CN108755140A - A kind of processing method of high-strength carbon fiber fishing rod - Google Patents

A kind of processing method of high-strength carbon fiber fishing rod Download PDF

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Publication number
CN108755140A
CN108755140A CN201810423927.4A CN201810423927A CN108755140A CN 108755140 A CN108755140 A CN 108755140A CN 201810423927 A CN201810423927 A CN 201810423927A CN 108755140 A CN108755140 A CN 108755140A
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China
Prior art keywords
parts
carbon fiber
solution
fishing rod
spare
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胡海燕
张俊
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Chaohu Junye Fishing Tackle Co Ltd
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Chaohu Junye Fishing Tackle Co Ltd
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Priority to CN201810423927.4A priority Critical patent/CN108755140A/en
Publication of CN108755140A publication Critical patent/CN108755140A/en
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    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/54Component parts, details or accessories; Auxiliary operations, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing
    • B29C70/545Perforating, cutting or machining during or after moulding
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
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    • C08K7/06Elements
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    • C08K9/08Ingredients agglomerated by treatment with a binding agent
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Abstract

The invention discloses a kind of processing methods of high-strength carbon fiber fishing rod, include the following steps:(1)Modified reinforcing filler preparation,(2)Carbon fiber modifying processing,(3)It is prepared by finished product fishing rod.Improvement is optimized to the processing method of carbon fiber fishing rod in the present invention, and the mechanical properties such as fishing rod intensity obtained, flexibility significantly improve, and with good corrosion resistant, heatproof, anti-aging property, comprehensive to use good quality, long lifespan.

Description

A kind of processing method of high-strength carbon fiber fishing rod
Technical field
The invention belongs to fishing gear processing technique fields, and in particular to a kind of processing method of high-strength carbon fiber fishing rod.
Background technology
Carbon fiber(carbon fiber), as its name suggests, it not only has the intrinsic intrinsic property of carbon material, and has both spinning The soft machinability of textured fiber is reinforcing fiber of new generation.Compared with traditional glass fibre (GF), Young's modulus is it More than 3 times;It is compared with Kafra fiber (KF-49), and not only Young's modulus is its 2 times or so, and organic solvent, Insoluble and in-expandable in acid, alkali, corrosion resistance are transcendent.There is scholar that PAN bases CF is immersed in highly basic NaOH in 1981 In solution, time-out is gone more than 30 years, it still keeps fibre morphology so far.
The manufacturing process of carbon fiber pole is all that impregnated fabric is cut into an one wide narrow trapezoidal volume in circle as glass pole On tapered steel mold core, then rolled tightly from the beginning to the end with transparent glass band is spiral, then be placed in electric furnace and dry glue, then Taken out from stove and exit horizontal core, remove the glass tape in rod body, trimmed, polishing, draw after paint, assembly fishing pole.Due to The cloth softness of rigid dipped glue, glass tape are rolled up very tight again, and rod body is strangled into rugged helical form, rather than carbon fiber cloth or glass What fine cloth was helically rolled into.
Fishing rod made of carbon fiber is a category and the essential article of rodman common in existing fishing gear, For the fishing rod of other materials, carbon fiber fishing rod has the characteristics that light, high-strength.Application No. is: 201410011138.1 disclosing a kind of high-strength carbon fiber fishing rod, carbon fiber fishing rod good bending property obtained;But its intensity Characteristic there are no special enhancing, and being constantly progressive with society, and people propose higher for the quality of carbon fiber fishing rod Requirement.
Invention content
The purpose of the present invention is for existing problem, provide a kind of processing method of high-strength carbon fiber fishing rod.
