CN103304944A - Formula of modified polymethyl methacrylate - Google Patents

Formula of modified polymethyl methacrylate Download PDF

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Publication number
CN103304944A
CN103304944A CN2013102904453A CN201310290445A CN103304944A CN 103304944 A CN103304944 A CN 103304944A CN 2013102904453 A CN2013102904453 A CN 2013102904453A CN 201310290445 A CN201310290445 A CN 201310290445A CN 103304944 A CN103304944 A CN 103304944A
Authority
CN
China
Prior art keywords
accounts
polymethyl methacrylate
prescription
modified polymethyl
acid formicester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN2013102904453A
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Chinese (zh)
Inventor
张根庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHU HUIFENG PLASTIC PRODUCT Co Ltd
Original Assignee
CHANGSHU HUIFENG PLASTIC PRODUCT Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHANGSHU HUIFENG PLASTIC PRODUCT Co Ltd filed Critical CHANGSHU HUIFENG PLASTIC PRODUCT Co Ltd
Priority to CN2013102904453A priority Critical patent/CN103304944A/en
Publication of CN103304944A publication Critical patent/CN103304944A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a formula of modified polymethyl methacrylate. The formula includes polymethyl methacrylate and additives, wherein the additive include a flexibilizer, an anti-impact modifier, a filling agent, a plasticizer, and a nucleating agent, the flexibilizer is carboxylated nitrile rubber, the anti-impact modifier is polymethyl methacrylate-butadiene-styrene, the filling agent is kaolin, the plasticizer is di-n-octyl phthalate, and the nucleating agent is titanium oxide. The prepared modified polymethyl methacrylate has the effects of being good in mechanical property, large in mechanical strength, good in flexibility and the like.

Description

A kind of prescription of modified polymethyl acid formicester
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of modified polymethyl acid formicester.
Background technology
It is hard that synthetic glass (polymethylmethacrylate) has quality, can heat moulding.Adiabatic insulation checks without advantages such as impacts x-ray, MRI, at home and abroad once once is used widely.Its shortcoming is poor mechanical property, mainly is that fragility is large, and shock resistance is poor, and when being subject to for the second time unexpected strike, synthetic glass is easily broken.
Summary of the invention
The object of the present invention is to provide that a kind of mechanical property is good, physical strength is large, the prescription of the modified polymethyl acid formicester of good toughness.
Technical scheme of the present invention is, a kind of prescription of modified polymethyl acid formicester, comprise polymethyl methacrylate and additive, described additive comprises toughner, anti-impact modifier, weighting agent, softening agent and Nucleating Agent, described toughner is carboxy nitrile rubber, and described anti-impact modifier is MBS, and described weighting agent is kaolin, described softening agent is dinoctyl phthalate, and described Nucleating Agent is titanium oxide.
In a preferred embodiment of the present invention, each composition weight percent of prescription of described modified polymethyl acid formicester is that polymethyl methacrylate accounts for 71.3%-77.7%, carboxy nitrile rubber accounts for 3.5%-4.4%, MBS accounts for 5.6%-6.7%, kaolin accounts for 8.7%-10.8%, dinoctyl phthalate accounts for 3.1%-4.2%, and titanium oxide accounts for 1.4%-2.6%.
In a preferred embodiment of the present invention, each composition weight percent of prescription of described modified polymethyl acid formicester is that polymethyl methacrylate accounts for 73.6%, carboxy nitrile rubber accounts for 3.8%, MBS accounts for 6.4%, kaolin accounts for 10.5%, dinoctyl phthalate accounts for 3.9%, and titanium oxide accounts for 1.8%.
Of the present invention is a kind of prescription of modified polymethyl acid formicester, makes the modified polymethyl acid formicester that makes have the effects such as mechanical property is good, physical strength large, good toughness.
Embodiment
The below is described in detail preferred embodiment of the present invention, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that protection scope of the present invention is made more explicit defining.
Of the present invention is a kind of prescription of modified polymethyl acid formicester, comprise polymethyl methacrylate and additive, described additive comprises toughner, anti-impact modifier, weighting agent, softening agent and Nucleating Agent, described toughner is carboxy nitrile rubber, described anti-impact modifier is MBS, described weighting agent is kaolin, and described softening agent is dinoctyl phthalate, and described Nucleating Agent is titanium oxide.
Further, each composition weight percent of prescription of described modified polymethyl acid formicester is that polymethyl methacrylate accounts for 71.3%-77.7%, carboxy nitrile rubber accounts for 3.5%-4.4%, MBS accounts for 5.6%-6.7%, kaolin accounts for 8.7%-10.8%, dinoctyl phthalate accounts for 3.1%-4.2%, and titanium oxide accounts for 1.4%-2.6%.
Further, each composition weight percent of prescription of described modified polymethyl acid formicester is that polymethyl methacrylate accounts for 73.6%, carboxy nitrile rubber accounts for 3.8%, MBS accounts for 6.4%, kaolin accounts for 10.5%, dinoctyl phthalate accounts for 3.9%, and titanium oxide accounts for 1.8%.
Further, each composition weight percent of prescription of described modified polymethyl acid formicester is that polymethyl methacrylate accounts for 75.2%, carboxy nitrile rubber accounts for 4.2%, MBS accounts for 5.8%, kaolin accounts for 9.1%, dinoctyl phthalate accounts for 3.3%, and titanium oxide accounts for 2.4%.
Of the present invention is a kind of prescription of modified polymethyl acid formicester, makes the modified polymethyl acid formicester that makes have the effects such as mechanical property is good, physical strength large, good toughness.
The above only is the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (3)

