CN103790002A - Corrosion-resistant tablecloth coating and preparation method thereof - Google Patents
Corrosion-resistant tablecloth coating and preparation method thereof Download PDFInfo
- Publication number
- CN103790002A CN103790002A CN201310753440.XA CN201310753440A CN103790002A CN 103790002 A CN103790002 A CN 103790002A CN 201310753440 A CN201310753440 A CN 201310753440A CN 103790002 A CN103790002 A CN 103790002A
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- parts
- corrosion
- tablecloth
- preparation
- coating
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- 239000011248 coating agent Substances 0.000 title claims abstract description 28
- 238000000576 coating method Methods 0.000 title claims abstract description 28
- 238000005260 corrosion Methods 0.000 title claims abstract description 23
- 230000007797 corrosion Effects 0.000 title claims abstract description 23
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 24
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000004793 Polystyrene Substances 0.000 claims abstract description 10
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims abstract description 10
- 229920002223 polystyrene Polymers 0.000 claims abstract description 10
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims abstract description 8
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229940090181 propyl acetate Drugs 0.000 claims abstract description 8
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 poly(4-methyl-1-pentene) Polymers 0.000 claims description 18
- 229920000306 polymethylpentene Polymers 0.000 claims description 9
- 239000011116 polymethylpentene Substances 0.000 claims description 9
- 229920005668 polycarbonate resin Polymers 0.000 claims description 7
- 239000004431 polycarbonate resin Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 150000003839 salts Chemical class 0.000 abstract description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 239000004417 polycarbonate Substances 0.000 abstract 1
- 229920000515 polycarbonate Polymers 0.000 abstract 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 238000009938 salting Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000007516 brønsted-lowry acids Chemical class 0.000 description 1
- 150000007528 brønsted-lowry bases Chemical class 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
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- Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to a corrosion-resistant tablecloth coating and a preparation method of the corrosion-resistant tablecloth coating. The corrosion-resistant tablecloth coating comprises the following components in parts by weight: 8-13 parts of butadiene, 4-6 parts of polystyrene, 7-9 parts of acrylonitrile butadiene styrene (ABS) resin, 4-5 parts of polycarbonate, 1-3 parts of poly 4-methyl-1-amylene, 2-4 parts of dicyclopentadiene, 15-18 parts of propyl acetate and 4-7 parts of propylene glycol. The tablecloth coating is prepared by the steps of heating at high temperature, evenly stirring, dissolving, cooling and the like; the prepared tablecloth coating has good corrosion-resistant effect, and can be used for preventing the corrosion of acid, alkali, salt and the like for a tablecloth.
Description
Technical field
The present invention relates to a kind of preparation method of tablecloth coating, particularly relate to a kind of preparation method of the tablecloth coating with good decay resistance.
Background technology
Conventional tablecloth is prepared from by synthetic fiber conventionally, and coating processing is not passed through on surface.In daily use, running into after the long-time corrosion of acetic acid, alkali lye, salting liquid, can produce disrepair phenomenon, affect the normal use of tablecloth.Conventionally researcher is less carries out special treatment to tablecloth and increases the corrosion resistance characteristic of tablecloth.If coating processing is carried out in the top layer of tablecloth, after coating is processed, after with acid solution or alkali lye, it being tested for a long time, there is good erosion-resisting effect, can improve the using value containing cated tablecloth.The coating of selecting what type is to improve the key point of decay resistance of tablecloth, needs our further investigated.
Summary of the invention
The technical problem solving: the anticorrosion effect of common home-use tablecloth is poor, after Long contact time bronsted lowry acids and bases bronsted lowry, meeting produces the problem of heavy corrosion phenomenon.
Technical scheme: the invention discloses a kind of corrosion resistant tablecloth coating and preparation method thereof, tablecloth coating is made up of according to weight ratio following composition: butadiene is that 8～13 parts, polystyrene are that 4～6 parts, ABS resin are that 7～9 parts, polycarbonate resin are that 4～5 parts, poly(4-methyl-1-pentene) are that 1～3 part, dicyclopentadiene are that 2～4 parts, propyl acetate are that 15～18 parts, propylene glycol are 4～7 parts.
A preparation method for corrosion resistant tablecloth coating, comprises the following steps: temperature of reaction kettle is adjusted to 160 ℃ by (1); (2) be that 7～9 parts, polycarbonate resin are that 4～5 parts, poly(4-methyl-1-pentene) are that 1～3 part, dicyclopentadiene are 2～4 parts to adding ABS resin in reactor, stir with paddle, speed of agitator is 140rpm～160rpm, and the time is 70～90min; (3) temperature of reaction kettle is down to 120 ℃, adding butadiene is that 8～13 parts, polystyrene are 4～6 parts, stirs; (4) adding propyl acetate after again temperature of reaction kettle being down to 90 ℃ is that 15～18 parts, propylene glycol are 4～7 parts, and speed of agitator is 140rpm～160rpm, and the time is 70～90min, then is cooled to room temperature.