The present invention is achieved by the following technical solutions:
A kind of processing method of high-strength carbon fiber fishing rod, includes the following steps:
(1)It is prepared by modified reinforcing filler:
A. hydrotalcite powder is first put into 5 ~ 7min of immersion treatment in salpeter solution, filters out put into sodium hydroxide solution after the completion Middle 6 ~ 8min of immersion treatment is filtered out put into 3 ~ 5min of immersion treatment in ethanol solution after the completion, finally filters out and use deionization again Water is spare after rinsing one time;After acid-base solution and alcoholic solution cleaning treatment, the impurity component on hydrotalcite powder surface is eliminated, is Subsequent processing is laid a good foundation;
B. will operation a treated that hydrotalcite powder is put into calcining furnace, it is 800 ~ 860 that heating, which keeps the temperature in calcining furnace, DEG C, it is taken out after 1 ~ 1.5h of calcination processing spare;Calcination processing effectively improves the specific surface area and reactivity of hydrotalcite powder;
C. will operation b treated that hydrotalcite powder is put into solution A, it is 50 ~ 55 DEG C that heating, which keeps the temperature of solution A, high speed It is filtered out after 30 ~ 35min of stir process spare;The solution A by following parts by weight material composition:4 ~ 8 parts of calcium carbonate, 3 ~ 6 Part citric acid, 12 ~ 15 parts of magnesium chlorides, 300 ~ 400 parts of deionized waters;In the environment of weak acid, carbanion in solution A and Magnesium ion to the anion in hydrotalcite powder exchange and substituted, and effectively enhances dispersion, the compatibility of hydrotalcite powder, and Improve its stability and reactivity;
D. will operation c treated that hydrotalcite powder is put into solution B, it is 62 ~ 68 DEG C that heating, which keeps the temperature of solution B, simultaneously It is ultrasonically treated, is filtered out after 35 ~ 40min spare;The solution B by following parts by weight material composition:5 ~ 8 parts of nanometers two Titanium oxide, 7 ~ 10 parts of gelatin, 10 ~ 12 parts of neopelexes, 1 ~ 3 part of trimethyloctadecyl ammonium chloride, 200 ~ 220 parts Deionized water;Under the processing of ultrasonic wave, nano-titanium dioxide intercalation is fixed on the interlayer of hydrotalcite powder, improve its intensity, Heatproof, corrosion resistant quality, while gelatin particle refinement is equally filled in interlayer, plays the role of elastomer, enhances hydrotalcite The rebound of powder, the slip characteristic of piece interlayer, so as to improve the filling using effect of hydrotalcite powder;
E. will operation d treated that hydrotalcite powder is put into drying box, take out to obtain modified reinforcing filler after being dried 1 ~ 2h It is spare;
(2)Carbon fiber modifying processing:
A. following substance is weighed by corresponding parts by weight:10 ~ 15 parts of titanate coupling agents, 4 ~ 7 parts of crosslinking agents, 8 ~ 12 parts of poly alkyl alcohols Ethylene oxide ether, 3 ~ 6 parts of calcium stearates, 20 ~ 25 parts of glycerine, 12 ~ 16 parts of ethyl acetate, 7 ~ 11 parts of six propylene of dipentaerythrite Acid esters, 2 ~ 4 parts of sodium pyrophosphates, 5 ~ 10 parts of polyethylene glycol, 15 ~ 20 parts of steps(1)Modified reinforcing filler obtained, 300 ~ 340 parts Deionized water;
B. all substances that a is weighed will be operated to be put into agitator tank jointly, it is standby to obtain solution C after 20 ~ 25min of high-speed stirred processing With;
C. carbon fiber is put into solution C made from operation b, it is 58 ~ 63 DEG C that heating, which keeps the temperature of solution C, immersion treatment 1 It is taken out after ~ 2h spare;
D. will operation c treated that carbon fiber is put into drying box, be dried after 8 ~ 10h take out modified carbon fiber is standby With;
(3)It is prepared by finished product fishing rod:
A. by step(2)Carbon fibre initial rinse fabric is made in the modified carbon fiber of gained according to a conventional method, has cut spare;
B. it is toasted under the conditions of the punching block core for brushing mould release being placed in 55 ~ 65 DEG C after handling 15 ~ 20min, then operation a is cut Good carbon fibre initial rinse fabric is wrapped on punching block core, is then rolled tightly with glass tape, is then dried outside again, and by punching block Core takes out, removes glass tape in rod body, and last trimmed, polishing gets product fishing rod after drawing paint, assembly.
Further, step(1)The mass fraction for operating the salpeter solution described in a is 6 ~ 8%, the sodium hydroxide The mass fraction of solution is 7 ~ 10%, and the volume fraction of the ethanol solution is 25 ~ 30%.
Further, step(1)The speed of agitator for operating the high-speed stirred processing described in c is 2000 ~ 2400 revs/min Clock.
