CN103837913A - Reflector and production process thereof - Google Patents

Reflector and production process thereof Download PDF

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Publication number
CN103837913A
CN103837913A CN201210487405.3A CN201210487405A CN103837913A CN 103837913 A CN103837913 A CN 103837913A CN 201210487405 A CN201210487405 A CN 201210487405A CN 103837913 A CN103837913 A CN 103837913A
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Prior art keywords
melting
point metal
low
alloy
gallium
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CN201210487405.3A
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CN103837913B (en
Inventor
刘静
熊铭烽
李海燕
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Space Liquid Metal Technology Development Jiangsu Co ltd
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Technical Institute of Physics and Chemistry of CAS
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Abstract

The invention provides a reflector production process. The production process comprises the following steps: S1, a low melting point metal ink is produced; S2, the low melting point metal ink is evenly coated on the back of a transparent substrate, the low melting point metal ink form a reflective film on the back of the transparent substrate; and S3, a protective film is coated on the reflective film and is used for encapsulation of the reflective film. In the invention, the production process is simple and can be completed quickly under normal conditions, so that the production and application efficiency is improved and the demand on the environment is reduced; and the low melting point metal ink is evenly coated on the surface of the transparent substrate so as to form the film with good reflecting characteristics, and the production process uses the characteristics for solar energy concentration, so that the solar light and heat utilization cost is greatly reduced. The invention also provides a reflector.

