CN103814901A - Composition of prohexadione calcium and fungicide - Google Patents
Composition of prohexadione calcium and fungicide Download PDFInfo
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- CN103814901A CN103814901A CN201410030965.5A CN201410030965A CN103814901A CN 103814901 A CN103814901 A CN 103814901A CN 201410030965 A CN201410030965 A CN 201410030965A CN 103814901 A CN103814901 A CN 103814901A
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Abstract
The invention discloses a composition of prohexadione calcium and a fungicide. The composition includes 5 to 50 parts by weight of the prohexadione calcium and 5 to 60 parts by weight of the fungicide; the bactericide is a triazole fungicide such as epoxiconazole, tebuconazole, hexaconazole and difenoconazole, or a carboxylic acid amide fungicide such as thifluzamide and fenoxanil, or a benzimidazole fungicide such as carbendazim and thiophanate-methyl, or an imidazole fungicide such as prochloraz and prochloraz-manganese chloride complex. The composition of the prohexadione calcium and the fungicide provided by the invention can achieve the purposes of vigorous growth control, disease resistance and yield increase, has no effect on next-stubble crops, reduces the pesticide costs of farmers, and increases the crop yield, so as to increase the income of farmers, and create enormous economic and social values.
Description
Technical field
The invention belongs to preparation technique of pesticide field, be specifically related to a kind of Prohexadione calcium and microbicide compositions.
Background technology
Prohexadione calcium is a kind of novel plant growth regulator, is the one of plant growth retardent.It,, by disturbing the biosynthetic final step of GA to work, blocks GA
12aldehyde is to GA
8synthetic, GA activation process is obstructed, and can makes the cell classification element level of ABA, zeatin and isopentenyladenosine type increase.Play and suppress to nourish and grow, promote the effect of reproductive growth, reach the object of increasing production and improving quality.Prohexadione calcium passes through leaf surface treatment, can shorten the cane length of many plants, compared with the triazole type delayer of current extensive use, Prohexadione calcium is to crop rotation plant non-residual toxicity, environmentally safe, can also promote plant nutrition to shift simultaneously, control prosperous length, promote lateral bud growth and root of hair, make cauline leaf keep dark green, improve ripening rate, promote fruit maturation.It also has the disease resistance of enhancing plant, cold-resistant ability, can improve the resistance of crop.Thereby be with a wide range of applications.
As everyone knows; plant growth retardent is to suppress the compound that GA biosynthesis causes plant growth to delay; according to the difference of active position and mode; can be divided three classes: compounds (as chlormequat, first piperazine), nitrogen-containing heterocycle compound (as the paclobutrazol of triazole type, triazolone) and acyl group cyclohexanedione (also claiming cyclohexanetriones); Prohexadione calcium belongs to the one of acyl group cyclohexanedione, is the growth retardant that a class is new.At present Prohexadione calcium is mainly used in the crops such as paddy rice, peanut, Chinese sorghum, has the features such as the prosperous obvious effect of increasing production of control, usage amount are little, low toxicity noresidue.And conventional delayer is as the application of the conditioning agents such as paclobutrazol, uniconazole P, chlormequat, alar-85, ethrel, have that drug effect is more and more not obvious, dosage is increasing always, high residue, the various problems such as expensive, therefore research safety, new varieties and application efficiently, be the active demand that current rice cropping is produced.
Paddy rice is Chinese first cereal crops, lodging is a key factor that affects rice yield, lodging can cause photosynthesis and kernel grouting to stop, greatly affect rice quality, make troubles to harvesting threshing simultaneously, occur shattering, fringe bud phenomenon, increase paddy percent of loss, thereby cause production declining, affect rice quality.The disease of paddy rice mainly contains banded sclerotial blight, false smut, rice blast.The generation of various diseases gently affects grain filling, heavy cause the withered lodging of plant, can not ear, the quality of General Influence rice and the output of paddy rice.Therefore provide one both can control rice lodging, can prevent and treat again the generation of disease, Prohexadione calcium and the microbicide compositions degeneration-resistant, disease resistance that improve paddy rice are very important.
Summary of the invention
For achieving the above object, the technical scheme that the present invention takes is, a kind of Prohexadione calcium and microbicide compositions, and the parts by weight of Prohexadione calcium are that the parts by weight of 5-50, bactericide are 5 ~ 60 parts.
Described bactericide is the triazole bactericidal agents such as epoxiconazole, Tebuconazole, own azoles alcohol, Difenoconazole, or the acid amide fungicides such as thifluzamide, zarilamid, or the benzimidazole germicide such as carbendazim, thiophanate-methyl, or the imidazoles bactericide such as Prochloraz, prochloraz-manganese chloride complex.
The prosperous sterilization composite pesticides of described control is wetting powder, is made up of the raw material of following portions by weight: 5 ~ 40 parts of Prohexadione calciums, 5 ~ 60 parts, bactericide, 0.5 ~ 3.0 part of wetting agent, 3.0 ~ 10 parts of dispersants, 50 ~ 150 parts, carrier.
The prosperous sterilization composite pesticides of described control is water dispersible granules, raw material by following portions by weight forms: Prohexadione calcium 5-50 part, 5 ~ 60 parts, bactericide, wetting agent 0.5-2.0 part, dispersant 3.0-10 part, disintegrant 3-8 part, 10 ~ 60 parts, binding agent 0.5-5 part, carrier.
Described disintegrant is any one or several in ammonium sulfate, urea, sucrose; Described binding agent is any one or several in dextrin, soluble starch, gum Arabic, polyvinylpyrrolidone, polyvinyl alcohol, sodium carboxymethylcellulose.
The prosperous sterilization composite pesticides of described control is suspending agent, raw material by following portions by weight forms: Prohexadione calcium 5-30 part, 5 ~ 60 parts, bactericide, wetting agent 0.1-2.0 part, dispersant 0.2-5.0 part, thickener 0.1-5.0 part, antifreezing agent 2.0-10 part, stabilizing agent 0.1-10 part, 20 ~ 100 parts, defoamer 0-3.0 part, water.
Described thickener is any one or several in sodium carboxymethylcellulose, xanthans, aluminium-magnesium silicate, sodium alginate, polyvinyl alcohol, polyacrylamide; Described antifreezing agent is any one or several in ethylene glycol, glycerine, polyethylene glycol, urea, sorbierite.
Described stabilizing agent is any one or several in bentonite, white carbon, precipitated calcium carbonate, formaldehyde; Described defoamer is any one or several in organosilicon, tributyl phosphate, polyether antifoam agent.
Described wetting agent is any one or several in neopelex, Nekal BX, wetting and penetrating agent JFC, lauryl sodium sulfate.
Described dispersant is that calcium lignosulfonate, dispersant NNO, dispersing agent C NF, Dispersant MF are any one or several.
Described carrier is any one or several of kaolin, bentonite, diatomite, white carbon, precipitated calcium carbonate, attapulgite.
Prohexadione calcium in the present invention and microbicide compositions adopt conventional agricultural chemicals using method, and the usage amount of wetting powder is every mu of 10 ~ 40g, and the usage amount of water dispersible granules is every mu of 10 ~ 40g, and the usage amount of suspending agent is every mu of 10 ~ 40g.
The beneficial effect that the present invention produces is, use Prohexadione calcium of the present invention and microbicide compositions, can reach the object that control is prosperous, disease-resistant, increase production, and second stubble crop is not affected, reduce peasant's drug cost, increase crop yield, thereby increased farmers' income, createed huge economic worth and social value.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but protection scope of the present invention is not limited to this.
Embodiment 1
Get Prohexadione calcium 15kg, own azoles alcohol 5.0kg; Dispersant NNO8kg, wetting agent neopelex 2kg, white carbon 1.5kg, kaolin 68.5kg mix 30 min in cone-type mixer; Cross airslide disintegrating mill, be crushed to 95% and cross 325 mesh sieves; In mixer, mix again 60 min, guarantee to mix; Obtain wetting powder of the present invention by the qualified rear packing of standard detection.
Embodiment 2
Get Prohexadione calcium 5kg, epoxiconazole 30kg, calcium lignosulfonate 3kg, Nekal BX 0.5kg, bentonite 50kg, in cone-type mixer, mix 30 min; Cross airslide disintegrating mill, be crushed to 95% and cross 325 mesh sieves; In mixer, mix again 60 min, guarantee to mix; Obtain wetting powder of the present invention by the qualified rear packing of standard detection.
Embodiment 3
Get Prohexadione calcium 40kg, Difenoconazole 60kg, dispersing agent C NF10kg, wetting and penetrating agent JFC3kg, diatomite 150kg, in cone-type mixer, mix 30 min; Cross airslide disintegrating mill, be crushed to 95% and cross 325 mesh sieves; In mixer, mix again 60 min, guarantee to mix; Obtain wetting powder of the present invention by the qualified rear packing of standard detection.
Embodiment 4
Take respectively Prohexadione calcium 15kg, thifluzamide 5.0kg, lauryl sodium sulfate 1kg, dispersant NNO 5kg, xanthans 0.2kg, aluminium-magnesium silicate 1kg, ethylene glycol 5 kg, silicone defoaming agent 0.5 kg, bentonite 1kg, 61.3 kg are for subsequent use for water; Load weighted material is joined in agitator tank and mixed, cross clipper or colloid mill precomminution, be circulated throughout sand mill 3 times, be crushed to qualified particle diameter, stir, finally filter, detection, fillingly get final product to obtain suspending agent of the present invention.
Embodiment 5
Take respectively Prohexadione calcium 5kg, prochloraz-manganese chloride complex 30kg, lauryl sodium sulfate 0.1kg, dispersant NNO 0.2kg, sodium alginate 0.1kg, glycerine 5 kg, polyethylene glycol, tributyl phosphate 3 kg, white carbon 0.1kg, 19 kg are for subsequent use for water; Load weighted material is joined in agitator tank and mixed, cross clipper or colloid mill precomminution, be circulated throughout sand mill 3 times, be crushed to qualified particle diameter, stir, finally filter, detection, fillingly get final product to obtain suspending agent of the present invention.
Embodiment 6
Take respectively Prohexadione calcium 30kg, Prochloraz 60kg, lauryl sodium sulfate 2kg, 100 kg are for subsequent use for dispersant NNO 3kg, polyvinyl alcohol 2kg, polyacrylamide 3kg, sorbierite 2kg, polyether antifoam agent 2kg, precipitated calcium carbonate 10kg, water; Load weighted material is joined in agitator tank and mixed, cross clipper or colloid mill precomminution, be circulated throughout sand mill 3 times, be crushed to qualified particle diameter, stir, finally filter, detection, fillingly get final product to obtain suspending agent of the present invention.
Embodiment 7
Get Prohexadione calcium 15.0kg, carbendazim 40.0kg, calcium lignosulfonate 5kg, dispersant NNO5 kg, lauryl sodium sulfate 1.5 kg, ammonium sulfate 3kg, soluble starch 3 kg, kaolin 25.5 kg.Each material is weighed up, in cone-type mixer, mix 30 min, cross airslide disintegrating mill, be crushed to 95% and cross 400 mesh sieves; After adding approximately 15% water to stir the material crushing; Drop into granulation in Squeezinggranulator; Detection after particle drying, packing get final product to obtain water dispersible granules of the present invention.
Embodiment 8
Get Prohexadione calcium 5kg, thiophanate-methyl 5 kg, Dispersant MF 2kg, dispersant NNO 3kg, lauryl sodium sulfate 0.5kg, urea 6 kg, polyvinylpyrrolidone 0.5 kg, attapulgite 10 kg.Each material is weighed up, in cone-type mixer, mix 30 min, cross airslide disintegrating mill, be crushed to 95% and cross 400 mesh sieves; After adding approximately 15% water to stir the material crushing; Drop into granulation in Squeezinggranulator; Detection after particle drying, packing get final product to obtain water dispersible granules of the present invention.
Embodiment 9
Get Prohexadione calcium 50kg, zarilamid 60 kg, dispersant NNO 3kg, lauryl sodium sulfate 2.0kg, sucrose 8 kg, polyvinylpyrrolidone 5 kg, attapulgite 60 kg.Each material is weighed up, in cone-type mixer, mix 30 min, cross airslide disintegrating mill, be crushed to 95% and cross 400 mesh sieves; After adding approximately 15% water to stir the material crushing; Drop into granulation in Squeezinggranulator; Detection after particle drying, packing get final product to obtain water dispersible granules of the present invention.
application test
1, test period: in July, 2011;
2, test site: the prosperous ancestral's kiln in Xuyi County of Jiangsu Province;
3, trial crops: paddy rice;
4, controlling object: the prosperous length of paddy rice control, prevent and treat banded sclerotial blight.
Rice varieties is, excellent No. 6 of emblem two, at rice transplanting about 20 days, tiller to shooting stage dispenser, choose 11Ge community, the Prohexadione calcium preparing with embodiment 1-9 respectively and microbicide compositions and alone Prohexadione calcium, the test of clear water blank, 24 square metres of each community areas, planting density 20cm × 20cm, repeats for 3 times; Investigate plant height and rice sheath blight disease disease index simultaneously; The every fringe grain husk of full heading time sample investigation is spent number and every square metre of spike number; In the maturing stage, each community is got respectively 10 clumps of rice strains at random, measures respectively the average plant height of paddy rice, length of internode and the stem stalk diameter of each community, and carries out species test; Output is gathered in separately, dries, raises only, taken in ripe time-division community.
The different chemicals treatment situations of crop field trial are as table 1
The different chemicals treatment of table 1 crop field trial
Different medicaments on the impact of Plant Height of Rice and stem stalk proterties as table 2:
Table 2
Different medicaments on the impact of Plant Height of Rice and other factors thereof as table 3:
Table 3
By the mensuration of, disease thick to crop plant height, stem, output etc., use Prohexadione calcium of the present invention and microbicide compositions all to have a clear superiority in aspect thick at plant height, stem, control prosperous successful; Prevent and treat rice sheath blight disease preventive effect and reach 54% ~ 71.8%, control the successful of prosperous volume increase.
Claims (10)
1. Prohexadione calcium and a microbicide compositions, is characterized in that, the parts by weight of Prohexadione calcium are that the parts by weight of 5-50 part, bactericide are 5 ~ 60 parts.
2. Prohexadione calcium as claimed in claim 1 and microbicide compositions, it is characterized in that, described bactericide is any one or several in epoxiconazole, Difenoconazole, Tebuconazole, own azoles alcohol, thifluzamide, zarilamid, carbendazim, thiophanate-methyl, prochloraz-manganese chloride complex, Prochloraz.
3. Prohexadione calcium as claimed in claim 1 and microbicide compositions, it is characterized in that, described Prohexadione calcium and microbicide compositions are wetting powder, are made up of the raw material of following portions by weight: 5 ~ 40 parts of Prohexadione calciums, 5 ~ 60 parts, bactericide, 0.5 ~ 3.0 part of wetting agent, 3.0 ~ 10 parts of dispersants, 50 ~ 150 parts, carrier.
4. Prohexadione calcium as claimed in claim 1 and microbicide compositions, it is characterized in that, described Prohexadione calcium and microbicide compositions are water dispersible granules, are made up of the raw material of following portions by weight: 10 ~ 60 parts of Prohexadione calcium 5-50 parts, 5 ~ 60 parts, bactericide, wetting agent 0.5-2.0 part, dispersant 3.0-10 part, disintegrant 3-8 part, binding agent 0.5-5 part, carrier.
5. Prohexadione calcium as claimed in claim 4 and microbicide compositions, is characterized in that, described disintegrant is any one or several in ammonium sulfate, urea, sucrose; Described binding agent is any one or several in dextrin, soluble starch, gum Arabic, polyvinylpyrrolidone, polyvinyl alcohol, sodium carboxymethylcellulose.
6. Prohexadione calcium as claimed in claim 1 and microbicide compositions, it is characterized in that, described Prohexadione calcium and microbicide compositions are suspending agent, are made up of the raw material of following portions by weight: 20 ~ 100 parts of Prohexadione calcium 5-30 parts, 5 ~ 60 parts, bactericide, wetting agent 0.1-2.0 part, dispersant 0.2-5.0 part, thickener 0.1-5.0 part, antifreezing agent 2.0-10 part, stabilizing agent 0.1-10 part, defoamer 0-3.0 part, water.
7. Prohexadione calcium as claimed in claim 6 and microbicide compositions, is characterized in that, described thickener is any one or several in sodium carboxymethylcellulose, xanthans, aluminium-magnesium silicate, sodium alginate, polyvinyl alcohol, polyacrylamide; Described antifreezing agent is any one or several in ethylene glycol, glycerine, polyethylene glycol, urea, sorbierite.
8. Prohexadione calcium as claimed in claim 6 and microbicide compositions, is characterized in that, described stabilizing agent is any one or several in bentonite, white carbon, precipitated calcium carbonate, formaldehyde; Described defoamer is any one or several in organosilicon, tributyl phosphate, polyether antifoam agent.
9. any Prohexadione calcium and the microbicide compositions as described in claim 3-8, is characterized in that, described wetting agent is any one or several in neopelex, Nekal BX, wetting and penetrating agent JFC, lauryl sodium sulfate; Described dispersant is that calcium lignosulfonate, dispersant NNO, dispersing agent C NF, Dispersant MF are any one or several.
10. any Prohexadione calcium and the microbicide compositions as described in claim 3-4, is characterized in that, described carrier is any one or several of kaolin, bentonite, diatomite, white carbon, precipitated calcium carbonate, attapulgite.
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| CN104365599A (en) * | 2014-09-29 | 2015-02-25 | 郑州郑氏化工产品有限公司 | Vegetable yield-increasing conditioning agent and use thereof |
| CN105237216A (en) * | 2015-10-22 | 2016-01-13 | 金正大生态工程集团股份有限公司 | Peanut growing control medical fertilizer wettable powder and method for controlling growth and increasing yield of peanut plants |
| CN105685026A (en) * | 2016-02-22 | 2016-06-22 | 郑州郑氏化工产品有限公司 | Water-dispersible granule with prohexadione calcium and method for preparing water-dispersible granules |
| CN107396931A (en) * | 2016-05-19 | 2017-11-28 | 陕西韦尔奇作物保护有限公司 | It is a kind of to increase composition containing the antibacterial of DCPTA and triazole type |
| CN107432278A (en) * | 2016-05-25 | 2017-12-05 | 陕西韦尔奇作物保护有限公司 | A kind of antimicrobial growth regulation composition containing DCPTA and amide-type |
| WO2018229055A1 (en) | 2017-06-12 | 2018-12-20 | Fine Agrochemicals Limited | Plant growth regulator and fungicide |
| EP3578047A1 (en) | 2018-06-07 | 2019-12-11 | Fine Agrochemicals Limited | Plant growth regulator system |
| CN110810180A (en) * | 2019-11-22 | 2020-02-21 | 扬州大学 | Method for regulating rice plant type, promoting photosynthetic production and improving yield |
| CN112236038A (en) * | 2018-03-22 | 2021-01-15 | 江苏龙灯化学有限公司 | Fungicidal compositions having carbendazim and tebuconazole and methods of using such compositions |
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| CN104365599A (en) * | 2014-09-29 | 2015-02-25 | 郑州郑氏化工产品有限公司 | Vegetable yield-increasing conditioning agent and use thereof |
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| CN112236038A (en) * | 2018-03-22 | 2021-01-15 | 江苏龙灯化学有限公司 | Fungicidal compositions having carbendazim and tebuconazole and methods of using such compositions |
| EP3578047A1 (en) | 2018-06-07 | 2019-12-11 | Fine Agrochemicals Limited | Plant growth regulator system |
| WO2019234234A1 (en) | 2018-06-07 | 2019-12-12 | Fine Agrochemicals Limited | Plant growth regulator system |
| CN110810180A (en) * | 2019-11-22 | 2020-02-21 | 扬州大学 | Method for regulating rice plant type, promoting photosynthetic production and improving yield |
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