Further, step(1)The frequency for operating the supersound process described in d is 200 ~ 220kHz.
Further, step(1)The temperature control operated in the drying box described in e is 90 ~ 100 DEG C.
Further, step(2)The speed of agitator for operating the high-speed stirred processing described in b is 3000 ~ 4000 revs/min Clock.
Further, step(2)The temperature control operated in the drying box described in d is 80 ~ 85 DEG C.
The present invention has carried out improvement processing to the processing method of carbon fiber fishing rod, and it is special especially to have been carried out to carbon fiber Modification is added to a kind of special modified enhancing wherein having prepared a kind of solution C for carbon fiber modifying in solution C Filler is modified by base matter of hydrotalcite powder, and hydrotalcite powder has special multilayered structure, by modification Its absorption, compatible, heatproof, binding ability are obviously improved afterwards, and in solution C under the mating reaction of other ingredients, modified enhancing is filled out Material grafting is fixed on the surface of carbon fiber, form one layer and wrap layer, in high temperature drying and processing closely with carbon fiber knot It closes and fixes, improve strength characteristics, while because being modified good rebound, the lamella slip characteristic that reinforcing filler itself has, and increase The strong flexibility of carbon fiber fishing rod, improves its synthesis and uses quality.
The present invention has the following advantages compared with prior art:
Improvement is optimized to the processing method of carbon fiber fishing rod in the present invention, the mechanical property such as fishing rod intensity obtained, flexibility It can significantly improve, and with good corrosion resistant, heatproof, anti-aging property, it is comprehensive to use good quality, long lifespan, great popularization Application value.
Specific implementation mode
Embodiment 1
A kind of processing method of high-strength carbon fiber fishing rod, includes the following steps:
(1)It is prepared by modified reinforcing filler:
A. hydrotalcite powder is first put into immersion treatment 5min in salpeter solution, filters out put into sodium hydroxide solution after the completion Immersion treatment 6min is filtered out put into immersion treatment 3min in ethanol solution after the completion, finally filters out and rinsed with deionized water again It is spare after one time;
B. will operation a treated that hydrotalcite powder is put into calcining furnace, it is 800 DEG C that heating, which keeps the temperature in calcining furnace, is forged It is taken out after burning processing 1h spare;
C. will operation b treated that hydrotalcite powder is put into solution A, it is 50 DEG C that heating, which keeps the temperature of solution A, high-speed stirred It is filtered out after processing 30min spare;The solution A by following parts by weight material composition:4 parts of calcium carbonate, 3 parts of citric acids, 12 Part magnesium chloride, 300 parts of deionized waters;
D. will operation c treated that hydrotalcite powder is put into solution B, it is 62 DEG C that heating, which keeps the temperature of solution B, is carried out at the same time It is ultrasonically treated, is filtered out after 35min spare;The solution B by following parts by weight material composition:5 parts of nano-titanium dioxides, 7 Part gelatin, 10 parts of neopelexes, 1 part of trimethyloctadecyl ammonium chloride, 200 parts of deionized waters;
E. will operation d treated that hydrotalcite powder is put into drying box, be dried after 1h take out modified reinforcing filler is standby With;
(2)Carbon fiber modifying processing:
A. following substance is weighed by corresponding parts by weight:10 parts of titanate coupling agents, 4 parts of crosslinking agents, 8 parts of aliphatic alcohol polyethenoxies Ether, 3 parts of calcium stearates, 20 parts of glycerine, 12 parts of ethyl acetate, 7 parts of six acrylate of dipentaerythrite, 2 parts of sodium pyrophosphates, 5 parts of polyethylene glycol, 15 parts of steps(1)Modified reinforcing filler obtained, 300 parts of deionized waters;
B. all substances that a is weighed will be operated to be put into agitator tank jointly, it is spare to obtain solution C after high-speed stirred processing 20min;
C. carbon fiber is put into solution C made from operation b, it is 58 DEG C that heating, which keeps the temperature of solution C, after immersion treatment 1h It takes out spare;
D. will operation c treated that carbon fiber is put into drying box, be dried after 8h take out modified carbon fiber is spare;
(3)It is prepared by finished product fishing rod:
A. by step(2)Carbon fibre initial rinse fabric is made in the modified carbon fiber of gained according to a conventional method, has cut spare;
B. it is toasted under the conditions of the punching block core for brushing mould release being placed in 55 DEG C after handling 15min, then the carbon that operation a has been cut Fiber prepreg is wrapped on punching block core, is then rolled tightly outside with glass tape again, is then dried, and punching block core is taken Go out, remove glass tape in rod body, last trimmed, polishing gets product fishing rod after drawing paint, assembly.
