CN103804012B - A kind of fire-retardant heat-insulation material and its preparation method and application - Google Patents
A kind of fire-retardant heat-insulation material and its preparation method and application Download PDFInfo
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- CN103804012B CN103804012B CN201210458125.XA CN201210458125A CN103804012B CN 103804012 B CN103804012 B CN 103804012B CN 201210458125 A CN201210458125 A CN 201210458125A CN 103804012 B CN103804012 B CN 103804012B
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- 239000012774 insulation material Substances 0.000 title claims abstract description 26
- 239000003063 flame retardant Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000002440 industrial waste Substances 0.000 claims abstract description 19
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 239000001301 oxygen Substances 0.000 claims abstract description 6
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 5
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 21
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 239000010881 fly ash Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 10
- 239000004568 cement Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000000835 fiber Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 238000009413 insulation Methods 0.000 claims description 5
- 238000012423 maintenance Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 235000019353 potassium silicate Nutrition 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 2
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- 239000005997 Calcium carbide Substances 0.000 claims description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 229910000102 alkali metal hydride Inorganic materials 0.000 claims description 2
- 150000008046 alkali metal hydrides Chemical class 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 2
- 239000001099 ammonium carbonate Substances 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 239000002956 ash Substances 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims description 2
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 claims description 2
- 230000008719 thickening Effects 0.000 claims description 2
- 239000002699 waste material Substances 0.000 claims description 2
- 239000010410 layer Substances 0.000 description 7
- 230000007613 environmental effect Effects 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 238000004134 energy conservation Methods 0.000 description 3
- 239000003469 silicate cement Substances 0.000 description 3
- 229920000715 Mucilage Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 239000010754 BS 2869 Class F Substances 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004794 expanded polystyrene Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 239000011396 hydraulic cement Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920006389 polyphenyl polymer Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Building Environments (AREA)
Abstract
The invention discloses a kind of fire-retardant heat-insulation material and its preparation method and application.Described fire-retardant heat-insulation material comprises silicon-aluminum containing matter powdery industrial waste and highly basic is carried out the cancellated sial oxygen chemical bond of chemical reaction formation according to certain proportioning, wherein, the parts by weight of described silicon-aluminum containing matter powdery industrial waste are 100 parts, the parts by weight of described highly basic are 2 ~ 10 parts, and the parts by weight of whipping agent are 0.1 ~ 10 part.Fire-retardant heat-insulation material of the present invention has the features such as lightweight, thermal conductivity is little, has excellent fire resistance and compressive property simultaneously.
Description
Technical field
The present invention relates to Material Field, be specifically related to a kind of fire-retardant heat-insulation material and preparation method thereof.
Background technology
Along with the raising of people's environmental protection, awareness of saving energy and the regulation of national policy, all trades and professions all environmental protection, energy-conservation in strengthen research and development capabilities, to protect the environment of human lives better.In building material field, building energy conservation is also an important developing direction, and wherein, the research and development of lagging material are its important branches.For meeting the demand that people improve indoor environment comfort level, realizing environmental protection, energy-conservation object simultaneously, having occurred the multiple lagging material containing corresponding industrial waste.
In conventional lagging material, for making it have certain intensity in conjunction with various raw material, cement plays adhesive property and provides the main ingredient of intensity.Because of consume energy in cement production process high, to reduce expense needed for environmental pollution large, therefore substituting cement with the environmental friendliness that realizes little as far as possible with other matrix materials is extraordinary mode.
Flyash is the solid waste that coal-fired electric field is discharged, and at present, it is still one of larger industrial residue of quantity discharged, if utilized, can greatly reduce it and stack occupation of land pollution.Flyash has the potential hydraulicity, cement is replaced to reach required adhesive property etc. if utilized, then except reducing the pollution of himself, highly energy-consuming, heavy-polluted cement can also be used less, realize environmental friendliness, therefore, the direction of actively developing is studied in the utilization of flyash in field of heat insulating materials.
Chinese invention patent application CN101575880A discloses a kind of exterior insulation system for polyphenyl plate thin plastering exterior wall, comprise wall body structure layer, thermal insulation layer, anti-cracking protective layer and finish coat is had successively outside wall body structure layer, wherein, thermal insulation layer is made up of bonding mucilage, fire-resistance expanded polystyrene panel, anti-cracking protective layer is made up of anticracking grout and the alkaline-resisting grid cloth of glass fibre, and finish coat is outer wall flexible putty.In this application for a patent for invention, bonding mucilage employs the flyash of 2-6wt%.But in this application for a patent for invention, the consumption of flyash is less, thus digests the limited in one's ability of industrial waste.And its lagging material adopted is organic insulation material, and corresponding flameproof effect is poor.
Chinese invention patent ZL02137686.7 discloses a kind of fire-retardant heat-insulation material, and this material comprises Class F fly ash, kaolin, calcium hydroxide, magnesium hydroxide, glass fibre and pearlstone.In the present invention, by there is the binding agent of hydraulic cement performance by being formed after calcium hydroxide and kaolin mixing, thus play cohesive action, but the heat-insulating property of this material and compressive property poor.
Thus, the present invention also contemplates this type of material and realize balance between environmental protection and energy saving, fire prevention, intensity and weight, cost on the basis overcoming the problems referred to above.
Summary of the invention
The object of this invention is to provide a kind of fire-retardant heat-insulation material and preparation method thereof, by silicon-aluminum containing matter powdery industrial waste and highly basic are carried out chemical reaction according to certain proportioning, thus form stable cancellated sial oxygen chemical bond, improve the heat-insulating property of fire-retardant heat-insulation material, resistance to elevated temperatures and compressive property.
To achieve these goals, a first aspect of the present invention provides a kind of fire-retardant heat-insulation material, described fire-retardant heat-insulation material comprises silicon-aluminum containing matter powdery industrial waste and highly basic is carried out the cancellated sial oxygen chemical bond of chemical reaction formation according to certain proportioning, wherein, the parts by weight of described silicon-aluminum containing matter powdery industrial waste are 100 parts, the parts by weight of described highly basic are 2 ~ 10 parts, and the parts by weight of whipping agent are 0.1 ~ 10 part.
In above-mentioned materials, silicon-aluminum containing matter powdery industrial waste can be selected from flyash, ashes, clay, kaolin, slag and red mud one or more; Highly basic can be selected from aminocompound, alkalimetal hydride and oxyhydroxide one or more or be selected from industrial alkali waste and contain above-mentioned highly basic composition; Whipping agent can be selected from aluminium powder, magnesium powder, zinc powder, barium powder, calcium carbide, ammonium chloride, ammonium hydrogencarbonate, hydrogen peroxide, tensio-active agent and sodium bicarbonate one or more.
Preferably, described highly basic is sodium hydroxide and/or potassium hydroxide.
Further, described fire-retardant heat-insulation material can also comprise the water glass of 10 ~ 50 weight parts and/or the cement of 10 ~ 50 weight parts.Wherein, described cement is preferably silicate cement.
Further, according to the actual requirements, in above-mentioned fire-retardant heat-insulation material, intensity activator, compound heat-insulation aggregate, hydrophober, thickening material, foaming stabiliser and/or high efficiency water reducing agent can also can be added.
Further, described fire-retardant heat-insulation material can also comprise fiber, fiber lattice cloth and/or wire netting.
A second aspect of the present invention provides a kind of method preparing above-mentioned fire-retardant heat-insulation material, comprising:
1) in the raw material comprising 100 weight part silicon-aluminum containing matter powdery industrial wastes and 2 ~ 10 weight part highly basic, add the water of 10 ~ 200 weight parts, carry out mix and blend, so that silicon-aluminum containing matter powdery industrial waste and highly basic carry out chemical reaction form cancellated sial oxygen chemical bond;
2) add 0.1 ~ 10 parts by weight of blowing agent to stir, then pour mixture into mould;
3) maintenance, the demoulding is carried out.
Preferably, described silicon-aluminum containing matter powdery industrial waste is the finely powdered silicon-aluminum containing matter powdery industrial waste through grinding or Screening Treatment.In addition, in aforesaid method, step (2) is preferably carried out under 20 ~ 50 DEG C of conditions; In aforesaid method, step (3) is preferably carried out under 20 ~ 100 DEG C of conditions.
A third aspect of the present invention provides a kind of fireproof heated board used for building exterior wall, and wherein, one or more layers in described fireproof heated board adopts above-mentioned fire-retardant heat-insulation material to obtain.
A fourth aspect of the present invention provides a kind of fireproof heat insulating door, and wherein, in described fireproof heat insulating door, internal layer and/or outer field one or more layers adopt above-mentioned fire-retardant heat-insulation material to obtain.
Embodiment
The present invention is further explained in detail by following examples, but below describe only for enabling general technical staff of the technical field of the invention clearly understand principle of the present invention and marrow, and do not mean that any type of restriction is carried out to the present invention.Except special instruction, the percentage ratio of sign and number are weight percentage and parts by weight.
