CN103788804B - A kind of encaustic tile paint for tiled surface and its preparation method and application - Google Patents
A kind of encaustic tile paint for tiled surface and its preparation method and application Download PDFInfo
- Publication number
- CN103788804B CN103788804B CN201410053821.1A CN201410053821A CN103788804B CN 103788804 B CN103788804 B CN 103788804B CN 201410053821 A CN201410053821 A CN 201410053821A CN 103788804 B CN103788804 B CN 103788804B
- Authority
- CN
- China
- Prior art keywords
- acrylic resin
- weight
- grams
- encaustic tile
- paint
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of encaustic tile paint for tiled surface and its preparation method and application, this encaustic tile paint is made up of acrylic resin, face, filler, auxiliary agent and solvent；Described acrylic resin is one or more in acrylic resin the 1st, acrylic resin 2 and acrylic resin 3；By weight percentage, this encaustic tile paint is composed of the following components: acrylic resin 2,1 35 weight % acrylic resin 3, the 1 25 weight % face of acrylic resin 1,1 35 weight % of 50 80 weight %, filler, 15 weight % auxiliary agents, 5 25 weight % solvents.The encaustic tile paint of the present invention be acrylic resin the 1st, acrylic resin the 2nd, the acrylic resin 3 by autonomous synthesis with the use of; as film-forming resin base-material; by face, filler select with compounding, auxiliary agent select with compounding and solvent select with compounding and disperse to reach predetermined fineness by milling apparatus, be finally reached the functional requirement being applicable to tiled surface, the encaustic tile paint of decoration and protection being provided.
Description
Technical field
The present invention relates to a kind of self-drying paint, relate in particular to a kind of encaustic tile paint for tiled surface and preparation method thereof
And application
Background technology
Tile is important roof waterpoof material, typically burns till with earth, and also the materials such as useful cement are made, and shape has
Arch, flat or hemicycle tubular etc..From the point of view of the data excavated and material object, watt China the initial stage in the Western Zhou Dynasty i.e. produce
Raw, and by the incoming Japan of Paekche while the Christian era 588 years and Buddhism.In Europe, within B.C. 640 years, build in Greece's Olympia
Temple of Hera, be have in the western architecture thing of roofing tile the most ancient, watt burning till with clay of temple.
At the commitment of China's tile history, tile is used primarily in inside the rich and honour family of comparison, because discovery tile
The effect kept off the rain and be incubated can be carried out, well more a lot of than wooden roof at that time or straw roof.With social development,
Tile has walked out the visual field of people at leisure for some time, because for our high building, directly uses reinforced concrete
Seem more firm, be more incubated.But, in the last few years, the durability that possessed by tile self, construction flexibility, can
Giving the unique distinctions such as abundant color effect, tile starts again slowly to enter in the sight line of people.
At present, tile mainly has two kinds of materials, and one is roof clay tile, and roof clay tile is a kind of domestic and international all very salable one
Plant tile material.Another kind is cement tile, and the material of cement tile is exactly cement, the same with the material built outside house.How
Make encaustic tile paint well be attached on the tile of unlike material, and provide preferable protective value and decorative effect to be coating industry
One of aspect of concern.
Encaustic tile paint involved in the present invention is just under this market background.This encaustic tile paint is the feature by autonomous synthesis
Collocation between acrylic resin is to reach to provide preferable adhesion properties and protective value at two kinds of main tile surface of bottom material
Purpose, is equipped with face, the fillers such as iron oxide red, chrome yellow, iron oxide yellow, titanium white, carbon black, phthalocyanine blue, middle colour black, talcum powder and reaches not
Requirement with decorative effect.
Content of the invention
It is an object of the invention to provide a kind of for tiled surface, the encaustic tile paint providing decoration and protective value.
The two of the purpose of the present invention are to provide a kind of encaustic tile paint for tiled surface, offer decoration and protective value
Preparation method.
The three of the purpose of the present invention are to provide a kind of encaustic tile paint for tiled surface, offer decoration and protective value
Application.
For achieving the above object, the present invention adopts the technical scheme that: a kind of encaustic tile paint for tiled surface, its feature
It is: this encaustic tile paint is made up of acrylic resin, face, filler, auxiliary agent and solvent；Described acrylic resin is for selected from acrylic acid
One or more in resin the 1st, acrylic resin 2 and acrylic resin 3；By weight percentage, this encaustic tile paint is by following group
It is grouped into:
Wherein, acrylic resin 1 is by butyl acrylate, acrylic acid, styrene, dimethylbenzene, dibenzoyl peroxide and mistake
Oxidation diisopropylbenzene (DIPB) synthesis, acrylic resin 2 is by butyl methacrylate, trimethylbenzene, dimethylbenzene, methyl methacrylate, first
Base acrylic acid and peroxidized t-butyl perbenzoate synthesis, acrylic resin 3 is by butyl methacrylate, toluene, dimethylbenzene, methyl
Methyl acrylate, methacrylic acid and dibenzoyl peroxide synthesis；
Described face, filler are selected from pigment iron oxide red, rutile titanium dioxide, chrome yellow, iron oxide yellow, phthalocyanine blue, middle look
One or more in element carbon black or filler 2500 mesh talcum powder；
Described auxiliary agent is selected from the BYK-130 of Byk Chemie GmbH, BYK-ATU, BYK-104S, BYK-306, hamming
928th, in the BASF Aktiengesellschaft EVA-1 OPE of this company, organobentonite, dioctyl phthalate
Plant or several mixtures.
By weight percentage, heretofore described acrylic resin 1 is composed of the following components:
Heretofore described acrylic resin 2 is composed of the following components:
Heretofore described acrylic resin 3 is composed of the following components:
Pigment iron oxide red in heretofore described face, filler is the 3602 of Shanghai Yipin Pigments Co., Ltd., gold
Red stone-type titanium dioxide is the R930 of Ishihara Sangyo Kaisha, Ltd. of Japan, and chrome yellow is the 103 of Shanghai Chrome Yellow Plant, and iron oxide yellow is bright
Containing the 4920 or 3910 of pigment Shanghai Co., Ltd, phthalocyanine blue is S173 or the BASF China of Shanghai Chemical Co., Ltd. of alliance
L6875 or L7101 of Co., Ltd, middle colour black is the N220 of Shanghai Li Shi Chemical Co., Ltd.；Filler 2500 mesh talcum
Powder is the CMS-888 of Heshan chemical industry (Liaoning) Co., Ltd.
Heretofore described BASF Aktiengesellschaft's EVA-1 OPE comes into operation after making wax slurry, and wax is starched
Consist of the following composition by weight percentage:
EVA-1 OPE 5-15 weight %
Butyl acetate 40-60 weight %
Dimethylbenzene 30-60 weight %.
Heretofore described solvent is composed of the following components by weight percentage:
Butanol 5-35 weight %
Butyl acetate 10-25 weight %
Dimethylbenzene 45-85% weight.
The preparation method for the encaustic tile paint of tiled surface of the present invention comprises the following steps:
A () prepares acrylic resin the 1st, acrylic resin the 2nd, acrylic resin 3；
Prepare acrylic resin 1: and account for methyl methacrylate, butyl methacrylate, methacrylic acid by proportioning
The peroxidized t-butyl perbenzoate answering addition total amount 60-70 weight % mixes as mix monomer A, stand-by；To account for and should add
Enter the dimethylbenzene of amount total amount 30-40 weight %, trimethylbenzene adds reaction pot, and heat temperature raising simultaneously opens stirring；When reaction pot temperature
When rising to 132 DEG C-143 DEG C, starting to drip mix monomer A, time for adding controls in 3-4 hour, during dropping, reaction pot
Temperature controls in the range of 132-143 DEG C；After mix monomer A dropping finishes, little the temperature range insulation 2 of 132-143 DEG C
When, then add and answer addition total amount 30-40 weight % peroxidized t-butyl perbenzoate, be incubated 3 hours more simultaneously；It is cooled to 80
After DEG C, add and account for the dimethylbenzene answering addition total amount 30-40 weight %, after stirring, be filtrated to get acrylic resin 1；
Prepare acrylic resin 2: by butyl acrylate, acrylic acid, styrene, dibenzoyl peroxide and account for should by proportioning
The cumyl peroxide of addition total amount 60-70 weight % mixes as mix monomer B, stand-by；To account for and answer addition total
The dimethylbenzene of amount 30-40 weight % is by adding reaction pot, and heat temperature raising simultaneously opens stirring, when reaction pot temperature rises to 115-125
DEG C when, start drip mix monomer B, time for adding controls in 2.5-3 hour, during dropping, should be by the temperature control of reaction pot
System is in the range of 115-125 DEG C；It after mix monomer B dropping finishes, is incubated 2 hours the temperature range of 115-125 DEG C, then
Add and account for the different benzene of peroxidating dipropyl answering addition total amount 30-40 weight %, after being added dropwise to complete, be incubated 4 hours；Insulation completes
After, it is warming up to 130-145 DEG C and carries out reflux dewatering, after being cooled to 80 DEG C, add to account for and answer the two of addition total amount 60-70 weight %
Toluene, is filtrated to get acrylic resin 2 after stirring；
Prepare acrylic resin 3: and account for methyl methacrylate, butyl methacrylate, methacrylic acid by proportioning
The benzoyl peroxide dibenzoyl answering addition total amount 65-75 weight % mixes as mix monomer C, stand-by；By proportioning by first
Benzene adds reaction pot, and heat temperature raising simultaneously opens stirring, when reaction pot temperature rises to 105 DEG C, starts to drip mix monomer C, drips
Control in 2.5-3 hour between the added-time, during dropping, the temperature of reaction pot should be controlled in the range of 105-115 DEG C；Mixing
After monomer C dropping finishes, being incubated 2 hours the temperature range of 105-115 DEG C, then dropping accounts for and answers addition total amount 25-35 weight
The benzoyl peroxide dibenzoyl of amount %, is incubated 2 hours simultaneously again；Insulation is warming up to 115-125 DEG C and carries out reflux dewatering；It is cooled to
After 80 DEG C, add dimethylbenzene by proportioning, filter after stirring；
B () is prepared EVA-1 OPE and is starched:
By proportioning, dimethylbenzene, BASF Aktiengesellschaft's EVA-1 OPE are put in reaction pot, heat temperature raising,
Open stirring；It after temperature is raised to 100-120 DEG C, is incubated 30-50min；After insulation terminates, open cooling water, be cooled to 70-90 DEG C
After, in the state of opening stirring, add butyl acetate by proportioning, be kept stirring for uniform state being cooled to normal temperature, filter
Stand-by；
C () prepares graining paste:
By the one in acrylic resin the 1st, acrylic resin the 2nd, acrylic resin 3, in auxiliary agent one or more, solvent
In one or more put in containers, after dispersed with stirring to uniform state, in the state of low rate mixing, put into pigment, at a high speed
Dispersed with stirring 60-9) min；Finely dispersed pigment slurry is ground to fineness being less than or equal to through grinder the skill of 20 μm
After art requires, filter stand-by；
Graining paste is composed of the following components by weight percentage:
(d), prepare extender paste:
Putting in container by acrylic resin the 2nd, xylene solvent, mixed aid, stirring is to after being uniformly dispersed, at a slow speed
Put into filler in the state of stirring, after high-speed stirred dispersion 30-40min, filter stand-by；
Extender paste is composed of the following components by weight percentage:
One in (e), just acrylic resin the 1st, acrylic resin 2 or acrylic resin 3, the one in auxiliary agent or several
The mixture of one or more in the mixture of kind, solvent puts in container, and dispersed with stirring is to the mixture of uniform state；
(f), in the state of low rate mixing, one or more in graining paste, extender paste are put into step (e) respectively
In mixture, and dispersed with stirring is to uniform state, i.e. obtains the encaustic tile being applicable to tiled surface, providing decoration and protective value
Paint.
The application of the encaustic tile paint for tile of the present invention, this encaustic tile paint application being used for tiled surface is painted on tile
On.There is provided decoration and protective value to tiled surface.
It when applying tiled surface, is diluted working viscosity 18-22s with the encaustic tile paint that the present invention is prepared by diluent
(applying-4 glasss), uses aerial spraying, and spray pressure is 0.4-0.6MPa.Encaustic tile paint prepared by the present invention can at tiled surface even
Continuous coating decoration, changes other tile coating when applying, needs the requirement of overlay painting interval time, shorten construction period.This
The encaustic tile paint of invention is when coating-spraying, and control dry film gross thickness is at (40-50) μm, through the encaustic tile of the encaustic tile paint spraying of the present invention
Product, provides excellent protection and decorative effect to tile.
Main performance technical indicator and the test side of the encaustic tile paint of tiled surface, offer decoration and protective value are provided
Method is as follows, is specifically shown in Table 1
Table 1
The invention has the advantages that:
1st, the encaustic tile paint of the present invention is to be joined by acrylic resin the 1st, acrylic resin the 2nd, the acrylic resin 3 of autonomous synthesis
Close and use, be equipped with auxiliary agent and reach to be applicable to the requirement of tiled surface.This encaustic tile paint potter's clay tile, cement tiled surface attached
Put forth effort excellent, provide preferable protective value and decorative effect to tile simultaneously.
2nd, the encaustic tile paint of the present invention can be constructed with one-component pattern, it is also possible to self-produced supporting component composition double-component
Type product, to meet the demand different to encaustic tile surface state.
3rd, easily, dryness is fine, it is possible to construct continuously, meets allegro application raw in the encaustic tile paint construction of the present invention
Production. art, be suitable for various environment, under various execution conditions on tile construction usage.
Detailed description of the invention
Some embodiments are set forth below be further described present disclosure, but protection scope of the present invention is never
It is confined to these embodiments.
Embodiment 1
By 15.8 grams of methyl methacrylates, 33.6 grams of butyl methacrylates, 0.55 gram of methacrylic acid and 0.20 gram
Peroxidized t-butyl perbenzoate mixes, and becomes mix monomer A；Anti-by adding after 9 grams of dimethylbenzene, 24.75 trimethylbenzene meterings
Answering pot, heat temperature raising simultaneously opens stirring；When reaction pot temperature rises to 132-143 DEG C, start to drip mix monomer A, during dropping
Between control during 3-4h, dropping, the temperature of reaction pot should be controlled in the range of 132-143 DEG C；Mix monomer A drips
It after finishing, is incubated 2 hours the temperature range of 132-143 DEG C, then adds 0.1 gram of peroxidized t-butyl perbenzoate, more simultaneously
It is incubated 3 hours；It is cooled to 80-90 DEG C, add 16 grams of dimethylbenzene, after stirring, be filtrated to get acrylic resin 1, stand-by.
By 15 grams of butyl acrylates, 1.0 grams of acrylic acid, 23.8 grams of styrene, 0.2 gram of dibenzoyl peroxide and 0.2 gram
The different phenylpropyl alcohol of peroxidating two mixes, and becomes mix monomer B；32 grams of dimethylbenzene add reaction pot, heat temperature raising unlatching stir
Mix；When reaction pot temperature rises to 115-125 DEG C, starting to drip mix monomer B, time for adding controls in 2.5-3 hour, dropping
During, the temperature of reaction pot should be controlled in the range of 115-125 DEG C；After mix monomer B dropping finishes, at 115-125
DEG C temperature range be incubated 2 hours, be subsequently adding the different phenylpropyl alcohol of 0.1 gram of peroxidating two, be incubated 4 hours；It after insulation completes, is warming up to
130-145 DEG C carries out reflux dewatering；After being cooled to 80 DEG C, add 27.6 grams of dimethylbenzene, filter after stirring, obtain acrylic acid
Resin 2, stand-by.
50 grams of dimethylbenzene, 10 grams of EVA-1 are put in reaction pot, heat temperature raising, open stirring；After temperature is raised to 105 DEG C,
Insulation 40min.After insulation terminates, open cooling water, after being cooled to 75 DEG C, in the state of opening stirring, add 40 grams of acetic acid
Butyl ester, is kept stirring for uniform state being cooled to normal temperature, is filtrated to get 10wt%EVA-1 wax slurry, stand-by.
40 grams of acrylic resins the 2nd, 4 grams of dimethylbenzene, 2 grams of BYK-104S and 0.5 gram of organobentonite are put into container respectively
In, after dispersed with stirring to uniform state, in the state of low rate mixing, putting into 55 grams of R930 titanium dioxides, high-speed stirred is disperseed
60min.By finely dispersed Titanium dioxide slurry through grinder be ground to fineness less than or equal to 20 μm technology require after,
It is filtrated to get titanium dioxide slurry, stand-by；70 grams of acrylic resins the 2nd, 15 grams of dimethylbenzene, 3 grams of butanol, 2 grams of BYK-ATU are put into respectively
In container, after dispersed with stirring to uniform state, putting into 10 grams of S173M phthalocyanine blues in the state of low rate mixing, high-speed stirred is divided
Dissipate 90min.Finely dispersed phthalocyanine blue slurry is ground to fineness being less than or equal to through grinder the technology requirement of 20 μm
After, it is filtrated to get phthalocyanine blue slurry, stand-by.
20 grams of acrylic resins the 2nd, 30 grams of dimethylbenzene, 4 grams of 10wt%EVA-1 wax slurries, 1 gram of BYK-130 are put into respectively
In container, stirring, to after being uniformly dispersed, puts into 2500 mesh talcum powder CMS-888 fillers, high-speed stirring in the state of low rate mixing
It after mixing dispersion 30min, is filtrated to get extender paste, stand-by.
Putting in a reservoir respectively by 35 grams of acrylic resins the 1st, 5 grams of 10wt%EVA-1 wax slurries, dispersed with stirring is to uniform shape
State, in the state of low rate mixing, puts into 19 grams of titanium dioxide slurries, 18 grams of phthalocyanine blue slurries and 23 grams of extender pastes, and stirring point respectively
It is dissipated to uniform state, i.e. obtain the encaustic tile paint being applicable to tiled surface, decoration and protective value being provided.Sampling carries out performance test
(parameter is shown in Table 2), performance filters after meeting the requirements, packaging.
Table 2
Embodiment 2
By 18.4 grams of methyl methacrylates, 21 grams of butyl methacrylates, 0.6 gram of methacrylic acid and 0.24 gram of peroxide
Change benzene dibenzoyl to mix, become mix monomer C；25 grams of dimethylbenzene are added reaction pot, and heat temperature raising simultaneously opens stirring；
When reaction pot temperature rises to 105 DEG C, starting to drip mix monomer C, time for adding controls during 2.5-3h, dropping, should
Control the temperature of reaction pot in the range of 105-115 DEG C；After mix monomer C dropping finishes, at the temperature model of 105-115 DEG C
Enclose insulation 2 hours, be subsequently adding 0.1 gram of benzoyl peroxide dibenzoyl, be incubated 2 hours more simultaneously；Insulation is warming up to 115-125 DEG C
Carry out reflux dewatering；After being cooled to 80 DEG C, add 34.66 grams of dimethylbenzene, filter after stirring, obtain acrylic resin 3, treat
With.
By 35.5 grams of acrylic resins the 3rd, 7 grams of dimethylbenzene, 5.5 grams of butanol, 1.5 grams of BYK-104S, 0.5 gram of organobentonites
Put into respectively in container, after dispersed with stirring to uniform state, in the state of low rate mixing, put into 50 grams of R930 titanium dioxides, at a high speed
Dispersed with stirring 60min.Finely dispersed Titanium dioxide slurry is ground to fineness being less than or equal to through grinder the skill of 20 μm
It after art requires, is filtrated to get titanium dioxide slurry, stand-by；By 58 grams of acrylic resins the 3rd, 18 grams of dimethylbenzene, 3 grams of butanol, 9 grams of acetic acid fourths
Ester, put into respectively in container for 2 gram 928, after dispersed with stirring to uniform state, put in 10 grams of N220 in the state of low rate mixing
Colour black, high-speed stirred disperses 90min.Super carbon black slurry in finely dispersed is ground to fineness little through grinder
It after the technology equal to 20 μm requires, is filtrated to get middle colour black slurry, stand-by.By 55 grams of acrylic resins the 3rd, 8 grams of dimethylbenzene,
1.5 grams of BYK-ATU, 0.5 gram of organobentonite put in container, respectively after dispersed with stirring to uniform state, at low rate mixing
Putting into 35 gram of 3602 iron oxide red under state, high-speed stirred disperses 90min.By finely dispersed iron oxide red slurry through grinding
Machine be ground to fineness less than or equal to 20 μm technology require after, be filtrated to get iron oxide red slurry, stand-by.
