CN103571191A - Formula of modified polyphenylene sulfide resin - Google Patents
Formula of modified polyphenylene sulfide resin Download PDFInfo
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- CN103571191A CN103571191A CN201310549075.0A CN201310549075A CN103571191A CN 103571191 A CN103571191 A CN 103571191A CN 201310549075 A CN201310549075 A CN 201310549075A CN 103571191 A CN103571191 A CN 103571191A
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- polyphenylene sulfide
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- sulfide resin
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Abstract
The invention discloses a formula of modified polyphenylene sulfide resin. The formula comprises polyphenylene sulfide resin and additives, wherein the additives include a filling agent, an impact modifier, a chemical resistance agent, a toughening agent and a cross-linking agent; and the formula comprises the following components in parts by weight: 600 parts of polyphenylene sulfide resin, 50 to 80 parts of filling agent, 60 to 120 parts of impact modifier, 20 to 40 parts of chemical resistance agent, 40 to 70 parts of toughening agent, and 15 to 30 parts of cross-linking agent. According to the formula, the impact modifier, the filling agent and the toughening agent are added to improve the mechanical strength, toughness, impact strength and other performances of polyphenylene sulfide resin, and thus the polyphenylene sulfide resin has outstanding comprehensive physical performances; due to addition of the chemical resistance agent, the corrosion resistance of the polyphenylene sulfide resin is improved; and the cross-linking agent is added to remain the performances of the polyphenylene sulfide resin and the additives, and thus the polyphenylene sulfide resin has all performances of the additives.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of formula of modified polyphenylene sulfide resin.
Background technology
Plastics are synthetic macromolecular compound, are to utilize raw material monomer with the material synthesizing or condensation reaction is polymerized, and additives such as synthetic resins and filler, softening agent, stablizer, lubricant, colorants, consist of.Most of plastics have light weight, chemical stabilization, can not corrosion, the advantage such as good, the good insulating of shock-resistance, therefore, plastics are widely used in the fields such as stationery goods, food and drink articles for use, package packing supplies.
Polyphenylene sulfide is a kind of novel high-performance thermoplastic resin, at electronics, automobile, machinery and chemical field, all has application.But polyphenylene sulfide fragility is large, poor toughness, and impact strength is low, and resistance to chemical corrosion is low, in the market development, there is very large defect, can not be used widely.
Summary of the invention
The object of the present invention is to provide that a kind of physical strength is high, good toughness, impact strength are high, the formula of corrosion resistant modified polyphenylene sulfide resin.
Technical scheme of the present invention is, a kind of formula of modified polyphenylene sulfide resin, comprise polyphenylene sulfide and additive, described additive comprises weighting agent, anti-impact modifier, chemically-resistant agent, toughner and linking agent, and the parts by weight of described each composition are: 600 parts described of polyphenylene sulfides, weighting agent 50-80 part, anti-impact modifier 60-120 part, chemically-resistant agent 20-40 part, toughner 40-70 part and linking agent 15-30 part.
In a preferred embodiment of the present invention, described weighting agent is glass powder, carbon fiber and talcous one or more mixture.
In a preferred embodiment of the present invention, described anti-impact modifier is chlorinatedpolyethylene.
In a preferred embodiment of the present invention, described chemically-resistant agent is toughened zirconium oxide.
In a preferred embodiment of the present invention, described toughner is Vinyl Acetate Copolymer.
In a preferred embodiment of the present invention, described linking agent is one or more mixtures of hydrogen peroxide Diisopropylamine, 2-phenylimidazole and Triethylenetetramine (TETA).
Of the present invention is a kind of formula of modified polyphenylene sulfide resin, by adding anti-impact modifier, weighting agent and toughner, increase the performances such as physical strength, toughness, impact strength of polyphenylene sulfide, make polyphenylene sulfide there is good physical synthesis performance, add the corrosion resistance that chemically-resistant agent can improve polyphenylene sulfide, linking agent can keep the performance of polyphenylene sulfide and additive constant, and the polyphenylene sulfide making has the properties of additive.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Of the present invention is a kind of formula of modified polyphenylene sulfide resin, comprise polyphenylene sulfide and additive, described additive comprises weighting agent, anti-impact modifier, chemically-resistant agent, toughner and linking agent, and the parts by weight of described each composition are: 600 parts described of polyphenylene sulfides, weighting agent 50-80 part, anti-impact modifier 60-120 part, chemically-resistant agent 20-40 part, toughner 40-70 part and linking agent 15-30 part.
Further, described weighting agent is glass powder, carbon fiber and talcous one or more mixture.
Further, described anti-impact modifier is chlorinatedpolyethylene.
Further, described chemically-resistant agent is toughened zirconium oxide.
Further, described toughner is Vinyl Acetate Copolymer.
Further, described linking agent is one or more mixtures of hydrogen peroxide Diisopropylamine, 2-phenylimidazole and Triethylenetetramine (TETA).
Embodiment 1: the parts by weight of each composition of formula of described modified polyphenylene sulfide resin are: 600 parts of polyphenylene sulfides; 75 parts of weighting agents; 80 parts of anti-impact modifiers; 30 parts of chemically-resistant agent; 60 parts of toughner; 25 parts of linking agents.
Of the present invention is a kind of formula of modified polyphenylene sulfide resin, by adding anti-impact modifier, weighting agent and toughner, increase the performances such as physical strength, toughness, impact strength of polyphenylene sulfide, make polyphenylene sulfide there is good physical synthesis performance, add the corrosion resistance that chemically-resistant agent can improve polyphenylene sulfide, linking agent can keep the performance of polyphenylene sulfide and additive constant, and the polyphenylene sulfide making has the properties of additive.
The foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; the variation that can expect without creative work or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (6)
1. the formula of a modified polyphenylene sulfide resin, comprise polyphenylene sulfide and additive, it is characterized in that: described additive comprises weighting agent, anti-impact modifier, chemically-resistant agent, toughner and linking agent, and the parts by weight of described each composition are: 600 parts described of polyphenylene sulfides, weighting agent 50-80 part, anti-impact modifier 60-120 part, chemically-resistant agent 20-40 part, toughner 40-70 part and linking agent 15-30 part.
2. the formula of modified polyphenylene sulfide resin according to claim 1, is characterized in that: described weighting agent is glass powder, carbon fiber and talcous one or more mixture.
3. the formula of modified polyphenylene sulfide resin according to claim 1, is characterized in that: described anti-impact modifier is chlorinatedpolyethylene.
4. the formula of modified polyphenylene sulfide resin according to claim 1, is characterized in that: described chemically-resistant agent is toughened zirconium oxide.
5. the formula of modified polyphenylene sulfide resin according to claim 1, is characterized in that: described toughner is Vinyl Acetate Copolymer.
6. the formula of modified polyphenylene sulfide resin according to claim 1, is characterized in that: described linking agent is one or more mixtures of hydrogen peroxide Diisopropylamine, 2-phenylimidazole and Triethylenetetramine (TETA).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310549075.0A CN103571191A (en) | 2013-11-08 | 2013-11-08 | Formula of modified polyphenylene sulfide resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310549075.0A CN103571191A (en) | 2013-11-08 | 2013-11-08 | Formula of modified polyphenylene sulfide resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103571191A true CN103571191A (en) | 2014-02-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310549075.0A Pending CN103571191A (en) | 2013-11-08 | 2013-11-08 | Formula of modified polyphenylene sulfide resin |
Country Status (1)
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| CN (1) | CN103571191A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104045828A (en) * | 2014-07-10 | 2014-09-17 | 苏州新区华士达工程塑胶有限公司 | Polyphenylene sulfide production method |
| CN104946125A (en) * | 2015-06-01 | 2015-09-30 | 芜湖县双宝建材有限公司 | Impact-resistance antistatic coating |
| CN112552684A (en) * | 2020-11-16 | 2021-03-26 | 中广核俊尔(浙江)新材料有限公司 | Low-linear expansion coefficient polyphenylene sulfide composite material special for micro-arc oxidation and preparation and application thereof |
| CN112852156A (en) * | 2019-11-12 | 2021-05-28 | 四川威琦尔智能科技有限公司 | Formula and preparation method of missile box shell material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1227234A (en) * | 1998-12-24 | 1999-09-01 | 中国科学院兰州化学物理研究所 | Method for preparing composite polymer material containing zirconium dioxide nanometer powder filling |
| CN102660210A (en) * | 2012-03-30 | 2012-09-12 | 浙江华正新材料股份有限公司 | Halogen-free high heat-resistant and heat-conducting resin film and manufacturing method thereof |
| CN102702746A (en) * | 2012-01-19 | 2012-10-03 | 五行材料科技（江苏）有限公司 | Dynamic crosslinking polyphenylene sulfide composite material and preparation method thereof |
| CN103305003A (en) * | 2013-07-11 | 2013-09-18 | 常熟市慧丰塑料制品有限公司 | Formula of modified polyphenylene sulfide plastic |
-
2013
- 2013-11-08 CN CN201310549075.0A patent/CN103571191A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1227234A (en) * | 1998-12-24 | 1999-09-01 | 中国科学院兰州化学物理研究所 | Method for preparing composite polymer material containing zirconium dioxide nanometer powder filling |
| CN102702746A (en) * | 2012-01-19 | 2012-10-03 | 五行材料科技（江苏）有限公司 | Dynamic crosslinking polyphenylene sulfide composite material and preparation method thereof |
| CN102660210A (en) * | 2012-03-30 | 2012-09-12 | 浙江华正新材料股份有限公司 | Halogen-free high heat-resistant and heat-conducting resin film and manufacturing method thereof |
| CN103305003A (en) * | 2013-07-11 | 2013-09-18 | 常熟市慧丰塑料制品有限公司 | Formula of modified polyphenylene sulfide plastic |
Non-Patent Citations (1)
| Title |
|---|
| 俞志明: "《中国化工商品大全（下册）》", 30 June 1989, article "抗冲击剂和加工改性剂", pages: 1058 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104045828A (en) * | 2014-07-10 | 2014-09-17 | 苏州新区华士达工程塑胶有限公司 | Polyphenylene sulfide production method |
| CN104946125A (en) * | 2015-06-01 | 2015-09-30 | 芜湖县双宝建材有限公司 | Impact-resistance antistatic coating |
| CN112852156A (en) * | 2019-11-12 | 2021-05-28 | 四川威琦尔智能科技有限公司 | Formula and preparation method of missile box shell material |
| CN112552684A (en) * | 2020-11-16 | 2021-03-26 | 中广核俊尔(浙江)新材料有限公司 | Low-linear expansion coefficient polyphenylene sulfide composite material special for micro-arc oxidation and preparation and application thereof |
| CN112552684B (en) * | 2020-11-16 | 2023-04-25 | 中广核俊尔(浙江)新材料有限公司 | Special low-linear expansion coefficient polyphenylene sulfide composite material for micro-arc oxidation and preparation and application thereof |
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Application publication date: 20140212 |