Description

Reflective mirror and manufacture craft thereof
Technical field
The present invention relates to reflective mirror field, particularly a kind of liquid metal reflective mirror and manufacture craft thereof.
Background technology
Along with the development of global economy, the consumption of the non-renewable energy resources such as oil, coal, rock gas grows with each passing day, and this makes energy shortage problem increasingly serious, finds alternative regenerative resource extremely urgent in each traditional energy consumption field.Sun power, as be the most also maximum energy source on the earth, has occupied most crucial status undoubtedly in following energy structure.
In solar energy and heat utilization, what first will face is that the sun power of point scattered radiation is concentrated, to improve the energy density of light and heat.The efficiency of beam condensing unit and price will directly affect efficiency and the economy of whole solar energy utilization system.At present, solar concentrator is mainly divided into imaging condenser and non-imaging condenser.Tradition imaging condenser is generally made of optical glass, and cost is high, and organic glass is easily aging, and produced simultaneously differing greatly reduced optically focused ratio greatly.Non-imaging condenser mainly contains refraction type light gathering mirror and mirror condenser.Mirror condenser mainly contains conical mirror, grooved parabolic concentrator, rotary paraboloid light-gathering mirror, bar shaped catoptron etc.Conventional mirror condenser material has sheet metal, paper tinsel and metal coating, the processing of these reflectorized materials needs the technological means such as high polish, vacuum high-temperature evaporation, the problem that corresponding process exists is that technique is too complicated, and some also needs to consume precious metal, such as silver etc.; The cost that this has improved solar energy utilization system greatly, has hindered the universal of solar energy utilization system.
In other application, the processing and fabricating of reflective mirror also adopts the method such as chemical silvering and vacuum evaporation mostly, and vacuum evaporation need to complete under high-temperature vacuum condition, and process conditions are too harsh, totally unfavorable to reducing production costs; In addition, chemical method can consume a lot of extra chemical substances, and addition product also easily causes environmental pollution.
Summary of the invention
The present invention is by providing a kind of liquid metal reflective mirror to replace traditional reflective mirror, and its manufacture craft is simple, and cost of manufacture is low, can improve and produce and application efficiency.
The present invention is achieved by the following technical programs:
A kind of reflective mirror, includes:
The substrate of light-permeable; Evenly be coated on the light reflecting membrane of described backside of substrate, this light reflecting membrane is made up of low-melting-point metal ink;
One diaphragm, it is coated on described light reflecting membrane, for described light reflecting membrane is encapsulated.
Described light reflecting membrane by spray, print, whitewash or pencil type apparatus at least one be evenly coated in this backside of substrate.
Described low-melting-point metal ink is made up of low-melting-point metal compound substance; Described low-melting-point metal compound substance is that the low-melting-point metal that contains partial oxide or the low-melting alloy that contains partial oxide are made.
Described low-melting-point metal compound substance is further added with the nano-particle material for strengthening reflection characteristic.
Described low-melting-point metal compound substance is made up of the low-melting-point metal that contains 0.1wt%~10wt% oxide or the low-melting alloy that contains 0.1wt% ~ 10wt% oxide;
Described low-melting-point metal comprises at least one in gallium, zinc, tin, sodium, potassium and mercury; Described low-melting alloy comprises at least one in gallium kirsite, gallium indium alloy, gallium ashbury metal, indium stannum alloy, gallium-indium-tin alloy, gallium indium tin kirsite, gallium indium tin zinc bismuth alloy, copper gallium indium alloy, gallium aluminium indium alloy or Na-K alloy.
A manufacture craft for reflective mirror, comprises the following steps:
S1, making low-melting-point metal ink;
S2, described low-melting-point metal ink is evenly coated on to the back side of a light-transparent substrate, described low-melting-point metal ink forms light reflecting membrane at the light-transparent substrate back side;
S3, on described light reflecting membrane coating protective film, for described light reflecting membrane is encapsulated.
Described step S1 further comprises:
S11, be mixed with metal fluid with low-melting-point metal compound substance, described metal flow physical efficiency is for applying;
S12, in air, described metal fluid is stirred, form low-melting-point metal ink.
Described low-melting-point metal ink by spray, print, whitewash or pencil type apparatus at least one be evenly coated in the back side of described light-transparent substrate, and form light reflecting membrane.
Described step S11 takes a step forward and comprises:
S10, in described low-melting-point metal compound substance, add for strengthening the nano-particle material of reflection characteristic.
Described low-melting-point metal compound substance is that the low-melting-point metal that contains partial oxide or the low-melting alloy that contains partial oxide are made.
Described low-melting-point metal compound substance is made up of the low-melting-point metal that contains 0.1wt% ~ 10wt% oxide or the low-melting alloy that contains 0.1wt% ~ 10wt% oxide;
Described low-melting-point metal comprises at least one in gallium, zinc, tin, sodium, potassium and mercury; Described low-melting alloy comprises at least one in gallium kirsite, gallium indium alloy, gallium ashbury metal, indium stannum alloy, gallium-indium-tin alloy, gallium indium tin kirsite, gallium indium tin zinc bismuth alloy, copper gallium indium alloy, gallium aluminium indium alloy or Na-K alloy.
