CN103589109B - Formula of reinforced melaminoformaldehyde resin - Google Patents
Formula of reinforced melaminoformaldehyde resin Download PDFInfo
- Publication number
- CN103589109B CN103589109B CN201310549074.6A CN201310549074A CN103589109B CN 103589109 B CN103589109 B CN 103589109B CN 201310549074 A CN201310549074 A CN 201310549074A CN 103589109 B CN103589109 B CN 103589109B
- Authority
- CN
- China
- Prior art keywords
- parts
- terpolycyantoamino
- formaldehyde resin
- agent
- linking agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011347 resin Substances 0.000 title claims abstract description 34
- 229920005989 resin Polymers 0.000 title claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 239000003063 flame retardant Substances 0.000 claims abstract description 18
- 239000000654 additive Substances 0.000 claims abstract description 12
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Substances O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 28
- 239000004609 Impact Modifier Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 8
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 3
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical group CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 claims description 3
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical group CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims description 3
- 239000000347 magnesium hydroxide Substances 0.000 claims description 3
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 claims 1
- 239000003431 cross linking reagent Substances 0.000 abstract 3
- 239000003607 modifier Substances 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 1
- 230000010354 integration Effects 0.000 abstract 1
- 238000005728 strengthening Methods 0.000 description 6
- 239000004033 plastic Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 2
- 238000005267 amalgamation Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- -1 stablizer Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a formula of reinforced melaminoformaldehyde resin. The formula comprises the melaminoformaldehyde resin and additives which comprise a wear-resisting agent, a fire retardant, a high-temperature resisting agent, a shock-resisting modifier and a cross-linking agent. The formula comprises the following detailed ingredients by weight: 500 parts of melaminoformaldehyde resin, 40-50 parts of wear-resisting agent, 60-80 parts of fire retardant, 15-30 parts of high-temperature resisting agent, 50-75 parts of shock-resisting modifier, and 5-20 parts of cross-linking agent. By adding the additives to improve the performances of the melaminoformaldehyde resin including abrasive resistance, fire resistance, heat resistance, mechanical strength, hardness and so on, the product can resist against tearing and creepage. Furthermore, the cross-linking agent can improve integration between the melaminoformaldehyde resin and the additives and keep the original performances stable.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of formula strengthening terpolycyantoamino-formaldehyde resin.
Background technology
Plastics are the macromolecular compound of synthesis, are the materials utilizing raw material monomer to be polymerized with synthesis or condensation reaction, are made up of additives such as synthetic resins and filler, softening agent, stablizer, lubricant, colorants.Most of plastics have light weight, chemical stabilization, can not the advantage such as good, the good insulating of corrosion, shock-resistance, therefore, plastics are widely used in the fields such as stationery goods, food service items, package packing supplies.
Terpolycyantoamino-formaldehyde resin is widely used in the products such as various plastics, rubber, pottery, refractory materials, therefore, need excellent physical strength, hardness, the performance such as fire-retardant, nowadays terpolycyantoamino-formaldehyde resin physical strength used, the performance such as fire-retardant, high temperature resistant are all general, often cause because of the strength of bearing is excessive or temperature is too high damaging after manufacturing product, the requirement of use cannot be met.
Summary of the invention
The object of the present invention is to provide that a kind of physical strength is high, high temperature resistant, wear-resistant, the formula of the enhancing terpolycyantoamino-formaldehyde resin of good product performance.
Technical scheme of the present invention is, a kind of formula strengthening terpolycyantoamino-formaldehyde resin, comprise terpolycyantoamino-formaldehyde resin and additive, described additive comprises anti-wear agent, fire retardant, high temperature resistant dose, anti-impact modifier and linking agent, and the parts by weight of described each composition are: described terpolycyantoamino-formaldehyde resin 500 parts, anti-wear agent 40-50 part, fire retardant 60-80 part, high temperature resistant dose of 15-30 part, anti-impact modifier 50-75 part and linking agent 5-20 part.
In a preferred embodiment of the present invention, described anti-wear agent is ceramic composite.