1. the prescription of modified polymethyl acid formicester, it is characterized in that: comprise polymethyl methacrylate and additive, described additive comprises toughner, anti-impact modifier, weighting agent, softening agent and Nucleating Agent, described toughner is carboxy nitrile rubber, described anti-impact modifier is MBS, described weighting agent is kaolin, and described softening agent is dinoctyl phthalate, and described Nucleating Agent is titanium oxide.
2. the prescription of modified polymethyl according to claim 1 acid formicester, it is characterized in that: each composition weight percent of prescription of described modified polymethyl acid formicester is that polymethyl methacrylate accounts for 71.3%-77.7%, carboxy nitrile rubber accounts for 3.5%-4.4%, MBS accounts for 5.6%-6.7%, kaolin accounts for 8.7%-10.8%, dinoctyl phthalate accounts for 3.1%-4.2%, and titanium oxide accounts for 1.4%-2.6%.
3. the prescription of modified polymethyl according to claim 2 acid formicester, it is characterized in that: each composition weight percent of prescription of described modified polymethyl acid formicester is that polymethyl methacrylate accounts for 73.6%, carboxy nitrile rubber accounts for 3.8%, MBS accounts for 6.4%, kaolin accounts for 10.5%, dinoctyl phthalate accounts for 3.9%, and titanium oxide accounts for 1.8%.
CN2013102904453A 2013-07-11 2013-07-11 Formula of modified polymethyl methacrylate Pending CN103304944A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2013102904453A CN103304944A (en) 2013-07-11 2013-07-11 Formula of modified polymethyl methacrylate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2013102904453A CN103304944A (en) 2013-07-11 2013-07-11 Formula of modified polymethyl methacrylate

Publications (1)

Publication Number Publication Date
CN103304944A true CN103304944A (en) 2013-09-18

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Family Applications (1)

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CN2013102904453A Pending CN103304944A (en) 2013-07-11 2013-07-11 Formula of modified polymethyl methacrylate

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CN (1) CN103304944A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104962025A (en) * 2015-07-28 2015-10-07 张家港市德力特新材料有限公司 Impact-resistance-modified organic glass
CN104987639A (en) * 2015-07-28 2015-10-21 张家港市德力特新材料有限公司 High-performance quartz glass
CN105907015A (en) * 2016-07-06 2016-08-31 南通鸿图橡塑有限公司 Elevator light panel plastic
CN107787342A (en) * 2015-04-27 2018-03-09 密执安州立大学董事会 Durability dredges ice surface

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004529992A (en) * 2000-10-31 2004-09-30 レーム ゲゼルシャフト ミツト ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフト PMMA moldings with improved low temperature impact resistance
CN101381502A (en) * 2008-10-16 2009-03-11 郑国书 Resin composition for laser making and preparation method thereof
CN101870794A (en) * 2010-07-09 2010-10-27 深圳市科聚新材料有限公司 Transparent and toughened polymethyl methacrylate (PMMA) material and preparation method thereof
CN102061056A (en) * 2011-01-13 2011-05-18 金发科技股份有限公司 Antistatic ABS (acrylonitrile-butadiene-styrene)/PMMA (polymethyl methacrylate) alloy and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2004529992A (en) * 2000-10-31 2004-09-30 レーム ゲゼルシャフト ミツト ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフト PMMA moldings with improved low temperature impact resistance
CN101381502A (en) * 2008-10-16 2009-03-11 郑国书 Resin composition for laser making and preparation method thereof
CN101870794A (en) * 2010-07-09 2010-10-27 深圳市科聚新材料有限公司 Transparent and toughened polymethyl methacrylate (PMMA) material and preparation method thereof
CN102061056A (en) * 2011-01-13 2011-05-18 金发科技股份有限公司 Antistatic ABS (acrylonitrile-butadiene-styrene)/PMMA (polymethyl methacrylate) alloy and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107787342A (en) * 2015-04-27 2018-03-09 密执安州立大学董事会 Durability dredges ice surface
CN104962025A (en) * 2015-07-28 2015-10-07 张家港市德力特新材料有限公司 Impact-resistance-modified organic glass
CN104987639A (en) * 2015-07-28 2015-10-21 张家港市德力特新材料有限公司 High-performance quartz glass
CN105907015A (en) * 2016-07-06 2016-08-31 南通鸿图橡塑有限公司 Elevator light panel plastic

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Application publication date: 20130918