A kind of reflective mirror provided by the invention and manufacture craft thereof, its production process is simple and quick, under normal condition, can complete, and has improved production and application efficiency, has reduced the requirement to environment; And this manufacture craft is utilized low-melting-point metal ink to be evenly coated in the film forming on light-transparent substrate surface to have good reflective characteristic, can be for Salar light-gathering, can obtain solar energy or heat energy that energy density is stronger, greatly reduce the cost of solar energy and heat utilization, for realizing the efficient of sun power and extensively utilizing the new choice of technology is provided; The present invention can also extend to more wide application, as can be used as family expenses clothing adornment mirror, automobile rearview mirror, dancing chamber mirror, or even the distorting mirror of entertainment field etc., to substitute traditional reflective mirror.
Accompanying drawing explanation
Fig. 1 is the fabrication processing figure of one embodiment of the invention.
Embodiment
Under regard to a kind of reflective mirror and manufacture craft thereof proposed by the invention, in conjunction with the accompanying drawings and embodiments describe in detail.
Embodiment 1:
The present embodiment provides a kind of reflective mirror, includes:
The substrate of light-permeable; Evenly be coated on the light reflecting membrane of described backside of substrate, this light reflecting membrane is made up of low-melting-point metal ink;
One diaphragm, it is coated on described light reflecting membrane, for described light reflecting membrane is encapsulated.
Described light reflecting membrane by spray, print, whitewash or pencil type apparatus at least one be evenly coated in this backside of substrate.
Described low-melting-point metal ink is made up of low-melting-point metal compound substance; Described low-melting-point metal compound substance is that the low-melting-point metal that contains partial oxide or the low-melting alloy that contains partial oxide are made.
Described low-melting-point metal compound substance is further added with the nano-particle material for strengthening reflection characteristic.
Described low-melting-point metal compound substance is made up of the low-melting-point metal that contains 0.1wt% ~ 10wt% oxide or the low-melting alloy that contains 0.1wt% ~ 10wt% oxide;
Described low-melting-point metal comprises at least one in gallium, zinc, tin, sodium, potassium and mercury; Described low-melting alloy comprises at least one in gallium kirsite, gallium indium alloy, gallium ashbury metal, indium stannum alloy, gallium-indium-tin alloy, gallium indium tin kirsite, gallium indium tin zinc bismuth alloy, copper gallium indium alloy, gallium aluminium indium alloy or Na-K alloy.
The present embodiment also provides a kind of manufacture craft of reflective mirror, as shown in Figure 1, comprises the following steps:
S1, making low-melting-point metal ink;
S2, described low-melting-point metal ink is evenly coated on to the back side of a light-transparent substrate, described low-melting-point metal ink forms light reflecting membrane at the light-transparent substrate back side;
S3, on described light reflecting membrane coating protective film, for described light reflecting membrane is encapsulated.
Described step S1 further comprises:
S11, be mixed with metal fluid with low-melting-point metal compound substance, described metal flow physical efficiency is for applying;
S12, in air, described metal fluid is stirred, form low-melting-point metal ink.
Described low-melting-point metal ink by spray, print, whitewash or pencil type apparatus at least one be evenly coated in the back side of described light-transparent substrate, and form light reflecting membrane.
Described step S11 takes a step forward and comprises:
S10, in described low-melting-point metal compound substance, add for strengthening the nano-particle material of reflection characteristic.
Described low-melting-point metal compound substance is that the low-melting-point metal that contains partial oxide or the low-melting alloy that contains partial oxide are made.
Described low-melting-point metal compound substance is made up of the low-melting-point metal that contains 0.1wt% ~ 10wt% oxide or the low-melting alloy that contains 0.1wt% ~ 10wt% oxide;
Described low-melting-point metal comprises at least one in gallium, zinc, tin, sodium, potassium and mercury; Described low-melting alloy comprises at least one in gallium kirsite, gallium indium alloy, gallium ashbury metal, indium stannum alloy, gallium-indium-tin alloy, gallium indium tin kirsite, gallium indium tin zinc bismuth alloy, copper gallium indium alloy, gallium aluminium indium alloy or Na-K alloy.
Embodiment 2:
The present embodiment the present invention will be further explained on the basis of embodiment 1 explanation.
A kind of reflective mirror, includes:
The substrate of light-permeable; Described substrate is light transmissive material, and described light transmissive material can be hard material as glass, resin or quartz, also can be soft material as transparent plastic, transparent rubber.That the shape of substrate can be set to is as required flat, the combination of circular cone type, parabolic trough, the paraboloid of revolution or bar shaped and these shapes, and the shape of described substrate also can be other various shapes of utilizing in occasion.
Evenly be coated on the light reflecting membrane of described backside of substrate, this light reflecting membrane is made up of low-melting-point metal ink, and the thickness of light reflecting membrane is 1-100 μ m;
Described light reflecting membrane by spray, print, whitewash or pencil type apparatus at least one be evenly coated in this backside of substrate; Applying low-melting-point metal ink can apply by existing printing equipment, coating equipment, the pencil type apparatus that is moistened with the brush of this low-melting-point metal ink or is filled with low-melting-point metal ink.The facility of bringing with brush is the making that can complete at the light-transparent substrate back side of various shapes light reflecting membrane, and brush can be used writing brush, oil painting brush or paintbrush.The pencil type apparatus that is filled with low-melting-point metal ink comprises: pen-type pencil type apparatus, ball pen type pencil type apparatus, neutral pen type pen shaped arrangement, print type printing equipment, point gum machine formula printing equipment or spray nozzle type pencil type apparatus.