Embodiment 1:
At room temperature, by 500g flyash, 30g sodium hydroxide, 200g water glass, 70g water and 10g PP fiber are stirred for slurry, the hydrogen peroxide (concentration is 30%) adding 20g rapid stirring 5 minutes afterwards, then, pour slurry shape mixture into mould, maintenance 24 hours under the condition of 60 DEG C, the demoulding, obtains final fire-retardant heat-insulation material.Sample is cut into the sample block of 40mm × 40mm × 40mm, measure its Technique performance parameter, the results are shown in Table 1.
Embodiment 2:
At room temperature, by 450g flyash, 50g silicate cement, 27g sodium hydroxide, 150g water glass, water 60g, 11g PP fiber is stirred for slurry, the hydrogen peroxide (concentration is 30%) adding 18g rapid stirring 5 minutes afterwards, pour slurry shape mixture into mould, maintenance 24 hours under the condition of 55 DEG C, the demoulding, obtains final fire-retardant heat-insulation material.Sample is cut into the sample block of 40mm × 40mm × 40mm, measure its Technique performance parameter, the results are shown in Table 1.
Comparative example:
At room temperature, by 150g flyash, 350g silicate cement, 250g water, 11g PP fiber is stirred for slurry, the hydrogen peroxide (concentration is 30%) adding 18g rapid stirring 5 minutes afterwards, pour slurry shape mixture into mould, normal temperature maintenance 24 hours, the demoulding, obtains final fire-retardant heat-insulation material.Sample is cut into the sample block of 40mm × 40mm × 40mm, measure its Technique performance parameter, the results are shown in Table 1.
Table 1
| Technique performance parameter | Embodiment 1 | Embodiment 2 | Comparative example |
| Unit weight (kg/M3) | 0.3-0.4 | 0.3-0.4 | 0.4-0.5 |
| Ultimate compression strength (Mpa) | 0.29-0.35 | 0.92-1.44 | 0.11-0.12 |
| Combustionproperty | A level is not fired | A level is not fired | A level is not fired |
| High temperature resistant (DEG C) | 1000 | 800 | 600 |
| Thermal conductivity (W/m.k) | 0.046-0.055 | 0.048-0.057 | 0.056-0.062 |
The term that this specification sheets is used and form of presentation are only used as descriptive and nonrestrictive term and form of presentation, are not intended to by any equivalents thereof exclude of the feature that represents and describe or its integral part outside when using these terms and form of presentation.
Although show and described several embodiment of the present invention, the present invention has not been restricted to described embodiment.On the contrary, those of ordinary skill in the art should recognize can carry out any accommodation and improvement to these embodiments when not departing from principle of the present invention and spirit, and protection scope of the present invention determined by appended claim and equivalent thereof.
Claims (14)
1. a fire-retardant heat-insulation material, it is characterized in that: described fire-retardant heat-insulation material comprises silicon-aluminum containing matter powdery industrial waste and highly basic are carried out the cancellated sial oxygen chemical bond of chemical reaction formation according to certain proportioning, wherein, the parts by weight of described silicon-aluminum containing matter powdery industrial waste are 100 parts, the parts by weight of described highly basic are 2 ~ 10 parts, and the parts by weight of whipping agent are 0.1 ~ 10 part.
2. material according to claim 1, wherein, described silicon-aluminum containing matter powdery industrial waste be selected from flyash, ashes, clay, kaolin, slag and red mud one or more.
3. material according to claim 1, wherein, described highly basic be selected from aminocompound, alkalimetal hydride and oxyhydroxide one or more, or be selected from industrial alkali waste and contain above-mentioned highly basic composition.
4. material according to claim 1, wherein, described highly basic is sodium hydroxide and/or potassium hydroxide.
5. material according to claim 1, wherein, described whipping agent be selected from aluminium powder, magnesium powder, zinc powder, barium powder, calcium carbide, ammonium chloride, ammonium hydrogencarbonate, hydrogen peroxide, tensio-active agent and sodium bicarbonate one or more.
6. material according to claim 1, wherein, described fire-retardant heat-insulation material also comprises the water glass of 10 ~ 50 weight parts and/or the cement of 10 ~ 50 weight parts.
7. the material according to any one of claim 1-6, wherein, described fire-retardant heat-insulation material comprises intensity activator, compound heat-insulation aggregate, hydrophober, thickening material, foaming stabiliser and/or high efficiency water reducing agent further.