In a preferred embodiment of the present invention, described fire retardant is one or more mixture of Tritolyl Phosphate, antimonous oxide and magnesium hydroxide.
In a preferred embodiment of the present invention, described high temperature resistant dose is carbofrax material.
In a preferred embodiment of the present invention, described anti-impact modifier is methacrylic ester-divinyl-styrol copolymer.
In a preferred embodiment of the present invention, described linking agent is one or more mixture of 2-ethyl-4 Methylimidazole, Triethylenetetramine (TETA) and dicumyl peroxide.
Of the present invention is a kind of formula strengthening terpolycyantoamino-formaldehyde resin, the wear resistance of terpolycyantoamino-formaldehyde resin is increased by adding anti-wear agent, the product that terpolycyantoamino-formaldehyde resin is made is not easy wearing and tearing, fire retardant can make terpolycyantoamino-formaldehyde resin have higher flame retardant properties, increase the security of product, the high temperature resistant dose of resistance toheat that can improve product, anti-impact modifier can increase the physical strength of terpolycyantoamino-formaldehyde resin, the performances such as hardness, make product anti tear, anti-creep, linking agent can improve the amalgamation of terpolycyantoamino-formaldehyde resin and additive, and keep original performance not change.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Of the present invention is a kind of formula strengthening terpolycyantoamino-formaldehyde resin, comprise terpolycyantoamino-formaldehyde resin and additive, described additive comprises anti-wear agent, fire retardant, high temperature resistant dose, anti-impact modifier and linking agent, and the parts by weight of described each composition are: described terpolycyantoamino-formaldehyde resin 500 parts, anti-wear agent 40-50 part, fire retardant 60-80 part, high temperature resistant dose of 15-30 part, anti-impact modifier 50-75 part and linking agent 5-20 part.
Further, described anti-wear agent is ceramic composite.
Further, described fire retardant is one or more mixture of Tritolyl Phosphate, antimonous oxide and magnesium hydroxide.
Further, described high temperature resistant dose is carbofrax material.
Further, described anti-impact modifier is methacrylic ester-divinyl-styrol copolymer.
Further, described linking agent is one or more mixture of 2-ethyl-4 Methylimidazole, Triethylenetetramine (TETA) and dicumyl peroxide.
Embodiment 1: the parts by weight of each composition of formula of described enhancing terpolycyantoamino-formaldehyde resin are: terpolycyantoamino-formaldehyde resin 500 parts; Anti-wear agent 45 parts; Fire retardant 65 parts; High temperature resistant dose 20 parts; Anti-impact modifier 55 parts; Linking agent 15 parts.
Of the present invention is a kind of formula strengthening terpolycyantoamino-formaldehyde resin, the wear resistance of terpolycyantoamino-formaldehyde resin is increased by adding anti-wear agent, the product that terpolycyantoamino-formaldehyde resin is made is not easy wearing and tearing, fire retardant can make terpolycyantoamino-formaldehyde resin have higher flame retardant properties, increase the security of product, the high temperature resistant dose of resistance toheat that can improve product, anti-impact modifier can increase the physical strength of terpolycyantoamino-formaldehyde resin, the performances such as hardness, make product anti tear, anti-creep, linking agent can improve the amalgamation of terpolycyantoamino-formaldehyde resin and additive, and keep original performance not change.
The foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (1)
1. one kind strengthens terpolycyantoamino-formaldehyde resin, be made up of terpolycyantoamino-formaldehyde resin and additive, it is characterized in that: described additive is by anti-wear agent, fire retardant, high temperature resistant dose, anti-impact modifier and linking agent composition, described anti-wear agent is ceramic composite, described fire retardant is Tritolyl Phosphate, one or more mixture of antimonous oxide and magnesium hydroxide, described high temperature resistant dose is carbofrax material, described anti-impact modifier is methacrylate butadi ene styrene copolymer, described linking agent is 2-ethyl-4-methylimidazole, one or more mixture of Triethylenetetramine (TETA) and dicumyl peroxide, the parts by weight of described each composition are: described terpolycyantoamino-formaldehyde resin 500 parts, anti-wear agent 40-50 part, fire retardant 60-80 part, high temperature resistant dose of 15-30 part, anti-impact modifier 50-75 part and linking agent 5-20 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310549074.6A CN103589109B (en) | 2013-11-08 | 2013-11-08 | Formula of reinforced melaminoformaldehyde resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310549074.6A CN103589109B (en) | 2013-11-08 | 2013-11-08 | Formula of reinforced melaminoformaldehyde resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103589109A CN103589109A (en) | 2014-02-19 |
| CN103589109B true CN103589109B (en) | 2015-05-06 |
Family
ID=50079444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310549074.6A Expired - Fee Related CN103589109B (en) | 2013-11-08 | 2013-11-08 | Formula of reinforced melaminoformaldehyde resin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103589109B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104496373A (en) * | 2014-11-27 | 2015-04-08 | 太仓顺如成建筑材料有限公司 | Sound-insulation novel building material |
| CN106280240A (en) * | 2016-08-16 | 2017-01-04 | 苏州市云林电子有限公司 | A kind of enhancing modified melamine resin rubber |
| CN106800736A (en) * | 2016-12-16 | 2017-06-06 | 芜湖天鸿汽车零部件有限公司 | A kind of automobile chassis thermal insulation board and preparation method thereof |
| CN109385041A (en) * | 2017-08-11 | 2019-02-26 | 广州原野实业有限公司 | Wear-resisting type melamine resin powder |
| CN107759972A (en) * | 2017-12-07 | 2018-03-06 | 郑州峰泰纳米材料有限公司 | A kind of high heat-resisting graphene oxide melamine resin and preparation method thereof |
| CN107892790A (en) * | 2017-12-07 | 2018-04-10 | 郑州峰泰纳米材料有限公司 | A kind of fire-proof heat-insulating melamine resin and preparation method thereof |
| CN107857971A (en) * | 2017-12-07 | 2018-03-30 | 郑州峰泰纳米材料有限公司 | A kind of flame retardant type graphene oxide melamine resin and preparation method thereof |
| CN107880485A (en) * | 2017-12-07 | 2018-04-06 | 郑州峰泰纳米材料有限公司 | A kind of melamine resin and preparation method thereof |
| CN108084649A (en) * | 2017-12-29 | 2018-05-29 | 溧阳市乔森塑料有限公司 | Modified melamine-formaldehyde moulding compound and its preparation method and application |
| CN110564135A (en) * | 2018-06-05 | 2019-12-13 | 苏州新益特塑胶科技有限公司 | Melamine formaldehyde plastic |
| CN110372992A (en) * | 2019-07-23 | 2019-10-25 | 安徽升隆电气有限公司 | A kind of detector for fire alarm system potent flameproof case material and preparation method thereof |
| CN110480902B (en) * | 2019-08-09 | 2021-11-23 | 东莞市瑞欣美耐皿制品有限公司 | Melamine utensil and preparation method thereof |
| CN110451902A (en) * | 2019-09-10 | 2019-11-15 | 高永明 | A kind of phase-change accumulation energy gravity flowing levelling mortar manufacturing method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101074310A (en) * | 2007-05-29 | 2007-11-21 | 严萍 | Production of domestic resin appliances with inorganic filler |
| WO2008123326A1 (en) * | 2007-03-23 | 2008-10-16 | Teijin Limited | Thermosetting resin composite composition, resin molded body, and method for producing the composition |
| CN103210026A (en) * | 2010-11-05 | 2013-07-17 | 巴斯夫欧洲公司 | Melamine resin foam material having an inorganic filler |
-
2013
- 2013-11-08 CN CN201310549074.6A patent/CN103589109B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008123326A1 (en) * | 2007-03-23 | 2008-10-16 | Teijin Limited | Thermosetting resin composite composition, resin molded body, and method for producing the composition |
| CN101074310A (en) * | 2007-05-29 | 2007-11-21 | 严萍 | Production of domestic resin appliances with inorganic filler |
| CN103210026A (en) * | 2010-11-05 | 2013-07-17 | 巴斯夫欧洲公司 | Melamine resin foam material having an inorganic filler |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103589109A (en) | 2014-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103589109B (en) | Formula of reinforced melaminoformaldehyde resin | |
| CN102850702A (en) | Modified polytetrafluoroethylene formula | |
| CN102020825A (en) | Flame-retardant permanent antistatic ABS material and preparation method thereof | |
| CN104403276A (en) | High-temperature-resistant and abrasion-resistant macromolecular material | |
| CN103709597B (en) | A kind of formula of modified urea formaldehyde resin | |
| CN103571191A (en) | Formula of modified polyphenylene sulfide resin | |
| CN103739935A (en) | Polypropylene plastic packing belt | |
| CN103740088A (en) | Formula for modifying polyether-ether-ketone plastics | |
| CN103483665A (en) | Cross-linking micro-foaming slipper plastic | |
| CN104830029A (en) | High-temperature-resistant and abrasion-resistant high-polymer material | |
| CN104017245A (en) | Chlorinated polyethylene rubber composition | |
| CN106084657A (en) | A kind of heat resistant and wear resistant macromolecular material | |
| WO2022110661A1 (en) | High toughness and high gloss gpps/cpe composite material, preparation method therefor, and application thereof | |
| CN104877311A (en) | High-temperature-resistant and wear-resistant high-molecular material | |
| CN104945840A (en) | Chemical resistant phenolic resin | |
| CN104945691A (en) | High-fatigue-resistance flame-retardant rubber material | |
| TW200708526A (en) | The transparent styrene resin composition | |
| CN103788493A (en) | Formula of reinforced polypropylene plastic | |
| CN103497379A (en) | Flame-retardant rubber with high insulating and abrasion-resistant property | |
| CN105623245A (en) | Wear-resistant high-performance modified polyamide | |
| CN103013029B (en) | Flame-retardant glass fiber-reinforced ABS/PA6 alloy material with high CTI value and high GWIT value | |
| CN102850797A (en) | Modified and reinforced polysulfone plastic formula | |
| KR102034636B1 (en) | Eco-blend resin composition comprising fiber glass and manufacturing method of eco-plastic material using the same | |
| CN104962006A (en) | Polyvinyl chloride resin nano environment-friendly cable material and preparation method thereof | |
| CN104910498A (en) | Wear-resistant plastic granule |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SUZHOU KAIFENG ELECTRONICS CO., LTD. Free format text: FORMER OWNER: SUZHOU SHUANGYING PACKAGING MATERIALS CO., LTD. Effective date: 20150413 |
|
| C14 | Grant of patent or utility model | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 215000 SUZHOU, JIANGSU PROVINCE TO: 215132 SUZHOU, JIANGSU PROVINCE |
|
| GR01 | Patent grant | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20150413 Address after: 215132 Xiangcheng District City, Suzhou province Huangqiao Street Lane Village Applicant after: SUZHOU KAIFENG ELECTRONIC & ELECTRICAL APPLIANCE CO., LTD. Address before: Xiangcheng District Huangqiao street party in Suzhou city in Jiangsu province 215000 more bang Wang Applicant before: SUZHOU SHUANGYING PACKAGE MATERIAL CO., LTD. |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20170531 Address after: 056000 Xin Ma Industrial Park, Handan, Hebei, Qiuxian Patentee after: Hebei weilibang Wood Co., Ltd. Address before: 215132 Xiangcheng District City, Suzhou province Huangqiao Street Lane Village Patentee before: SUZHOU KAIFENG ELECTRONIC & ELECTRICAL APPLIANCE CO., LTD. |
|
| CB03 | Change of inventor or designer information |
Inventor after: Nie Xiuwu Inventor before: Xu Yuansen |
|
| CB03 | Change of inventor or designer information | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150506 Termination date: 20171108 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |