CN103770340B - A kind of high resiliency carbon fiber fishing rod - Google Patents
A kind of high resiliency carbon fiber fishing rod Download PDFInfo
- Publication number
- CN103770340B CN103770340B CN201410011171.4A CN201410011171A CN103770340B CN 103770340 B CN103770340 B CN 103770340B CN 201410011171 A CN201410011171 A CN 201410011171A CN 103770340 B CN103770340 B CN 103770340B
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- CN
- China
- Prior art keywords
- carbon fiber
- fishing rod
- raw material
- following weight
- auxiliary agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 30
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 30
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 11
- -1 ethoxylated dodecyl alcohol sodium sulphate Chemical class 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 239000003607 modifier Substances 0.000 claims abstract description 8
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001071 citrus reticulata blanco var. mandarin Substances 0.000 claims abstract description 4
- 239000007822 coupling agent Substances 0.000 claims abstract description 4
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 4
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims abstract description 4
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical class CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims abstract description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229930182478 glucoside Natural products 0.000 claims abstract description 4
- 239000005543 nano-size silicon particle Substances 0.000 claims abstract description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 4
- 229910000077 silane Inorganic materials 0.000 claims abstract description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 4
- 239000001488 sodium phosphate Substances 0.000 claims abstract description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 claims abstract description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 4
- 239000013638 trimer Substances 0.000 claims abstract description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims abstract description 4
- 239000004744 fabric Substances 0.000 claims description 12
- 239000000835 fiber Substances 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 238000004080 punching Methods 0.000 claims description 7
- 239000012467 final product Substances 0.000 claims description 6
- 239000003973 paint Substances 0.000 claims description 4
- 230000001680 brushing effect Effects 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000011521 glass Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/30—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
- B29C70/34—Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K87/00—Fishing rods
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Marine Sciences & Fisheries (AREA)
- Animal Husbandry (AREA)
- Biodiversity & Conservation Biology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of high resiliency carbon fiber fishing rod, it is obtained according to carbon fiber fishing rod common manufacturing method by modified carbon fiber raw material; Obtaining by after the raw material blending of following weight parts of carbon fiber surface modifier: obtaining by after the raw material blending of following weight parts of carbon fiber surface modifier: pentaerythrite 5-6, acrylonitrile 1-2, ethyl acrylate 3-4, mandarin oil 1-2, BTA 1-2, titanate coupling agent TMC-TTS? 1-2,2-methyl methacrylate 1-2, crosslinking agent TAC? 1-2, auxiliary agent 4-5; Auxiliary agent is made up of the raw material of following weight portion: ethoxylated dodecyl alcohol sodium sulphate 1-2, carborundum 0.1-0.2, silane coupler? DL602? 2-3, di-n-octyl sebacate 2-4, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2, sodium phosphate trimer 1-2, alcohol ether glucoside 0.2-0.4, nano silicon 3-4.
Description
Technical field
The present invention relates to fishing tackle field, is exactly a kind of high resiliency carbon fiber fishing rod.
Background technology
Carbon fiber (carbonfiber), as the term suggests it not only has the intrinsic intrinsic property of material with carbon element, having again the soft machinability of textile fabric concurrently, is fortifying fibre of new generation.Compared with traditional glass fibre (GF), Young's modulus is that they are more than 3 times; It is compared with Kafra fiber (KF-49), and not only Young's modulus is its about 2 times, and insoluble not swollen in organic solvent, acid, alkali, and corrosion resistance is transcendent.Have scholar to be immersed in highly basic NaOH solution in 1981 by PAN base CF, time-out goes more than 30 year, and it still keeps fibre morphology so far.
The manufacturing process of the fine pole of carbon is the same with glass pole, all impregnated fabric is cut into narrow trapezoidal of a head breadth one to twist on conical punching block core, then rolled tightly from the beginning to the end with clear glass band curl, be placed on again in electric furnace and glue is dried, take out from stove again and horizontal core is exited, remove the glass tape on pole body, through repair, polish, draw paint, assembling after fishing pole.Because the cloth of firm dipped glue is soft, glass tape is rolled up again very tight, pole body is strangled into rugged helical form, instead of carbon fiber cloth or glass-fiber-fabric spirality are rolled into.
Summary of the invention
The object of the present invention is to provide a kind of high resiliency carbon fiber fishing rod.