Described low-melting-point metal ink is made up of low-melting-point metal compound substance; Described low-melting-point metal compound substance is that the low-melting-point metal that contains partial oxide or the low-melting alloy that contains partial oxide are made.
Described low-melting-point metal compound substance is further added with the nano-particle material for strengthening reflection characteristic; Described nano material as size at 1nm to nano silicon, the nano-ceramic particle etc. of 900nm.
Described low-melting-point metal compound substance is made up of the low-melting-point metal that contains 0.1wt% ~ 10wt% oxide or the low-melting alloy that contains 0.1wt% ~ 10wt% oxide; These low-melting-point metals are made into after alloy according to a certain percentage, and fusing point further reduces; Described low-melting-point metal comprises at least one in gallium, zinc, tin, sodium, potassium and mercury; Described low-melting alloy comprises at least one in gallium kirsite, gallium indium alloy, gallium ashbury metal, indium stannum alloy, gallium-indium-tin alloy, gallium indium tin kirsite, gallium indium tin zinc bismuth alloy, copper gallium indium alloy, gallium aluminium indium alloy or Na-K alloy; These low-melting-point metal compound substances are highly susceptible to making and can be directly coated in suprabasil metallic ink.
One diaphragm, it is coated on described light reflecting membrane, for described light reflecting membrane is encapsulated; This diaphragm can be the inorganics plated films such as epoxy resin, silicon rubber or epoxy silicone, monox, silicon dioxide, utilizes printing, pastes or be coated on described light reflecting membrane and form and encapsulate by other modes; Described diaphragm thickness range is 1-100mm.
The present embodiment provides a kind of manufacture craft of reflective mirror, comprises the following steps:
S1, making low-melting-point metal ink; Specifically comprise the following steps:
S11, be mixed with metal fluid with low-melting-point metal compound substance, described metal flow physical efficiency is for applying;
S12, in air, described metal fluid is stirred, form low-melting-point metal ink; It is partially oxidized for metal fluid in air, described metal fluid being stirred, the viscosity that increases metal fluid with and with the adhesiveness of the substrate of various materials.
S2, described low-melting-point metal ink is evenly coated on to the back side of a light-transparent substrate, described low-melting-point metal ink forms light reflecting membrane at the light-transparent substrate back side; Can first select material and the shape of substrate, the surface of contact of low-melting-point metal ink and substrate is as reflective mirror.
S3, on described light reflecting membrane coating protective film, for described light reflecting membrane is encapsulated.
Described step S1 further comprises:
Described low-melting-point metal ink by spray, print, whitewash or pencil type apparatus at least one be evenly coated in the back side of described light-transparent substrate, and form light reflecting membrane.
Described step S11 takes a step forward and comprises:
S10, in described low-melting-point metal compound substance, add for strengthening the nano-particle material of reflection characteristic.
Consistent to the relevant restriction in above-mentioned reflective mirror to the further restriction of substrate, light reflecting membrane, diaphragm and low-melting-point metal ink in the present embodiment.
Embodiment 3:
The present embodiment, take the thick glass parabolical substrate of 0.5cm as example, illustrates the manufacture craft of the reflective mirror in the present invention:
The alloy of making certain proportioning after first gallium and indium being melted respectively carries out the stirring of certain hour in air, makes alloy part oxidized, makes the low-melting-point metal ink of certain fluidity; With oil painting brush, described low-melting-point metal ink is coated in equably to the back side of glass parabolical substrate again, forms light reflecting membrane, its coating thickness is 20 μ m; Finally on low-melting-point metal ink, coating silicon rubber encapsulates, and just can become the diaphragm of light reflecting membrane after silicon rubber is dry, and silicon rubber thickness is 2mm.
A kind of reflective mirror provided by the invention and manufacture craft thereof, its production process is simple and quick, under normal condition, can complete, and has improved production and application efficiency, has reduced the requirement to environment; And this manufacture craft is utilized low-melting-point metal ink to be evenly coated in the film forming on light-transparent substrate surface to have good reflective characteristic, can be for Salar light-gathering, can obtain solar energy or heat energy that energy density is stronger, greatly reduce the cost of solar energy and heat utilization, for realizing the efficient of sun power and extensively utilizing the new choice of technology is provided; The present invention can also extend to more wide application, as can be used as family expenses clothing adornment mirror, automobile rearview mirror, dancing chamber mirror, or even the distorting mirror of entertainment field etc., to substitute traditional reflective mirror.
Above embodiment is only for illustrating the present invention; and be not limitation of the present invention; the those of ordinary skill in relevant technologies field; without departing from the spirit and scope of the present invention; can also make a variety of changes and modification; therefore all technical schemes that are equal to also belong to category of the present invention, and scope of patent protection of the present invention should be defined by the claims.