Further, step(1)The mass fraction for operating the salpeter solution described in a is 6%, and the sodium hydroxide is molten The mass fraction of liquid is 7%, and the volume fraction of the ethanol solution is 25%.
Further, step(1)The speed of agitator for operating the high-speed stirred processing described in c is 2000 revs/min.
Further, step(1)The frequency for operating the supersound process described in d is 200kHz.
Further, step(1)The temperature control operated in the drying box described in e is 90 DEG C.
Further, step(2)The speed of agitator for operating the high-speed stirred processing described in b is 3000 revs/min.
Further, step(2)The temperature control operated in the drying box described in d is 80 DEG C.
Embodiment 2
A kind of processing method of high-strength carbon fiber fishing rod, includes the following steps:
(1)It is prepared by modified reinforcing filler:
A. hydrotalcite powder is first put into immersion treatment 6min in salpeter solution, filters out put into sodium hydroxide solution after the completion Immersion treatment 7min is filtered out put into immersion treatment 4min in ethanol solution after the completion, finally filters out and rinsed with deionized water again It is spare after one time;
B. will operation a treated that hydrotalcite powder is put into calcining furnace, it is 830 DEG C that heating, which keeps the temperature in calcining furnace, is forged It is taken out after burning processing 1.2h spare;
C. will operation b treated that hydrotalcite powder is put into solution A, it is 53 DEG C that heating, which keeps the temperature of solution A, high-speed stirred It is filtered out after processing 32min spare;The solution A by following parts by weight material composition:6 parts of calcium carbonate, 5 parts of citric acids, 14 Part magnesium chloride, 360 parts of deionized waters;
D. will operation c treated that hydrotalcite powder is put into solution B, it is 66 DEG C that heating, which keeps the temperature of solution B, is carried out at the same time It is ultrasonically treated, is filtered out after 37min spare;The solution B by following parts by weight material composition:7 parts of nano-titanium dioxides, 9 Part gelatin, 11 parts of neopelexes, 2 parts of trimethyloctadecyl ammonium chlorides, 210 parts of deionized waters;
E. will operation d treated that hydrotalcite powder is put into drying box, take out to obtain modified reinforcing filler after being dried 1.5h It is spare;
(2)Carbon fiber modifying processing:
A. following substance is weighed by corresponding parts by weight:13 parts of titanate coupling agents, 6 parts of crosslinking agents, 10 parts of aliphatic alcohol polyethenoxies Ether, 5 parts of calcium stearates, 23 parts of glycerine, 14 parts of ethyl acetate, 9 parts of six acrylate of dipentaerythrite, 3 parts of sodium pyrophosphates, 8 parts of polyethylene glycol, 17 parts of steps(1)Modified reinforcing filler obtained, 320 parts of deionized waters;
B. all substances that a is weighed will be operated to be put into agitator tank jointly, it is spare to obtain solution C after high-speed stirred processing 23min;
C. carbon fiber is put into solution C made from operation b, it is 60 DEG C that heating, which keeps the temperature of solution C, immersion treatment 1.5h After take out it is spare;
D. will operation c treated that carbon fiber is put into drying box, be dried after 9h take out modified carbon fiber is spare;
(3)It is prepared by finished product fishing rod:
A. by step(2)Carbon fibre initial rinse fabric is made in the modified carbon fiber of gained according to a conventional method, has cut spare;
B. it is toasted under the conditions of the punching block core for brushing mould release being placed in 60 DEG C after handling 18min, then the carbon that operation a has been cut Fiber prepreg is wrapped on punching block core, is then rolled tightly outside with glass tape again, is then dried, and punching block core is taken Go out, remove glass tape in rod body, last trimmed, polishing gets product fishing rod after drawing paint, assembly.
