CN103835022A - 一种纤维素共混纤维及其制备方法 - Google Patents
一种纤维素共混纤维及其制备方法 Download PDFInfo
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- CN103835022A CN103835022A CN201410082632.7A CN201410082632A CN103835022A CN 103835022 A CN103835022 A CN 103835022A CN 201410082632 A CN201410082632 A CN 201410082632A CN 103835022 A CN103835022 A CN 103835022A
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- 239000000835 fiber Substances 0.000 title claims abstract description 72
- 229920002678 cellulose Polymers 0.000 title claims abstract description 52
- 239000001913 cellulose Substances 0.000 title claims abstract description 44
- 238000002360 preparation method Methods 0.000 title claims abstract description 40
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 29
- 229920002239 polyacrylonitrile Polymers 0.000 claims abstract description 29
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 29
- 229920000656 polylysine Polymers 0.000 claims abstract description 21
- 108010039918 Polylysine Proteins 0.000 claims abstract description 13
- 235000010980 cellulose Nutrition 0.000 claims description 49
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 28
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 28
- 208000012886 Vertigo Diseases 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 25
- 238000009987 spinning Methods 0.000 claims description 23
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- 239000002608 ionic liquid Substances 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 5
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- 229920001519 homopolymer Polymers 0.000 claims description 2
- 238000005304 joining Methods 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 229920003043 Cellulose fiber Polymers 0.000 abstract description 2
- 229920001661 Chitosan Polymers 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 66
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000012986 modification Methods 0.000 description 6
- 230000004048 modification Effects 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- LFTLOKWAGJYHHR-UHFFFAOYSA-N N-methylmorpholine N-oxide Chemical compound CN1(=O)CCOCC1 LFTLOKWAGJYHHR-UHFFFAOYSA-N 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 3
- 229920002521 macromolecule Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 2
- SJRXVLUZMMDCNG-UHFFFAOYSA-N Gossypin Natural products OC1C(O)C(O)C(CO)OC1OC1=C(O)C=C(O)C2=C1OC(C=1C=C(O)C(O)=CC=1)=C(O)C2=O SJRXVLUZMMDCNG-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- SJRXVLUZMMDCNG-KKPQBLLMSA-N gossypin Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=C(O)C=C(O)C2=C1OC(C=1C=C(O)C(O)=CC=1)=C(O)C2=O SJRXVLUZMMDCNG-KKPQBLLMSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229920000768 polyamine Polymers 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229940126680 traditional chinese medicines Drugs 0.000 description 2
- 210000005239 tubule Anatomy 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- FHDQNOXQSTVAIC-UHFFFAOYSA-M 1-butyl-3-methylimidazol-3-ium;chloride Chemical compound [Cl-].CCCCN1C=C[N+](C)=C1 FHDQNOXQSTVAIC-UHFFFAOYSA-M 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
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- 239000012153 distilled water Substances 0.000 description 1
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- 238000002481 ethanol extraction Methods 0.000 description 1
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- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
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- 239000002351 wastewater Substances 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
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Abstract
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Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201410082632.7A CN103835022B (zh) | 2014-03-07 | 2014-03-07 | 一种纤维素共混纤维及其制备方法 |
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CN201410082632.7A CN103835022B (zh) | 2014-03-07 | 2014-03-07 | 一种纤维素共混纤维及其制备方法 |
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CN103835022A true CN103835022A (zh) | 2014-06-04 |
CN103835022B CN103835022B (zh) | 2014-10-29 |
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CN201410082632.7A Active CN103835022B (zh) | 2014-03-07 | 2014-03-07 | 一种纤维素共混纤维及其制备方法 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104389099A (zh) * | 2014-11-18 | 2015-03-04 | 太仓市宏亿化纤有限公司 | 一种抗紫外线防静电纺织面料及其制备方法 |
CN112609262A (zh) * | 2020-11-25 | 2021-04-06 | 龙帛生物科技有限公司 | 一种环保型可降解纤维及其制备工艺 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2059585A1 (en) * | 1991-01-21 | 1992-07-22 | Yuichi Fukui | Water-repellent hygroscopic fiber |
CN1390991A (zh) * | 2002-07-23 | 2003-01-15 | 湘潭陈氏精密化学有限公司 | 变性粘胶纤维及其制造方法 |
CN1544729A (zh) * | 2003-11-17 | 2004-11-10 | 阎子鹏 | 植物蛋白-腈纶-聚乙烯醇复合纤维及其制造方法 |
CN1944723A (zh) * | 2006-11-01 | 2007-04-11 | 天津工业大学 | 一种改性粘胶纤维及其制造方法 |
CN101074287A (zh) * | 2007-06-27 | 2007-11-21 | 东华大学 | 一种纤维素/聚丙烯腈均相混合溶液的制备方法 |
CN101568674A (zh) * | 2006-12-26 | 2009-10-28 | 可隆株式会社 | 纤维素-聚乙烯醇复合纤维及其制备方法 |
-
2014
- 2014-03-07 CN CN201410082632.7A patent/CN103835022B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2059585A1 (en) * | 1991-01-21 | 1992-07-22 | Yuichi Fukui | Water-repellent hygroscopic fiber |
CN1390991A (zh) * | 2002-07-23 | 2003-01-15 | 湘潭陈氏精密化学有限公司 | 变性粘胶纤维及其制造方法 |
CN1544729A (zh) * | 2003-11-17 | 2004-11-10 | 阎子鹏 | 植物蛋白-腈纶-聚乙烯醇复合纤维及其制造方法 |
CN1944723A (zh) * | 2006-11-01 | 2007-04-11 | 天津工业大学 | 一种改性粘胶纤维及其制造方法 |
CN101568674A (zh) * | 2006-12-26 | 2009-10-28 | 可隆株式会社 | 纤维素-聚乙烯醇复合纤维及其制备方法 |
CN101074287A (zh) * | 2007-06-27 | 2007-11-21 | 东华大学 | 一种纤维素/聚丙烯腈均相混合溶液的制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104389099A (zh) * | 2014-11-18 | 2015-03-04 | 太仓市宏亿化纤有限公司 | 一种抗紫外线防静电纺织面料及其制备方法 |
CN112609262A (zh) * | 2020-11-25 | 2021-04-06 | 龙帛生物科技有限公司 | 一种环保型可降解纤维及其制备工艺 |
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CN103835022B (zh) | 2014-10-29 |
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