CN103818091A - Method for preparing polymer decoration film through blending imitated silver foil - Google Patents
Method for preparing polymer decoration film through blending imitated silver foil Download PDFInfo
- Publication number
- CN103818091A CN103818091A CN201310491744.3A CN201310491744A CN103818091A CN 103818091 A CN103818091 A CN 103818091A CN 201310491744 A CN201310491744 A CN 201310491744A CN 103818091 A CN103818091 A CN 103818091A
- Authority
- CN
- China
- Prior art keywords
- printing
- base material
- film
- revs
- facial mask
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
The invention relates to a method for preparing an anti-pollution antibacterial polymer furniture decoration film. The decoration film is formed by closely compounding a base material and a printing surface film, the printing surface film is formed by sequentially and closely compounding a printing film, a silvery-white basic-color layer and a pure-silvery surface film, and the pure-silvery surface film is directly laminated with the base material on the inner layer of the decoration film. The preparation method comprises the following process steps: step1, rolling the base material; step 2, preparing the printing film; step 3, printing the surface film; step 4, performing hot-pressing lamination. Thus, the product prepared by the method for preparing the anti-pollution antibacterial polymer furniture decoration film has the advantages that the decoration film can replace silver foil and silver skin, the fastness and the appearance effect are superior to those of the silver foil and the silver skin, and the cost is lower than that of the silver foil and that of the silver skin.
Description
Technical field
The preparation method who the present invention relates to the synthetic high-molecular decorative film of a kind of imitative silver foil blend, belongs to ornament materials preparation field.
Background technology
Before the present invention makes, needed the high-grade place of decorating all to solve with pure silver foil or parchment covering veneer in the past.It mainly has the following disadvantages:
1, make because silver foil, parchment covering need consume very expensive rare metal silver, itself valency is high, add foliation skin processing charges processed very high, and cost is very large.
2, carry out decorative appearance complex process with silver foil, parchment covering, difficulty is large.
3, silver foil, parchment covering are for a long time in air, and surface is dust stratification dirt easily, not easy to clean, affects outward appearance vividness, easily damaged.
4,, because silver foil, parchment covering belong to valuables, be vulnerable to lawless person's infringement.
5, because silver foil, parchment covering are thin and not firm, the scope of application is restricted, and is difficult for using on a large scale.
Summary of the invention
The object of the invention is to overcome above-mentioned deficiency, provide a kind of energy to substitute silver foil, parchment covering, and fastness and appearance all can be better than silver foil parchment covering, cost is lower than the preparation method of the synthetic high-molecular decorative film of imitative silver foil blend of silver foil parchment covering.
The object of the present invention is achieved like this:
A kind of preparation method of antifouling and antibiosis macromolecule furniture decoration film, this decorating film is closely composited with printing facial mask is two-layer altogether by base material, described printing facial mask again by print film, the basic chromatograph of silvery white and fine silver look facial mask totally three layers be closely composited successively, and described fine silver look facial mask is directly fitted at internal layer and the base material of described decorating film, and its preparation method comprises following processing step:
Step 1, rolled base material
(1) batching
Adopting PVC resin is major ingredient, adds PE reinforcing agent, 1000 order titanium dioxides, dibutyl ester, background color slurry and other auxiliary agents, and the weight portion proportioning that feeds intake of each component is as follows:
100 parts of polyvinyl chloride resins
11 parts of PE reinforcing agents
1000 20 ~ 25 parts of order titanium dioxides
25 ~ 30 parts of dibutyl esters
1 part, background color slurry
1 part of other auxiliary agent
(2) stir
The material weighing up by proportioning, first PVC resin is added, add again PE reinforcing agent and 1000 order titanium dioxides, stir 3 minutes, then add dibutyl ester, stir 7 minutes, add again background color slurry and other auxiliary agents, then stir 5 minutes, make compound, when stirring, heat to 105 ℃ ~ 115 ℃, 145 ~ 160 revs/min of mixing speeds;
(3) plasticizing
The compound being fully stirred is entered to banbury and be heated to 170 ℃ ~ 175 ℃, plastify under sealing state with the rotating speeds of 120 ~ 130 revs/min, this process is 20 minutes, and compound is tentatively plastified;
(4) refining is filtered
The compound of preliminary plasticizing is delivered into extruder, control temperature at 175 ℃ ~ 180 ℃, 85 ~ 95 revs/min of extruder screw rotating speeds, pushs and advance stirring refining, then push to die orifice through 180 order screen packs, contaminant filter to be fallen;
(5) calendering
The clinker conveyor of plasticizing completely after filtering is entered to five roll calendars, according to thickness, width and specification requirement, be rolled into the opaque base material of required specification, stack temperature is controlled at 180 ℃ ~ 185 ℃, 40 ~ 42 revs/min of rotating speeds;
(6) sided corona treatment
The base material being rolled into is delivered to corona treatment plant with deflector roll and carries out sided corona treatment, and sided corona treatment speed is 60 ms/min;
(7) cooling
Base material after sided corona treatment, then it is for subsequent use to be delivered to the heat insulation cooling cylinder roller of five rollers rolling after cooling through deflector roll, cooling cylinder roll temperature is 10 ~ 30 ℃;
Step 2, preparation print film
(1) batching
Adopting PVC resin is major ingredient, adds PE reinforcing agent, dibutyl ester, fire-retardant N H1197 and other auxiliary agents, and the weight portion proportioning that feeds intake of each component is as follows:
100 parts of polyvinyl chloride resins
12 parts of PE reinforcing agents
23 ~ 28 parts of dibutyl esters
1 part of fire-retardant N H1197
1 part of other auxiliary agent;
(2) stir
Weigh up material by proportioning, first polyvinyl chloride resin is added to mixer, add again PE reinforcing agent to stir 3 minutes, add again dibutyl ester to stir 7 minutes, add again fire-retardant N H1197 and other auxiliary agents to stir again 5 minutes, make compound, heat during this time to 105 ℃ ~ 115 ℃, 145 ~ 160 revs/min of mixing speeds;
(3) plasticizing
Add banbury to be heated to 170 ℃ ~ 175 ℃ the compound being stirred, in turning round under sealing state with the speed of 125 ~ 130 revs/min, plasticizing, tentatively plastified compound through 20 minutes;
(4) refining is filtered
The compound of preliminary plasticizing is delivered into extruder, control temperature at 175 ℃ ~ 180 ℃, 85 ~ 95 revs/min of extruder screw rotating speeds, pushs and advance stirring refining, then push to die orifice through 220 order screen packs, contaminant filter to be fallen;
(5) calendering
The clinker conveyor of plasticizing completely after filtering is entered to five roll calendars, be rolled into print film according to print film specification requirement, stack temperature is controlled at 180 ℃ ~ 185 ℃, 38 ~ 40 revs/min of rotating speeds
(6) cooling
By for subsequent use the print film being rolled into rolling after the heat insulation cooling cylinder cooling and shaping of five rollers, 95 ~ 105 ms/min of cooling cylinder cooling velocities, cooling cylinder roll temperature is 10 ~ 20 ℃;
Step 3, printing facial mask
(1) first printing
Configure ink pigment according to fine silver color and luster, in the print film of preparation, carry out first printing silvery white Essential colour;
(2) dry for the first time
Print film after printed silver white Essential colour is by electric heating warming to 130 ℃ ~ 135 ℃;
(3) second printing
Silver powder and ink are mixed well and carried out the second printing on print film the same face, make to print face and become silver foil or the same fine silver look facial mask of parchment covering;
(4) dry for the second time
Dry and dry equally for the second time for the first time, make printing facial mask;
(5) rolling
The printing facial mask rolling of drying through secondary printing is for subsequent use;
Step 4, hot pressing laminating
(1) smooth drying
Make-up machine on the base material having rolled and the printing facial mask frame that prints is heated to 100 ℃ ~ 105 ℃;
(2) opposite side
(3) degasification
(4) laminating
Base material after degasification and print film are heated to 160 ~ 170 ℃ through laminating minute surface two-wheel roller, pressurize 0.25 kilogram, and base material and print film by two layers in the initial plasticizing phase fit together;
(5) cooling and shaping
Print film firm laminating and the upper cooling cylinder roller of base material traction are got off through cooling and shaping, be then wound into imitative silver foil high-molecular decorative film finished product;
The PE reinforcing agent wherein using in the batching of step 1 and step 2 is made up of following mode:
(1), batching
Adopting PE powder is major ingredient, adds dioctyl phthalate dibutyl ester, phthalic acid, dibutyl ester, SA dioctyl ester, epoxidized soybean oil, tributyl 2-acetylcitrate, cyclohexane 1, the different base ester of dioctyl phthalate two, zirconate to advocate connection agent, carbon white powder by proportioning;
The weight proportion of its each component is:
PE powder 70-80 part
Dioctyl phthalate dioctyl ester 2-4 part
Phthalic acid 2-4 part
SA dioctyl ester 0.5-1 part
Epoxidized soybean oil 1.5-2.5 part
Tributyl 2-acetylcitrate 1-2 part
Cyclohexane 1 0.5-1 part
The different base ester of dioctyl phthalate two 1-1.5 part
Zirconate is advocated connection agent 1.5-2 part
Paris white 10-12 part
(2), first powder is weighed up and drops into vibratory sieve and screen out " flake " and impurity by said ratio, all feed diameters exceed material grain and " flake " of 3.2 microns and all screen out;
(3), by the powder input homogenizer after screening out, add liquid material by proportioning;
(4), start homogenizer stirring wheel motor, start mixer heating source push button simultaneously, its medium speed is 180 revs/min, temperature is 135 ~ 145 ℃;
(5), the blowing that shuts down after 8 ~ 10min high-speed stirred.
Compared with prior art, the invention has the beneficial effects as follows:
Tool of the present invention has the following advantages and effect:
(1) make polymeric membrane there is anti-flaming function.
All add fire-retardant N H1197 at base material and printing in facial mask, reached inside and outside fire-retardant effect.
(2) there is silver foil parchment covering effect.
Owing to adopting silver powder as outermost layer printing in printing, make that color and luster and silver foil, parchment covering are the same reaches equal effect.
(3) make the further modified optimization of polymeric membrane physicochemical property.
In the time preparing base material and printing facial mask, add PE reinforcing agent to carry out blend copolymerization plasticizing synthetic, modification has become the higher decorating film of more optimizing of physical and chemical index.
(4) cost is low
The present invention adopts secondary printing, and the utilization rate of silver powder has reached the best, has saved production cost.And macromolecular material itself is different from valuable silver foil, parchment covering.
(5) be convenient to decoration construction
Because imitative silver foil high-molecular decorative film plasticity is large, be suitable for various occasions, the laminating of environmentally conscious materials aspect is decorated, and unlike silver foil, parchment covering, non-processing and frangible difficult laminating are decorated.
(6) be convenient to clean
Due to printing surface inside, outside is transparent face, laminating decorate after product, easy cleaning after object laying dust, does not affect inherent quality and color and luster.
(7) degree of safety is high
Owing to being imitative silver foil, parchment covering rather than true silver foil parchment covering, after knowing, lawless person can not steal, scrape the malfeasances such as stripping.
(8) purposes is wide, effective.
This product is formed by macromolecular material laminating completely, meets environmental requirement and market demand trend completely, and alternative silver foil, parchment covering carry out high-class terminals product appearance decoration.
Therefore the preparation method of this antifouling and antibiosis macromolecule furniture decoration film prepares product has can substitute silver foil, parchment covering, and fastness and appearance all can be better than silver foil parchment covering, and cost is lower than the advantage of silver foil parchment covering.
The specific embodiment
The preparation method of a kind of antifouling and antibiosis macromolecule furniture decoration film the present invention relates to, this decorating film is closely composited with printing facial mask is two-layer altogether by base material.Described printing facial mask again by print film, the basic chromatograph of silvery white and fine silver look facial mask totally three layers be closely composited successively, and described fine silver look facial mask is directly fitted at internal layer and the base material of described decorating film.Its preparation method comprises following processing step:
Step 1, rolled base material
(1) batching
Adopting PVC resin is major ingredient, adds PE reinforcing agent, 1000 order titanium dioxides, dibutyl ester, background color slurry and other auxiliary agents, and the weight portion proportioning that feeds intake of each component is as follows:
100 parts of polyvinyl chloride resins
11 parts of PE reinforcing agents
1000 20 ~ 25 parts of order titanium dioxides
25 ~ 30 parts of dibutyl esters
1 part, background color slurry
1 part of other auxiliary agent
(2) stir
The material weighing up by proportioning, first PVC resin is added, add again PE reinforcing agent and 1000 order titanium dioxides, stir 3 minutes, then add dibutyl ester, stir 7 minutes, add again background color slurry and other auxiliary agents, then stir 5 minutes, make compound, when stirring, heat to 105 ℃ ~ 115 ℃, 145 ~ 160 revs/min of mixing speeds.
(3) plasticizing
The compound being fully stirred is entered to banbury and be heated to 170 ℃ ~ 175 ℃, plastify under sealing state with the rotating speeds of 120 ~ 130 revs/min, this process is 20 minutes, and compound is tentatively plastified.
(4) refining is filtered
The compound of preliminary plasticizing is delivered into extruder, control temperature at 175 ℃ ~ 180 ℃, 85 ~ 95 revs/min of extruder screw rotating speeds, pushs and advance stirring refining, then push to die orifice through 180 order screen packs, contaminant filter to be fallen.
(5) calendering
The clinker conveyor of plasticizing completely after filtering is entered to five roll calendars, according to thickness, width and specification requirement, be rolled into the opaque base material of required specification, stack temperature is controlled at 180 ℃ ~ 185 ℃, 40 ~ 42 revs/min of rotating speeds.
(6) sided corona treatment
The base material being rolled into is delivered to corona treatment plant with deflector roll and carries out sided corona treatment, and to increase laminating fastness, sided corona treatment speed is 60 ms/min.
(7) cooling
Base material after sided corona treatment, then it is for subsequent use to be delivered to the heat insulation cooling cylinder roller of five rollers rolling after cooling through deflector roll, cooling cylinder roll temperature is 10 ~ 30 ℃.
Step 2, preparation print film
(1) batching
Adopting PVC resin is major ingredient, adds PE reinforcing agent, dibutyl ester, fire-retardant N H1197 and other auxiliary agents, and the weight portion proportioning that feeds intake of each component is as follows:
100 parts of polyvinyl chloride resins
12 parts of PE reinforcing agents
23 ~ 28 parts of dibutyl esters
1 part of fire-retardant N H1197
1 part of other auxiliary agent.
(2) stir
Weigh up material by proportioning, first polyvinyl chloride resin is added to mixer, add again PE reinforcing agent to stir 3 minutes, add again dibutyl ester to stir 7 minutes, add again fire-retardant N H1197 and other auxiliary agents to stir again 5 minutes, make compound, heat during this time to 105 ℃ ~ 115 ℃, 145 ~ 160 revs/min of mixing speeds.
(3) plasticizing
Add banbury to be heated to 170 ℃ ~ 175 ℃ the compound being stirred, in turning round under sealing state with the speed of 125 ~ 130 revs/min, plasticizing, tentatively plastified compound through 20 minutes.
(4) refining is filtered
The compound of preliminary plasticizing is delivered into extruder, control temperature at 175 ℃ ~ 180 ℃, 85 ~ 95 revs/min of extruder screw rotating speeds, pushs and advance stirring refining, then push to die orifice through 220 order screen packs, contaminant filter to be fallen.
(5) calendering
The clinker conveyor of plasticizing completely after filtering is entered to five roll calendars, be rolled into print film according to print film specification requirement, stack temperature is controlled at 180 ℃ ~ 185 ℃, 38 ~ 40 revs/min of rotating speeds
(6) cooling
By for subsequent use the print film being rolled into rolling after the heat insulation cooling cylinder cooling and shaping of five rollers, 95 ~ 105 ms/min of cooling cylinder cooling velocities, cooling cylinder roll temperature is 10 ~ 20 ℃.
Step 3, printing facial mask
(1) first printing
Configure ink pigment according to fine silver color and luster, in the print film of preparation, carry out first printing silvery white Essential colour.
(2) dry for the first time
Print film after printed silver white Essential colour, by electric heating warming to 130 ℃ ~ 135 ℃, is fallen solvent evaporates in ink, make printing colouring after pigment solidify, reach color fastness.
(3) second printing
Adopt secondary printing technique in order to save silver powder, silver powder is mixed well and carried out the second printing on print film the same face with a small amount of ink, make to print face and become silver foil or the same fine silver look facial mask of parchment covering.
(4) dry for the second time
Dry and dry equally for the second time for the first time, make printing facial mask.
(5) rolling
The printing facial mask rolling of drying through secondary printing is for subsequent use.
Step 4, hot pressing laminating
(1) smooth drying
Make-up machine on the base material having rolled and the printing facial mask frame that prints is heated to 100 ℃ ~ 105 ℃, adopt tension force roller and twill roller that base material and printing facial mask longitudinally, are laterally drawn floating whole, and the water evaporation of base material and printing facial mask is fallen, with gassing after preventing and bright spot.
(2) opposite side
Utilize light eye opposite side device adjust base material and printing facial mask longitudinally move towards, make to print facial mask and base material upper and lower two layers to edging, prevent dislocation join.
(3) degasification
Fold through degasification two-wheel, base material and printing, the air between facial mask first pushes away, produces bubble when preventing from fitting.
(4) laminating
Base material after degasification and print film are heated to 160 ~ 170 ℃ through laminating minute surface two-wheel roller, pressurize 0.25 kilogram, base material by two layers in the initial plasticizing phase and print film fit together the printing surface of print film wherein in internal layer and the base material jail of directly fitting, and make fine silver look facial mask at internal layer.
(5) cooling and shaping
Print film firm laminating and the upper cooling cylinder roller of base material traction are got off through cooling and shaping, be then wound into imitative silver foil high-molecular decorative film finished product.
Described hot pressing laminating (1) ~ (5) operation speed is 60 ~ 65 ms/min.
The PE reinforcing agent wherein using in the batching of step 1 and step 2 is made up of following mode:
(1), batching
Adopting PE powder is major ingredient, adds dioctyl phthalate dibutyl ester, phthalic acid, dibutyl ester, SA dioctyl ester, epoxidized soybean oil, tributyl 2-acetylcitrate, cyclohexane 1, the different base ester of dioctyl phthalate two, zirconate to advocate connection agent, carbon white powder by proportioning.
The weight proportion of its each component is:
PE powder 70-80 part
Dioctyl phthalate dioctyl ester 2-4 part
Phthalic acid 2-4 part
SA dioctyl ester 0.5-1 part
Epoxidized soybean oil 1.5-2.5 part
Tributyl 2-acetylcitrate 1-2 part
Cyclohexane 1 0.5-1 part
The different base ester of dioctyl phthalate two 1-1.5 part
Zirconate is advocated connection agent 1.5-2 part
Paris white 10-12 part
(2), first powder is weighed up and drops into vibratory sieve and screen out " flake " and impurity by said ratio, all feed diameters exceed material grain and " flake " of 3.2 microns and all screen out.
(3), by the powder input homogenizer after screening out, add liquid material by proportioning.
(4), start homogenizer stirring wheel motor, start mixer heating source push button simultaneously, its medium speed is 180 revs/min, temperature is 135 ~ 145 ℃.
(5), after 8 ~ 10min high-speed stirred, shut down that to be delivered to a rolled base material magazine that feeds intake for subsequent use for blowing.
(6), PE reinforcing agent general with rolled base material continuous productive process, can not too much overstock to cause and lump and affect that rolled base material feeds intake and the uniformity.
Claims (1)
1. the preparation method of an antifouling and antibiosis macromolecule furniture decoration film, it is characterized in that this decorating film is closely composited with printing facial mask is two-layer altogether by base material, described printing facial mask again by print film, the basic chromatograph of silvery white and fine silver look facial mask totally three layers be closely composited successively, and described fine silver look facial mask is directly fitted at internal layer and the base material of described decorating film, and its preparation method comprises following processing step:
Step 1, rolled base material
(1) batching
Adopting PVC resin is major ingredient, adds PE reinforcing agent, 1000 order titanium dioxides, dibutyl ester, background color slurry and other auxiliary agents, and the weight portion proportioning that feeds intake of each component is as follows:
100 parts of polyvinyl chloride resins
11 parts of PE reinforcing agents
1000 20 ~ 25 parts of order titanium dioxides
25 ~ 30 parts of dibutyl esters
1 part, background color slurry
1 part of other auxiliary agent
(2) stir
The material weighing up by proportioning, first PVC resin is added, add again PE reinforcing agent and 1000 order titanium dioxides, stir 3 minutes, then add dibutyl ester, stir 7 minutes, add again background color slurry and other auxiliary agents, then stir 5 minutes, make compound, when stirring, heat to 105 ℃ ~ 115 ℃, 145 ~ 160 revs/min of mixing speeds;
(3) plasticizing
The compound being fully stirred is entered to banbury and be heated to 170 ℃ ~ 175 ℃, plastify under sealing state with the rotating speeds of 120 ~ 130 revs/min, this process is 20 minutes, and compound is tentatively plastified;
(4) refining is filtered
The compound of preliminary plasticizing is delivered into extruder, control temperature at 175 ℃ ~ 180 ℃, 85 ~ 95 revs/min of extruder screw rotating speeds, pushs and advance stirring refining, then push to die orifice through 180 order screen packs, contaminant filter to be fallen;
(5) calendering
The clinker conveyor of plasticizing completely after filtering is entered to five roll calendars, according to thickness, width and specification requirement, be rolled into the opaque base material of required specification, stack temperature is controlled at 180 ℃ ~ 185 ℃, 40 ~ 42 revs/min of rotating speeds;
(6) sided corona treatment
The base material being rolled into is delivered to corona treatment plant with deflector roll and carries out sided corona treatment, and sided corona treatment speed is 60 ms/min;
(7) cooling
Base material after sided corona treatment, then it is for subsequent use to be delivered to the heat insulation cooling cylinder roller of five rollers rolling after cooling through deflector roll, cooling cylinder roll temperature is 10 ~ 30 ℃;
Step 2, preparation print film
(1) batching
Adopting PVC resin is major ingredient, adds PE reinforcing agent, dibutyl ester, fire-retardant N H1197 and other auxiliary agents, and the weight portion proportioning that feeds intake of each component is as follows:
100 parts of polyvinyl chloride resins
12 parts of PE reinforcing agents
23 ~ 28 parts of dibutyl esters
1 part of fire-retardant N H1197
1 part of other auxiliary agent;
(2) stir
Weigh up material by proportioning, first polyvinyl chloride resin is added to mixer, add again PE reinforcing agent to stir 3 minutes, add again dibutyl ester to stir 7 minutes, add again fire-retardant N H1197 and other auxiliary agents to stir again 5 minutes, make compound, heat during this time to 105 ℃ ~ 115 ℃, 145 ~ 160 revs/min of mixing speeds;
(3) plasticizing
Add banbury to be heated to 170 ℃ ~ 175 ℃ the compound being stirred, in turning round under sealing state with the speed of 125 ~ 130 revs/min, plasticizing, tentatively plastified compound through 20 minutes;
(4) refining is filtered
The compound of preliminary plasticizing is delivered into extruder, control temperature at 175 ℃ ~ 180 ℃, 85 ~ 95 revs/min of extruder screw rotating speeds, pushs and advance stirring refining, then push to die orifice through 220 order screen packs, contaminant filter to be fallen;
(5) calendering
The clinker conveyor of plasticizing completely after filtering is entered to five roll calendars, be rolled into print film according to print film specification requirement, stack temperature is controlled at 180 ℃ ~ 185 ℃, 38 ~ 40 revs/min of rotating speeds
(6) cooling
By for subsequent use the print film being rolled into rolling after the heat insulation cooling cylinder cooling and shaping of five rollers, 95 ~ 105 ms/min of cooling cylinder cooling velocities, cooling cylinder roll temperature is 10 ~ 20 ℃;
Step 3, printing facial mask
(1) first printing
Configure ink pigment according to fine silver color and luster, in the print film of preparation, carry out first printing silvery white Essential colour;
(2) dry for the first time
Print film after printed silver white Essential colour is by electric heating warming to 130 ℃ ~ 135 ℃;
(3) second printing
Silver powder and ink are mixed well and carried out the second printing on print film the same face, make to print face and become silver foil or the same fine silver look facial mask of parchment covering;
(4) dry for the second time
Dry and dry equally for the second time for the first time, make printing facial mask;
(5) rolling
The printing facial mask rolling of drying through secondary printing is for subsequent use;
Step 4, hot pressing laminating
(1) smooth drying
Make-up machine on the base material having rolled and the printing facial mask frame that prints is heated to 100 ℃ ~ 105 ℃;
(2) opposite side
(3) degasification
(4) laminating
Base material after degasification and print film are heated to 160 ~ 170 ℃ through laminating minute surface two-wheel roller, pressurize 0.25 kilogram, and base material and print film by two layers in the initial plasticizing phase fit together;
(5) cooling and shaping
Print film firm laminating and the upper cooling cylinder roller of base material traction are got off through cooling and shaping, be then wound into imitative silver foil high-molecular decorative film finished product;
The PE reinforcing agent wherein using in the batching of step 1 and step 2 is made up of following mode:
(1), batching
Adopting PE powder is major ingredient, adds dioctyl phthalate dibutyl ester, phthalic acid, dibutyl ester, SA dioctyl ester, epoxidized soybean oil, tributyl 2-acetylcitrate, cyclohexane 1, the different base ester of dioctyl phthalate two, zirconate to advocate connection agent, carbon white powder by proportioning;
The weight proportion of its each component is:
PE powder 70-80 part
Dioctyl phthalate dioctyl ester 2-4 part
Phthalic acid 2-4 part
SA dioctyl ester 0.5-1 part
Epoxidized soybean oil 1.5-2.5 part
Tributyl 2-acetylcitrate 1-2 part
Cyclohexane 1 0.5-1 part
The different base ester of dioctyl phthalate two 1-1.5 part
Zirconate is advocated connection agent 1.5-2 part
Paris white 10-12 part
(2), first powder is weighed up and drops into vibratory sieve and screen out " flake " and impurity by said ratio, all feed diameters exceed material grain and " flake " of 3.2 microns and all screen out;
(3), by the powder input homogenizer after screening out, add liquid material by proportioning;
(4), start homogenizer stirring wheel motor, start mixer heating source push button simultaneously, its medium speed is 180 revs/min, temperature is 135 ~ 145 ℃;
(5), the blowing that shuts down after 8 ~ 10min high-speed stirred.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310491744.3A CN103818091B (en) | 2013-10-21 | 2013-10-21 | The preparation method of the imitative blended synthesis high-molecular decorative film of silver foil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310491744.3A CN103818091B (en) | 2013-10-21 | 2013-10-21 | The preparation method of the imitative blended synthesis high-molecular decorative film of silver foil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103818091A true CN103818091A (en) | 2014-05-28 |
| CN103818091B CN103818091B (en) | 2016-04-27 |
Family
ID=50753507
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310491744.3A Active CN103818091B (en) | 2013-10-21 | 2013-10-21 | The preparation method of the imitative blended synthesis high-molecular decorative film of silver foil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103818091B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752793A (en) * | 2018-06-14 | 2018-11-06 | 江苏海美新材料有限公司 | A kind of preparation method of antifouling anti-scribble high-molecular decorative film |
| CN111923545A (en) * | 2020-07-23 | 2020-11-13 | 安徽嘉阳新材料科技有限公司 | PVC furniture film and processing technology thereof |
| CN114986954A (en) * | 2022-06-23 | 2022-09-02 | 全椒光太胶粘制品有限公司 | Production process for repairing furniture film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101850689A (en) * | 2010-03-08 | 2010-10-06 | 徐文亚 | Method for preparing clinquant high molecular decorative film |
| CN102191840A (en) * | 2011-03-25 | 2011-09-21 | 赵小东 | Method for preparing silver foil-like high polymer decorating film |
| CN102189883A (en) * | 2010-03-05 | 2011-09-21 | 徐文亚 | Preparation method of clinquant decorative film |
-
2013
- 2013-10-21 CN CN201310491744.3A patent/CN103818091B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102189883A (en) * | 2010-03-05 | 2011-09-21 | 徐文亚 | Preparation method of clinquant decorative film |
| CN101850689A (en) * | 2010-03-08 | 2010-10-06 | 徐文亚 | Method for preparing clinquant high molecular decorative film |
| CN102191840A (en) * | 2011-03-25 | 2011-09-21 | 赵小东 | Method for preparing silver foil-like high polymer decorating film |
Non-Patent Citations (4)
| Title |
|---|
| 师昌绪主编: "《材料科学与工程手册下卷 第8篇 高分子材料篇》", 31 January 2004, 化学工业出版社 * |
| 张子成编著: "《塑料产品设计》", 31 January 2012, 国防工业出版社 * |
| 李祥高编著: "《精细化学品化学》", 30 April 2013, 华东理工大学出版社 * |
| 潘旺林编著: "《注塑工入门》", 31 January 2008, 安徽科学技术出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108752793A (en) * | 2018-06-14 | 2018-11-06 | 江苏海美新材料有限公司 | A kind of preparation method of antifouling anti-scribble high-molecular decorative film |
| CN111923545A (en) * | 2020-07-23 | 2020-11-13 | 安徽嘉阳新材料科技有限公司 | PVC furniture film and processing technology thereof |
| CN111923545B (en) * | 2020-07-23 | 2023-09-15 | 安徽嘉阳新材料科技有限公司 | PVC furniture film and processing technology thereof |
| CN114986954A (en) * | 2022-06-23 | 2022-09-02 | 全椒光太胶粘制品有限公司 | Production process for repairing furniture film |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103818091B (en) | 2016-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101850689B (en) | Method for preparing clinquant high molecular decorative film | |
| CN102134820B (en) | Wall cloth and preparation method thereof | |
| CN101531081B (en) | Method for preparing carved wood grain-simulated PVC decorative film | |
| CN103738035B (en) | Antifouling antibacterial high-molecular furniture decorative film and preparation method thereof | |
| CN102719033A (en) | Ceiling decorative soft film material and production process thereof | |
| CN109594745B (en) | Anti-slip colorful PVC waterproof coiled material floor | |
| CN107877892A (en) | The preparation method of imitative engraving UV scratch resistance graining films | |
| CN103818091B (en) | The preparation method of the imitative blended synthesis high-molecular decorative film of silver foil | |
| CN105778341A (en) | Wall-like brick high-molecular hard wall decorative material and preparation method thereof | |
| CN106995571A (en) | A kind of water-based ink printing PVC film and preparation method thereof | |
| CN110219434B (en) | High-wear-resistance TPU stone plastic floor and preparation method thereof | |
| CN102191840A (en) | Method for preparing silver foil-like high polymer decorating film | |
| CN205637405U (en) | Imitative wall brick polymer stereoplasm wall body ornamental material | |
| CN101850624B (en) | Method for preparing aluminium plastic sheet-imitation high molecular hard coiled material | |
| CN103818021B (en) | High emulational leather high-molecular decorative film and preparation method thereof | |
| CN105924822A (en) | Camouflage knitted interlayer wader material and preparation method thereof | |
| CN201665122U (en) | Gold foil imitation high molecular decorative film | |
| CN102189883A (en) | Preparation method of clinquant decorative film | |
| CN201665121U (en) | Gold foil imitation decorative film | |
| CN101850642B (en) | Method for preparing ball leather-emulated high-molecular decorative film | |
| CN113059877B (en) | Novel wood-like decorative leather for automobile interior and preparation method thereof | |
| CN108582935B (en) | PETG decorative material and preparation method thereof | |
| CN102691394A (en) | Preparation method for printing face membrane of silver foil-imitated macromolecular decoration membrane | |
| CN102189887A (en) | Clinquant high-molecular decorative film | |
| CN204186020U (en) | A kind of stone paper substrate anion wall wallpaper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20181219 Address after: 214421 No. 58 Haida Road, Huashizhen, Jiangyin City, Wuxi City, Jiangsu Province Patentee after: Jiangsu Econess Energy Co.,Ltd. Address before: 214421 Huashi Town Industrial Park, Jiangyin City, Wuxi City, Jiangsu Province Patentee before: Jiangyin Huadong Decorative Material Co., Ltd. |