In the state of stirring at low speed, by 60 grams of acrylic resins the 3rd, 1.5 grams of butanol, 3 grams of o-phthalic acid dibutyl esters,
0.5 gram of BYK-306,30 grams of titanium dioxide slurries, colour black slurry, 2 grams of iron oxide reds slurries put into containers item by item in 3 grams, and dispersed with stirring is extremely
Uniform state, i.e. obtains the encaustic tile paint being applicable to tiled surface, providing decoration and protective value.Sampling carries out performance test (ginseng
Number is shown in Table 3), performance filters after meeting the requirements, packaging.
Table 3
Embodiment 3
By 14.4 grams of methyl methacrylates, 25 grams of butyl methacrylates, 0.6 gram of methacrylic acid and 0.25 gram of peroxide
Change benzene dibenzoyl to mix, become mix monomer C；27 grams of toluene are added reaction pot, and heat temperature raising simultaneously opens stirring；When
When reaction pot temperature rises to 105 DEG C, starting to drip mix monomer C, time for adding controls during 2.5-3h, dropping, Ying Jiang
The temperature of reaction pot controls in the range of 105-115 DEG C；After mix monomer C dropping finishes, the temperature range of 105-115 DEG C
It is incubated 2 hours, is subsequently adding 0.12 gram of benzoyl peroxide dibenzoyl, be incubated 2 hours more simultaneously；Insulation is warming up to 115-125 DEG C
Carry out reflux dewatering；After being cooled to 80 DEG C, add 32.63 grams of dimethylbenzene, filter after stirring, obtain acrylic resin 3, treat
With.
By 58 grams of acrylic resins the 3rd, 18 grams of dimethylbenzene, 3 grams of butanol, 9 grams of butyl acetates, put into container respectively for 2 gram 928
In, after dispersed with stirring to uniform state, in the state of low rate mixing, putting into colour black in 10 grams of N220, high-speed stirred is disperseed
90min.Super carbon black slurry in finely dispersed is ground to the technology less than or equal to 20 μm for the fineness requiring through grinder
After, it is filtrated to get middle colour black slurry, stand-by.By 55 grams of acrylic resins the 3rd, 8 grams of dimethylbenzene, 1.5 grams of BYK-ATU, 0.5 gram have
Machine bentonite puts in container respectively, after dispersed with stirring to uniform state, puts into 35 gram of 3602 oxygen in the state of low rate mixing
Changing iron oxide red, high-speed stirred disperses 90min.Finely dispersed iron oxide red slurry is ground to fineness being less than through grinder
It after technology equal to 20 μm requires, is filtrated to get iron oxide red slurry, stand-by.
In the state of stirring at low speed, by 60 grams of acrylic resins the 3rd, 1.5 grams of butanol, 3 grams of o-phthalic acid dibutyl esters,
0.5 gram of BYK-306, colour black slurry, 19 grams of iron oxide reds slurries put into containers item by item in 16 grams, dispersed with stirring to uniform state,
I.e. obtain the encaustic tile paint being applicable to tiled surface, decoration and protective value being provided.Sampling carries out performance test (parameter is shown in Table 4),
Performance filters after meeting the requirements, packaging.
Table 4
The encaustic tile paint of the present invention is to be coordinated by acrylic resin the 1st, acrylic resin the 2nd, the acrylic resin 3 of autonomous synthesis
Use, as film-forming resin base-material, by face, filler select with compounding, auxiliary agent select selection with compounding and solvent with
Compound and disperse to reach predetermined fineness by milling apparatus, being finally reached and tiled surface, offer decoration and protection are provided
Functional requirement.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, on the premise of without departing from the inventive method, can also make some improvement and supplementary, and these improve and supplement and also should be regarded as
Protection scope of the present invention.
Claims (3)
1. the encaustic tile paint for tiled surface, it is characterised in that: this encaustic tile paint by acrylic resin, face, filler, auxiliary agent and
Solvent forms；By weight percentage, this encaustic tile paint is composed of the following components:
Wherein, acrylic resin 2 is by butyl acrylate, acrylic acid, styrene, dimethylbenzene, dibenzoyl peroxide and peroxidating
Diisopropylbenzene (DIPB) synthesizes, and acrylic resin 1 is by butyl methacrylate, trimethylbenzene, dimethylbenzene, methyl methacrylate, methyl-prop
Olefin(e) acid and peroxidized t-butyl perbenzoate synthesis, acrylic resin 3 is by butyl methacrylate, toluene, dimethylbenzene, metering system
Acid methyl esters, methacrylic acid and dibenzoyl peroxide synthesis；
Described pigment is in pigment iron oxide red, rutile titanium dioxide, chrome yellow, iron oxide yellow, phthalocyanine blue, middle colour black
One or more, filler is 2500 mesh talcum powder；
Described auxiliary agent is selected from the BYK-130 of Byk Chemie GmbH, BYK-ATU, BYK-104S, BYK-306, this public affairs of hamming
928th, the BASF Aktiengesellschaft EVA-1 OPE of department, organobentonite, the one in dioctyl phthalate or
Several mixtures；
Described BASF Aktiengesellschaft's EVA-1 OPE comes into operation after making wax slurry, and wax is starched by weight percentage
Meter consists of the following composition:
EVA-1 OPE 5-15 weight %
Butyl acetate 40-60 weight %
Dimethylbenzene 30-60 weight %；
By weight percentage, described acrylic resin 1 is composed of the following components:
Described acrylic resin 2 is composed of the following components:
Described acrylic resin 3 is composed of the following components:
2. a kind of encaustic tile paint for tiled surface according to claim 1, it is characterised in that: in described face, filler
Pigment iron oxide red be the 3602 of Shanghai Yipin Pigments Co., Ltd., rutile titanium dioxide be Japan stone originate in industry strain formula
The R930 of commercial firm, chrome yellow is the 103 of Shanghai Chrome Yellow Plant, and iron oxide yellow is the 4920 or 3910 of bright Sheng pigment Shanghai Co., Ltd,
Phthalocyanine blue is L6875 or L7101 of the S173 of Shanghai Chemical Co., Ltd. of alliance or Basf China Co., Ltd, middle pigment carbon
Black is the N220 of Shanghai Li Shi Chemical Co., Ltd., and filler 2500 mesh talcum powder is the CMS-of Heshan chemical industry (Liaoning) Co., Ltd
888。
3. it described in a claim 1, is applicable to the application of the encaustic tile paint of tile, it is characterised in that: this is applicable to the encaustic tile of tile
Paint application is painted on tile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410053821.1A CN103788804B (en) | 2014-02-18 | 2014-02-18 | A kind of encaustic tile paint for tiled surface and its preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410053821.1A CN103788804B (en) | 2014-02-18 | 2014-02-18 | A kind of encaustic tile paint for tiled surface and its preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103788804A CN103788804A (en) | 2014-05-14 |
| CN103788804B true CN103788804B (en) | 2016-11-09 |
Family
ID=50664880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410053821.1A Active CN103788804B (en) | 2014-02-18 | 2014-02-18 | A kind of encaustic tile paint for tiled surface and its preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103788804B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104231809A (en) * | 2014-09-30 | 2014-12-24 | 句容金猴机械研究所有限公司 | Encaustic tile paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5063008A (en) * | 1973-10-08 | 1975-05-29 | ||
| JPS5373231A (en) * | 1976-12-13 | 1978-06-29 | Kansai Paint Co Ltd | Coating for cement roof tile |
| CN101020793A (en) * | 2007-03-14 | 2007-08-22 | 四川蓝雅精工科技发展有限公司 | Prepn process of titania-silica color glaze pigment-filler for ceramic |
| CN101761013A (en) * | 2008-12-29 | 2010-06-30 | 许春雷 | Colored multilayer regenerated aggregate concrete kerbstone |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1506420A (en) * | 2002-12-11 | 2004-06-23 | 上海材料研究所 | Color cement tile paint and its prepn process |
