CN103801855A - Novel silver-free copper solder - Google Patents

Novel silver-free copper solder Download PDF

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Publication number
CN103801855A
CN103801855A CN201310630662.2A CN201310630662A CN103801855A CN 103801855 A CN103801855 A CN 103801855A CN 201310630662 A CN201310630662 A CN 201310630662A CN 103801855 A CN103801855 A CN 103801855A
Authority
CN
China
Prior art keywords
solder
copper
brazing
low
novel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310630662.2A
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Chinese (zh)
Inventor
田攀
田海红
王秀珍
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Lantu Culture Communication Co Ltd Shinan Branch
Original Assignee
Qingdao Lantu Culture Communication Co Ltd Shinan Branch
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Qingdao Lantu Culture Communication Co Ltd Shinan Branch filed Critical Qingdao Lantu Culture Communication Co Ltd Shinan Branch
Priority to CN201310630662.2A priority Critical patent/CN103801855A/en
Publication of CN103801855A publication Critical patent/CN103801855A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/30Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
    • B23K35/302Cu as the principal constituent

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)

Abstract

The invention relates to brazing solder, particularly to novel silver-free copper solder. The solder comprises the components as follows: Cu, Sn, P and Zn. The solder is low in melting temperature, good in flowability, good in wettability and spreadability, better in mechanical property, reliable in quality, not high in price, thin and firm in welding joint, capable of being applied to brazing of most of copper alloys such as copper, bronze, low brass and the like in cooperation with silver soldering flux, excellent in property and low in cost.

Description

A kind of novel without ag-cu solder
Technical field
The present invention relates to a kind of brazing solder, especially a kind of novel without ag-cu solder.
Background technology
Being of wide application of copper solder brazing technology, can produce for passenger vehicle, the radiator of truck and engineering machinery, warm-air drier, oil cooler, charge air cooler, condenser and evaporimeter etc., especially the application of EGR (EGR) technology on engine in recent years can make whole automobile cooling system change, to the resistance to elevated temperatures of heat exchanger, the requirement of heat dispersion and intensity also significantly improves thereupon, red copper/brazed copper heat exchangers of using the hard pin welding technology of copper to manufacture has now just had the stage of showing one's capabilities, so copper base hard solder just becomes the indispensable brazing material of copper solder brazing.
Summary of the invention
The present invention is intended to address the above problem, and provides a kind of novel without ag-cu solder, and its fusion temperature is lower, and wettability is better, and good fluidity is a kind of desirable copper base solder brazing solder, and its technical scheme adopting is as follows:
A kind of novel without ag-cu solder, it is characterized in that, described comprises without ag-cu solder constituent: Cu, Sn, P, Zn, its each composition by weight percentage (unit: wt%) is followed successively by: Sn 4.5-5.5, P 5.5-7.0, Zn 2.0-3.0, Cu surplus; Described solder fusion temperature is 600~660 ℃, belongs to copper solder brazing low temperature hard solder; Described Sn can reduce the fusing point of Cu, improves the mobility of solder; Described Zn can form solid solution at the edge of crystal grain, and the solid solution forming between solder and mother metal is combined, thereby improves the ability to function of solder and copper, reduces solder fusing point; Described P can be combined with Cu solid solution, improves the intensity of weld seam.
Tool of the present invention has the following advantages: its fusion temperature is low, good fluidity, there is good wetting and spreading property, mechanical property is also better, reliable in quality, price is not high yet, and weld seam is thin, firm, coordinate silver-colored brazing flux can brazed copper, most of copper alloys such as bronze and low brass, be a kind of function admirable, with low cost novel without ag-cu solder.
The specific embodiment
Below in conjunction with example, the invention will be further described:
A kind of novel without ag-cu solder, it is characterized in that, described comprises without ag-cu solder constituent: Cu, Sn, P, Zn, its each composition by weight percentage (unit: wt%) is followed successively by: Sn 4.5-5.5, P 5.5-7.0, Zn 2.0-3.0, Cu surplus; Described solder fusion temperature is 600~660 ℃, belongs to copper solder brazing low temperature hard solder; Described Sn can reduce the fusing point of Cu, improves the mobility of solder; Described Zn can form solid solution at the edge of crystal grain, and the solid solution forming between solder and mother metal is combined, thereby improves the ability to function of solder and copper, reduces solder fusing point; Described P can be combined with Cu solid solution, improves the intensity of weld seam.
Describe the present invention with way of example above, but the invention is not restricted to above-mentioned specific embodiment, all any changes of doing based on the present invention or modification all belong to the scope of protection of present invention.

Claims (2)

1. novel without an ag-cu solder, it is characterized in that, described comprises without ag-cu solder constituent: Cu, Sn, P, Zn, its each composition by weight percentage (unit: wt%) is followed successively by: Sn 4.5-5.5, P 5.5-7.0, Zn 2.0-3.0, Cu surplus.
2. a kind of copper radiator soldering tin-lead solder according to claim 1, is characterized in that: described solder fusion temperature is 600~660 ℃, belongs to copper solder brazing low temperature hard solder.
CN201310630662.2A 2013-12-02 2013-12-02 Novel silver-free copper solder Pending CN103801855A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310630662.2A CN103801855A (en) 2013-12-02 2013-12-02 Novel silver-free copper solder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310630662.2A CN103801855A (en) 2013-12-02 2013-12-02 Novel silver-free copper solder

Publications (1)

Publication Number Publication Date
CN103801855A true CN103801855A (en) 2014-05-21

Family

ID=50699496

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310630662.2A Pending CN103801855A (en) 2013-12-02 2013-12-02 Novel silver-free copper solder

Country Status (1)

Country Link
CN (1) CN103801855A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104353939A (en) * 2014-11-17 2015-02-18 安徽瑞研新材料技术研究院有限公司 Novel lead-free copper alloy new material and processing technology thereof
CN106498228A (en) * 2016-10-11 2017-03-15 何国良 Preparation method and new material of a kind of high conductivity without yellow gold

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS575836A (en) * 1980-06-16 1982-01-12 Nippon Mining Co Ltd High strength copper alloy having excellent heat resistance for use as conductive material
CN1039986A (en) * 1989-04-08 1990-02-28 浙江大学材料制造厂 A kind of copper-based polybasic alloy soldering materials
US4935076A (en) * 1988-05-11 1990-06-19 Mitsui Mining & Smelting Co., Ltd. Copper alloy for use as material of heat exchanger
WO2005014870A1 (en) * 2003-08-04 2005-02-17 Vacuumschmelze Gmbh & Co. Kg Brazing solder alloy based on copper and method for brazing

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS575836A (en) * 1980-06-16 1982-01-12 Nippon Mining Co Ltd High strength copper alloy having excellent heat resistance for use as conductive material
US4935076A (en) * 1988-05-11 1990-06-19 Mitsui Mining & Smelting Co., Ltd. Copper alloy for use as material of heat exchanger
CN1039986A (en) * 1989-04-08 1990-02-28 浙江大学材料制造厂 A kind of copper-based polybasic alloy soldering materials
WO2005014870A1 (en) * 2003-08-04 2005-02-17 Vacuumschmelze Gmbh & Co. Kg Brazing solder alloy based on copper and method for brazing

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
谭敦吉等: "Cu-Zn-P-Sn钎焊合金研究", 《湖南冶金》, no. 5, 30 September 1988 (1988-09-30) *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104353939A (en) * 2014-11-17 2015-02-18 安徽瑞研新材料技术研究院有限公司 Novel lead-free copper alloy new material and processing technology thereof
CN106498228A (en) * 2016-10-11 2017-03-15 何国良 Preparation method and new material of a kind of high conductivity without yellow gold

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Application publication date: 20140521