Further, step(1)The mass fraction for operating the salpeter solution described in a is 7%, and the sodium hydroxide is molten The mass fraction of liquid is 9%, and the volume fraction of the ethanol solution is 28%.
Further, step(1)The speed of agitator for operating the high-speed stirred processing described in c is 2200 revs/min.
Further, step(1)The frequency for operating the supersound process described in d is 210kHz.
Further, step(1)The temperature control operated in the drying box described in e is 95 DEG C.
Further, step(2)The speed of agitator for operating the high-speed stirred processing described in b is 3600 revs/min.
Further, step(2)The temperature control operated in the drying box described in d is 83 DEG C.
Embodiment 3
A kind of processing method of high-strength carbon fiber fishing rod, includes the following steps:
(1)It is prepared by modified reinforcing filler:
A. hydrotalcite powder is first put into immersion treatment 7min in salpeter solution, filters out put into sodium hydroxide solution after the completion Immersion treatment 8min is filtered out put into immersion treatment 5min in ethanol solution after the completion, finally filters out and rinsed with deionized water again It is spare after one time;
B. will operation a treated that hydrotalcite powder is put into calcining furnace, it is 860 DEG C that heating, which keeps the temperature in calcining furnace, is forged It is taken out after burning processing 1.5h spare;
C. will operation b treated that hydrotalcite powder is put into solution A, it is 55 DEG C that heating, which keeps the temperature of solution A, high-speed stirred It is filtered out after processing 35min spare;The solution A by following parts by weight material composition:8 parts of calcium carbonate, 6 parts of citric acids, 15 Part magnesium chloride, 400 parts of deionized waters;
D. will operation c treated that hydrotalcite powder is put into solution B, it is 68 DEG C that heating, which keeps the temperature of solution B, is carried out at the same time It is ultrasonically treated, is filtered out after 40min spare;The solution B by following parts by weight material composition:8 parts of nano-titanium dioxides, 10 Part gelatin, 12 parts of neopelexes, 3 parts of trimethyloctadecyl ammonium chlorides, 220 parts of deionized waters;
E. will operation d treated that hydrotalcite powder is put into drying box, be dried after 2h take out modified reinforcing filler is standby With;
(2)Carbon fiber modifying processing:
A. following substance is weighed by corresponding parts by weight:15 parts of titanate coupling agents, 7 parts of crosslinking agents, 12 parts of aliphatic alcohol polyethenoxies Ether, 6 parts of calcium stearates, 25 parts of glycerine, 16 parts of ethyl acetate, 11 parts of six acrylate of dipentaerythrite, 4 parts of pyrophosphoric acids Sodium, 10 parts of polyethylene glycol, 20 parts of steps(1)Modified reinforcing filler obtained, 340 parts of deionized waters;
B. all substances that a is weighed will be operated to be put into agitator tank jointly, it is spare to obtain solution C after high-speed stirred processing 25min;
C. carbon fiber is put into solution C made from operation b, it is 63 DEG C that heating, which keeps the temperature of solution C, after immersion treatment 2h It takes out spare;
D. will operation c treated that carbon fiber is put into drying box, be dried after 10h take out modified carbon fiber is spare;
(3)It is prepared by finished product fishing rod:
A. by step(2)Carbon fibre initial rinse fabric is made in the modified carbon fiber of gained according to a conventional method, has cut spare;
B. it is toasted under the conditions of the punching block core for brushing mould release being placed in 65 DEG C after handling 20min, then the carbon that operation a has been cut Fiber prepreg is wrapped on punching block core, is then rolled tightly outside with glass tape again, is then dried, and punching block core is taken Go out, remove glass tape in rod body, last trimmed, polishing gets product fishing rod after drawing paint, assembly.
Further, step(1)The mass fraction for operating the salpeter solution described in a is 8%, and the sodium hydroxide is molten The mass fraction of liquid is 10%, and the volume fraction of the ethanol solution is 30%.
Further, step(1)The speed of agitator for operating the high-speed stirred processing described in c is 2400 revs/min.
Further, step(1)The frequency for operating the supersound process described in d is 220kHz.
Further, step(1)The temperature control operated in the drying box described in e is 100 DEG C.
Further, step(2)The speed of agitator for operating the high-speed stirred processing described in b is 4000 revs/min.
