CN103772836B - A kind of polystyrene and the composite modified plastics of polycarbonate - Google Patents
A kind of polystyrene and the composite modified plastics of polycarbonate Download PDFInfo
- Publication number
- CN103772836B CN103772836B CN201310729146.5A CN201310729146A CN103772836B CN 103772836 B CN103772836 B CN 103772836B CN 201310729146 A CN201310729146 A CN 201310729146A CN 103772836 B CN103772836 B CN 103772836B
- Authority
- CN
- China
- Prior art keywords
- accounts
- polycarbonate
- polystyrene
- composite modified
- modified plastics
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004793 Polystyrene Substances 0.000 title claims abstract description 30
- 239000004417 polycarbonate Substances 0.000 title claims abstract description 30
- 229920000515 polycarbonate Polymers 0.000 title claims abstract description 30
- 229920002223 polystyrene Polymers 0.000 title claims abstract description 30
- 239000004033 plastic Substances 0.000 title claims abstract description 20
- 229920003023 plastic Polymers 0.000 title claims abstract description 20
- 239000002131 composite material Substances 0.000 title claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 10
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 6
- -1 and tint permanence Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Present invention is disclosed a kind of polystyrene and the composite modified plastics of polycarbonate, comprise polystyrene, polycarbonate, compatilizer, toughner, anti-impact modifier, weighting agent and thermo-stabilizer, described compatilizer is that maleic anhydride connects, described toughner is polybutadiene rubber, described anti-impact modifier is MBS, described weighting agent is diatomite, and described thermo-stabilizer is Dythal.The polystyrene that obtains and the composite modified plastics of polycarbonate are made to have the effects such as heat-resistant stable is good, wear-resistant, good toughness, stable performance.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of polystyrene and the composite modified plastics of polycarbonate.
Background technology
Polystyrene itself is current optimal high-frequency insulation material, and tint permanence, water tolerance, stable chemical performance are good, but property is crisp, the embrittlement of easy generation stress, thermotolerance is not high, and wear resistance is poor, and polycarbonate has outstanding shock strength, higher Young's modulus and dimensional stability, tint permanence is good, thermotolerance is than nylon, and polyoxymethylene is high, and electrical insulating property is better, solidity to corrosion, but wear resistance is not good enough, high temperature facile hydrolysis, poor with other resin-phase dissolubilities, more easily produce stress cracking.
Summary of the invention
The object of the present invention is to provide that a kind of heat-resistant stable is good, wear-resistant, good toughness, the polystyrene of stable performance and the composite modified plastics of polycarbonate.
Technical scheme of the present invention is, a kind of polystyrene and the composite modified plastics of polycarbonate, comprise polystyrene, polycarbonate, compatilizer, toughner, anti-impact modifier, weighting agent and thermo-stabilizer, described compatilizer is that maleic anhydride connects, described toughner is polybutadiene rubber, described anti-impact modifier is MBS, and described weighting agent is diatomite, and described thermo-stabilizer is Dythal.
In a preferred embodiment of the present invention, described polystyrene and each composition by weight percent of the composite modified plastics of polycarbonate are that polystyrene accounts for 42%-53%, polycarbonate accounts for 21%-25%, maleic anhydride connects to prop up and accounts for 1.8%-3.7%, polybutadiene rubber accounts for 3.2%-4.3%, MBS accounts for 2.8%-3.9%, and diatomite accounts for 15.3%-16.4%, and Dythal accounts for 2.9%-4.7%.
In a preferred embodiment of the present invention, described polystyrene and each composition by weight percent of the composite modified plastics of polycarbonate be that polystyrene accounts for 46%, polycarbonate accounts for 23%, maleic anhydride connects to prop up and accounts for 3.2%, polybutadiene rubber accounts for 4.1%, MBS accounts for 3.6%, and diatomite accounts for 16.2%, and Dythal accounts for 3.9%.
Of the present invention is a kind of polystyrene and the composite modified plastics of polycarbonate, makes the polystyrene that obtains and the composite modified plastics of polycarbonate have the effects such as heat-resistant stable is good, wear-resistant, good toughness, stable performance.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Of the present invention is a kind of polystyrene and the composite modified plastics of polycarbonate, comprise polystyrene, polycarbonate, compatilizer, toughner, anti-impact modifier, weighting agent and thermo-stabilizer, described compatilizer is that maleic anhydride connects, described toughner is polybutadiene rubber, described anti-impact modifier is MBS, described weighting agent is diatomite, and described thermo-stabilizer is Dythal.