| CN1891769A (en) * | 2005-07-05 | 2007-01-10 | 上海材料研究所 | Colour cement tile coating, and its preparing process |
| CN101575219A (en) * | 2008-05-05 | 2009-11-11 | 铜陵麒麟涂料有限责任公司 | Water-based encarpus tile coating and preparation method thereof |
-
2014
- 2014-02-18 CN CN201410053821.1A patent/CN103788804B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5063008A (en) * | 1973-10-08 | 1975-05-29 | ||
| JPS5373231A (en) * | 1976-12-13 | 1978-06-29 | Kansai Paint Co Ltd | Coating for cement roof tile |
| CN101020793A (en) * | 2007-03-14 | 2007-08-22 | 四川蓝雅精工科技发展有限公司 | Prepn process of titania-silica color glaze pigment-filler for ceramic |
| CN101761013A (en) * | 2008-12-29 | 2010-06-30 | 许春雷 | Colored multilayer regenerated aggregate concrete kerbstone |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103788804A (en) | 2014-05-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101845258B (en) | Low-volatility and quick-drying aqueous toy coating and preparation method thereof | |
| CN101481584B (en) | Dry powder latex paint for inner wall and preparation thereof | |
| CN103555115B (en) | A kind of galvanized sheet coating and preparation method thereof | |
| CN104845446A (en) | High-weather-resistance printing ink, as well as preparation method and application thereof | |
| CN101935487A (en) | Automatic temperature control infrared radiation coating and application thereof | |
| CN103788862A (en) | Two-component matte polyurethane top-coat paint and preparation method thereof | |
| CN102993941A (en) | Environment-friendly wood paint | |
| CN110041772A (en) | A kind of container water paint special and preparation method thereof | |
| CN104231685A (en) | Water-based UV paint used on organic glass, and preparation method thereof | |
| CN104311728A (en) | Thermoplastic acrylic resin for water transfer printing, preparation method of thermoplastic acrylic resin and water transfer printing ink composition | |
| CN105694563A (en) | Water-resistant paint | |
| CN103788804B (en) | A kind of encaustic tile paint for tiled surface and its preparation method and application | |
| CN107974121A (en) | The formula and production method of a kind of drawing pigment | |
| CN105348908A (en) | Metal color glass printing ink | |
| CN104119754A (en) | Acrylate series colorful coating material | |
| CN103588419B (en) | Method for preparing quartz plate with changeable colors | |
| CN103820998B (en) | PVC synthetic leather surface conditioning agent, PVC synthetic leather and preparation method thereof | |
| CN102101956B (en) | Preparation method of low-carbon light reflecting energy-saving coating | |
| CN103614060A (en) | Polyurethane brilliant white finish based on construction tolerance | |
| CN108864811A (en) | A kind of two-way mirror ink and preparation method thereof that weatherability is good | |
| CN103708849B (en) | A kind of ceramic ink jet printing colorant and preparation method thereof | |
| CN103952043B (en) | Universal lacquer and preparation method thereof, universal paint | |
| CN104861827A (en) | Solvent-free epoxy self-leveling floor coating suitable for low-temperature environment | |
| CN104530943A (en) | Wear-resistant polyurea terrace coating and preparation method and application thereof | |
| CN101591481B (en) | Inorganic dry powder painting |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 201108 Guanghua Road, Shanghai, Minhang District No. 521 Patentee after: Shanghai Huayi Fine Chemical Co., Ltd. Shanghai paint factory Address before: 201108 Guanghua Road, Shanghai, Minhang District No. 521 Patentee before: Shanghai Paint Manufacture Factory |
|
| CP01 | Change in the name or title of a patent holder | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190603 Address after: 201512 Huadao 707, Jinshan District, Shanghai Patentee after: SHANGHAI HUAYI PAINT CO., LTD. Address before: No. 521 Guanghua Road, Minhang District, Shanghai 201108 Patentee before: Shanghai Huayi Fine Chemical Co., Ltd. Shanghai paint factory |
|
| TR01 | Transfer of patent right |