CN103774424B - The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod - Google Patents
The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod Download PDFInfo
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- CN103774424B CN103774424B CN201410011175.2A CN201410011175A CN103774424B CN 103774424 B CN103774424 B CN 103774424B CN 201410011175 A CN201410011175 A CN 201410011175A CN 103774424 B CN103774424 B CN 103774424B
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- carbon fiber
- fishing rod
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Abstract
The invention discloses the corrosion-resistant carbon fiber modifying agent of a kind of fishing rod, by obtained after the raw material blending of following weight parts: tri (propylene glycol) diacrylate 6-8, phenyl glycidyl ether 1-2, trimethylolpropane triacrylate 3-4, phosphate 1-2, lemon oil 1-2, acetyl triethyl citrate 2-3, dimethicone 1-2, auxiliary agent 4-5; The carbon fiber corrosion resistance and good that the present invention obtains, after obtained fishing rod, the life-span is long, durable in use, economical.
Description
Technical field
The present invention relates to fishing tackle field, is exactly the corrosion-resistant carbon fiber modifying agent of a kind of fishing rod.
Background technology
Carbon fiber (carbonfiber), as the term suggests it not only has the intrinsic intrinsic property of material with carbon element, having again the soft machinability of textile fabric concurrently, is fortifying fibre of new generation.Compared with traditional glass fibre (GF), Young's modulus is that they are more than 3 times; It is compared with Kafra fiber (KF-49), and not only Young's modulus is its about 2 times, and insoluble not swollen in organic solvent, acid, alkali, and corrosion resistance is transcendent.Have scholar to be immersed in highly basic NaOH solution in 1981 by PAN base CF, time-out goes more than 30 year, and it still keeps fibre morphology so far.
The manufacturing technique of the fine pole of carbon is the same with glass pole, all impregnated fabric is cut into narrow trapezoidal of a head breadth one to twist on conical punching block core, then rolled tightly from the beginning to the end with clear glass band curl, be placed on again in electric furnace and glue is dried, take out from stove again and horizontal core is exited, remove the glass tape on pole body, through repair, polish, draw paint, assembling after fishing pole.Because the cloth of firm dipped glue is soft, glass tape is rolled up again very tight, pole body is strangled into rugged helical form, instead of carbon fiber cloth or glass-fiber-fabric spirality are rolled into.
Summary of the invention
The object of the present invention is to provide the corrosion-resistant carbon fiber modifying agent of a kind of fishing rod
Above-mentioned purpose is realized by following scheme:
The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod, is characterized in that: by obtained after the raw material blending of following weight parts: tri (propylene glycol) diacrylate 6-8, phenyl glycidyl ether 1-2, trimethylolpropane triacrylate 3-4, phosphate 1-2, lemon oil 1-2, acetyl triethyl citrate 2-3, dimethicone 1-2, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: bentonite 2-4, silane coupler DL6022-3, nano-sized molybdenum oxide 1-2, propyl alcohol 5-7, di-n-octyl sebacate 2-4, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2, zinc oxide 1-2, NaOH 0.1-0.2; The preparation method of auxiliary agent is by after each raw material blending, and stir 1-2 hour at 35-38 DEG C after, cooling, to obtain final product.
The corrosion-resistant carbon fiber modifying agent of described a kind of fishing rod, it is characterized in that: using method is: carbon fiber is immersed in carbon fiber surface modifier and take out after 1-2 hour, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 80-90 DEG C of baking oven 12-24h, to obtain final product;
Method is: it is obtained according to carbon fiber fishing rod common manufacturing method by modified carbon fiber raw material;
The corrosion-resistant carbon fiber modifying agent of described a kind of fishing rod, is characterized in that: gained modified carbon fiber using method be: utilize the carbon fibre initial rinse fabric that modified carbon fiber is obtained, conveniently fishing rod preparation technology preparation and fishing rod.