8. the material according to any one of claim 1-6, wherein, described fire-retardant heat-insulation material comprises fiber, fiber lattice cloth and/or wire netting further.
9. prepare a method for material described in any one of claim 1-8, comprising:
1) in the raw material comprising 100 weight part silicon-aluminum containing matter powdery industrial wastes and 2 ~ 10 weight part highly basic, add the water of 10 ~ 200 weight parts, carry out mix and blend, so that silicon-aluminum containing matter powdery industrial waste and highly basic carry out chemical reaction form cancellated sial oxygen chemical bond;
2) add 0.1 ~ 10 parts by weight of blowing agent to stir, then pour mixture into mould;
3) maintenance, the demoulding is carried out.
10. preparation method according to claim 9, wherein, described silicon-aluminum containing matter powdery industrial waste is the finely powdered silicon-aluminum containing matter powdery industrial waste through grinding or Screening Treatment.
11. preparation methods according to claim 9, wherein, step (2) is carried out under 20 ~ 50 DEG C of conditions.
12. preparation methods according to claim 9, wherein, step (3) is carried out under 20 ~ 100 DEG C of conditions.
13. 1 kinds of fireproof heated boards used for building exterior wall, wherein, one or more layers in described fireproof heated board obtains with material according to any one of claim 1-8.
14. 1 kinds of fireproof heat insulating doors, wherein, in described fireproof heat insulating door, internal layer and/or outer field one or more layers obtain with material according to any one of claim 1-8.
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| CN104119052B (en) * | 2014-06-24 | 2016-04-20 | 济南大学 | A kind of utilize dealkalize red mud and red mud iron selection tailings to prepare inorganic clad plate and preparation method |
| CN104193274B (en) * | 2014-08-28 | 2016-05-11 | 重庆大学 | Alkali slag foamed concrete |
| CN106946509B (en) * | 2017-03-24 | 2019-06-25 | 广州大学 | Alkali-activated carbonatite flyash/slag foam concrete and preparation method thereof |
| CN108129161A (en) * | 2018-02-02 | 2018-06-08 | 曲水标威新型建材有限公司 | Composite aerated brick and preparation method |
| CN109469253A (en) * | 2018-12-14 | 2019-03-15 | 中北大学 | A kind of assembled integrated interior wall and preparation method thereof of the polymers of base containing Desulphurization |
| CN109653387B (en) * | 2018-12-14 | 2021-03-02 | 中北大学 | Desulfurized ash based geopolymer insulation board and preparation method thereof, and assembled integrated insulation wall and preparation method thereof |
| CN111825409B (en) * | 2019-04-18 | 2022-04-05 | 中国地质大学（北京） | Novel light heat-insulating material with kaolin as aggregate and preparation method thereof |
| CN110105083B (en) * | 2019-05-24 | 2020-12-11 | 中国地质大学（北京） | Red mud-based heat insulation material and preparation method and application thereof |
| CN112723911B (en) * | 2021-01-19 | 2021-07-27 | 河北工业大学 | Regenerated powder-based inorganic cementing material toughening and crack reducing foaming agent and application thereof |
| CN115093244B (en) * | 2022-07-05 | 2023-02-24 | 中国矿业大学(北京) | Fireproof heat-insulating material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101941822A (en) * | 2010-08-26 | 2011-01-12 | 无锡吉兴汽车声学部件科技有限公司 | Thermal insulation board |
| CN102701688A (en) * | 2012-06-07 | 2012-10-03 | 江苏尼高科技有限公司 | Compound foam cement heat preserving material produced by using caustic slag cement and preparation method thereof |
| CN102775098A (en) * | 2012-07-10 | 2012-11-14 | 张木玲 | Fireproof heat-insulating material as well as preparation method and application thereof |
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| CN101948293B (en) * | 2010-09-30 | 2013-10-09 | 广州市建筑科学研究院有限公司 | Novel non-cement-based inorganic artificial stone slab and preparation method thereof |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101941822A (en) * | 2010-08-26 | 2011-01-12 | 无锡吉兴汽车声学部件科技有限公司 | Thermal insulation board |
| CN102701688A (en) * | 2012-06-07 | 2012-10-03 | 江苏尼高科技有限公司 | Compound foam cement heat preserving material produced by using caustic slag cement and preparation method thereof |
| CN102775098A (en) * | 2012-07-10 | 2012-11-14 | 张木玲 | Fireproof heat-insulating material as well as preparation method and application thereof |
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