The ABS resin adding when preparation is preferably 8～9 parts.
The poly(4-methyl-1-pentene) adding when preparation is preferably 2～3 parts.
The polystyrene adding when preparation is preferably 4～5 parts.
Beneficial effect: the tablecloth coating of preparation of the present invention is after being applied on tablecloth, can tolerate 30wt% acetum soak 10 days to 30 days unchanged, the soaking in sodium carbonate solution 30 days to 50 days of tolerance 40wt% is unchanged, the sodium chloride solution of tolerance 30wt% soak 40 days to 60 days unchanged.
The specific embodiment
Embodiment 1
(1) temperature of reaction kettle is adjusted to 160 ℃; (2) be that 7kg, polycarbonate resin are that 5kg, poly(4-methyl-1-pentene) are that 1kg, dicyclopentadiene are 4kg to adding ABS resin in reactor, stir with paddle, speed of agitator is 160rpm, and the time is 70min; (3) temperature of reaction kettle is down to 120 ℃, adding butadiene is that 8kg, polystyrene are 6kg, stirs; (4) adding propyl acetate after again temperature of reaction kettle being down to 90 ℃ is that 15kg, propylene glycol are 7kg, and speed of agitator is 160rpm, and the time is 70min, then is cooled to room temperature, is prepared into corrosion resistant tablecloth coating.
Embodiment 2
(1) temperature of reaction kettle is adjusted to 160 ℃; (2) be that 8kg, polycarbonate resin are that 4kg, poly(4-methyl-1-pentene) are that 3kg, dicyclopentadiene are 3kg to adding ABS resin in reactor, stir with paddle, speed of agitator is 140rpm, and the time is 90min; (3) temperature of reaction kettle is down to 120 ℃, adding butadiene is that 11kg, polystyrene are 4kg, stirs; (4) adding propyl acetate after again temperature of reaction kettle being down to 90 ℃ is that 17kg, propylene glycol are 4kg, and speed of agitator is 150rpm, and the time is 90min, then is cooled to room temperature, is prepared into corrosion resistant tablecloth coating.
Embodiment 3
(1) temperature of reaction kettle is adjusted to 160 ℃; (2) be that 9kg, polycarbonate resin are that 5kg, poly(4-methyl-1-pentene) are that 2kg, dicyclopentadiene are 2kg to adding ABS resin in reactor, stir with paddle, speed of agitator is 150rpm, and the time is 80min; (3) temperature of reaction kettle is down to 120 ℃, adding butadiene is that 13kg, polystyrene are 5kg, stirs; (4) adding propyl acetate after again temperature of reaction kettle being down to 90 ℃ is that 18kg, propylene glycol are 6kg, and speed of agitator is 140rpm, and the time is 80min, then is cooled to room temperature, is prepared into corrosion resistant tablecloth coating.
By being coated in the whole outer surfaces of tablecloth after the tablecloth coating heating of embodiment 1, embodiment 2, embodiment 3, dry, coating layer thickness is 0.5mm.The tablecloth of embodiment 1, embodiment 2, embodiment 3 being put into respectively to the acetum of 30wt% places 10 days, 30 days, 50 days, put into respectively the soaking in sodium carbonate solution 30 days, 50 days, 70 days of 40wt%, the sodium chloride solution of putting into 30wt% soaks 40 days, 50 days, 60 days.
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Acid accumulator resistance | Corrosion-free phenomenon after 10 days | Corrosion-free phenomenon after 30 days | After 50 days, tablecloth has trickle corrosion phenomenon |
| Alkaline-resisting intensity | Corrosion-free phenomenon after 30 days | Corrosion-free phenomenon after 50 days | After 70 days, tablecloth has obvious corrosion phenomenon |
| Salt tolerant intensity | Corrosion-free phenomenon after 40 days | Corrosion-free phenomenon after 50 days | Corrosion-free phenomenon after 60 days |
The tablecloth coating of preparing by this method can effectively tolerate the corrosion of acid solution, alkali lye and salting liquid, can be widely used in the surface of tablecloth, improves its decay resistance.
Claims (5)
1. a corrosion resistant tablecloth coating, is characterized in that tablecloth coating is made up of according to weight ratio following composition: butadiene is that 8～13 parts, polystyrene are that 4～6 parts, ABS resin are that 7～9 parts, polycarbonate resin are that 4～5 parts, poly(4-methyl-1-pentene) are that 1～3 part, dicyclopentadiene are that 2～4 parts, propyl acetate are that 15～18 parts, propylene glycol are 4～7 parts.
2. the preparation method of a kind of corrosion resistant tablecloth coating according to claim 1, is characterized in that preparation method comprises the following steps: temperature of reaction kettle is adjusted to 160 ℃ by (1); (2) be that 7～9 parts, polycarbonate resin are that 4～5 parts, poly(4-methyl-1-pentene) are that 1～3 part, dicyclopentadiene are 2～4 parts to adding ABS resin in reactor, stir with paddle, speed of agitator is 140rpm～160rpm, and the time is 70～90min; (3) temperature of reaction kettle is down to 120 ℃, adding butadiene is that 8～13 parts, polystyrene are 4～6 parts, stirs; (4) adding propyl acetate after again temperature of reaction kettle being down to 90 ℃ is that 15～18 parts, propylene glycol are 4～7 parts, and speed of agitator is 140rpm～160rpm, and the time is 70～90min, then is cooled to room temperature.
3. the preparation method of a kind of corrosion resistant tablecloth coating according to claim 2, the ABS resin adding while it is characterized in that preparing is 8～9 parts.
4. the preparation method of a kind of corrosion resistant tablecloth coating according to claim 2, the poly(4-methyl-1-pentene) adding while it is characterized in that preparing is 2～3 parts.
5. the preparation method of a kind of corrosion resistant tablecloth coating according to claim 2, the polystyrene adding while it is characterized in that preparing is 4～5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310753440.XA CN103790002B (en) | 2013-12-31 | 2013-12-31 | A kind of corrosion resistant tablecloth coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310753440.XA CN103790002B (en) | 2013-12-31 | 2013-12-31 | A kind of corrosion resistant tablecloth coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103790002A true CN103790002A (en) | 2014-05-14 |
| CN103790002B CN103790002B (en) | 2015-12-09 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310753440.XA Expired - Fee Related CN103790002B (en) | 2013-12-31 | 2013-12-31 | A kind of corrosion resistant tablecloth coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103790002B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614200A (en) * | 2016-12-14 | 2017-05-10 | 浙江海洋大学 | Support rod type purse seine aquaculture engineering shore connecting technique |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278076A (en) * | 2005-10-03 | 2008-10-01 | H.E.F.公司 | Corrosion resistant coating based on silicon, carbon, hydrogen and nitrogen |
| CN102964970A (en) * | 2012-12-24 | 2013-03-13 | 青岛宣威涂层材料有限公司 | Epoxy acrylic anticorrosive paint |
| CN103061107A (en) * | 2013-01-04 | 2013-04-24 | 深圳市飞世尔实业有限公司 | Manufacturing method of anti-corrosion coating on surface of FeCrAl and 310/316 stainless steel fiber sintered felt |
-
2013
- 2013-12-31 CN CN201310753440.XA patent/CN103790002B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101278076A (en) * | 2005-10-03 | 2008-10-01 | H.E.F.公司 | Corrosion resistant coating based on silicon, carbon, hydrogen and nitrogen |
| CN102964970A (en) * | 2012-12-24 | 2013-03-13 | 青岛宣威涂层材料有限公司 | Epoxy acrylic anticorrosive paint |
| CN103061107A (en) * | 2013-01-04 | 2013-04-24 | 深圳市飞世尔实业有限公司 | Manufacturing method of anti-corrosion coating on surface of FeCrAl and 310/316 stainless steel fiber sintered felt |
Non-Patent Citations (1)
| Title |
|---|
| 王天堂等: "高性能防腐蚀VEGF 鳞片涂料的性能和应用", 《金属腐蚀控制》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614200A (en) * | 2016-12-14 | 2017-05-10 | 浙江海洋大学 | Support rod type purse seine aquaculture engineering shore connecting technique |
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| Publication number | Publication date |
|---|---|
| CN103790002B (en) | 2015-12-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zhao Zhexue Inventor after: Chen Guoqing Inventor after: Zhang Xiaoya Inventor before: Zhang Dexuan |
|
| COR | Change of bibliographic data | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191226 Address after: 215200 group 28, Fu Village, Taoyuan Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Wujiang yongru Textile Co.,Ltd. Address before: 7 groups of friendship village Songling town of Wujiang District of Suzhou City, Jiangsu province 215200 split eight community Patentee before: SUZHOU XUANDE TEXTILE SCIENCE & TECHNOLOGY Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20151209 |
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| CF01 | Termination of patent right due to non-payment of annual fee |