Beneficial effect of the present invention is: the carbon fiber corrosion resistance and good that the present invention obtains, and after obtained fishing rod, the life-span is long, durable in use, economical.
Detailed description of the invention
The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod, by obtained after the raw material blending of following weight kg:
Tri (propylene glycol) diacrylate 8, phenyl glycidyl ether 2, trimethylolpropane triacrylate 3, phosphate 2, lemon oil 2, acetyl triethyl citrate 3, dimethicone 2, auxiliary agent 5;
Auxiliary agent is made up of the raw material of following weight kg: bentonite 4, silane coupler DL6022, nano-sized molybdenum oxide 2, propyl alcohol 7, di-n-octyl sebacate 4, ethoxylated dodecyl alcohol 1, potassium permanganate 0.2, zinc oxide 1, NaOH 0.2; The preparation method of auxiliary agent is by after each raw material blending, and stir after 2 hours at 38 DEG C, cooling, to obtain final product.
The corrosion-resistant carbon fiber modifying agent of described a kind of fishing rod, using method is: immersed by carbon fiber in carbon fiber surface modifier and take out after 1 hour, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 88 DEG C of baking oven 18h, to obtain final product;
Method is: it is obtained according to carbon fiber fishing rod common manufacturing method by modified carbon fiber raw material;
Gained modified carbon fiber using method be: utilize the carbon fibre initial rinse fabric that modified carbon fiber is obtained, conveniently fishing rod preparation technology preparation and fishing rod.
The preparation method of fishing rod is:
(1) will the obtained carbon fibre initial rinse fabric of modified carbon fiber be utilized to have cut for subsequent use;
(2), after the punching block core brushing mould release toasts 10-30 minute at 55-65 DEG C, the carbon fibre initial rinse fabric cut is wound around thereon;
(3) rolled tightly with opp film outside, post-drying, punching block core exits again, and removes the opp film on pole body, after repairing, polish, draw paint, assembling, namely obtain fishing rod.
Prepare the fishing rod of total length 5.3m, test.1000,1500, the weight of 2000g act on the point of fishing rod respectively state under fishing rod is placed in the horizontal plane, thereafter, be center of rotation with fishing rod afterbody the point front end of fishing rod is lifted gradually obliquely from horizontal plane, then, the angle between horizontal plane when weight leaves horizontal plane and fishing rod afterbody is measured.1. described sample is the present embodiment, and 2. described sample is general common carbon fibers fishing rod, and its result as shown in table 1 below.
Table 1
As shown in table 1 with sample 2. compared with, the raising of the present embodiment sample 1. bendability can be found out especially under each different loads.
Claims (3)
1. the corrosion-resistant carbon fiber modifying agent of fishing rod, is characterized in that: by obtained after the raw material blending of following weight parts:
Tri (propylene glycol) diacrylate 6-8, phenyl glycidyl ether 1-2, trimethylolpropane triacrylate 3-4, phosphate 1-2, lemon oil 1-2, acetyl triethyl citrate 2-3, dimethicone 1-2, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: bentonite 2-4, silane coupler DL6022-3, nano-sized molybdenum oxide 1-2, propyl alcohol 5-7, di-n-octyl sebacate 2-4, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2, zinc oxide 1-2, NaOH 0.1-0.2; The preparation method of auxiliary agent is by after each raw material blending, and stir 1-2 hour at 35-38 DEG C after, cooling, to obtain final product.
2. the corrosion-resistant carbon fiber modifying agent of a kind of fishing rod according to claim 1, it is characterized in that: using method is: carbon fiber is immersed in carbon fiber surface modifier and take out after 1-2 hour, with distilled water flushing carbon fiber until rinsing rear liquid is after neutrality, carbon fiber is put into 80-90 DEG C of baking oven 12-24h, to obtain final product;
Method is: it is obtained according to carbon fiber fishing rod common manufacturing method by modified carbon fiber raw material.
