CN103788328B - 氧化自交联型水性丙烯酸聚氨酯分散体及其制备方法 - Google Patents
氧化自交联型水性丙烯酸聚氨酯分散体及其制备方法 Download PDFInfo
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- CN103788328B CN103788328B CN201310393559.0A CN201310393559A CN103788328B CN 103788328 B CN103788328 B CN 103788328B CN 201310393559 A CN201310393559 A CN 201310393559A CN 103788328 B CN103788328 B CN 103788328B
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/67—Unsaturated compounds having active hydrogen
- C08G18/671—Unsaturated compounds having only one group containing active hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
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Abstract
Description
A1 | A2 | A3 | A4 | |
不饱和脂肪酸 | ||||
亚麻油酸 | 40 | 40 | ||
妥尔油酸 | 40 | |||
亚油酸 | 40 | |||
单体混合物 | ||||
甲基丙烯酸甲酯 | 40 | 14 | 14 | |
甲基丙烯酸正丁酯 | 40 | 18 | 12 | |
苯乙烯 | 6 | |||
乙烯基甲苯 | 6 | 6 | 12 | |
甲基丙烯酸 | 12 | 12 | 20 | 20 |
过氧化二叔丁基醚 | 2 | 2 | ||
过氧化苯甲酸叔丁酯 | 2 | 2 | ||
酸值(mgKOH/g) | 156 | 156 | 210 | 210 |
B1 | B2 | B3 | B4 | |
丙烯酸预聚物A | ||||
A1 | 175 | |||
A2 | 175 | |||
A3 | 175 | |||
A4 | 175 | |||
不饱和脂肪酸 | ||||
亚麻油酸 | 70 | |||
亚油酸 | 70 | |||
妥尔油酸 | 70 | 70 | ||
二元醇或多元醇 | ||||
三羟甲基丙烷 | 70 | 70 | 70 | 70 |
助溶剂 | ||||
二丙二醇二甲醚 | 70 | 70 | ||
丙酮 | 70 | 70 | ||
异氰酸酯化合物 | ||||
异佛尔酮二异氰酸酯 | 65 | 65 | ||
甲苯二异氰酸酯 | 65 | 65 |
Claims (7)
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CN201310393559.0A CN103788328B (zh) | 2013-09-02 | 2013-09-02 | 氧化自交联型水性丙烯酸聚氨酯分散体及其制备方法 |
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CN201310393559.0A CN103788328B (zh) | 2013-09-02 | 2013-09-02 | 氧化自交联型水性丙烯酸聚氨酯分散体及其制备方法 |
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CN103788328A CN103788328A (zh) | 2014-05-14 |
CN103788328B true CN103788328B (zh) | 2015-11-25 |
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CN201310393559.0A Active CN103788328B (zh) | 2013-09-02 | 2013-09-02 | 氧化自交联型水性丙烯酸聚氨酯分散体及其制备方法 |
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Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104211904B (zh) * | 2014-08-28 | 2016-12-07 | 江苏兴文包装有限公司 | 环保型植物油基聚氨酯连结料树脂、瓦楞纸板油墨及制法 |
CN105131816A (zh) * | 2015-08-27 | 2015-12-09 | 岳西县盛宏工贸有限责任公司 | 一种金属用纤维涂料及其制备方法 |
CN105131814A (zh) * | 2015-08-27 | 2015-12-09 | 岳西县盛宏工贸有限责任公司 | 一种金属用锌钡白涂料及其制备方法 |
CN105349022A (zh) * | 2015-11-30 | 2016-02-24 | 上海华谊精细化工有限公司 | 一种丙烯酸改性阴离子水性氨酯油分散体及其制备和以其为基料的木器涂料 |
CN105348487B (zh) * | 2015-12-16 | 2018-03-20 | 江南大学 | 一种蓖麻油酸基uv固化水性树脂的制备方法 |
CN106317370A (zh) * | 2016-08-29 | 2017-01-11 | 佛山市高明同德化工有限公司 | 一种水性聚氨酯丙烯酸酯其制备方法及其水性涂料 |
CN109897172B (zh) * | 2017-12-11 | 2021-06-29 | 万华化学集团股份有限公司 | 醇酸树脂及聚氨酯和丙烯酸酯改性醇酸树脂的制备方法及应用 |
CN107955101A (zh) * | 2017-12-19 | 2018-04-24 | 上海华谊精细化工有限公司 | 一种氧化交联型水性丙烯酸乳液的制备方法 |
CN108219106B (zh) * | 2017-12-26 | 2020-08-28 | 万华化学(宁波)有限公司 | 一种水性聚氨酯-丙烯酸酯杂化共聚物及其制备方法 |
CN109082220A (zh) * | 2018-06-22 | 2018-12-25 | 安徽菱湖漆股份有限公司 | 一种双组份环保型烟草机械防腐装饰面漆及其制备方法 |
CN108977096A (zh) * | 2018-08-02 | 2018-12-11 | 佛山市高明区爪和新材料科技有限公司 | 一种耐水型聚氨酯胶膜的制备方法 |
CN110951040B (zh) * | 2019-12-06 | 2022-04-12 | 嘉兴学院 | 一种阳离子水性聚氨酯皮革固色剂及其制备方法 |
CN111234687A (zh) * | 2020-03-10 | 2020-06-05 | 浙江华德新材料有限公司 | 一种自交联丙烯酸聚氨酯分散体水性多彩涂料及制备方法 |
CN111234686A (zh) * | 2020-03-10 | 2020-06-05 | 浙江华德新材料有限公司 | 一种自交联丙烯酸聚氨酯分散体真石漆及其制备方法 |
CN114395822A (zh) * | 2021-09-01 | 2022-04-26 | 长春工业大学 | 一种物理与化学协同超疏水的水性聚氨酯膜的制备方法 |
Citations (2)
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CN102408537A (zh) * | 2011-09-19 | 2012-04-11 | 福建宝利特新材料科技有限公司 | 一种合成革用丙烯酸酯改性水性聚氨酯乳液的制备方法 |
CN102827325A (zh) * | 2012-08-27 | 2012-12-19 | 上海涂料有限公司技术中心 | 一种核壳型聚氨酯/丙烯酸复合乳液的制备方法及其应用 |
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MY149508A (en) * | 2007-07-05 | 2013-09-13 | Univ Malaya | Environmentally friendly natural oil-based toner resin |
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CN102408537A (zh) * | 2011-09-19 | 2012-04-11 | 福建宝利特新材料科技有限公司 | 一种合成革用丙烯酸酯改性水性聚氨酯乳液的制备方法 |
CN102827325A (zh) * | 2012-08-27 | 2012-12-19 | 上海涂料有限公司技术中心 | 一种核壳型聚氨酯/丙烯酸复合乳液的制备方法及其应用 |
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Address after: 200331 Jingtai Road, No. 709, building 2, building 201, room, room 2 Patentee after: Shanghai Huayi Fine Chemical Co., Ltd. Technology Center Address before: 200062 Shanghai city Putuo District Yunling Road No. 345 Patentee before: Shanghai Coating Co., Ltd.Technology Center |
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Effective date of registration: 20170327 Address after: 200020 Shaanxi South Road, Shanghai, No. 345 Patentee after: SHANGHAI HUAYI FINE CHEMICAL CO., LTD. Address before: 200331 Jingtai Road, No. 709, building 2, building 201, room, room 2 Patentee before: Shanghai Huayi Fine Chemical Co., Ltd. Technology Center |