Further, described polystyrene and each composition by weight percent of the composite modified plastics of polycarbonate are that polystyrene accounts for 42%-53%, polycarbonate accounts for 21%-25%, maleic anhydride connects to prop up and accounts for 1.8%-3.7%, polybutadiene rubber accounts for 3.2%-4.3%, MBS accounts for 2.8%-3.9%, and diatomite accounts for 15.3%-16.4%, and Dythal accounts for 2.9%-4.7%.
Further, described polystyrene and each composition by weight percent of the composite modified plastics of polycarbonate be that polystyrene accounts for 46%, polycarbonate accounts for 23%, maleic anhydride connects to prop up and accounts for 3.2%, polybutadiene rubber accounts for 4.1%, MBS accounts for 3.6%, and diatomite accounts for 16.2%, and Dythal accounts for 3.9%.
Further, described polystyrene and each composition by weight percent of the composite modified plastics of polycarbonate be that polystyrene accounts for 51.1%, polycarbonate accounts for 21.4%, maleic anhydride connects to prop up and accounts for 2.1%, polybutadiene rubber accounts for 3.4%, MBS accounts for 3.2%, and diatomite accounts for 15.5%, and Dythal accounts for 3.3%.
Of the present invention is a kind of polystyrene and the composite modified plastics of polycarbonate, makes the polystyrene that obtains and the composite modified plastics of polycarbonate have the effects such as heat-resistant stable is good, wear-resistant, good toughness, stable performance.
The foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (1)
1. a polystyrene and the composite modified plastics of polycarbonate, it is characterized in that: comprise polystyrene, polycarbonate, compatilizer, toughner, anti-impact modifier, weighting agent and thermo-stabilizer, described compatilizer is maleic anhydride graft, described toughner is polybutadiene rubber, described anti-impact modifier is MBS, described weighting agent is diatomite, described thermo-stabilizer is Dythal, described polystyrene and each composition by weight percent of the composite modified plastics of polycarbonate are that polystyrene accounts for 46%, polycarbonate accounts for 23%, maleic anhydride graft accounts for 3.2%, polybutadiene rubber accounts for 4.1%, MBS accounts for 3.6%, diatomite accounts for 16.2%, Dythal accounts for 3.9%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310729146.5A CN103772836B (en) | 2013-12-26 | 2013-12-26 | A kind of polystyrene and the composite modified plastics of polycarbonate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310729146.5A CN103772836B (en) | 2013-12-26 | 2013-12-26 | A kind of polystyrene and the composite modified plastics of polycarbonate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103772836A CN103772836A (en) | 2014-05-07 |
| CN103772836B true CN103772836B (en) | 2016-03-02 |
Family
ID=50565634
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310729146.5A Expired - Fee Related CN103772836B (en) | 2013-12-26 | 2013-12-26 | A kind of polystyrene and the composite modified plastics of polycarbonate |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103772836B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105367928A (en) * | 2015-11-09 | 2016-03-02 | 无锡市锡山区仁景模具厂 | Road-traffic-stone forming die |
| CN106317834A (en) * | 2016-09-29 | 2017-01-11 | 芜湖豫新世通汽车空调有限公司 | PC/PP air blower shell of automotive air conditioner and preparation method of PC/PP air blower shell |
| CN106398161A (en) * | 2016-09-29 | 2017-02-15 | 芜湖豫新世通汽车空调有限公司 | PC/PE automobile air conditioner forced blast shell and preparation method thereof |
| CN106317832A (en) * | 2016-09-29 | 2017-01-11 | 芜湖豫新世通汽车空调有限公司 | PC/PVC air blower shell of automotive air conditioner and preparation method of PC/PVC air blower shell |
| CN106398160A (en) * | 2016-09-29 | 2017-02-15 | 芜湖豫新世通汽车空调有限公司 | PC/PVAL automobile air conditioner air-blowing casing and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203246A (en) * | 1997-05-14 | 1998-12-30 | 大赛璐化学工业株式会社 | Thermoplastic resin composition |
| CN1288022A (en) * | 2000-09-28 | 2001-03-21 | 广州金发科技发展有限公司 | High transparent and fire-retardant polycarbonate and polycarbonate/polystyrene alloy |
| CN1377911A (en) * | 2001-04-04 | 2002-11-06 | 中国石油化工股份有限公司 | Syndiotactic polyphenlethylene/polycarbonate composite material |