3. the corrosion-resistant carbon fiber modifying agent of a kind of fishing rod according to claim 1, is characterized in that: the using method of gained modified carbon fiber is: utilize the carbon fibre initial rinse fabric that modified carbon fiber is obtained, conveniently fishing rod preparation technology prepares and obtains fishing rod.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011175.2A CN103774424B (en) | 2014-01-09 | 2014-01-09 | The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011175.2A CN103774424B (en) | 2014-01-09 | 2014-01-09 | The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103774424A CN103774424A (en) | 2014-05-07 |
| CN103774424B true CN103774424B (en) | 2015-11-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410011175.2A Expired - Fee Related CN103774424B (en) | 2014-01-09 | 2014-01-09 | The corrosion-resistant carbon fiber modifying agent of a kind of fishing rod |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108755140A (en) * | 2018-05-07 | 2018-11-06 | 巢湖市俊业渔具有限公司 | A kind of processing method of high-strength carbon fiber fishing rod |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3853600A (en) * | 1971-05-12 | 1974-12-10 | Celanese Corp | Improved carbon fiber reinforced composite article |
| CN101858037A (en) * | 2010-06-18 | 2010-10-13 | 济南大学 | Emulsion type carbon fiber sizing agent and preparation method and application thereof |
| CN102206919A (en) * | 2011-04-22 | 2011-10-05 | 中国科学院宁波材料技术与工程研究所 | Graphene modified carbon fiber emulsion sizing agent and preparation method thereof |
| CN102212967A (en) * | 2011-04-06 | 2011-10-12 | 东华大学 | Carbon fiber emulsion sizing agent improved by carbon nano tube and preparation method of carbon fiber emulsion sizing agent |
| CN103451931A (en) * | 2012-06-04 | 2013-12-18 | 金发科技股份有限公司 | Carbon fiber surface modifier, modified carbon fiber, composite material, and preparation methods thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001181960A (en) * | 1999-12-22 | 2001-07-03 | Seiji Motojima | Coiled carbon fiber and its manufacturing method |
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2014
- 2014-01-09 CN CN201410011175.2A patent/CN103774424B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3853600A (en) * | 1971-05-12 | 1974-12-10 | Celanese Corp | Improved carbon fiber reinforced composite article |
| CN101858037A (en) * | 2010-06-18 | 2010-10-13 | 济南大学 | Emulsion type carbon fiber sizing agent and preparation method and application thereof |
| CN102212967A (en) * | 2011-04-06 | 2011-10-12 | 东华大学 | Carbon fiber emulsion sizing agent improved by carbon nano tube and preparation method of carbon fiber emulsion sizing agent |
| CN102206919A (en) * | 2011-04-22 | 2011-10-05 | 中国科学院宁波材料技术与工程研究所 | Graphene modified carbon fiber emulsion sizing agent and preparation method thereof |
| CN103451931A (en) * | 2012-06-04 | 2013-12-18 | 金发科技股份有限公司 | Carbon fiber surface modifier, modified carbon fiber, composite material, and preparation methods thereof |
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| CN103774424A (en) | 2014-05-07 |
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Address after: 242100 Langxi City, Anhui Province Town Development Zone Patentee after: ANHUI GUANTING TECHNOLOGY Co.,Ltd. Address before: 242100 Langxi City, Anhui Province Town Development Zone Patentee before: LANG XI PU RUI TAI FISHING TACKLE Co.,Ltd. |
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Effective date of registration: 20210415 Address after: 226100 No. 38 Zhonghua East Road, three Factory Street, Haimen City, Nantong, Jiangsu Patentee after: Nantong an art design Co.,Ltd. Address before: 242100 Cross Town Development Zone, Langxi County, Xuancheng City, Anhui Province Patentee before: ANHUI GUANTING TECHNOLOGY Co.,Ltd. |
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Granted publication date: 20151125 Termination date: 20220109 |