Above-mentioned purpose is realized by following scheme:
A kind of high resiliency carbon fiber fishing rod, is characterized in that: preparation method is:
(1) will the obtained carbon fibre initial rinse fabric of modified carbon fiber be utilized to have cut for subsequent use;
(2), after the punching block core brushing mould release toasts 10-30 minute at 55-65 DEG C, the carbon fibre initial rinse fabric cut is wound around thereon;
(3) rolled tightly with opp film outside, hot briquetting at 120-130 DEG C in rear feeding curing oven, punching block core exits, and removes the opp film on pole body again, after repairing, polish, draw paint, assembling, namely obtain fishing rod;
The preparation method of described modified carbon fiber is: immersed by carbon fiber in carbon fiber surface modifier and take out after 1-2 hour, wash to neutrality, carbon fiber is put into 85-95 DEG C of baking oven 12-24h, to obtain final product;
Obtaining by after the raw material blending of following weight parts of carbon fiber surface modifier:
Pentaerythrite 5-6, acrylonitrile 1-2, ethyl acrylate 3-4, mandarin oil 1-2, BTA 1-2, titanate coupling agent TMC-TTS1-2,2-methyl methacrylate 1-2, crosslinking agent TAC1-2, auxiliary agent 4-5; Auxiliary agent is made up of the raw material of following weight portion: ethoxylated dodecyl alcohol sodium sulphate 1-2, carborundum 0.1-0.2, silane coupler DL6022-3, di-n-octyl sebacate 2-4, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2, sodium phosphate trimer 1-2, alcohol ether glucoside 0.2-0.4, nano silicon 3-4.
2, a kind of high resiliency carbon fiber fishing rod according to claim 1, is characterized in that: the preparation method of auxiliary agent is by after each raw material blending, after stirring 5-12 minute, to obtain final product at 32-40 DEG C.
Beneficial effect of the present invention is: the present invention uses special carbon fiber modifying agent, and gained carbon fibre initial rinse fabric interface performance is had clear improvement, and elasticity is high, not fragile, is simple and easy to use, good hand touch of fishing.
Detailed description of the invention
A kind of high resiliency carbon fiber fishing rod, preparation method is:
(1) will the obtained carbon fibre initial rinse fabric of modified carbon fiber be utilized to have cut for subsequent use;
(2) the punching block core brushing mould release toasted after 30 minutes at 65 DEG C, was wound around thereon by the carbon fibre initial rinse fabric cut;
(3) rolled tightly with opp film outside, hot briquetting at 130 DEG C in rear feeding curing oven, punching block core exits, and removes the opp film on pole body again, after repairing, polish, draw paint, assembling, namely obtain fishing rod;
The preparation method of described modified carbon fiber is: immersed by carbon fiber in carbon fiber surface modifier and take out after 2 hours, wash to neutrality, carbon fiber is put into 87 DEG C of baking oven 15h, to obtain final product;
Obtaining by after the raw material blending of following weight (kg) of carbon fiber surface modifier:
Pentaerythrite 6, acrylonitrile 2, ethyl acrylate 4, mandarin oil 2, BTA 2, titanate coupling agent TMC-TTS1,2-methyl methacrylate 2, crosslinking agent TAC2, auxiliary agent 5;
Auxiliary agent is made up of the raw material of following weight (kg): ethoxylated dodecyl alcohol sodium sulphate 1, carborundum 0.2, silane coupler DL6022, di-n-octyl sebacate 2, ethoxylated dodecyl alcohol 2, potassium permanganate 0.2,, sodium phosphate trimer 2, alcohol ether glucoside 0.2, nano silicon 4.
The preparation method of auxiliary agent is by after each raw material blending, stirs after 12 minutes, to obtain final product at 40 DEG C.
Prepare the fishing rod of total length 5.5m, test.1000,1500, the weight of 2000g act on the point of fishing rod respectively state under fishing rod is placed in the horizontal plane, thereafter, be center of rotation with fishing rod afterbody the point front end of fishing rod is lifted gradually obliquely from horizontal plane, then, the angle between horizontal plane when weight leaves horizontal plane and fishing rod afterbody is measured.1. described sample is the present embodiment, and 2. described sample is general common carbon fibers fishing rod, and its result as shown in table 1 below.
Table 1
As shown in table 1 with sample 2. compared with, the raising of the present embodiment sample 2. bendability can be found out especially under each different loads.
Claims (2)
1. a high resiliency carbon fiber fishing rod, is characterized in that: preparation method is:
(1) will the obtained carbon fibre initial rinse fabric of modified carbon fiber be utilized to have cut for subsequent use;
(2), after the punching block core brushing mould release toasts 10-30 minute at 55-65 DEG C, the carbon fibre initial rinse fabric cut is wound around thereon;
(3) rolled tightly with opp film outside, hot briquetting at 120-130 DEG C in rear feeding curing oven, punching block core exits, and removes the opp film on pole body again, after repairing, polish, draw paint, assembling, namely obtain fishing rod;
The preparation method of described modified carbon fiber is: immersed by carbon fiber in carbon fiber surface modifier and take out after 1-2 hour, wash to neutrality, carbon fiber is put into 85-95 DEG C of baking oven 12-24h, to obtain final product;
Carbon fiber surface modifier is by obtained after the raw material blending of following weight parts: pentaerythrite 5-6, acrylonitrile 1-2, ethyl acrylate 3-4, mandarin oil 1-2, BTA 1-2, titanate coupling agent TMC-TTS1-2,2-methyl methacrylate 1-2, crosslinking agent TAC1-2, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: ethoxylated dodecyl alcohol sodium sulphate 1-2, carborundum 0.1-0.2, silane coupler DL6022-3, di-n-octyl sebacate 2-4, ethoxylated dodecyl alcohol 1-2, potassium permanganate 0.1-0.2, sodium phosphate trimer 1-2, alcohol ether glucoside 0.2-0.4, nano silicon 3-4.
2. a kind of high resiliency carbon fiber fishing rod according to claim 1, is characterized in that: the preparation method of auxiliary agent is by after each raw material blending, after stirring 5-12 minute, to obtain final product at 32-40 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011171.4A CN103770340B (en) | 2014-01-09 | 2014-01-09 | A kind of high resiliency carbon fiber fishing rod |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011171.4A CN103770340B (en) | 2014-01-09 | 2014-01-09 | A kind of high resiliency carbon fiber fishing rod |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103770340A CN103770340A (en) | 2014-05-07 |
| CN103770340B true CN103770340B (en) | 2016-03-23 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201410011171.4A Active CN103770340B (en) | 2014-01-09 | 2014-01-09 | A kind of high resiliency carbon fiber fishing rod |
Country Status (1)
| Country | Link |
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| CN (1) | CN103770340B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108755140A (en) * | 2018-05-07 | 2018-11-06 | 巢湖市俊业渔具有限公司 | A kind of processing method of high-strength carbon fiber fishing rod |
| CN110527057B (en) * | 2019-09-10 | 2021-10-19 | 界首市超强渔具有限公司 | Preparation method of light insulating fishing rod material |
| CN114806127B (en) * | 2022-05-10 | 2024-02-20 | 中山市卡邦碳纤维材料制品有限公司 | Carbon fiber pipe and manufacturing method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0383532A (en) * | 1989-08-28 | 1991-04-09 | Daiwa Seiko Inc | Fishing rod and its production |
| JP2000106793A (en) * | 1994-09-06 | 2000-04-18 | Daiwa Seiko Inc | Internally threaded fishing rod |
| JP2001314139A (en) * | 2000-05-10 | 2001-11-13 | Shimano Inc | Fishing rod body |
| KR20020013026A (en) * | 2000-08-10 | 2002-02-20 | 조문수 | fishing rod |
| WO2004064509A1 (en) * | 2003-01-24 | 2004-08-05 | Shimano Inc. | Rod body and fishing rod |
| JP2005027587A (en) * | 2003-07-08 | 2005-02-03 | Shimano Inc | Rod body and fishing rod |
| CN2770352Y (en) * | 2005-03-21 | 2006-04-12 | 孙树刚 | Fishing rod |
| CN201044598Y (en) * | 2007-02-05 | 2008-04-09 | 王峰 | Helix intensified fishing rod |
| CN201674891U (en) * | 2010-05-12 | 2010-12-22 | 励金友 | Fishing rod |
| CN201938235U (en) * | 2011-02-09 | 2011-08-24 | 张龙 | Reinforced fishing rod |
-
2014
- 2014-01-09 CN CN201410011171.4A patent/CN103770340B/en active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0383532A (en) * | 1989-08-28 | 1991-04-09 | Daiwa Seiko Inc | Fishing rod and its production |
| JP2000106793A (en) * | 1994-09-06 | 2000-04-18 | Daiwa Seiko Inc | Internally threaded fishing rod |
| JP2001314139A (en) * | 2000-05-10 | 2001-11-13 | Shimano Inc | Fishing rod body |
| KR20020013026A (en) * | 2000-08-10 | 2002-02-20 | 조문수 | fishing rod |
| WO2004064509A1 (en) * | 2003-01-24 | 2004-08-05 | Shimano Inc. | Rod body and fishing rod |
| JP2005027587A (en) * | 2003-07-08 | 2005-02-03 | Shimano Inc | Rod body and fishing rod |
| CN2770352Y (en) * | 2005-03-21 | 2006-04-12 | 孙树刚 | Fishing rod |
| CN201044598Y (en) * | 2007-02-05 | 2008-04-09 | 王峰 | Helix intensified fishing rod |
| CN201674891U (en) * | 2010-05-12 | 2010-12-22 | 励金友 | Fishing rod |
| CN201938235U (en) * | 2011-02-09 | 2011-08-24 | 张龙 | Reinforced fishing rod |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103770340A (en) | 2014-05-07 |
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| C06 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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| CP01 | Change in the name or title of a patent holder |
Address after: 242100 Langxi City, Anhui Province Town Development Zone Patentee after: ANHUI GUANTING TECHNOLOGY Co.,Ltd. Address before: 242100 Langxi City, Anhui Province Town Development Zone Patentee before: LANG XI PU RUI TAI FISHING TACKLE Co.,Ltd. |
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| CP03 | Change of name, title or address |
Address after: 242100 Shizi Town Industrial Park, Langxi County, Xuancheng City, Anhui Province Patentee after: Anhui Guanting Carbon Fiber Technology Co.,Ltd. Address before: 242100 Cross Town Development Zone, Langxi County, Xuancheng City, Anhui Province Patentee before: ANHUI GUANTING TECHNOLOGY Co.,Ltd. |
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