| CN101570614A (en) * | 2008-04-29 | 2009-11-04 | 上海虹权新材料科技有限公司 | Polystyrene raw material for producing carrier band and production technology thereof |
| CN102532846A (en) * | 2010-12-31 | 2012-07-04 | 第一毛织株式会社 | Flameproof thermoplastic resin composition |
-
2013
- 2013-12-26 CN CN201310729146.5A patent/CN103772836B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1203246A (en) * | 1997-05-14 | 1998-12-30 | 大赛璐化学工业株式会社 | Thermoplastic resin composition |
| CN1288022A (en) * | 2000-09-28 | 2001-03-21 | 广州金发科技发展有限公司 | High transparent and fire-retardant polycarbonate and polycarbonate/polystyrene alloy |
| CN1377911A (en) * | 2001-04-04 | 2002-11-06 | 中国石油化工股份有限公司 | Syndiotactic polyphenlethylene/polycarbonate composite material |
| CN101570614A (en) * | 2008-04-29 | 2009-11-04 | 上海虹权新材料科技有限公司 | Polystyrene raw material for producing carrier band and production technology thereof |
| CN102532846A (en) * | 2010-12-31 | 2012-07-04 | 第一毛织株式会社 | Flameproof thermoplastic resin composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103772836A (en) | 2014-05-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103772836B (en) | A kind of polystyrene and the composite modified plastics of polycarbonate | |
| WO2009031407A1 (en) | Nucleator masterbatch for polyolefin resin | |
| ATE513010T1 (en) | FLAME RETARDED IMPACT MODIFIED POLYCARBONATE COMPOSITIONS | |
| JP2008095094A5 (en) | ||
| CN103319825B (en) | A kind of formula of modified Teflon-ethylene copolymer | |
| TW200738818A (en) | Flame retardant polycarbonate compositions having good transparency and low haze, method of manufacture, and articles prepared therefrom | |
| CN103305003A (en) | Formula of modified polyphenylene sulfide plastic | |
| CN103709513A (en) | Polyformaldehyde-polypropylene compound modified plastic | |
| CN104479325A (en) | Plastic material for electronic product casing | |
| CN103304954B (en) | Polyoxymethylene plastic plate | |
| CN105440503A (en) | Flame-retardant PVC waterproof coiled material | |
| CN102911457A (en) | Acrylonitrile butadiene styrene (ABS) blending modification polyvinyl chloride (PVC) spool and preparation method thereof | |
| WO2013028008A3 (en) | Biodegradable resin composition, and draining board core material and draining board produced therefrom | |
| CN103571191A (en) | Formula of modified polyphenylene sulfide resin | |
| CN103304944A (en) | Formula of modified polymethyl methacrylate | |
| CN103740047A (en) | Super-steel polyformaldehyde plastic | |
| CN103709591A (en) | Formula of phenolic resin modified plastic | |
| CN103333474B (en) | A kind of high performance antistatic PC/ABS Alloy And Preparation Method and application | |
| CN107163320A (en) | A kind of nitrile rubber flexible pipe glue and preparation method thereof | |
| CN104312070A (en) | High-performance flame retardant HIPS composite material | |
| CN103304935A (en) | Polyvinyl chloride and polyethylene compound modified plastic | |
| CN103342884A (en) | High-performance antistatic glass fibre reinforced polycarbonate composite material, and preparation method and applications thereof | |
| CN103319880A (en) | Polyphenyl ether and polyvitriol compound modified plastic | |
| CN104327437A (en) | Modified HIPS composite material | |
| CN105647004A (en) | Environmentally-friendly modified car bumper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160202 Address after: 215138 Xiangcheng District, Jiangsu Yangcheng Lake Town (Hunan City) Hunan Road Applicant after: Xiangcheng District, Suzhou City sensible composite material factory Address before: 215000, Shiqiao village, Beiqiao street, Suzhou, Jiangsu, Xiangcheng District Applicant before: Suzhou Hanxin Plastic Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Zheng Boqian Inventor before: Liu Rong |
|
| COR | Change of bibliographic data | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160913 Address after: Jinping District 515000 in Guangdong province Shantou City Shengping Industrial Zone No. second 04B2-2 Patentee after: Shantou Shanyou Plastic Product Co., Ltd. Address before: 215138 Xiangcheng District, Jiangsu Yangcheng Lake Town (Hunan City) Hunan Road Patentee before: Xiangcheng District, Suzhou City sensible composite material factory |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160302 Termination date: 20191226 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |