-29 | 2020-10-20 | 安徽老石人石业有限公司 | Maintenance-free and cracking-resistant stone protective agent for home decoration marble |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1537904A (en) * | 2003-04-17 | 2004-10-20 | 王钟贤 | Nanometer ecological energy-saving paint |
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN103666275A (en) * | 2013-12-10 | 2014-03-26 | 张家港市民扬塑胶科技有限公司 | Water-based anti-bacterial mould-proof paint |
-
2015
- 2015-01-21 CN CN201510029632.5A patent/CN104629555A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1537904A (en) * | 2003-04-17 | 2004-10-20 | 王钟贤 | Nanometer ecological energy-saving paint |
| CN101486863A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly waterborne paint and preparation thereof |
| CN103666275A (en) * | 2013-12-10 | 2014-03-26 | 张家港市民扬塑胶科技有限公司 | Water-based anti-bacterial mould-proof paint |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104893473A (en) * | 2015-06-18 | 2015-09-09 | 张家港市山牧新材料技术开发有限公司 | Environment-friendly compound paint |
| CN104893473B (en) * | 2015-06-18 | 2017-07-07 | 广州通路信息科技有限公司 | A kind of composite environmental-friendly paint |
| CN107142009A (en) * | 2017-06-27 | 2017-09-08 | 陆文韬 | A kind of environment-friendlywater-based water-based paint |
| CN111793395A (en) * | 2020-05-29 | 2020-10-20 | 安徽老石人石业有限公司 | Maintenance-free and cracking-resistant stone protective agent for home decoration marble |
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Application publication date: 20150520 |