Claims (11)

1. a reflective mirror, is characterized in that, includes:
The substrate of light-permeable; Evenly be coated on the light reflecting membrane of described backside of substrate, this light reflecting membrane is made up of low-melting-point metal ink;
One diaphragm, it is coated on described light reflecting membrane, for described light reflecting membrane is encapsulated.
2. reflective mirror as claimed in claim 1, is characterized in that, described light reflecting membrane by spray, print, whitewash or pencil type apparatus at least one be evenly coated in this backside of substrate.
3. reflective mirror as claimed in claim 1, is characterized in that, described low-melting-point metal ink is made up of low-melting-point metal compound substance; Described low-melting-point metal compound substance is that the low-melting-point metal that contains partial oxide or the low-melting alloy that contains partial oxide are made.
4. reflective mirror as claimed in claim 3, is characterized in that, described low-melting-point metal compound substance is further added with the nano-particle material for strengthening reflection characteristic.
5. the reflective mirror as described in claim 3 or 4, is characterized in that, described low-melting-point metal compound substance is made up of the low-melting-point metal that contains 0.1wt% ~ 10wt% oxide or the low-melting alloy that contains 0.1wt% ~ 10wt% oxide;
Described low-melting-point metal comprises at least one in gallium, zinc, tin, sodium, potassium and mercury; Described low-melting alloy comprises at least one in gallium kirsite, gallium indium alloy, gallium ashbury metal, indium stannum alloy, gallium-indium-tin alloy, gallium indium tin kirsite, gallium indium tin zinc bismuth alloy, copper gallium indium alloy, gallium aluminium indium alloy or Na-K alloy.
6. a manufacture craft for reflective mirror, is characterized in that, comprises the following steps:
S1, making low-melting-point metal ink;
S2, described low-melting-point metal ink is evenly coated on to the back side of a light-transparent substrate, described low-melting-point metal ink forms light reflecting membrane at the light-transparent substrate back side;
S3, on described light reflecting membrane coating protective film, for described light reflecting membrane is encapsulated.
7. manufacture craft as claimed in claim 6, is characterized in that, described step S1 further comprises:
S11, be mixed with metal fluid with low-melting-point metal compound substance, described metal flow physical efficiency is for applying;
S12, in air, described metal fluid is stirred, form low-melting-point metal ink.
8. manufacture craft as claimed in claim 6, is characterized in that, described low-melting-point metal ink by spray, print, whitewash or pencil type apparatus at least one be evenly coated in the back side of described light-transparent substrate, and form light reflecting membrane.
9. manufacture craft as claimed in claim 7, is characterized in that, described step S11 takes a step forward and comprises:
S10, in described low-melting-point metal compound substance, add for strengthening the nano-particle material of reflection characteristic.
10. the manufacture craft as described in claim 7 or 9, is characterized in that, described low-melting-point metal compound substance is that the low-melting-point metal that contains partial oxide or the low-melting alloy that contains partial oxide are made.
11. manufacture crafts as claimed in claim 10, is characterized in that, described low-melting-point metal compound substance is made up of the low-melting-point metal that contains 0.1wt% ~ 10wt% oxide or the low-melting alloy that contains 0.1wt% ~ 10wt% oxide;
Described low-melting-point metal comprises at least one in gallium, zinc, tin, sodium, potassium and mercury; Described low-melting alloy comprises at least one in gallium kirsite, gallium indium alloy, gallium ashbury metal, indium stannum alloy, gallium-indium-tin alloy, gallium indium tin kirsite, gallium indium tin zinc bismuth alloy, copper gallium indium alloy, gallium aluminium indium alloy or Na-K alloy.
CN201210487405.3A 2012-11-26 2012-11-26 Reflective mirror and manufacture craft thereof Active CN103837913B (en)

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CN103837913B CN103837913B (en) 2016-05-04

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106597657A (en) * 2016-12-05 2017-04-26 清华大学 Electrowetting-based liquid metal zooming micro reflector
CN106772728A (en) * 2016-12-12 2017-05-31 云南科威液态金属谷研发有限公司 Deformable minute surface
CN107557718A (en) * 2016-06-24 2018-01-09 中国科学院理化技术研究所 A kind of method for preparing inorganic nano material layer on flexible material surface
CN108461651A (en) * 2018-03-28 2018-08-28 京东方科技集团股份有限公司 Dot structure and preparation method thereof, display panel
JP2020521993A (en) * 2017-04-18 2020-07-27 マジック リープ, インコーポレイテッドMagic Leap,Inc. Waveguide with reflective layer formed by reflective flowable material

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CN101971100A (en) * 2008-03-03 2011-02-09 Asml荷兰有限公司 Lithographic apparatus, plasma source, and reflecting method

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US3497377A (en) * 1966-10-31 1970-02-24 Boeing Co Mirror configurations
GB1455148A (en) * 1972-12-21 1976-11-10 Glaverbel Oxide cotaing method
US4009947A (en) * 1973-02-15 1977-03-01 Canon Kabushiki Kaisha Reflecting mirror
CN1212671A (en) * 1996-01-09 1999-03-31 日本板硝子株式会社 Coated glass for buildings
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107557718A (en) * 2016-06-24 2018-01-09 中国科学院理化技术研究所 A kind of method for preparing inorganic nano material layer on flexible material surface
CN106597657A (en) * 2016-12-05 2017-04-26 清华大学 Electrowetting-based liquid metal zooming micro reflector
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JP2020521993A (en) * 2017-04-18 2020-07-27 マジック リープ, インコーポレイテッドMagic Leap,Inc. Waveguide with reflective layer formed by reflective flowable material
CN108461651A (en) * 2018-03-28 2018-08-28 京东方科技集团股份有限公司 Dot structure and preparation method thereof, display panel

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