Further, step(2)The temperature control operated in the drying box described in d is 85 DEG C.
Comparative example 1
This comparative example 1 compared with Example 2, with etc. mass parts commercially available hydrotalcite powder step of replacing(2)Operate the step in a Suddenly(1)Modified reinforcing filler ingredient obtained, method and step all same in addition to this.
Comparative example 2
This comparative example 2 compared with Example 2, eliminates step(2)Operate the step in a(1)Modified enhancing obtained is filled out Expect ingredient, method and step all same in addition to this.
Control group
Application No. is:201410011138.1 disclosing a kind of high-strength carbon fiber fishing rod.
In order to compare effect of the present invention, system is corresponded to above-described embodiment 2, comparative example 1, comparative example 2, control group The carbon fiber fishing rod obtained is tested for the property, and specific correction data is as shown in table 1 below:
Table 1
Note:Load described in upper table 1/angular properties test is control fishing pole length for 5.3m, 1500,2500, The weight of 3500g places fishing rod in the horizontal plane, thereafter, with fishing-rod tail in the state of being respectively acting on the point of fishing rod Portion for center of rotation increasingly slopes lifts the point front end of fishing rod from horizontal plane, then, measures weight and leaves level Angle between horizontal plane when face and fishing rod tail portion.
The intensity of carbon fiber fishing rod and flexility made from the method for the present invention it can be seen from upper table 1 have significantly Improve, synthesis is effectively promoted using quality, and corresponding service life is extended, great popularizing value and city Field competitiveness.

Claims (7)

1. a kind of processing method of high-strength carbon fiber fishing rod, which is characterized in that include the following steps:
(1)It is prepared by modified reinforcing filler:
A. hydrotalcite powder is first put into 5 ~ 7min of immersion treatment in salpeter solution, filters out put into sodium hydroxide solution after the completion Middle 6 ~ 8min of immersion treatment is filtered out put into 3 ~ 5min of immersion treatment in ethanol solution after the completion, finally filters out and use deionization again Water is spare after rinsing one time;
B. will operation a treated that hydrotalcite powder is put into calcining furnace, it is 800 ~ 860 that heating, which keeps the temperature in calcining furnace, DEG C, it is taken out after 1 ~ 1.5h of calcination processing spare;
C. will operation b treated that hydrotalcite powder is put into solution A, it is 50 ~ 55 DEG C that heating, which keeps the temperature of solution A, high speed It is filtered out after 30 ~ 35min of stir process spare;The solution A by following parts by weight material composition:4 ~ 8 parts of calcium carbonate, 3 ~ 6 Part citric acid, 12 ~ 15 parts of magnesium chlorides, 300 ~ 400 parts of deionized waters;
D. will operation c treated that hydrotalcite powder is put into solution B, it is 62 ~ 68 DEG C that heating, which keeps the temperature of solution B, simultaneously It is ultrasonically treated, is filtered out after 35 ~ 40min spare;The solution B by following parts by weight material composition:5 ~ 8 parts of nanometers two Titanium oxide, 7 ~ 10 parts of gelatin, 10 ~ 12 parts of neopelexes, 1 ~ 3 part of trimethyloctadecyl ammonium chloride, 200 ~ 220 parts Deionized water;
E. will operation d treated that hydrotalcite powder is put into drying box, take out to obtain modified reinforcing filler after being dried 1 ~ 2h It is spare;
(2)Carbon fiber modifying processing:
A. following substance is weighed by corresponding parts by weight:10 ~ 15 parts of titanate coupling agents, 4 ~ 7 parts of crosslinking agents, 8 ~ 12 parts of poly alkyl alcohols Ethylene oxide ether, 3 ~ 6 parts of calcium stearates, 20 ~ 25 parts of glycerine, 12 ~ 16 parts of ethyl acetate, 7 ~ 11 parts of six propylene of dipentaerythrite Acid esters, 2 ~ 4 parts of sodium pyrophosphates, 5 ~ 10 parts of polyethylene glycol, 15 ~ 20 parts of steps(1)Modified reinforcing filler obtained, 300 ~ 340 parts Deionized water;
B. all substances that a is weighed will be operated to be put into agitator tank jointly, it is standby to obtain solution C after 20 ~ 25min of high-speed stirred processing With;
C. carbon fiber is put into solution C made from operation b, it is 58 ~ 63 DEG C that heating, which keeps the temperature of solution C, immersion treatment 1 It is taken out after ~ 2h spare;
D. will operation c treated that carbon fiber is put into drying box, be dried after 8 ~ 10h take out modified carbon fiber is standby With;
(3)It is prepared by finished product fishing rod:
A. by step(2)Carbon fibre initial rinse fabric is made in the modified carbon fiber of gained according to a conventional method, has cut spare;
B. it is toasted under the conditions of the punching block core for brushing mould release being placed in 55 ~ 65 DEG C after handling 15 ~ 20min, then operation a is cut Good carbon fibre initial rinse fabric is wrapped on punching block core, is then rolled tightly with glass tape, is then dried outside again, and by punching block Core takes out, removes glass tape in rod body, and last trimmed, polishing gets product fishing rod after drawing paint, assembly.
2. a kind of processing method of high-strength carbon fiber fishing rod according to claim 1, which is characterized in that step(1)Behaviour The mass fraction for making the salpeter solution described in a is 6 ~ 8%, and the mass fraction of the sodium hydroxide solution is 7 ~ 10%, described Ethanol solution volume fraction be 25 ~ 30%.
3. a kind of processing method of high-strength carbon fiber fishing rod according to claim 1, which is characterized in that step(1)Behaviour The speed of agitator for making the high-speed stirred processing described in c is 2000 ~ 2400 revs/min.
4. a kind of processing method of high-strength carbon fiber fishing rod according to claim 1, which is characterized in that step(1)Behaviour The frequency for making the supersound process described in d is 200 ~ 220kHz.
5. a kind of processing method of high-strength carbon fiber fishing rod according to claim 1, which is characterized in that step(1)Behaviour The temperature control made in the drying box described in e is 90 ~ 100 DEG C.
6. a kind of processing method of high-strength carbon fiber fishing rod according to claim 1, which is characterized in that step(2)Behaviour The speed of agitator for making the high-speed stirred processing described in b is 3000 ~ 4000 revs/min.
7. a kind of processing method of high-strength carbon fiber fishing rod according to claim 1, which is characterized in that step(2)Behaviour The temperature control made in the drying box described in d is 80 ~ 85 DEG C.
CN201810423927.4A 2018-05-07 2018-05-07 A kind of processing method of high-strength carbon fiber fishing rod Pending CN108755140A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100795174B1 (en) * 2006-10-04 2008-01-16 주식회사은성사 Carbon fiber for fishing rod with coating carbon nano tube and method for manufacturing of the same and fishing rod by using of the same
CN103770340A (en) * 2014-01-09 2014-05-07 郎溪普瑞泰渔具制造有限公司 High-elasticity carbon fiber fishing rod
CN103774424A (en) * 2014-01-09 2014-05-07 郎溪普瑞泰渔具制造有限公司 Corrosion-resistant carbon fiber modifier for fishing rod
CN103790004A (en) * 2014-01-09 2014-05-14 郎溪普瑞泰渔具制造有限公司 High-strength carbon fiber fishing rod
CN107804989A (en) * 2017-11-02 2018-03-16 马鞍山市宝奕金属制品工贸有限公司 A kind of bentonite filler for construction material manufacture

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100795174B1 (en) * 2006-10-04 2008-01-16 주식회사은성사 Carbon fiber for fishing rod with coating carbon nano tube and method for manufacturing of the same and fishing rod by using of the same
CN103770340A (en) * 2014-01-09 2014-05-07 郎溪普瑞泰渔具制造有限公司 High-elasticity carbon fiber fishing rod
CN103774424A (en) * 2014-01-09 2014-05-07 郎溪普瑞泰渔具制造有限公司 Corrosion-resistant carbon fiber modifier for fishing rod
CN103790004A (en) * 2014-01-09 2014-05-14 郎溪普瑞泰渔具制造有限公司 High-strength carbon fiber fishing rod
CN107804989A (en) * 2017-11-02 2018-03-16 马鞍山市宝奕金属制品工贸有限公司 A kind of bentonite filler for construction material manufacture

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Application publication date: 20181106